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| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 韋文誠(Wen-Cheng J. Wei) | |
| dc.contributor.author | Dan Wang | en |
| dc.contributor.author | 王丹 | zh_TW |
| dc.date.accessioned | 2021-06-15T12:54:15Z | - |
| dc.date.available | 2016-07-26 | |
| dc.date.copyright | 2016-07-26 | |
| dc.date.issued | 2016 | |
| dc.date.submitted | 2016-07-18 | |
| dc.identifier.citation | [1] http://web3.moeaboe.gov.tw/ECW/business/content/ContentLink.aspx?menu_id=378.
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| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/50716 | - |
| dc.description.abstract | 本研究探討了鎳、錳、鈷摻雜之鐵酸鉍鍶（Bi0.7Sr0.3FeO3-δ）鈣鈦礦材料之合成特性，電性與應用於中溫固態燃料電池陰極之電性表現。以EDTA-檸檬酸法合成不同摻雜量的粉末，利用X光繞射法(XRD)確定不同元素摻雜的固溶極限，利用能量色散X射線光谱(EDS)進行定量成分分析，探究合成粉末的均勻性，利用热機械分析量測試樣的熱膨脹係數。以兩點及四點直流電量測，X射线光电子能谱分析（XPS）及熱重分析(TGA)探討材料的導電特性以及氧成份的非當量比。結果顯示鎳的固溶極限為3 at%，而錳的固溶量至少為50 at%，鉍鐵基試樣的熱膨脹係數都約在(13.1±0.38 )x10-6 K-1，接近于氧化鈰且明顯低於鑭鍶鈷鐵（LSCF6428）。電性的結果顯示錳的摻雜明顯提高了總導電性。採用四點式量測离子导电率，其中Bi0.7Sr0.3FeO2.95-0.022 在800 oC的离子导电率为4.21 x10-3 S.cm-1。 以乾壓法製備300 μm陽極,以旋渡法（spin-coating）在陽極製備微米平坦層，電解質層及陰極層組裝為單電池，以交流阻抗（EIS）分析有無平坦層與不同燒結溫度下陰極之界面極化電阻與接觸電阻。其中一組電池含Bi0.7Sr0.3Fe0.5Mn0.5O2.88-0.03 +20 SDC 陰極在800 oC之輸出為119 mW.cm-2. | zh_TW |
| dc.description.abstract | The effects of nickel, cobalt and manganese doping in bismuth-based ferrite perovskite (Bi0.7Sr0.3FeO3-δ) used as cathode of solid oxide fuel cells have been investigated in this study. The cathode powders were synthesized by EDTA-citric acid method. The phase purity of synthesized perovskites were analyzed by X-ray Diffraction (XRD). The solubility limit of Ni was 3 at%, while Mn can substitute for Fe at least 50 at% in BSF. Electrical conductivity by 2-probe and 4-probe DC methods showed that the 50 mol% doping of Mn on B-site improved the electrical conductivity significantly. The oxygen nonstoichiometry was analyzed by X-ray photoelectron spectroscopy (XPS) and thermogravimetric analysis (TGA) to reveal the deficiency of oxygen and ionic conductivity in the ferrites. The ionic conductivity of BSF was 4.21 x10-3 S.cm-1 at 800 oC. Anode disk of 300 μm thick coated with thin layer (μm layer thickness) of electrolyte by spin-coating method. The polarization resistance and contact resistance of the half-cell with an 8YSZ-N flat layer and cathode sintered by different sintering temperatures were analyzed by electrochemical impedance spectra analysis (EIS). Finally, the optimal cathode (Bi0.7Sr0.3Fe0.5Mn0.5O 2.88-0.034+20 SDC) was assembled to a full cell and the maximum power output was 119 mW.cm-2 at 800 oC. | en |
| dc.description.provenance | Made available in DSpace on 2021-06-15T12:54:15Z (GMT). No. of bitstreams: 1 ntu-105-R03527068-1.pdf: 6594241 bytes, checksum: f9ae86b7f003c1c9c5ed4cd229ec072f (MD5) Previous issue date: 2016 | en |
| dc.description.tableofcontents | 摘要 III
Abstract IV Contents V List of Figures VII List of Tables XII Chapter 1 Introduction 1 Chapter 2 Literature Review 4 2.1 Cathode Materials and Cell Design for Solid Oxide Fuel Cells 4 2.1.1 Development of Cathode Materials 4 2.1.2 Performance of SOFCs 6 2.2 Iron and Manganese Based Cathodes 6 2.2.1 Effect of Fe in B-site of Perovskite Structure 6 2.2.2 Effect of Mn in B-site of Perovskite Structure 8 2.3 X-Ray Photoelectron Spectroscopy (XPS) Analysis 8 2.3.1 Introduction of XPS 8 2.3.2 Argon Monomer Sputtering Effect on Iron Oxide 9 Chapter 3 Experimental Procedure 20 3.1 Materials 20 3.2 Fabrication of Cathode Materials 20 3.2.1 EDTA-Citric Acid Method 20 3.2.2 Sol-Gel Method 21 3.3 Single Cell Fabrication 21 3.3.1 Anode Preparation 21 3.3.2 Preparation of Flat Layer 22 3.3.3 Preparation of Electrolyte Film 22 3.3.4 Preparation of Cathode Film 23 3.4 Characterization 23 3.4.1 X-ray Diffraction Analysis 23 3.4.2 Microstructural Analysis 24 3.4.3 Composition Analysis by EDS 24 3.4.4 Density Measurement 24 3.4.5 Electrical Conductivity 24 3.4.6 Ionic Conductivity 25 3.4.7 Thermal Expansion Analysis (TMA) 25 3.4.8 Sedimentation Test 26 3.4.9 Particle Size Measurement 26 3.4.10 X-ray Photoelectron Spectroscopy Analysis (XPS) 27 3.4.11 Thermogravimetric Analysis (TGA) 27 3.4.12 Electrochemical Impedance Spectra Analysis (EIS) 27 3.5 Single Cell Test 28 Chapter 4 Results 34 4.1 Properties of Synthesized Powders 34 4.1.1 Phase Identification 34 4.1.2 Quantitative Analysis of Composition 34 4.1.3 Thermal Expansion Analysis 35 4.1.4 Particle Size and Dispersion Properties 36 4.1.5 Sintering behavior of BSFMn0.5 36 4.2 Conduction Behavior of Cathode Materials 47 4.2.1 Electrical Conductivity 47 4.2.2 Valence State Analysis 48 4.2.3 Thermogravimetric Analysis 50 4.2.4 Ionic Conductivity 51 4.3 Assembly and Properties of Single Cell 62 4.3.1 Preparation of Anode Substrate 62 4.3.2 Flat Layer of Nano-sized 8YSZ Film 63 4.3.3 Preparation of Electrolyte Film 64 4.3.4 Preparation of Cathode Film 65 4.4 Cell Tests 78 4.4.1 I-V Test of BSFMn0.5 Cell and Fuel Utilization 78 4.4.2 Interface Reaction between BSFMn0.5 and 8YSZ 79 4.4.3 Interface Reaction between BSFMn0.5 and 20SDC 80 Chapter 5 Discussion 87 5.1 Conductivity Mechanism 87 5.2 Effect of Solid Loading on Film Thickness 90 5.3 Effect of Spin-coating Cycles on Film Thickness 92 Chapter 6 Conclusions 99 Chapter 7 References 102 | |
| dc.language.iso | en | |
| dc.subject | 陰極 | zh_TW |
| dc.subject | 陰極 | zh_TW |
| dc.subject | 鈣鈦礦 | zh_TW |
| dc.subject | 鉍鐵基 | zh_TW |
| dc.subject | 導電性 | zh_TW |
| dc.subject | 氧的非當量比 | zh_TW |
| dc.subject | 鉍鐵基 | zh_TW |
| dc.subject | 固態燃料電池 | zh_TW |
| dc.subject | 固態燃料電池 | zh_TW |
| dc.subject | 鈣鈦礦 | zh_TW |
| dc.subject | 氧的非當量比 | zh_TW |
| dc.subject | 導電性 | zh_TW |
| dc.subject | bismuth-based ferrite perovskite | en |
| dc.subject | cathode | en |
| dc.subject | conductivity | en |
| dc.subject | oxygen nonstoichiometry | en |
| dc.subject | SOFC | en |
| dc.subject | bismuth-based ferrite perovskite | en |
| dc.subject | cathode | en |
| dc.subject | conductivity | en |
| dc.subject | oxygen nonstoichiometry | en |
| dc.subject | SOFC | en |
| dc.title | 摻雜型鉍鐵基鈣鈦礦材料用於中溫固態燃料電池陰極之研究 | zh_TW |
| dc.title | Doped Bismuth Ferrite-based Perovskite Type Cathode Materials for IT-SOFCs | en |
| dc.type | Thesis | |
| dc.date.schoolyear | 104-2 | |
| dc.description.degree | 碩士 | |
| dc.contributor.oralexamcommittee | 吳玉娟,洪逸明 | |
| dc.subject.keyword | 鉍鐵基,鈣鈦礦,陰極,導電性,氧的非當量比,固態燃料電池, | zh_TW |
| dc.subject.keyword | bismuth-based ferrite perovskite,cathode,conductivity,oxygen nonstoichiometry,SOFC, | en |
| dc.relation.page | 107 | |
| dc.identifier.doi | 10.6342/NTU201601017 | |
| dc.rights.note | 有償授權 | |
| dc.date.accepted | 2016-07-18 | |
| dc.contributor.author-college | 工學院 | zh_TW |
| dc.contributor.author-dept | 材料科學與工程學研究所 | zh_TW |
| 顯示於系所單位： | 材料科學與工程學系 | |
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