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完整後設資料紀錄
DC 欄位 | 值 | 語言 |
---|---|---|
dc.contributor.advisor | 駱尚廉(Shang-Lien Lo) | |
dc.contributor.author | Ying-Chu Chen | en |
dc.contributor.author | 陳映竹 | zh_TW |
dc.date.accessioned | 2021-06-15T06:56:02Z | - |
dc.date.available | 2015-01-25 | |
dc.date.copyright | 2011-02-20 | |
dc.date.issued | 2011 | |
dc.date.submitted | 2011-02-09 | |
dc.identifier.citation | 安會琴、朱寶林、吳紅豔、張明、王淑榮、張守民、吳世準、黃唯平,2008,鈦酸鹽奈米管與二硫化碳修飾鈦酸鹽奈米管的合成、表面及其去除重金屬離子性能,高等學校化學學報。
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dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/48418 | - |
dc.description.abstract | 氧化鈦奈米管為近年新興之奈米材料,其具有高比表面積、優良吸附與光催化能力,而被廣泛應用於各領域研究中。以微波水熱法可於三小時內製備完成氧化鈦奈米管,其較傳統水熱法以更短的時間、更省的能源以及更簡潔的程序製成,且保有其吸附與光催化效能。
以微波水熱法製備之氧化鈦奈米管主要是由鈉、鈦、氧以及氫原子所構成,其化學結構式主要可歸為NaxH2-xTi3O7類型。氧化鈦奈米管表面之鈉原子含量受製備時所注入之微波功率影響甚大,隨微波功率之增加而使表面更多鈉原子嵌入管壁,且鈉原子可藉由離子交換機制與污染物反應,進而使污染物穩固吸附於管壁。氧化鈦奈米管管壁之鈦原子則於其吸附或光催化反應中皆未有明顯作用或變化。 本研究以微波水熱法製備氧化鈦奈米管,探討其吸附與光催化潛勢,包括對重金屬鉛離子之吸附潛勢鑑定、對全氟辛酸之光催化潛勢鑑定,以及同時添加半導體硫化鎘與氧化鈦奈米管光催化水中氨氮之研究,最後則探討氧化鈦奈米管之表面化學反應機制。 研究結果發現,氧化鈦奈米管之吸附能力比光催化能力優良。以比表面積50 m2/g之二氧化鈦於強鹼環境中以微波能輔助加熱可製備出比表面積為原材料三倍之高的氧化鈦奈米管。由於氧化鈦奈米管之高比表面積提供大量活性吸附位置,其可於短時間內完成吸附反應並達平衡,且近乎完全去除水中鉛離子,以等溫吸附模式計算可得知每克氧化鈦奈米管之最大吸附潛勢為2,000 mg Pb(II)/g。氧化鈦奈米管之等電位點約在pH值為3,提高反應環境之pH值使得氧化鈦奈米管之表面愈呈負電性,而有利於吸附重金屬陽離子;反之則有利於吸附陰離子污染物。氧化鈦奈米管雖可作為觸媒輔助光催化反應,但由於異相光催化效應促使固態氧化鈦奈米管無法於水溶液環境中提升其光催化效率,且有遮蔽效應之產生。水中氨氮與全氟辛酸兩污染物於氧化鈦奈米管之光催化反應系統下可達50%之去除效率,且觸媒之存在可提升反應途徑之完整性。 | zh_TW |
dc.description.abstract | Titanate nanotubes are nano-materials with special properties, such as high specific area, adsorption capacity and strong photocatalytic capability; and they have been widely studied for applications in various fields recently. Titanate nanotubes can be synthesized within three hours by a microwave hydrothermal method, which is simpler and more time and energy efficient than conventional hydrothermal methods. This study aimed at evaluating the adsorption capacity and photocatalytic capability of titanate nanotubes, made by the microwave hydrothermal method, in removing some common pollutants from aqueous media, and exploring the reaction mechanisms.
Titanate nanotubes synthesized by a microwave hydrothermal method are mainly consist of sodium, titanium, oxygen, and hydrogen atoms, and their chemical structure can be represented as NaxH2-xTi3O7. The sodium content on the surfaces of titanate nanotubes was increased with irradiation power; this phenomenon could be attributed to the intercalation of sodium atoms in the TNT nanostructure which enlarges the space between inter-layers. The sodium ions on the surfaces can exchange with target ions, as well as be adsorbed onto the inner and outer surfaces of titanate nanotubes. However, the titanium ions on the surfaces of titanate nanotubes had minor effects on their adsorption and photocatalytic reactions. Titanate tubes used in this study were synthesized from commercial titanium dioxide (Degussa P25). Lead, ammonia, and perfluorooctanoic acid (PFOA) were chosen as the target polluants. The research firstly evaluated the removal of lead ions from water by titanate nanotubes through adsorption. It then evaluated their photocatalyic capability in reducing concentrations of ammonia nitrogen and perfluorooctanoic acid in aqueous solutions. For the case of ammonia removal, the nanotubes were combined with cadmium sulfide to enhance their photocatalytic capacity. Effects were also made to discuss plausible mechanisms for the adsorption and photocatalyitc reactions. The experimental results indicate that these titanate nanotubes are good adsorbents. Titanate nanotubes synthesized by the microwave hydrothermal method have specific surface area three times larger than that of Degussa P25 (50 m2/g). Due to their high specific surface areas, they could remove almost 100% of lead ions from water through adsorption and the reaction was fast and reached equilibrium within 30 minutes. The maximum adsorption capacity was found to be 2,000 mg Pb(II)/g of titanate nanotubes. The pHZPC of titanate nanotubes is around 3, thus they are more favorable in adsorbing cations under higher pH values and in adsorbing anions under acidic conditions. Although titanate nanotubes could be catalysts in photocatalytic removal of pollutants, they were not effective as expected. It might be caused by the fact that these reactions were heterogeneous in nature and the shielding effects caused by the porous structure of the nanotubes. About half of ammonia nitrogen and perfluorooctanoic acids in aqueous solutions could be removed by titanate nanotubes under UV irradiation, and the presence of the nanotubes as photocatalysts could enhance the completeness of the reactions. | en |
dc.description.provenance | Made available in DSpace on 2021-06-15T06:56:02Z (GMT). No. of bitstreams: 1 ntu-100-F95541210-1.pdf: 4813928 bytes, checksum: a8777f1d27d45cbc2a0ea3d1eb372af7 (MD5) Previous issue date: 2011 | en |
dc.description.tableofcontents | 中文摘要 I
英文摘要 III 目錄 VII 圖目錄 XI 表目錄 XIII 第一章 緒論 1 1-1研究緣起 1 1-2研究目的與內容 2 第二章 文獻回顧 5 2-1重金屬鉛離子、氨氮以及全氟辛酸對環境之污染與危害 5 2-1-1重金屬鉛離子 5 2-1-2全氟辛酸 8 2-1-3氨氮 11 2-2降解環境污染技術之回顧 14 2-2-1吸附技術 14 2-2-2光催化技術 22 2-3氧化鈦奈米管之製備技術 33 2-3-1微波理論 33 2-3-2水熱法製備氧化鈦奈米管之技術 35 2-3-3氧化鈦奈米管之形成機制 37 第三章 實驗材料與方法 39 3-1研究架構與內容 39 3-2 材料製備方法 41 3-2-1氧化鈦奈米管之製備 41 3-2-2硫化鎘之製備 42 3-3反應實驗 43 3-3-1反應動力學 43 3-3-2等溫吸附曲線 44 3-3-3擬一階反應動力曲線 45 3-3-4光催化技術 46 3-4產物分析 47 3-4-1火焰式原子吸收光譜儀與感應耦合電漿原子發射光譜儀 47 3-4-2高效能液相層析儀 49 3-4-3離子層析儀 50 3-4-4氨電極 51 3-5材料表面之特性鑑定 52 3-5-1比表面積測定-比表面積與孔洞分析儀 52 3-5-2表面形貌鑑定-電子顯微鏡 53 3-5-3表面化學元素分析-化學分析電子能譜儀 54 3-5-4能隙測定-紫外光/可見光光譜儀 55 3-5-5表面化學結構分析-拉曼光譜儀與傅立葉紅外線光譜儀 56 第四章 結果與討論 59 4-1氧化鈦奈米管之結構鑑定 59 4-2氧化鈦奈米管吸附效率之探討 64 4-2-1重金屬鉛離子 64 4-2-2吸附反應機制 74 4-3氧化鈦奈米管光催化效率之探討 79 4-3-1氨氮 79 4-3-2全氟辛酸 93 4-3-3光催化反應機制 106 第五章 結論與建議 109 參考文獻 111 附錄 129 | |
dc.language.iso | zh-TW | |
dc.title | 以微波水熱法合成氧化鈦奈米管之吸附與光催化潛勢研究 | zh_TW |
dc.title | Titanate Nanotubes Synthesized by a Microwave Hydrothermal Method: Study on Their Adsorption and Photocatalytic Potential | en |
dc.type | Thesis | |
dc.date.schoolyear | 99-1 | |
dc.description.degree | 博士 | |
dc.contributor.oralexamcommittee | 顧洋(Young Ku),吳先琪(Shian-Chee Wu),施養信(Yang-Hsin Shih),黃志彬(Chih-Pin Huang) | |
dc.subject.keyword | 光催化,全氟辛酸,吸附,氨氮,氧化鈦奈米管,鉛離子,微波水熱法, | zh_TW |
dc.subject.keyword | photocatalysis,perfluorooctanoic acid,adsorption,ammonia nitrogen,titanate nanotubes,lead ions,microwave hydrothermal method, | en |
dc.relation.page | 135 | |
dc.rights.note | 有償授權 | |
dc.date.accepted | 2011-02-09 | |
dc.contributor.author-college | 工學院 | zh_TW |
dc.contributor.author-dept | 環境工程學研究所 | zh_TW |
顯示於系所單位: | 環境工程學研究所 |
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