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| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 馬鴻文(Hwong-Wen Ma) | |
| dc.contributor.author | Ting-Chieh Lin | en |
| dc.contributor.author | 林鼎傑 | zh_TW |
| dc.date.accessioned | 2021-06-15T05:43:04Z | - |
| dc.date.available | 2011-05-20 | |
| dc.date.copyright | 2010-08-20 | |
| dc.date.issued | 2010 | |
| dc.date.submitted | 2010-08-19 | |
| dc.identifier.citation | 一.西文文獻
1.APME, 1990-2003. Boustead, I.: ECO-PROFILES of the European plastics industry. 2.Boustead I, 1997. Life Cycle Assessment – The Logical Approach to Decision Making 3.Clift et al., 2000. Relationships Between Environmental Impacts and Added Value Along the Supply Chain 4.European Commission, 2000. GREEN PAPER Environmental issues of PVC 5.European Commission, July 2004. Life Cycle Assessment of PVC and of principal competing materials 6.Global Footprint Network, 2008. Global Footprint Network 2008 Report 7.Global Footprint Network, 2009. Ecological Footprint Standards 2009 8.Goeminne et al., 2009. The concept of ecological debt: some steps towards an enriched sustainability paradigm 9.Go ̈ ran Finnveden et al., 2009. Recent developments in Life Cycle Assessment 10.G. Rebitzer et al., 2003. Life cycle assessment Part 1: Framework, goal and scope definition, inventory analysis, and applications 11.Green Peace et al., 2003. PVC-Free Future: A Review of Restrictions and PVC free Policies Worldwide 12.ICIS, 2010. China may step up PVC exports as overcapacity looms 13.IEA, 2009. Chemical and PetroChemical Sector-Potential of best practice technology and other measures for improving energy efficiency. P48 14.IPP, 2003. COMMUNICATION FROM THE COMMISSION TO THE COUNCIL AND THE EUROPEAN PARLIAMENT: Integrated Product Policy - Building on Environmental Life cycle Thinking, 18.03.2003. 15.Itsubo et al., 2006. Development of LIME2 -Updated Comprehensive Japanese LCIA Methodology-, pp.165-166. 16.Møller, S. et al., 1995, Environmental Aspects of PVC. Danish Environmental Protection Agency, Copenhagen 17.O' Neill et al., 2003. Life Cycle Assessment and Environmental Impact of Plastic Products[BOOK] 18.Peereboom, et al., 1999. Influence of Inventory Data Sets on Life-CycleAssessment Results: A Case Study on PVC 19.Pennington et al.,2004. LCA Part 2: Current impact assessment practice, p735 20.Popova et al., 1973. Health status of workers exposed to phthalate plasticizers in the manufacture of artificial leather and films based on PVC resins, in Environmental Health Perspective 21.PRé Consultant, 2006. SimaPro7 Demo manual, p16 22.PRé Consultants, 2010. What is new in software and database update 7.2.0 23.ReCiPe, 2008. Report I: Characterisation, First Edition. 24.Ren et al., 2005. Olefins from conventional and heavy feedstocks: Energy use in steam cracking and alternative processes 25.SRI Consulting, 2009. PVC Resins 26.Steinberger et al., 2009. A spatially explicit life cycle inventory of the global textile chain. 27.Tan et al., 2004. An LCA study of a primary aluminum supply chain. 28.Tukker et al., 2006. The Oslo declaration on sustainable consumption. Journal of Industrial Ecology 10, 9–14. 29.Washington Toxics Coalition, ANTI-VINYL, -PBT AND -DIOXIN ADOPTED ACROSS .AMERICA AND AROUND THE WORLD REPORT 30.Wiedmann et al., 2006, Examining the global environmental impact of regional consumption activities — Part 2: Review of input–output models for the assessment of environmental impacts embodied in trade 31.Wiedmann et al., 2009, A review of recent multi-region input–output models used for consumption-based emission and resource accounting 32.WWF, 2008. Living Planet Report 2008. 33.UN, 1997. Kyoto Protocol 二.中文文獻 1.經濟部技術處,2008。2008-09高分子產業年鑑 2.經濟部技術處,2009。2009-10石化產業年鑑 3.中興工程,2009。固定污染源毒性空氣污染物( 戴奧辛及重金屬) 管制規 範研擬、控制技術評估及排放清冊調查計畫,行政院環保署 4.經濟部,2008。工業生產統計年報 5.工業局,2010。石化產業政策環評初稿 6.台塑石化公司,2010。六輕五期計畫環境影響說明書 7.台綜院,2007。「能源產業溫室氣體盤查與認證、驗證推動」,能源局委辦計畫 8.台灣中油股份有限公司,2007。台灣中油股份有限公司三輕更新擴產計畫 9.國光石化科技股份有限公司,2009。國光石化科技公司建廠計畫環境影響說明書 10.國光石化科技股份有限公司,2010。彰化縣西南角(大城)海埔地工業區計畫環境影響評估報告書 11.雲林縣環保局,2008。加強離島工業區空氣污染物整合執行計畫 12.經濟部能源局,2008。97年能源平衡表-油當量 13.經濟部能源局,2008。2008年石油產品供給表 14.經濟部礦物局,2008。主要礦產品產銷年報 15.鄭尊仁,2004。聚氯乙烯工人慢性肝危害與基因多形性相關研究 16.環保署,空氣污染排放清冊(Taiwan Emission Data System, TEDS 7.0) 17.環保署,2006-2008。石化產業水污染排放申報資料 三.網站資訊: 1.IEA, 2007. Statistics & Balances: http://www.iea.org/stats/index.asp 2.The Center for Health, Environment & Justice: http://www.chej.org/ 3. US EPA, Speciate 4.2 Database: http://cfpub.epa.gov/si/speciate/index.cfm 4. 財政部關稅總局-進出口資料庫: http://web.customs.gov.tw/statistic/statistic/mnhStatistic.asp 5. 經濟部技術處-產銷存資料庫: http://itisweb2.itis.org.tw/itispss/itispss_start.aspx 6. 環保署-環保新聞查詢: http://ivy5.epa.gov.tw/enews/fact_index.asp | |
| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/46904 | - |
| dc.description.abstract | 我國為全球PVC主要生產與出口國之一,為了釐清因國內PVC使用或外銷需求所衍生之跨國環境債問題,本研究針對PVC跨國生產鏈之各主要原料供應國進行生命週期盤查,並搭配產量進行境內與境外排放之分配,再藉由生命週期衝擊評估模式分析境內與境外之衝擊型態。另一方面為了瞭解上游製程更新對國產PVC之整體環境效益,本研究選擇電力與乙烯生產這兩個主要衝擊熱點,進行CHP技術更新與乙烯能源效率提升之衝擊減量效果分析。
2008年,國產PVC產量約138萬噸,其中直接出口約79萬噸。剩下用於國內生產下游產品之59萬噸PVC中,又有約10萬噸出口至其他國家,剩下49萬噸為實際之國內PVC需求。故國產PVC與其下游產品於國內使用之比例為35%,國外使用之比例為 65%。 根據基線年之評估結果,國產PVC總共造成11700 DALYs的人體健康損害與5.12物種×年之生態系損害。其中人體健康損害貢獻度依序為電力需求(48%)、其他能源使用(23%)、乙烯生產(15%)、原油開採(11%)等,而生態系損害之趨勢亦雷同。若以衝擊類別而言,氣候變遷為人體健康損害之主要來源(77%),其次為懸浮微粒生成(13%)與人體毒性(10%)。故以製程而言,電力、其他能源與乙烯生產過程為國產PVC之環境熱點。在汙染物方面,溫室氣體為主要貢獻源,而國內排放佔了91%,其中又以境內電力所貢獻之50%為首。 在技術更新的部分,衝擊減量效果最顯著者為國內製程之CHP更新(未包含乙烯製程),其在人體健康與生態系損害方面分別較基線年降低15%與10%。其次依序為中油輕裂廠CHP更新(人體健康減7%、生態系減8%)、中油輕裂廠製程更新(人體健康減4%、生態系減5%)、台塑輕裂廠CHP更新(人體健康減3%、生態系減4%)。若四種技術更新情境同時實行,將產生3413個DALYs的健康效益(減量 29%)與 13.64物種×年之生態效益(減量27%)。 結合境內外衝擊分析與國產PVC流向後,可將我國PVC環境債區分為以下三類(1)境內衝擊-國內使用:台灣每年承受474個DALYs之健康損失與0.04個物種×年之生態損害以生產PVC供國內使用。(2)境內衝擊-國外使用(台灣為債權國):台灣每年承受880個DALYs之健康損失與0.075個物種×年之生態損害以生產PVC供他國使用。(3)境外衝擊-國內使用(台灣為債務國):國外每年承受439個DALYs之健康損失與0.009個物種×年之生態損害以生產PVC上游原物料供台灣生產PVC自用。值得注意的是,全球共同承受之全球尺度衝擊雖無法區分為境內或境外,但其損害量大幅超越區域性衝擊,達到8596個DALYs與48.686物種×年。 | zh_TW |
| dc.description.abstract | Taiwan is one of the main PVC producer and exporter in the world. In order to inspect the ecological debt of Taiwan made PVC induced by multi-national supply chain and consumption location, this research collects the inventory data from main supply contries of Taiwan-made PVC (cradle to gate) and allocates the domestic/overseas emissions by the ratio of Taiwan-made or imported raw materials. Via the combination of life cycle impact assessment, we could then evaluate the traits of domestic/overseas environmental impacts of Taiwan-made PVC quantitatively. In addition, with the purpose to understand the impact reduction potential via process renewal, electricity & ethylene production were choosen to set several policy scenarios as they are the main impact contributors (hotspots) during the PVC manufacturing process in Taiwan.
In 2008, Taiwan produced 1.38 Mt of PVC, among which 0.79 Mt were directly exported. In the remaining 0.59 Mt of PVC, 0.1 Mt were processed into final products and exported, the other 0.49Mt were the actual PVC demand in Taiwan. Overall, 35% of Taiwan made PVC were used domestically, and 65% of PVC were for exporting purpose. Based on the LCIA result of baseline year, Taiwan-made PVC contributed 11700 DALYs of human health damage & 5.12 species loss of ecological damage in 2008. Where electricity consumption(48%), other energy consumption(23%), ethylene production(15%), crude oil extraction(11%) are the main contributors in human health damage, where the trends in ecological damage is consistent with human health damage. In terms of human health damage contributions from each impact category, climate change stands for the highest impact(77%), followed by particulate matter formation(13%) and human toxicity(10%). Furthermore, the main substances responsible for environmental damages of PVC measured from cradle to gate are green house gases, in which 91% emitted domestically and mainly from electric generation. Regarding to the reduction potential of process renewal , CHP renewal from domestic processes (exclude ethylene production) is most prominent with a reduction potential of 15% in human health & 10% in ecological damage compared to baseline. Followed by CPC cracker’s CHP renewal (7% in human health, 8% in ecological damage), CPC cracker renewal (4% in human health, 5% in ecological damage), Formosa cracker’s CHP renewal (3% in human health, 4% in ecological damage). Collectively bring forth to a reduction of 3413 DALYs (29% reduction) and 13.64 species loss (27% reduction). By integrating domestic/overseas impact assessment and PVC flow analysis, we can then divide the ecological debt into three categories: (1)Domestic impact-Domestic consumption: Taiwan bears 474 DALYs & 0.04 species loss to produce PVC for domestic use (2)Domestic impact-Overseas consumption: Taiwan bears 880 DALYs & & 0.075 species loss to produce PVC for overseas use (3)Overseas impact-Domestic consumption: Other foreign countries bear 439 DALYs & 0.009 species loss to produce raw materials for Taiwan-made PVC which consumpted domestically. Be worthy of note, global scale impacts like climate change cannot be divided into domestic/overseas impacts, but actually predominant the total human health or ecological damage, reaching 8596 DALYs & 48.686 species loss in baseline year. | en |
| dc.description.provenance | Made available in DSpace on 2021-06-15T05:43:04Z (GMT). No. of bitstreams: 1 ntu-99-R97541209-1.pdf: 2073461 bytes, checksum: b71aef7b26d64b0bc59a92583b784d66 (MD5) Previous issue date: 2010 | en |
| dc.description.tableofcontents | 摘要 i
Abstract iii 總目錄 v 圖目錄 viii 表目錄 xi 第一章 緒論 1 1.1研究緣起 1 1.2 研究目的與流程 3 第二章 文獻回顧 5 2.1 PVC產業現況及其環境影響 5 2.1.1 PVC製程與全球產業現況 5 2.1.2 台灣PVC產業現況 9 2.1.3 PVC之環境考量與各國管理政策 11 2.2 LCA應用於PVC環境衝擊分析 15 2.2.1 LCA簡介 15 2.2.2 LCA於PVC之應用 18 2.3 環境/生態債分析方法 23 2.3.1 環境/生態債基本概念 23 2.3.2分析方法 25 第三章 研究方法 31 3.1目標與範疇界定 33 3.2生命週期盤查 35 3.2.1盤查-乙烯生產 40 3.2.2 盤查-氯乙烯製程 43 3.2.3 盤查-電力 44 3.3 環境衝擊評估方法 47 3.4 環境債分析概念 49 3.5境內與境外衝擊 51 3.5.1程序樹之區分 54 3.5.2 境內外排放之評估工具 59 3.6 PVC使用地點區分 60 3.7 具空間特殊性之盤查方法比較 63 第四章 結果與討論 65 4.1 PVC基線年之生命週期評估 66 4.1.1 環境熱點分析 69 4.1.2 按製程、電力、其他能源分類 71 4.1.3 各製程之衝擊評估結果 73 4.2 技術更新之環境效益 80 4.2.1不同CHP技術之比較 81 4.2.2 CHP技術更新-輕裂廠 85 4.2.3 CHP技術更新-其他國內製程 89 4.2.4 不同輕油裂解程序之比較 93 4.2.5乙烯能源效率提升 97 4.2.6 技術更新情境比較 100 4.3 環境債分析 102 4.3.1 境內境外衝擊比較 102 4.3.2 PVC與其產品之國內外使用比例 108 4.3.3 國產PVC之環境債分析 111 第五章 結論與建議 113 5.1 結論 113 5.2 建議 115 參考文獻 116 附錄一 台灣輕油裂解廠製程排放係數(不包含電力耗用) 121 附錄二 台灣輕油裂解廠CHP排放係數 122 附錄三 台灣PVC上游原料進出口資料與投入下游產品之國產比例 123 附錄四 區分境內/境外衝擊之製程的電力投入資料 124 | |
| dc.language.iso | zh-TW | |
| dc.subject | LCA | zh_TW |
| dc.subject | 汽電共生廠 | zh_TW |
| dc.subject | 輕油裂解廠 | zh_TW |
| dc.subject | 供應鏈 | zh_TW |
| dc.subject | 生產鏈 | zh_TW |
| dc.subject | 氯乙烯 | zh_TW |
| dc.subject | PVC | zh_TW |
| dc.subject | 生態債 | zh_TW |
| dc.subject | 環境債 | zh_TW |
| dc.subject | Ecological Debt | zh_TW |
| dc.subject | TRACi | zh_TW |
| dc.subject | 空間特性生命週期盤查 | zh_TW |
| dc.subject | Spatial LCI | zh_TW |
| dc.subject | 生命週期評估 | zh_TW |
| dc.subject | Steam Cracker | en |
| dc.subject | PVC | en |
| dc.subject | Ecological Debt | en |
| dc.subject | Life Cycle Assessment (LCA) | en |
| dc.subject | spatial LCI | en |
| dc.subject | TRACi Environmental | en |
| dc.subject | Supply Chain | en |
| dc.subject | CHP | en |
| dc.title | 應用空間特殊性生命週期評估於台灣PVC供應鏈之環境衝擊與環境債分析 | zh_TW |
| dc.title | Analyzing the Ecological Debt and Environmental Impact of Taiwan-Made PVC with Spatially Explicit Life Cycle Assessment | en |
| dc.type | Thesis | |
| dc.date.schoolyear | 98-2 | |
| dc.description.degree | 碩士 | |
| dc.contributor.oralexamcommittee | 李公哲(Kung-Cheh Li),洪明龍(Ming-Lung Hung) | |
| dc.subject.keyword | LCA,生命週期評估,Spatial LCI,空間特性生命週期盤查,TRACi,Ecological Debt,環境債,生態債,PVC,氯乙烯,生產鏈,供應鏈,輕油裂解廠,汽電共生廠, | zh_TW |
| dc.subject.keyword | PVC,Ecological Debt,Life Cycle Assessment (LCA),spatial LCI,TRACi Environmental,Supply Chain,Steam Cracker,CHP, | en |
| dc.relation.page | 124 | |
| dc.rights.note | 有償授權 | |
| dc.date.accepted | 2010-08-20 | |
| dc.contributor.author-college | 工學院 | zh_TW |
| dc.contributor.author-dept | 環境工程學研究所 | zh_TW |
| 顯示於系所單位: | 環境工程學研究所 | |
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