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| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 陳建彰 | |
| dc.contributor.author | Chang-Han Xu | en |
| dc.contributor.author | 許昶漢 | zh_TW |
| dc.date.accessioned | 2021-06-15T12:43:30Z | - |
| dc.date.available | 2016-08-02 | |
| dc.date.copyright | 2016-08-02 | |
| dc.date.issued | 2016 | |
| dc.date.submitted | 2016-07-26 | |
| dc.identifier.citation | [1] A. Yu, V. Chabot, and J. Zhang, Electrochemical supercapacitors for energy storage and delivery: fundamentals and applications: CRC Press, 2013.
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| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/50502 | - |
| dc.description.abstract | 本研究利用快速常壓電漿燒結製程，製作二氧化錫/奈米碳管複合材料並且運用到超級電容的電極上。奈米多孔隙二氧化錫/奈米碳管將料是由混合二氧化錫奈米粉末、奈米碳管、乙基纖維素(ethyl celluloses)和無水萜品醇(terpineol)等碳基有機物製成二氧化錫/奈米碳管奈米粒子膠體溶液，漿料經由網印後，再利用氮氣常壓噴射電漿進行燒結。隨著常壓電漿燒結時間增加，二氧化錫/奈米碳管複材的沾濕性也隨之增加(水接觸角變小)，因此電解液可以有效地浸入奈米孔洞結構，提升超電容的儲能效率。常壓電漿燒結有兩種模式，固定載台及載台移動，其中固定載台單點燒結120秒其比電容可達188.42 F/g、載台移動(1.5 mm/s) 的燒結條件下，比電容可達89.6 F/g。我們成功將常壓電漿燒結應用在超級電容的電極上，常壓電漿不須真空腔體及泵浦且製程時間相對快速，在工業上的應用具有高度發展潛力的。 | zh_TW |
| dc.description.abstract | We demonsrate a supercapacitor made of nanoporous SnO2/CNT (carbon nanotube) composites that are sintered by nitrogen atmospheric pressure plasma jets (APPJs). The sreen-printing technique is first used to print a paste that contains SnO2 and CNT nanoparticles, ethyl celluloses, terpinoel. A nitrogen APPJ is then used to sinter the printed paste. With the increasing of APPJ sintering time, the wettability of SnO2/CNT composites also increases (lower water contact angle). Two different APPJ operation configurations are used in this study: one is with the stage fixed; the other is with a stage being scanned (moving stage, in order to process a sample with larger area). With the stage fixed, the best achieved specific capacitance is 188.42 F/g with 120 s processing duration. On the other hand, with the scanning stage, the best achieved specifnic capacitance is 89.6 F/g with 1.5 mm/s scanning speed. The scanning speed influences the processing time at a designated spot on the sample, thereby resulting in various properties of sintered SnO2/CNT composites. APPJ can be operated at a regular atmospheric pressure without using vacuum chambers and pumps that are expensive and require routine maintenance. Therefore, this technology has become a cost-effective tool readily for industrical application. | en |
| dc.description.provenance | Made available in DSpace on 2021-06-15T12:43:30Z (GMT). No. of bitstreams: 1 ntu-105-R03543073-1.pdf: 5613078 bytes, checksum: 2c3f26e7b718fa963ab19ad7b5089361 (MD5) Previous issue date: 2016 | en |
| dc.description.tableofcontents | 致謝 i
中文摘要 ii ABSTRACT iii 目錄 iv 圖目錄 vii 表目錄 xii 第一章 緒論 1 1.1 前言 1 1.2 研究動機 3 1.3 論文大綱 5 第二章 理論與文獻回顧 6 2.1 二氧化錫(Tin Oxide, SnO2)之基本性質 6 2.1.1 氧化錫之薄膜結構 6 2.2 氧化錫薄膜的製備 7 2.2.1 電子束蒸鍍法 7 2.2.2 網印法 8 2.3 氧化錫之文獻回顧 9 2.3.1 傳統爐管退火之SnO2薄膜 9 2.4 奈米碳管(carbon nanotube, CNT)之基本性質 10 2.4.1 導電性與機械性質 11 2.5 超級電容之簡介 11 2.6 常壓電漿之基本介紹 17 2.6.1 電漿原理 17 2.6.2 常壓電漿種類與工作原理 17 2.6.3 常壓電漿的優勢 20 第三章 實驗方法與流程 21 3.1 實驗藥品與儀器 21 3.2 實驗規劃 23 3.3 實驗流程 24 3.3.1 基板清洗 24 3.3.2 漿料製作 24 3.3.3 以網印法製備氧化錫/奈米碳管試片實驗流程 25 3.4 製程儀器與原理 28 3.4.1 迴旋濃縮機 28 3.4.2 網印機 29 3.4.3 常壓電漿(Atmospheric pressure plasma jet, APPJ)燒結處理 30 3.4.4 電子束蒸鍍機(E-beam evaporator) 32 3.5 量測儀器與原理 33 3.5.1 掃描式電子顯微鏡(Scanning electron microscope, SEM) 33 3.5.2 X光繞射儀(X-ray diffraction, XRD) 35 3.5.3 電化學阻抗分析儀 35 3.5.4 電阻率(電導率)量測 40 第四章 實驗結果與討論 41 4.1 實驗一 不同SnO2/CNT比例之超級電容 41 4.2 實驗二 常壓電漿載台移動速率對超級電容特性之影響 48 4.2.1 掃描常壓電漿溫度 48 4.2.2 水接觸角 50 4.2.3 二氧化錫/50wt.%-奈米碳管薄膜之表面型態 50 4.2.4 二氧化錫/50wt.%-奈米碳管之X光繞射分析 51 4.2.5 二氧化錫/50wt.%-奈米碳管之電學分析 52 4.2.6 改變常壓電漿載台移動速率對超級電容特性之影響 53 4.2.7 EIS阻抗分析 63 4.3 實驗三 單點常壓電漿燒結時間對超級電容特性之影響 68 4.3.1 單點常壓電漿溫度 68 4.3.2 經單點常壓燒結之水接觸角 69 4.3.3 二氧化錫/50wt.%-奈米碳管薄膜之表面型態 69 4.3.4 二氧化錫/50wt.%-奈米碳管之X光繞射分析 71 4.3.5 二氧化錫/50wt.%-奈米碳管之電學分析 72 4.3.6 在不同常壓電漿燒結時間條件下二氧化錫/50wt.%-奈米碳管超電容特性量測 73 4.3.7 EIS阻抗分析 92 4.4 充電後超電容點亮發光二極體 98 第五章 結論與未來展望 99 第六章 附錄 100 參考文獻 108 | |
| dc.language.iso | zh-TW | |
| dc.subject | 超級電容 | zh_TW |
| dc.subject | 奈米碳管 | zh_TW |
| dc.subject | 常壓電漿 | zh_TW |
| dc.subject | 奈米碳管 | zh_TW |
| dc.subject | 二氧化錫 | zh_TW |
| dc.subject | 二氧化錫 | zh_TW |
| dc.subject | 超級電容 | zh_TW |
| dc.subject | 常壓電漿 | zh_TW |
| dc.subject | CNT | en |
| dc.subject | SnO2 | en |
| dc.subject | supercapacitor | en |
| dc.subject | APPJ | en |
| dc.subject | CNT | en |
| dc.subject | SnO2 | en |
| dc.subject | APPJ | en |
| dc.subject | supercapacitor | en |
| dc.title | 常壓電漿燒結氧化錫/奈米碳管複合材料於超級電容之應用 | zh_TW |
| dc.title | Atmospheric-Pressure Plasma Jet Processed SnO2/CNT Nanocomposites for Supercapacitor Application | en |
| dc.type | Thesis | |
| dc.date.schoolyear | 104-2 | |
| dc.description.degree | 碩士 | |
| dc.contributor.oralexamcommittee | 陳奕君,陳林祈,張世航 | |
| dc.subject.keyword | 二氧化錫,奈米碳管,常壓電漿,超級電容, | zh_TW |
| dc.subject.keyword | SnO2,CNT,APPJ,supercapacitor, | en |
| dc.relation.page | 110 | |
| dc.identifier.doi | 10.6342/NTU201601317 | |
| dc.rights.note | 有償授權 | |
| dc.date.accepted | 2016-07-27 | |
| dc.contributor.author-college | 工學院 | zh_TW |
| dc.contributor.author-dept | 應用力學研究所 | zh_TW |
| 顯示於系所單位： | 應用力學研究所 | |
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