請用此 Handle URI 來引用此文件:
http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/49152
完整後設資料紀錄
DC 欄位 | 值 | 語言 |
---|---|---|
dc.contributor.advisor | 蔡曜陽 | |
dc.contributor.author | Yu-Sheng Wang | en |
dc.contributor.author | 王昱勝 | zh_TW |
dc.date.accessioned | 2021-06-15T11:17:33Z | - |
dc.date.available | 2021-08-26 | |
dc.date.copyright | 2016-08-26 | |
dc.date.issued | 2016 | |
dc.date.submitted | 2016-08-18 | |
dc.identifier.citation | [1]L.A. Dobrzański, , D. Pakuła, E. Hajduczek, “Structure and properties of the multi-component TiAlSiN coatings obtained in the PVD process in the nitride tool ceramics,” Journal of Materials Processing Technology, Vol 157–158, 20 Dec 2004, Pp 331–340.
[2]S. Mathur, P. Kuhn, CVD of titanium oxide coatings: comparative evaluation of thermal and plasma assisted processes, Surf. Coat. Technol., 201 (2006), pp. 807–814 [3]M. Shokouhfar, C. Dehghanian, A. Baradaran, Preparation of ceramic coating on Ti substrate by plasma electrolytic oxidation in different electrolytes and evaluation of its corrosion resistance, Appl. Surf. Sci., 257 (2011), pp. 2617–2624 [4]洪胤庭博士“純鈦及鈦合金特性及製程介紹”中工高雄會刊第21卷第1期 Li J, Behaviour of titanium and titania-based ceramics in vitro and in vivo, vol. 14, 1993, 99. 1495-1502. [5]W.D. Brewer, R.K. Bird, T.A., WallaceTitanium alloys and processing for high speed aircraft, Mater Sci Eng A, 243 (1–2) (1998), pp. 299–304 [6]X. Fan, B. Feng, Y. Di, X. Lu, K. Duan, J. Wang, et al., Preparation of bioactive TiO2 film on porous titanium by micro-arc oxidation, Appl. Surf. Sci., 258 (2012), pp. 7584–7588 [7]H. Habazaki, S. Tsunekawa, E. Tsuji, T. Nakayama, Formation and characterization of wear-resistant PEO coatings formed on β-titanium alloy at different electrolyte temperatures, Applied Surface Science, 259 (2012), pp. 711–718 [8]L.R. Krishna, P.S.V.N.B. Gupta, G. Sundararajan, The influence of phase gradient within the micro arc oxidation (MAO) coatings on mechanical and tribological behaviors, Surf. Coat. Technol., 269 (2015), pp. 54–63 [9]Jun-Hua Wang” Effects of single pulse energy on the properties of ceramic coatingprepared by micro-arc oxidation on Ti alloy ” Applied Surface Science 324 (2015) 405–413 [10]陳文杰“7075鋁合金經微弧氧化處理後之耐磨耗特性”南亞學報第二十九期 周偉萍, 利用微弧氧化技術在鎂合金表面製備黑色氧化膜之研究”大同大學材料工程研究所碩士班, June 2012 [11]Mohannad M.S. Al Bosta, Suggested mechanism for the MAO ceramic coating on aluminium substrates using bipolar current mode in the alkaline silicate electrolytes, Applied Surface Science, 308 (2014), pp. 121–138 [12]鄧志威, 有色金屬表面微弧氧化技術評述, 金屬熱處理, 2000年第1期 [13]J.L. Xu, Microstructure and corrosion resistance behavior of ceramic coatings on biomedical NiTi alloy prepared by micro-arc oxidation, Applied Surface Science, 254 (2008), pp. 6642–6647 [14]黃平”用微弧氧化技術處理醫用鈦合金表面的研究'《稀有金属材料與工程》2002年 第4期 [15]J.H. Wang, J. Wang, Y. Lu, M.H. Du, F.Z. Han, Effects of single pulse energy on the properties of ceramic coating prepared by micro-arc oxidation on Ti alloy, Appl. Surf. Sci., 324 (2015), pp. 405–413 [16]謝昇龍”以雙極脈衝微弧氧化法與水熱法在純鈦基板上披覆高附著性與生物活性之膜層”大同大學材料工程研究所碩士班 July 2010 [17]Y. Yang, H. Wu, Effects of current density on microstructure of titania coatings by micro-arc oxidation, J. Mater. Sci. Technol., 28 (2012), pp. 321–324 [18]Y. Wang, T. Lei, L. Guo, and B. Jiang, 'Fretting wear behaviour of microarc oxidation coatings formed on titanium alloy against steel in unlubrication and oil lubrication', Applied Surface Science, 8113-8120, 2006. [19]A. L. Yerokhin, X. Nie, A. Leyland, A. Matthews, “Characterization of Oxide Films Produced by Plasma Electrolytic Oxidation of A Ti-6Al-4V Alloy”, Surface and Coatings Technology, 195-206, 2000. [20]L. H. Li, Y. M. Kong, H. W. Kim, Y. W. Kim, H. E. Kim, S. J. Heo, and J. Y. Koak, “Improved biological performance of Ti implants due to surface modification by micro-arc oxidation”, Biomaterials,2867-2875, 2004. [21]李宣東、吳曉宏,“微等離子體氧化法在TiO2 膜的光催化活性研究”,稀有金屬,第27 卷第6 期, 661-664, 2003. [22]Z. Liu, W. Wang, H. Liu, T. Wang, M. Qj, “Formation and characterization of titania coatings with cortex-like slots formed on Ti by micro-arc oxidation treatment”, Applied Surface Science 266, pp. 250-255, 2013. [23]S Xin,. L Song,. R Zhao,. and X Hu,. “Influence of cathodic current on composition, structure and properties of 〖Al〗_2 O_3 coatings on aluminum alloy prepared by micro-arc oxidation process”, Thin Solid Films, 59, 237-242, 2005. [24]G Sundararajan, , “Mechanisms underlying the formation of thick alumina coatings through the MAO coating technology”, Surface and Coatings Technology, 167, 269-277, 2003. [25]Kalpakjian, S., Schmid, S., “Manufacturing Engineering And Technology 5^th Edition“ , Prentice Hall Inc., 2006. [26]Lutjering, G., Williams, J.C., “Titanium - 2^ed Edition” , Springer Verlag, 2007. 台灣輕金屬協會”鈦金屬特性紹”http://www.twlma.org.tw/Industry02.aspx [27]A.L.Yerokhin, X. Nie, A. Leyland, A. Matthews and S. J. Dowey,“Plasma electrolysis for surface engineering”, Surface and Coatings Technology, 73-93, 1997. [28]V.N. Duradzhy, A.S. Parsadanyan, “Metal Heating in Electrolytic Plasma”, Shtiintsa, Kishinev, in Russian, 1988. [29]V.I. Tchernenko, L.A. Snezhko, I.I. Papanova, “Coatings by Anodic Spark Electrolysis”, Khimiya, Leningrad, in Russian , 1991. [30]Y. Hana, S.H.Honga, K.W. Xub, “Porous nanocrystalline titania films by plasma electrolytic oxidation” Surface and Coatings Technology, Volume 154, Issues 2–3, 15 May 2002, Pages 314–318 [31]A.L. Yerokhin, A. Leyland, A. Matthews, Kinetic aspects of aluminium titanate layer formation on titanium alloys by plasma electrolytic oxidation, Appl. Surf. Sci., 200 (2002), pp. 172–184 [32]J.L. Delplancke, A. Garnier, Y. Massiani, R. Winand, Influence of the anodizing procedure on the structure and the properties of titanium oxide films and its effect on copper nucleation, Electrochim. Acta, 39 (1994), pp. 1281–1289 [33]H. Habazaki, Y. Oikawa, K. Fushimi, K. Shimizu, S. Nagata, P. Skeldon, G.E. Thompson, Formation of porous anodic films on Ti-Si alloys in hot phosphate-glycerol electrolyte, Electrochim. Acta, 53 (2007), pp. 1775–1781 [34]Habazaki, H., et al., Spark anodizing of beta-Ti alloy for wear-resistant coating, Surface & Coating Technology, 2007.201(21):p. 8730-8737 [35]E. Matykina, et al., Destruction of coating material during spark anodizing of titanium, Electrochim. Acta, 51 (22) (2006), pp. 4709–4715 [36]Q LU, J ALBERCH, T HASHIMOTO, SJ GARCIA-VERGARA, H HABAZAKI, P SKELDON, GE THOMPSON, Porous anodic oxides on titanium and on a Ti-W alloy , Corrosion Science, 50 (2) (2008), pp. 548–553 | |
dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/49152 | - |
dc.description.abstract | 本實驗藉由單極脈衝電源供應器控制電源參數,使用矽酸鈉及氫氧化鈉為電解液,以純鈦為基材進行微弧氧化處理,探討改變陽極開壓時間、陽極關壓時間、加工時間及電流不同參數對氧化膜的形成影響。
本實驗分成三個部分,第一部分主要討論不同電流對於膜層的影響,而電流設定為0.2 A、0.4 A、0.5 A、0.6 A及0.8 A。第二部分探討加工時間採用電壓真正有作用之時間為60 sec、120 sec及180 sec,藉以來觀察膜層成長的變化狀況。實驗結果發現在加工時間 60 sec及0.5 A此電流以上膜層表面會有白色粉末產生,而電流越大與加工時間越長白色粉末更為明顯。 第二部分主要討論在定電流下不同脈衝時間下對氧化膜的影響,以Ton 為變數時固定Toff時間,當Ton時間縮短膜層表面較易產生白色粉末;以Toff為變數時固定Ton時間,當其時間增長也較易產生白色粉末。在較短Ton 及較長Toff其電壓上升較快且鄰近正極之電解液的陰離子因參與反應而耗損,若Ton過長或Toff過短,將造成陰離子擴散補充不及而減緩膜層成長速度,因此脈衝時間Ton 與Toff必須取得一個平衡,否則抑制了薄膜的成長。 在不同電流、加工時間、Ton時間及Toff時間皆對直流單極脈衝的微弧氧化的膜層結果是否形成白色粉末表面皆有很大之影響,因此控制以上不同參數對氧化膜結果極為重要。 | zh_TW |
dc.description.abstract | In this paper, it’s compared the qualities of the titanium oxide layer modified by micro-arc oxidation (MAO) under difference process conditions, they were compared with applied current, acting time, pulse on time and pulse off time. From obeservating the surface topography of SEM and optical microscope, it is shown impact of difference process conditions to the qualities of titanium oxide layer. Moreover, ot can be demonstrated the optimization conditions to generate the titanium oxide layer by MAO.
The experiments are divided into the three parts. In first part, it was designed to the four current conditions at the same acting time and same pulse conditions. The results show generation the oxide film at current 0.5 A, 0.6 A and 0.8A it have TiO2 white powder. | en |
dc.description.provenance | Made available in DSpace on 2021-06-15T11:17:33Z (GMT). No. of bitstreams: 1 ntu-105-R02522728-1.pdf: 5251445 bytes, checksum: d618d85ac8b2a3b5ce6354c9d013c946 (MD5) Previous issue date: 2016 | en |
dc.description.tableofcontents | 中文摘要 ii
Abstract iii 目錄 iv 圖目錄 vi 表目錄 ix 第一章 緒論 1 1.1 研究背景以及動機 1 1.2 文獻回顧 3 1.2.1 陽極處理 3 1.2.2 微弧氧化製程 4 1.2.3 鈦金屬微弧氧化製程 5 1.3 研究目的 7 1.4 論文大綱 8 第二章 相關技術理論介紹 9 2.1 鈦金屬 9 2.1.1 鈦金屬簡介 9 2.1.2 鈦金屬及鈦合金分類 11 2.1.3 鈦金屬應用 15 2.2 二氧化鈦 16 2.2.1 二氧化鈦簡介 16 2.2.2 粉狀二氧化鈦 19 2.2.3 薄膜狀二氧化鈦 19 2.3 微弧氧化 21 2.3.1 發展歷史 21 2.3.2 微弧氧化薄膜生成過程 22 2.3.3 微弧氧化膜層結構及成分特性 22 2.3.4 電漿電解物理、化學基礎理論 23 2.3.5 微弧氧化膜層應用 30 第三章 實驗步驟與方法 32 3.1 實驗規劃 32 3.2 實驗規劃流程圖 33 3.3 實驗方法 34 3.3.1 材料準備 34 3.3.2 微弧氧化製程 34 3.4 實驗設備 36 第四章 實驗結果與討論 40 4.1 電流參數對氧化膜之影響 40 4.2 加工時間對氧化膜之影響 45 4.3 脈衝時間Ton對氧化膜之影響 48 4.4 脈衝時間Toff對氧化膜之影響 51 4.5 電流與加工時間對氧化膜之影響 54 第五章 結論與未來展望 60 5.1 結論 60 5.2 未來展望 61 參考文獻 62 | |
dc.language.iso | zh-TW | |
dc.title | 微弧氧化加工於鈦金屬鍍膜白色粉末之研究 | zh_TW |
dc.title | The Study of micro-arc oxidation on The Titanium Coating | en |
dc.type | Thesis | |
dc.date.schoolyear | 104-2 | |
dc.description.degree | 碩士 | |
dc.contributor.oralexamcommittee | 王阿成,洪榮洲 | |
dc.subject.keyword | 微弧氧化,純鈦,單極直流脈衝,表面形貌, | zh_TW |
dc.subject.keyword | MAO,Ti, | en |
dc.relation.page | 66 | |
dc.identifier.doi | 10.6342/NTU201602951 | |
dc.rights.note | 有償授權 | |
dc.date.accepted | 2016-08-20 | |
dc.contributor.author-college | 工學院 | zh_TW |
dc.contributor.author-dept | 機械工程學研究所 | zh_TW |
顯示於系所單位: | 機械工程學系 |
文件中的檔案:
檔案 | 大小 | 格式 | |
---|---|---|---|
ntu-105-1.pdf 目前未授權公開取用 | 5.13 MB | Adobe PDF |
系統中的文件,除了特別指名其著作權條款之外,均受到著作權保護,並且保留所有的權利。