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完整後設資料紀錄
DC 欄位 | 值 | 語言 |
---|---|---|
dc.contributor.advisor | 黃孝平 | |
dc.contributor.author | Yuan-Lin Lin | en |
dc.contributor.author | 林媛翎 | zh_TW |
dc.date.accessioned | 2021-06-15T05:05:53Z | - |
dc.date.available | 2010-07-27 | |
dc.date.copyright | 2010-07-27 | |
dc.date.issued | 2010 | |
dc.date.submitted | 2010-07-26 | |
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Ind. Eng. Chem. Res., 2007. 46(4): p. 1099-1104. [53] Sundmacher, K. and A. Kienle, Reactive Distillation : Status and Future Directions, in K. Sundmacher and A. Kienle, Editors. 2002, Wiley-VCH Verlag GmbH & Co. KGaA. [54] Takamatsu, Y. and T. Kaneshima, 'Process for the Preparation of Cyclohexanol', U.S. Patent 6552235 B2. Apr. 22, 2003 | |
dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/46373 | - |
dc.description.abstract | 環己醇為目前高分子工業中大量被用做製造尼龍前驅物之原料,但現今工業使用之製程大部分有其安全性缺點,日本Asahi公司使用之一步水合反應製程雖改善安全性,但卻遭遇反應速率低之問題,且多操作單元步驟也使得經濟效益較低。本研究將以Asahi製程之一步水合反應整合至反應蒸餾系統為主題,探討熱力學性質對於該系統之影響,其中汽液液分相之三相共存為本系統之特點,並提出含雜質與不含雜質進料之反應蒸餾塔架構組態,針對最佳化設計找到合適的動態控制架構。第二部分為研究Steyer等人於2007年提出之兩步反應生產環己醇程序,並以Katariya等人於2009年提出之兩步反應系統架構為基礎,探討各設計變數於系統之影響;最後將討論整合性架構之可行性,其為包含兩反應段之單一反應蒸餾塔,此為首次提出之架構概念。 | zh_TW |
dc.description.abstract | In the industrial market, Nylon 6, 6 is an important product and its production rate has reached 1.1 million tons per year by 1999. On the other hand, cyclohexanol has been used as a precursor in the synthesis of intermediates of Nylon 6, 6, i.e. the adipic acid and ε-caprolactam. An “Asahi process” to produce cyclohexanol from benzene by consecutive hydrogenation and one-step hydration steps has been commercialized since 1986. However, the one-step hydration step suffering from very low reaction rate and conversion is the bottleneck in the process. As a result, it is desirable to enhance this hydration step for better production. In this thesis, it is aimed to study the design and control of such a hydration step by employing reactive distillation. Moreover, the possibility of using reactive distillation in alternative two-step reactions is also studied in this thesis and a novel configuration, a two reaction zone in one reactive distillation column, is proposed. | en |
dc.description.provenance | Made available in DSpace on 2021-06-15T05:05:53Z (GMT). No. of bitstreams: 1 ntu-99-R97524019-1.pdf: 1154433 bytes, checksum: addd70ac2e16eba3ce52f4072071edde (MD5) Previous issue date: 2010 | en |
dc.description.tableofcontents | 致謝 I
摘要 III Abstract V 目錄 VII 圖目錄 IX 表目錄 XI 1 緒論 1 1.1 前言 1 1.2 文獻回顧 3 1.3 研究動機 6 1.4 組織架構 7 2 動力學及熱力學 8 2.1 前言 8 2.2 動力學模式 9 2.3 熱力學模式 13 2.3.1 系統使用之熱力學模式 13 2.3.2 一步水合反應熱力學性質探討 17 2.3.3 兩步反應熱力學性質探討 19 3 一步水合反應穩態設計 25 3.1 前言 25 3.2 最適化方法 27 3.3 不含雜質進料架構設計 30 3.3.1 設計概念 30 3.3.2 設計結果 33 3.4 含雜質之進料架構設計 37 3.4.1 i-1設計概念 38 3.4.2 i-2設計概念 39 3.4.3 i-1架構最適化模擬結果 41 3.4.4 i-2架構最適化模擬結果 42 3.5 結論 44 4 一步水合反應動態控制架構設計 46 4.1 前言 46 4.2 控制環路設計 46 4.3 控制架構探討 48 4.3.1 控制架構分類(CS1~CS3) 48 4.3.2 系統所承受之干擾 49 4.3.3 開環路溫度靈敏度測試分析方法 49 4.3.4 RGA配對分析 49 4.3.5 控制器參數調諧方法 50 4.4 i-1程序之控制架構探討 52 4.4.1 (i-1)-CS1單點溫度控制動態模擬結果 53 4.4.2 (i-1)-CS2雙點溫度控制動態模擬結果 56 4.4.3 (i-1)-CS3雙點溫度控制動態模擬結果 59 4.5 i-2程序之控制架構探討 62 4.5.1 (i-2)-CS2雙點溫度控制動態模擬結果 63 4.5.2 (i-2)-CS3雙點溫度控制動態模擬結果 66 4.6 開環路濃度控制擾動測試 69 4.7 控制架構比較分析 71 5 兩步反應穩態設計分析 73 5.1 前言 73 5.2 酯化塔穩態設計 74 5.2.1 酯化塔穩態設計概念 74 5.2.2 酯化塔穩態設計結果 76 5.3 水解塔穩態設計 78 5.3.1 水解塔穩態設計概念 78 5.3.2 水解塔設計結果 79 5.3.3 水解塔其餘組態探討 86 5.4 整合至單一塔之可能性探討 88 5.4.1 整合塔之設計概念 88 5.4.2 整合塔之模擬結果 89 5.4.3 整合塔其他架構探討 91 5.5 結果與分析 93 6 結論 94 參考文獻 96 附錄 102 A 年總成本計算公式 102 B 庫存環路控制器參數 104 作者簡介 106 | |
dc.language.iso | zh-TW | |
dc.title | 非均相反應性蒸餾系統應用於環己醇製程之設計與控制 | zh_TW |
dc.title | Design and Control of Heterogeneous Reactive Distillation Process for Cyclohexanol Synthesis | en |
dc.type | Thesis | |
dc.date.schoolyear | 98-2 | |
dc.description.degree | 碩士 | |
dc.contributor.oralexamcommittee | 鄭西顯,錢義隆,陳誠亮 | |
dc.subject.keyword | 反應性蒸餾系統,最佳化設計,動態控制,環己醇,非均相, | zh_TW |
dc.subject.keyword | reactive distillation,design,process control,cyclohexanol,heterogeneous, | en |
dc.relation.page | 106 | |
dc.rights.note | 有償授權 | |
dc.date.accepted | 2010-07-27 | |
dc.contributor.author-college | 工學院 | zh_TW |
dc.contributor.author-dept | 化學工程學研究所 | zh_TW |
顯示於系所單位: | 化學工程學系 |
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