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完整後設資料紀錄
DC 欄位 | 值 | 語言 |
---|---|---|
dc.contributor.advisor | 陳俊維(CHUN-WEI CHEN) | |
dc.contributor.author | CHUNG-WEI LIN | en |
dc.contributor.author | 林忠緯 | zh_TW |
dc.date.accessioned | 2021-06-15T11:10:14Z | - |
dc.date.available | 2022-02-08 | |
dc.date.copyright | 2017-02-08 | |
dc.date.issued | 2016 | |
dc.date.submitted | 2016-09-29 | |
dc.identifier.citation | [1] http://solarpv.itri.org.tw/aboutus/sense/principle.asp 太陽能資訊網
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'Recombination study of combined halides (Cl, Br, I) perovskite solar cells.' The journal of physical chemistry letters 5.10 (2014): 1628-1635. [13] Fickler, Robert, et al. 'Quantum entanglement of high angular momenta.'Science 338.6107 (2012): 640-643. [14] Heo, Jin Hyuck, and Sang Hyuk Im. 'CH3NH3PbBr3–CH3NH3PbI3 Perovskite– Perovskite Tandem Solar Cells with Exceeding 2.2 V Open Circuit Voltage.' Advanced Materials (2015). [15] Ryu, Seungchan, et al. 'Voltage output of efficient perovskite solar cells with high open-circuit voltage and fill factor.' Energy & Environmental Science 7.8 (2014): 2614-2618. [16] Cai, Bing, et al. 'High performance hybrid solar cells sensitized by organolead halide perovskites.' Energy & Environmental Science 6.5 (2013): 1480-1485. [17] Noel, Nakita K., et al. 'Lead-free organic–inorganic tin halide perovskites for photovoltaic applications.' Energy & Environmental Science 7.9 (2014): 3061-3068. [18] Kojima.A, Teshima,K,Shirai.Y,Miyasaka.T,Organmetal halid perovskites as visiblelight sensitizers for photocoltaic cells.Journal of the American Chemical Society , 2009,131(17),6050-6051 [19] Kim,H-S, C.R.Im, J.H.Lee, M.Gratzel, M.Park,Lead iodide perovskite sensitized all solid-state submicron thin film mesoscopic solar cell with efficiency exceeding , Scientific Reports,2012,2,591 [20] J.Burschka, N.Pellet, S.J.Moon, M.Gratzel,Sequential deposition as a route to high performance perovskite-sensitized solar cells. Nature,2013,499(7458),326-319 [21] Zhou, Huanping, et al. 'Interface engineering of highly efficient perovskite solar cells.' Science 345.6196 (2014): 542-546. [22] Saliba, Michael, et al. 'Cesium-containing triple cation perovskite solar cells: improved stability, reproducibility and high efficiency.' Energy & Environmental Science 9.6 (2016): 1989-1997. [23] J.H.Heo, S.H.Im, S.I.Seok, M.Gratzel,Efficient inorganic-organic hybrid heterojunction solar cells containing perovskite compound and polymeric hole conductors. Nat Photon,2013,7(6),286-291 [24] M.Liu, H.J.Snaith ,Effocoemt planar heterojunction perovskite solar cells by vapour deposition. Nature,2013,501(7467),395-398 [25] Nie, Wanyi, et al. 'High-efficiency solution-processed perovskite solar cells with millimeter-scale grains.' Science 347.6221 (2015): 522-525. [26] Eperon, Giles E., et al. 'Morphological Control for High Performance, Solution‐ Processed Planar Heterojunction Perovskite Solar Cells.' Advanced Functional Materials 24.1 (2014): 151-157. [27] Jeon, Nam Joong, et al. 'Solvent engineering for high-performance inorganic– organic hybrid perovskite solar cells.' Nature materials 13.9 (2014): 897-903. [28] Xiao, Zhengguo, et al. 'Solvent Annealing of Perovskite‐Induced Crystal Growth for Photovoltaic ‐ Device Efficiency Enhancement.' Advanced Materials26.37 (2014): 6503-6509. [29] Li, Shao-Sian, et al. 'Intermixing-seeded growth for high-performance planar heterojunction perovskite solar cells assisted by precursor-capped nanoparticles.' Energy & Environmental Science 9.4 (2016): 1282-1289. [30] Liu, Dianyi, and Timothy L. Kelly. 'Perovskite solar cells with a planar heterojunction structure prepared using room-temperature solution processing techniques.' Nature photonics 8.2 (2014): 133-138. [31] Ke, Weijun, et al. 'Low-temperature solution-processed tin oxide as an alternative electron transporting layer for efficient perovskite solar cells.'Journal of the American Chemical Society 137.21 (2015): 6730-6733. [32] Baena, Juan Pablo Correa, et al. 'Highly efficient planar perovskite solar cells through band alignment engineering.' Energy & Environmental Science 8.10 (2015): 2928-2934. [33] Song, Jiaxing, et al. 'Low-temperature SnO 2-based electron selective contact for efficient and stable perovskite solar cells.' Journal of Materials Chemistry A3.20 (2015): 10837-10844. [34] Leijtens, Tomas, et al. 'Overcoming ultraviolet light instability of sensitized TiO2 with meso-superstructured organometal tri-halide perovskite solar cells.'Nature communications 4 (2013). [35] Ito, Seigo, et al. 'Effects of surface blocking layer of Sb2S3 on nanocrystalline TiO2 for CH3NH3PbI3 perovskite solar cells.' The Journal of Physical Chemistry C 118.30 (2014): 16995-17000. [36] Li, Wenzhe, et al. 'Enhanced UV-light stability of planar heterojunction perovskite solar cells with caesium bromide interface modification.' Energy & Environmental Science 9.2 (2016): 490-498. [37] You, Jingbi, et al. 'Improved air stability of perovskite solar cells via solutionprocessed metal oxide transport layers.' Nature nanotechnology 11.1 (2016): 75-81. [38] Osada, Minoru, and Takayoshi Sasaki. 'Two‐Dimensional Dielectric Nanosheets: Novel Nanoelectronics From Nanocrystal Building Blocks.'Advanced Materials 24.2 (2012): 210-228. [39] https://en.wikipedia.org/wiki/Rutile [40] https://en.wikipedia.org/wiki/Anatase [41] Osada, Minoru, and Takayoshi Sasaki. 'Nanosheet architectonics: a hierarchically structured assembly for tailored fusion materials.' Polymer Journal 47.2 (2015): 89- 98. [42] Sasaki, T.; Ebina, Y.; Kitami, Y.; Watanabe, M.; Oikawa, T. Two-Dimensional Diffraction of Molecular Nanosheet Crystallites of Titanium Oxide. J. Phys. Chem. B, 2001, 105, 6116–6121 [43] Inukai, K.; Hotta, Y.; Taniguchi, M.; Tomura, S.; Yamagishi,A. Formation of a Clay Monolayer at an Air Water Interface. J. Chem. Soc., Chem. Commun. 1994, 959. [44] Leijtens, Tomas, et al. 'Overcoming ultraviolet light instability of sensitized TiO2 with meso-superstructured organometal tri-halide perovskite solar cells.'Nature communications 4 (2013). [45] Wang, Yong, et al. 'Lattice distortion oriented angular self-assembly of monolayer titania sheets.' Journal of the American Chemical Society 133.4 (2010): 695-697 | |
dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/48848 | - |
dc.description.abstract | 在近期幾年內,興起了利用有機-無機鈣鈦礦材料來當作太陽能電池中的光吸收層的研究,在這短短的幾年時間內,鈣鈦礦太陽能電池轉換效率已經可以到達21%。而大部分的固態鈣鈦礦太陽能電池使用一種需要高溫燒結製成的金屬氧化物材料,緻密二氧化鈦Compact TiO2,來當作電子傳輸層,然而這個高溫製成將會限制一些鈣鈦礦太陽能電池在某些領域的應用,如應用在可繞式基板上、或者是結合其他材料做成串聯式太陽能電池。在我們的研究中,我們利用了一種低溫合成的金屬氧化物,原子層級厚度二氧化鈦Atomic Ti0.87O2,來當作我們的電子傳輸層。藉由Langmuir-Blodgett 沉積方法,我們可以在全低溫製程(小於150 度)下將原子層級厚度二氧化鈦非常服貼且覆蓋率相當好地沉積在基板上面,製作鈣鈦礦太陽能電池。利用約五奈米厚度地原子層級厚度二氧化鈦,即可大幅地降低載子再結合和漏電流的機率,使效率可以達到14.05%,其元件表現效率可略高於使用高溫燒結的緻密二氧化鈦元件。更重要的是,我們發現利用原子層級二氧化鈦其元件表現穩定性比緻密二氧化鈦來的好許多,在二十天過後,原子層級二氧化鈦其元件表現效率還能達到原始的70%,而利用緻密二氧化鈦的元件只能表現其原本的10%效率。在這個研究中我們可以藉由原子層級二氧化鈦,去製作一個全低溫溶液製成,原子
層級厚度電子傳輸層,穩定性佳的鈣鈦礦太陽能電池。 | zh_TW |
dc.description.abstract | A recently emerging class of solid-state hybrid organic–inorganic perovskite-based solar cells,using CH3NH3PbX3(X=Cl,Br,I) as light harvesting materials, had demonstrated remarkably high power conversion efficiencies of nearly 21%. Most state-of-the-art perovskite solar cells typically have a device structure that is based on a hightemperature sintered metal oxide(compact TiO2) as electron transporting layer(ETL) which may cause the limitation of perovskite solar cells to be deposited on flexible substrates and affect their compatibility with fabrication processes in multi-junction solar cells. In this work, the utilization of atomically thin titania (atomic Ti0.87O2) deposited at room temperature as an ultra-thin electron transporting layer in perovskite solar cell was demonstrated.Through Langmuir-Blodgett deposition process at room temperature,atomic Ti0.87O2 was conformally deposited on FTO substrate with a high coverage and eliminated the requirement of high temperature process (over 500C) to deposit compact TiO2. The incorporation of multi-layer Ti0.87O2 (around 5 nm) effectively decreased the recombination of electron and hole and leaded to a reduced leakage current. This resulted in a promising device performance (14.05%) that is compatible to the device fabricated using high-temperature sintered metal oxide as electron selection layer. More importantly, we find devices using atomic Ti0.87O2 as electron transporting layer have a better stability in atomsphere. After 30 days, the atomic Ti0.87O2 devices remain about 70% of their original efficiency, unlike compact TiO2 devices, which remain 10% of original efficiency. With the atomic Ti0.87O2 electron transporting layer, we can successfully make a whole low temperature solution process, an atomically thin film ETL, and a stable deivces. | en |
dc.description.provenance | Made available in DSpace on 2021-06-15T11:10:14Z (GMT). No. of bitstreams: 1 ntu-105-R03527065-1.pdf: 6096185 bytes, checksum: 5fd8d7e2b3cafde62ad080f0c2945f0b (MD5) Previous issue date: 2016 | en |
dc.description.tableofcontents | 口試委員會審定書 ........................................................................................................... 2
國立台灣大學碩士學位論文 口試委員會審定書 ......................................................... 2 致謝 ................................................................................................................................... 3 中文摘要 ........................................................................................................................... 6 ABSTRACT ...................................................................................................................... 7 圖目錄 ............................................................................................................................. 11 表目錄 ............................................................................................................................. 16 第1 章 鈣鈦礦太陽能電池 ................................................................................. 17 1.1 太陽能電池(Solar Cells) ………………………………………………….17 1.2 鈣鈦礦太陽能電池(Perovskite solar cells) .................................................. 20 1.2.1 鈣鈦礦結構與性質 ............................................................................. 20 1.2.2 甲基胺離子鈣鈦礦材料特性 ............................................................. 21 1.2.3 鈣鈦礦太陽能電池發展史 ................................................................. 26 1.2.4 鈣鈦礦太陽能電池工作原理 ............................................................. 31 第2 章 文獻回顧.................................................................................................. 33 2.1 前言 .............................................................................................................. 33 2.2 鈣鈦礦薄膜沉積方法 .................................................................................. 33 2.2.1 一步驟沉積法 ..................................................................................... 33 2.2.2 二步驟沉積法 ..................................................................................... 34 2.2.3 氣相沉積法 ......................................................................................... 35 2.3 鈣鈦礦薄膜表面形貌品質之改善 .............................................................. 36 2.4 鈣鈦礦太陽能電池傳輸層之改善 .............................................................. 42 2.5 研究動機 ...................................................................................................... 48 第3 章 元件製程與實驗儀器介紹 ..................................................................... 50 3.1 實驗流程 ...................................................................................................... 51 3.2 材料與元件製備 .......................................................................................... 51 3.2.1 基板清理 ............................................................................................. 51 3.2.2 電子傳輸層 ......................................................................................... 52 3.2.3 光吸收層 ............................................................................................. 53 3.2.4 電洞傳輸層 ......................................................................................... 53 3.3 元件穩定性和電子轉移能力量測的樣品製作 .......................................... 54 3.4 實驗儀器介紹 .............................................................................................. 55 3.4.1 EQE 量測 ............................................................................................ 55 3.4.2 X 光繞射分析儀 ................................................................................. 56 3.4.3 穿透式電子顯微鏡 ............................................................................. 57 3.4.4 掃描式電子顯微鏡 ............................................................................. 58 3.4.5 紫外光-可見光-近紅外光吸收光譜 .................................................. 58 3.4.6 旋轉塗佈機 ......................................................................................... 59 3.4.7 真空鍍機 ............................................................................................. 60 3.4.8 太陽光模擬器及電流密度-電壓特性量測設備 ............................... 61 3.4.9 光致螢光與時間解析光致螢光 ......................................................... 62 第4 章 實驗結果與討論 ..................................................................................... 65 4.1 Atomic Ti0.87O2 材料分析介紹 ................................................................... 65 4.2 不同層之Atomic Ti0.87O2 與Compact TiO2 沉積於FTO 基板之表面形貌 68 4.3 Atomic Ti0.87O2 與Compact TiO2 之鈣鈦礦太陽能電池元件表現 ........... 70 4.4 Atomic Ti0.87O2 及Compact TiO2 電子傳輸層之電子轉移能力測量 ...... 76 4.5 Atomic Ti0.87O2 及Compact TiO2 元件表現穩定性量測及分析 ................ 79 第5 章 結論.......................................................................................................... 85 第6 章 未來展望.................................................................................................. 86 第7 章 參考資料.................................................................................................. 87 | |
dc.language.iso | zh-TW | |
dc.title | 利用原子級厚度二氧化鈦金屬氧化物作為鈣鈦礦電池之電子傳輸層 | zh_TW |
dc.title | Atomically thin metal oxide Titania as electron
transporting layer for Perovskite Solar Cells | en |
dc.type | Thesis | |
dc.date.schoolyear | 105-1 | |
dc.description.degree | 碩士 | |
dc.contributor.oralexamcommittee | 溫政彥(CHENG-YEN WEN),邱雅萍(YA-PING CHIU) | |
dc.subject.keyword | 鈣鈦礦太陽能電池,CH3NH3PbIxCl3-x,原子級厚度薄膜,低溫製成,穩定性, | zh_TW |
dc.subject.keyword | Perovskite solar cells,CH3NH3PbIxCl3-x,atomically thin layer,low temper process,stability, | en |
dc.relation.page | 91 | |
dc.identifier.doi | 10.6342/NTU201603616 | |
dc.rights.note | 有償授權 | |
dc.date.accepted | 2016-09-29 | |
dc.contributor.author-college | 工學院 | zh_TW |
dc.contributor.author-dept | 材料科學與工程學研究所 | zh_TW |
顯示於系所單位: | 材料科學與工程學系 |
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