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完整後設資料紀錄
DC 欄位 | 值 | 語言 |
---|---|---|
dc.contributor.advisor | 吳乃立(Nae-Lih Wu) | |
dc.contributor.author | Tzu-Yang Huang | en |
dc.contributor.author | 黃子洋 | zh_TW |
dc.date.accessioned | 2021-06-15T16:25:58Z | - |
dc.date.available | 2020-08-17 | |
dc.date.copyright | 2015-08-17 | |
dc.date.issued | 2015 | |
dc.date.submitted | 2015-08-14 | |
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dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/52750 | - |
dc.description.abstract | 將製程副產物回收再利用、使廢料轉變成高價值產品,這種兼具環保及收益的概念在工業上越來越受到重視。多晶矽太陽能發電模組削切成薄片過程中約30% - 50%的矽會以奈米粉體顆粒的形式隨著研磨漿液流失,由於目前世界太陽能矽晶年需求量約為二十萬噸,因此後續伴隨產生的廢料中所含矽粉是非常可觀且大量的。奈米矽為具有高比電容量潛力的鋰離子電池負極材料,然而其實際應用最需要克服的瓶頸在於,充放電過程中因體積變化引起電極材料的粉化,而導致電容量迅速的損失。在此研究中,我們利用切割廢料漿液處理過後回收而得的矽基粉體,以創新的做法形成高機械強度與高導電度的矽鎳複合物微米二次粒子,有效地改善以這種材料作為鋰離子電池負極的循環穩定性能,經由掃描式電子顯微鏡觀察電極板截面變化,發現充放電過程的體積膨脹可被抑制。
我們整合了X光吸收光譜與X光繞射分析,提出了粉體在機械研磨中的固相反應機制:2 NiO + 3 Si → 2 a-NiSi + a-SiO2,並且發現透過調整高能球磨的時間與摻入碳黑,可導致矽在研磨過程中氧化程度的改變,進一步影響其電化學性能。此外,程溫還原(TPR)分析的結果亦顯示部分氧化鎳在球磨過程中被矽粒子還原。4小時研磨與1 wt.%碳黑的摻入,經過700°C還原煆燒而得的矽鎳複合物,是在此研究的各種製程條件中具有最高電化學性能的材料,能在高速充放電(5C)下保有較高的可逆電容量。 最後藉由調整極板漿料的酸性程度並控制鋰離子遷入材料時的截止電位,得到具有良好循環壽命的負極。電化學測試結果顯示其在100圈的完全(深度)充放電下仍能保有85%的維持率;若截止電位控制在40 mV,100圈充放電後,電容量仍無衰退跡象。如此我們成功地將矽晶切割廢料回收再利用並製備出高性能、高價值的鋰離子電池負極材料。 | zh_TW |
dc.description.abstract | Turning the recycled waste into high-value products is of strategic importance for industrial processes. Despite the fact that most of the high-purity Si is wasted during wafer slicing in fabricating photovoltaic (PV) modules, the applications of recycled kerf-loss Si (K-Si) still remain limited and may not meet the cost of purification from slurry containing abrasive silicon carbide (SiC). K-Si was found to be ragged-edge particles in nano-size, while micro-sized SiC single-crystallites featured sharp edge. A simple and facile method was developed to synthesize structurally robust Si-SiC-Ni composite microparticles (SSNs) from processed kerf-loss powder with the addition of metal Ni. Owing to their mechanically robust and conductive nature, the SSN electrodes exhibited suppressed expansion and stable cycling performance as lithium-ion battery (LiB) anodes.
Adjustment in milling time with addition of carbon black (CB) resulted in different amount of amorphous silicon oxide (a-SiO2) formed during high-energy ball-mill. Analysis from X-ray absorption spectroscopy (XAS) combined with X-ray diffraction (XRD) led to the proposed mechanism of solid-phase reaction facilitated by ball-mill: 2 NiO + 3 Si → 2 a-NiSi + a-SiO2. Temperature programmed reduction (TPR) analysis further underlined the fact that part of NiO has been irreversibly reduced by Si particles in the milling step. As a result from process analysis and optimization, composite milled with 1 wt.% CB for 4 hours and calcined at 700°C was found to exhibit the most promising electrochemical behavior, suggesting a reversible capacity up to 769 mAh/g. Cycling stability was further improved by modifying the acidity of electrode-slurry and cut-off voltage for lithiation. Modified SSN anodes retained 85% retention of capacity after 100 cycles of full lithiation/delithiation at 300 mA/g and no capacity decay was observed for electrode cut off at 40 mV for lithiation in the first 100 cycles, which is expected to meet the requirement of practical applications in LiB and suggests an alternative for the usage of Si recovered from kerf loss. | en |
dc.description.provenance | Made available in DSpace on 2021-06-15T16:25:58Z (GMT). No. of bitstreams: 1 ntu-104-R02524008-1.pdf: 3278690 bytes, checksum: 55c9f13d9f0cbecdab334faf184f02f2 (MD5) Previous issue date: 2015 | en |
dc.description.tableofcontents | 致謝 I
摘要 III Abstract IV Table of Contents VI List of Tables IX List of Figures X Chapter 1. Motivation 1 Chapter 2. Literature Review 3 2-1. Features of Rechargeable Li-ion Batteries 3 2-1-1. Basic Concepts of Li-ion Batteries 3 2-1-2. Historical Developments of Li-battery Research 6 2-1-3. Engineering Design of High Capacity Anodes 10 2-2. Introduction to Silicon-Based Anode Materials 12 2-2-1. Anodes Made of Pure Silicon Powder 12 2-2-2. Nanostructured Si Anode Materials 16 Chapter 3. Experimental 21 3-1. Chemicals and Materials 21 3-2. Preparation of Si-SiC-Ni Composite 22 3-3. Material Characterizations and Analyses 23 3-3-1. Microscopy 23 3-3-2. Particle Size Distribution 24 3-3-3. X-ray Diffraction 24 3-3-4. X-ray Absorption Spectroscopy 27 3-3-5. Resistivity of Powder-like Mixture 28 3-4. Electrochemical Characterizations 29 3-4-1. Preparation of Electrodes and Assembly of Cells 29 3-4-2. Galvanostatic test 30 3-4-3. Electrochemical Impedance Spectroscopy 30 Chapter 4. Characterizations of Kerf Loss 31 4-1. Introduction 31 4-2. Material Characterizations 31 4-3. Electrochemical Performance 36 Chapter 5. Process Analysis and Optimization in Synthesizing Si-SiC-Ni Composite 39 5-1. Introduction 39 5-2. Synthesis and Characterizations 40 5-3. Effect of Milling Time and Carbon Additive 47 5-4. Temperature Programmed Reduction 61 5-5. Temperature of Reductive Calcination 64 Chapter 6. Toward Better Cycling Stability of Si-SiC-Ni Composite Anodes 68 6-1. Introduction 68 6-2. Acidity of Electrode-Slurry 68 6-3. Different Cut-off Voltage for Lithiation 70 Chapter 7. Conclusions and Outlook 74 References 76 | |
dc.language.iso | en | |
dc.title | 回收矽晶切割廢料製備鋰離子電池矽-鎳複合負極 | zh_TW |
dc.title | Si-Ni Composite from Recycled Solar-Grade Kerf-Loss Silicon and Its Application in Lithium-ion Batteries | en |
dc.type | Thesis | |
dc.date.schoolyear | 103-2 | |
dc.description.degree | 碩士 | |
dc.contributor.oralexamcommittee | 吳弘俊,方家振 | |
dc.subject.keyword | 鋰離子電池,矽負極,矽鎳合金,太陽能矽晶切割廢料,資源永續, | zh_TW |
dc.subject.keyword | Li-ion batteries,Anodes,Silicon,Nickel,Kerf loss,Recycling, | en |
dc.relation.page | 84 | |
dc.rights.note | 有償授權 | |
dc.date.accepted | 2015-08-14 | |
dc.contributor.author-college | 工學院 | zh_TW |
dc.contributor.author-dept | 化學工程學研究所 | zh_TW |
顯示於系所單位: | 化學工程學系 |
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