二元及三元鈦鎳基形狀記憶合金相變態行為及制振能之研究

Yu-Ning Lee; 李宥寧

請用此 Handle URI 來引用此文件： http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/50651

完整後設資料紀錄

DC 欄位	值	語言
dc.contributor.advisor	吳錫侃
dc.contributor.author	Yu-Ning Lee	en
dc.contributor.author	李宥寧	zh_TW
dc.date.accessioned	2021-06-15T12:50:45Z	-
dc.date.available	2016-08-02
dc.date.copyright	2016-08-02
dc.date.issued	2016
dc.date.submitted	2016-07-21
dc.identifier.citation	[1] L.C. Chang and T.A. Read, Trans. AIME., 189 (1951) p.47. [2] M.W. Burkart and T.A. Read, Trans. AIME, 197 (1953) p.1516. [3] E. Hornbogen and G.Wassermann, Z. Metallkd., 47 (1956) p.427. [4] W.J. Buehler, R.C. Wiley and J.V. Gilfrich, J. Appl. Phys., 34 (1963) p.1475. [5] T. Tadaki and C.M. Wayman, Scripta Metall., 14 (1980) p.911. [6] K. Otsuka and K. Shimizu, International Metals Reviews., 31 (1986) p.93. [7] R.F. Hehemann and G.D. Sandrock, Scripta Metall., 5 (1971) p.801. [8] G.M.Michal and R. Sinclair, Acta Cryst ., B37(1981) p.1803. [9] Y. Kudoh , M. Tokonami , S. Miyazaki and K.Otsuka ,Acta Metall., 33 (1985) p.2049. [10] S. Miyazaki and K. Otsuka , Metall .Trans., 17A(1986) p.53. [11] S. Miyazaki and C.M. Wayman , Acta Metall., 36(1988) p.181. [12] K. M.Nowles and D.A. Smith , Acta Metall., 29 (1981) p.101. [13] O. Marsumoto , S. Miyazaki , K. Otsuka and H. Tamura , Acta Metall., 35 (1987) p.2137. [14] R.J. Wasilews, S.R. Butler, J.E. Hanlon and D. Worden, Metall. Trans., 2 (1971) p.229. [15] K. Otsuka, T. Sawamura, K.Shimizu and C.M. Wayman, Metall. Trans.,2 (1971) p.2583. [16] K. Otsuka, T. Sawamura and K. Shimizu, Phys. Stat. Sol. A, 5 (1971) p.457. [17] G.D. Sandrock, A.J. Perkin, R.F. Hechemann, Metall. Trans., 2 (1971) p.2769. [18] Y. Kudoh, M. Tokonami, S. Miyazaki and K. Otsuka, Acta Metall., 33 (1985) p.2049. [19] M. Nishida, C.M. Wayman and T. Honma, Metall. Mater. Trans. A., 17 (1986) p.1505. [20] T. Homa and M. Matsumoto , Int’l Conf. Ti ’80,1980 ,p.1455. [21] S.K. Wu and C.M. Wayman,Metallography, 20(1987) p.359. [22] S.K. Wu , Ph.D Thesis , University of Illinois at Urbama-Champaign,USA,1986. [23] W. J. Buehler, J. W. Gilfrich and R.C. Wiley, J. Appl. Phys., 34 (1963) p.1475. [24] Z. Nishiyamma , Martensite Transformation , Academic Press ,New York,(1978.) [25] H. Warlimont and L. Delay , Prog , Mater. Sci.18(1974) [26] N. Nakanishi , Prog. Mater. Sci ,24 (1979) p.143. [27] Shape Memory Alloys, H. Funakubo, Gordon and Breach Sci.Publ., New York(1987) [28] P. Thamburaja , H. Pan, and F. S. Chau, Acta Mater., 53 (2005) p.3821. [29] J. A. Shaw and S. Kyriakides, J. Mech. Phys. Solids, 43 (1995) p.1243. [30] T. A. Schroder and C. M. Wayman, Scripta Mater., 11 (1977) p.225. [31] J. Perkins and R. O. Sponholz, Met. Trans., 15A (1984) p.313. [32] L. Delaey and J. Thienel, Shape Memory Effects in Alloys, Plenum Press, New York (1975) p.341. [33] K. Takezawa and S. Sato, Trans. JIM (Supplement) 17 (1976) p.233. [34] M. Nishida and T. Honma, Scripta Mater., 18 (1984) p.1293. [35] H. C. Lin, S. K. Wu, T. S. Chou and H. P. Kao, Acta Mater., 39 (1991) p.2069 [36] H. C. Tong and C. M. Wayman, Acta Mater., 22 (1974) p.887. [37] R. J. Salzbrenner and M. Cohen, Acta Mater., 27 (1979) p.739. [38] D. P. Dunne and C. M. Wayman, Met. Trans., 4 (1973) p.147. [39] C.M. Wayman, Trans. JIM., 17 (1976) p.159. [40] T. Saburi, S. Nenno and C.M. Wayman, ICOMAT-79, 1979, p.619. [41] T. Saburi and S, Nenno, in: Proc. Int. Conf. On Solid to Solid Phase Transformations, ASM, Metals Park, Ohio (1982) p.1455. [42] P. Thamburaja, H. Pan, and F. S. Chau, Acta Mater., 53 (2005) p.3821. [43] J. A. Shaw and S. Kyriakides, J. Mech. Phys. Solids, 43 (1995) p.1243. [44] T. Honma, Proc, Guklin, Symp. of Shape Memory Alloys, 1986, Guilin, China,1986, p.709. [45] T. Honma, ICOMAT, 86 ,1986, p.709. [46] K. Otsuka and K. Shimizu, Metals Forum, 4 (1981) p.142. [47] K. Otsuka, S. Sawamura and K. Shimizu, Phys. Stat. Sol., 5 (1971) p.457. [48] K. Otsuka and T. Kakeshita, MRS Bulletin, 27 (2002) p.91. [49] O. Matsumoto, S. Miyazaki, K. Otsuka and H. Tamura, Acta Mater., p.35 (1987) 2137. [50] K. M. Knowls and K.A. Smith, Acta Mater., 29 (1981) p.101. [51] K. H. Eckelmeyer, Scripta Mater., 10 (1976) p.677. [52] J. E. Hanlon, S. R. Butler, and R. J. Wasilewski, Trans.AIME, 239 (1967) p.1323. [53] T. Tadaki, Y. Nakata and K. Shimizu., Trans. JIM., 28 (1987) p.883. [54] S. Miyazaki, Y. Igo and K. Otsuka, Acta Mater., 34 (1986) p.275. [55] T. Saburi, T. Tatsumi and S. Nenno, J. de Physique, 43 (1982) C4-261. [56] G. Airoldi, G. Bellini and C.D. Franceso, J. Phys. F, 14 (1984) p.1983. [57] H.S. Lin, S.K.Wu, T.S. Chou and H.P. Kuo, Acta Mater., 39 (1991) p.2069. [58] M. Nishida and C.M. Wayman, Metall., 21 (1988) p.275. [59] C. M. Hwang, M. Meichle, M. B. Salamen and C. M. Wayman, Phil. Mag. A, 47 (1983) p.31. [60] D.P. Dautovich and G.R. Purdy, Can. Metal. Quart, 4 (1965) p.129. [61] O. Mercier and K.N. Melten, Acta Mater., 27 (1979) p.1467. [62] H. C. Ling and R Kaplow, Met. Trans., 12A (1981) p.2101. [63] M. Nishita and T. Honma, Scripa Metall. Mater., 19 (1985) p.983. [64] M. Nishita, C. M. Wayman, R. kainuma and T. Honma, Scripta Mater., 20 (1986) p.899. [65] M. Nishita and C. M. Wayman, Metall. Trans., 5 (1987) p.785. [66] 謝超英，哈爾濱工業大學博士論文,(1990). [67] X. Ren, N. Miura, K. Taniwaki K. Otsuka, T Suzuki and K. Tanaka, Mater. Sci. Eng. A 90 (1990) p.273. [68] L. Bataillard and R. Gotthardt, J. Phys., C8 (1995) p.167. [69] J. Khalil-Allafi, X. Ren and G. Eggeler, Acta Mater., 50 (2002) p.793. [70] A. Dlouhy, J. Khalil-Allafi and G. Eggeler, Phil. Mag., 50 (2003) p.339. [71] G. Fan, W. Chen, S. Yang, J. Zhu, X. Ren and K. Otsuka, Acta Mater., p.52 (2004) 4351. [72] J. Michutta, Ch. Somsen, A. Yawny, A. Dlauhy and G. Eggeler, Acta Mater., 54 (2006) p.3525. [73] H.C. Konkersloot and J.H.N. Van Vucht, J. Less. Comm. Met.20, (1970) ,p.83 [74] V.N. Khachin, N.M. Matveea, V.P. Sivokha,”High-Temperature Effects of Shape Memory in TiNi-TiPd Alloys”,DAN SSSR 251, (1981),p.167 [75] P.G. Lindquist, Ph. D Thesis (1988), University of Illinois [76] Y.C. Lo and S.K. Wu, Scripta Metall.,(1991), p.1875a [77] S.H. Chang and S.K. Wu, Mater. Sci. Eng. A, 454 ,(2007), p.379. [78] J.F. Delorme, R. Schmid, M. Robin and P. Gobin, J. Phys., 32 (1971) C2-101. [79] H.C. Lin, S.K. Wu, T.S. Chou, J. Alloys Comps. , 355 ,(2003), p.90. [80] J.S. Zhu, R. Schaller, W. Benoit, Physics Letters A, 141 ,(1989), p.177. [81] K. Iwasaki, R. Hasiguti, Trans. JIM 28 ,(1987), p.363. [82] O. Mercier, K.N. Melton, Y. De Préville, Acta Metall. 27 ,(1979), p.1467. [83] S.K. Wu, H.C. Lin, T.S. Chou, Acta Metall. 38 ,(1990), p.95. [84] H.C. Lin, S.K. Wu, M.T. Yeh, Metall. Mater. Trans. A 24 ,(1993), p.2189. [85] K. Sugimoto, T. Mori, K. Otsuka, K. Shimizu, Scripta Metall. 8 ,(1974), p.1341. [86] Y. Liu, J. Van Humbeeck, R. Stalmans, L. Delaey, J. Alloys Comps.247 (1997), p.115. [87] B. Coluzzi, A. Biscarini, R. Campanella, L. Trotta, G . Mazzolai, A. Tuissi, F.M. Mazzolai, Acta Mater., 47 ,(1999), p.1965. [88] S.K. Wu, H.C. Lin, J. Alloys Comp., 355 ,(2003), p.72. [89] W. Cai, X.L. Lu, L.C. Zhao, Mater. Sci. Eng. A, 394 ,(2005), p.78. [90] J. Van Humbeeck, J. Alloys Comp., 355 ,(2003), p.58. [91] I. Yoshida, T. Ono, M. Asai, J. Alloys Comps., 310 ,(2000), p.339. [92] J.S. Zhu, P.C.W. Fung, M. Gu, Phys. Stat. Sol., 141 ,(1994), p.353. [93] A. Biscarini, R. Campanella, B. Coluzzi, G . Mazzolai, L. Trotta, A. Tuissi, F.M. Mazzolai, Acta Mater., 47 ,(1999), p.4525. [94] B. Coluzzi, A. Biscarini, R. Campanella, G . Mazzolai, L. Trotta, F.M. Mazzolai, J. Alloys Comps., 310 ,(2000), p.300. [95] H.C. Lin, S.K. Wu, T.S. Chou and H.P. Kao, Acta Metall. Mater., 39 , (1991), p.2069. [96] H.C. Lin, S.K. Wu and M.T. Yeh, Metall. Mater. Trans., A 24 ,(1993), p.2189. [97] J. Van Humbeeck, J. Alloys Comps., 355 ,(2003), p.58. [98] I. Yoshida, T. Ono and M. Asai , J. Alloys Comps., 310 ,(2000), p.339. [99] J.S. Zhu, P.C.W. Fung and M. Gu, Phys. Stat. Sol., 141 ,(1994), p.353. [100] F. Deborde, V. Pelosin and A. Riviére, Scripta Mater., 33 ,(1995), p.1993. [101] S. Golyandin, S. Kustov, K. Sapozhnikov, M. Parlinska, R. Gotthardt and J. Van Humbeeck, J. Alloys Comps., 310 ,(2000), p.312. [102] T. Redeker, A.D Bacher, C. Arcos, H.D Kaesz, K. Stovall, Abstr Paper, Am. Chem. Soc., 216,(1998), p.188 [103] S. Sarkar, X. Ren, K. Otsuka, Physical review letters, (2005) PRL 95, 205702. [104] G.V. Markova,A. V. Shuytcev, A.V. Kasimtcev, Mater. Sci. Forum,738-739 (2013), p.377 [105] C. Chien , Ph.D Thesis , National Taiwan University , Taiwan , 2015. [106] JCPDS-International Center for Diffraction Data(ICDD) ,No.18-899 (1959) [107] JCPDS-International Center for Diffraction Data(ICDD) ,No.44-113 (1987) [108] JCPDS-International Center for Diffraction Data(ICDD) ,No.44-114 (1987) [109] Y. Watanabe, T. Saburi, Y. Nakagawa and S. Nenno , J.Jap.Inst.Metals ,54(1990) p.861. [110] T. Onda , Y. Bando , T. Ohba and K. Otsuka , Mater. Trans., 33, (1992),p.354.
dc.identifier.uri	http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/50651	-
dc.description.abstract	本研究針對二元及三元鈦鎳形狀記憶合金(SMA)之制振能及相變態行為等性質作一系列之探討。由DMA研究結果發現，二元Ti50-xNi50+x (x=0~1.6 at%) SMAs 固溶處理後B2 B19’變態者有較高的tanδ值，而固溶並時效後之B2R相變態者，其制震能則較差，推測可能因Ti3Ni4析出物妨礙R相兄弟晶界面之移動有關。 Ti50-xNi50+x (x>1.0 at%) SMAs 250℃或350℃時效都有鬆弛峰在R相內產生，透過不同頻率與鬆弛峰峰值溫度的變化來求冷卻及加熱下形成鬆弛峰所需的活化能，發現R相內形成者其冷卻過程的ev值均大於加熱過程者;同時也比較後發現B19’者之活化能值最小， R者其次，而B19者其活化能值最大，顯示氫原子牽住B19’,B19 及R相麻田散體之雙晶界面的能力大小不同。而三元Ti50Ni50-xPdx (x=7,10及13 at%) SMAs的B2 B19變態，發現其tanδ值會隨著Pd含量的增加而下降，且這三種Ti50Ni50-xPdx SMAs其tanδ值、Storage Modulus E0 軟化值以及Strain Variation等皆比Ti50Ni45Pd5 SMA之B2RB19’變態者來得大，顯示擁有B2 B19變態者的制振能較佳，推測其原因為B2 B19相變態時有較大的E0 軟化而使Strain Variation相對較高。此外，Ti50Ni40Pd10 SMA的tanδ曲線中，在低溫下發現有一變態峰的存在，在-130℃的低溫XRD實驗也發現有B19’相之波峰存在，顯示其在低溫下應有B19B19’麻田散體變態的產生。而在持溫條件下作的DMA實驗也顯示Ti50Ni40Pd10 SMA之本質內耗(IFPT+IFI)B2→B19比其他的Ti50Ni50-xPdx SMAs 來得大。	zh_TW
dc.description.abstract	In this study , transformation behaviors and damping capacities of binary and ternary TiNi-based shape memory alloys (SMAs) are investigated. Damping properties of Ti50-xNi50+x (x=0~1.6 at%) and Ti50Ni50-xPdx (x=5~13 at%) SMAs are characterized under temperature and frequency sweep tests by dynamic mechanical analyzer (DMA). According to DMA tested results, solid solution treated binary Ti50-xNi50+x SMAs exhibited B2B19’ one stage transformation have higher magnitude of tan δ value than aged ones exhibited B2R transformation. It is suggested that Ti3Ni4 precipitates might hinder the mobility of R-phase variants‘ interfaces. Besides, relaxation peak appears in R-phase after Ti50-xNi50+x (x>1.0 at%) SMAs have been low-temperature aged. Comparing to other literatures, the activation energy to form the relaxation peak in B19 phase is higher than those in R-phase and B19’ phase. This phenomenon indicates that the abilities of H atoms pinning twin boundaries in B19,B19’ and R-phase are different. For ternary Ti50Ni50-xPdx SMAs, tan δ value magnitude , storage modulus (E0) and strain variation exhibited in B2B19 transformation are all higher than those in B2RB19’ one due to twin boundaries in B19 phase are easier movable and the B2B19 has higher E0 softening and strain variation during transformaiton. For the inherent internal friction under isothermal condition DMA test, it shows the (IFPT+IFI)B2→B19 of Ti50 Ni40Pd10 SMA exhibits higher tanδ value than the other ternary TiNiPd SMAs, and a transformation peak appears at ≈-75℃ in Ti50Ni40Pd10 SMA which has been further confirmed as B19B19’ transformation by the low temperature XRD test.	en
dc.description.provenance	Made available in DSpace on 2021-06-15T12:50:45Z (GMT). No. of bitstreams: 1 ntu-105-R03527053-1.pdf: 9618774 bytes, checksum: 5f842e8c289b221af36e40b1e5b6a6dd (MD5) Previous issue date: 2016	en
dc.description.tableofcontents	致謝 i 摘要 iii Abstract v 目錄 vii 第一章前言 1 第二章文獻回顧 3 2-1 形狀記憶合金簡介 5 2-1-1 熱彈性麻田散體相變態 5 2-1-2 形狀記憶效應(SME)之機制 7 2-1-3 超彈性/擬彈性(PE)之機制 7 2-2 R相變態及鈦鎳形狀記憶合金的結構 9 2-3 富鎳鈦鎳形狀記憶合金之時效處理效應 10 2-4 富鎳鈦鎳形狀記憶合金之多階相變態行為 11 2-5 三元鈦鎳鈀形狀記憶合金之變態順序 14 2-6 鈦鎳形狀記憶合金的制振能特性 15 第三章實驗步驟 31 3-1 三元鈦鎳鈀形狀記憶合金之試片準備 31 3-2 熱處理 32 3-3 差分掃描熱分析儀(DSC)量測 32 3-4 微硬度(Mircovickers)量測 35 3-5 動態機械分析儀(DMA)量測 35 第四章 Ti50-xNi50+x (x=0~1.6 at%)二元鈦鎳形狀記憶合金變態特性及制振能之研究 43 4-1 DSC 結果與討論 43 4-1-1 Ti50Ni50 SMA固溶處理後之DSC 結果 43 4-1-2 Ti49.6Ni50.4 SMA固溶處理後之DSC 結果 44 4-1-3 Ti49.3Ni50.7 SMA固溶處理後之DSC 結果 44 4-1-4 Ti49Ni51 SMA固溶處理後之DSC 結果 44 4-1-5 Ti49Ni51 SMA 250℃時效之DSC 結果 45 4-1-6 Ti48.7Ni51.3 SMA 350℃時效之DSC 結果 45 4-1-6 Ti48.4Ni51.6 SMA 350℃時效之DSC 結果 46 4-2 DMA 結果與討論 46 4-2-1 Ti50Ni50 SMA固溶處理後之DMA 結果 47 4-2-2 Ti49.6Ni50.4 SMA 固溶處理後之DMA 結果 48 4-2-3 Ti49.3Ni50.7 SMA固溶處理後之DMA 結果 48 4-2-4 Ti49Ni51 SMA 於250℃時效後之DMA 結果 49 4-2-5 Ti48.7Ni51 .3 SMA 於350℃時效後之DMA 結果 51 4-2-5 Ti48.4Ni51 .6 SMA 於350℃時效後之DMA 結果 52 4-3 本章之結語 54 第五章 Ti50Ni50-xPdx (x=5~13 at%)三元鈦鎳形狀記憶合金變態特性及制振能之研究 79 5-1 DSC 結果與討論 79 5-1-1 Ti50Ni45Pd5 SMA固溶處理後之DSC 結果 79 5-1-2 Ti50Ni43Pd7 SMA固溶處理後之DSC 結果 80 5-1-3 Ti50Ni40Pd10 SMA固溶處理後之DSC 結果 80 5-1-4 Ti50Ni37Pd13 SMA固溶處理後之DSC 結果 81 5-1-5 Ti50Ni50-xPdx (x=5,7,10,13 at%) SMAs 之DSC結果與討論 81 5-2 DMA 結果與討論 82 5-2-1 在3℃/min之冷卻及加熱速率下之DMA結果 82 5-2-1-1 Ti50Ni45Pd5 SMA固溶處理後之DMA 結果 83 5-2-1-2 Ti50Ni43Pd7 SMA固溶處理後之DMA 結果 84 5-2-1-3 Ti50Ni40Pd10 SMA固溶處理後之DMA 結果 84 5-2-1-4 Ti50Ni37Pd13 SMA固溶處理後之DMA 結果 85 5-2-2 Isothermal持溫狀態下之DMA結果 86 5-2-2-1 Ti50Ni45Pd5 SMA固溶處理後之Isothermal DMA結果 86 5-2-2-2 Ti50Ni43Pd7 SMA固溶處理後之Isothermal DMA結果 87 5-2-2-3 Ti50Ni40Pd10 SMA固溶處理後之Isothermal DMA結果 88 5-2-1-4 Ti50Ni37Pd13 SMA固溶處理後之Isothermal DMA結果 88 5-2-3 Ti50Ni50-xPdx (x=5,7,10,13 at%) DMA之結果與討論 89 5-3 Ti50Ni50-XPdX (x=5,7,10,13 at%) SMAs之硬度試驗結果 90 第六章結論 115 參考文獻 117
dc.language.iso	zh-TW
dc.title	二元及三元鈦鎳基形狀記憶合金相變態行為及制振能之研究	zh_TW
dc.title	Transformation Behaviors and Damping Capacities of Binary and Ternary TiNi-Based Shape Memory Alloys	en
dc.type	Thesis
dc.date.schoolyear	104-2
dc.description.degree	碩士
dc.contributor.oralexamcommittee	周棟勝,張世航,簡甄
dc.subject.keyword	二元及三元鈦鎳形狀記憶合金,制振能,鬆弛峰,相變態性質,本質內耗特性,	zh_TW
dc.subject.keyword	Binary and ternary TiNi SMAs,Damping capacities,Relaxation peak,Transformation behaviors,Inherent internal friction,	en
dc.relation.page	121
dc.identifier.doi	10.6342/NTU201601105
dc.rights.note	有償授權
dc.date.accepted	2016-07-21
dc.contributor.author-college	工學院	zh_TW
dc.contributor.author-dept	材料科學與工程學研究所	zh_TW
顯示於系所單位：	材料科學與工程學系

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