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完整後設資料紀錄
DC 欄位 | 值 | 語言 |
---|---|---|
dc.contributor.advisor | 張慶源 | |
dc.contributor.author | Ru-Shiou Peng | en |
dc.contributor.author | 彭如秀 | zh_TW |
dc.date.accessioned | 2021-06-15T05:04:27Z | - |
dc.date.available | 2012-07-28 | |
dc.date.copyright | 2010-07-28 | |
dc.date.issued | 2010 | |
dc.date.submitted | 2010-07-26 | |
dc.identifier.citation | Adhoum, N. and L. Monser, Removal of phthalate on modified activated carbon: application to the treatment of industrial wastewater. Sep. Purif. Technol., 38(3), 233-239 (2004).
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dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/46341 | - |
dc.description.abstract | 本研究內容以電化學氧化程序(electrochemical oxidation process, EC)為基礎,並結合臭氧程序(electrochemical ozonation, EC/OZ)、光化學(photo electrochemical oxidation, EC/UV)及光電化學臭氧化程序(photo electrochemical ozonation, EC/OZ/UV)等高級氧化程序(advanced oxidation processes, AOPs)處理dimethyl phthalate (DMP)之研究。探討不同電壓(EV)、pH值及臭氧濃度(CO3, in)等參數對DMP分解效率(ηDMP)與總有機碳(total organic carbons, TOCs)去除率(ηTOC)之影響。
研究結果顯示,以EC程序處理DMP,EV = 4 volts (V),反應時間(t)達80 min後,ηDMP = 8%,但僅將其分解形成其他有機副產物,無法將之礦化。使用EC/UV程序處理DMP於EV = 4 V, PUV = 100 Watts(W), t = 80 min時,其ηDMP及ηTOC分別為47.5及11.5%,較UV程序之30.4及5.7%為佳。提供CO3, in為10 mg L-1的O3及EV = 4 V,以EC/OZ程序處理DMP,於t = 80 min,其ηDMP及ηTOC分別可達94.4%及4.2%。若固定EV = 4 V,將CO3, in由10增加為16 mg L-1時,於t = 80 min時,ηDMP可提升至99%,且ηTOC可提高為30%。而EC/UV/OZ程序處理DMP,當EV = 4 V、PUV = 100 W及CO3, in = 10 mg L-1之條件下在60 min內,即可完全分解DMP,當t = 80 min後,ηTOC可達62.7%。若將CO3, in增加到30 mg L-1時,在t = 80 min後,其ηTOC可提升至88.3%。 | zh_TW |
dc.description.abstract | This study investigated the treatment of dimethyl phthalate (DMP) via various oxidation proesses such as 1) electrochemical oxidation (EC), 2) ozonation (OZ) with EC (EC/OZ), 3) ultraviolet (UV) with EC (EC/UV) and 4) photo ozonation with EC (EC/OZ/UV). The efficiencies of decomposition of DMP (ηDMP) and mineralization of total organic carbons (ηTOC) were evaluated under different operation voltages, pH values and concentrations of applied ozone (CO3, in).
The results showed that ηDMP is about 8% at reaction time (t) of 80 min, under the EC process with EV = 4 V. During the EC/UV process with EV = 4 V, PUV = 100 watts (W), the ηDMP and ηTOC are 47.5 and 11.5%, respectively. These are higher than 30.4 and 5.7% under UV process. However, the ability of oxidation in terms of ηTOC under EC process is too weak. For the EC/OZ process with EV = 4 V and CO3,in = 10 mg L-1, ηDMP and ηTOC are 94.4 and 4.2%, respectively, after t = 80 min. An increase of CO3, in from 10 to 16 mg L-1 further increases ηDMP to 99% and ηTOC to 30% after t = 80 min. As for the EC/UV/OZ process with Ev = 4 V, CO3, in = 10 mg L-1 and PUV = 100 W, the DMP was nearly completely decomposed at t = 60 min, while the ηTOC is 62.7% after t = 80 min. In case of CO3, in increased from 10 to 30 mg L-1, the value of ηTOC raises to 88.3% after t = 80 min. | en |
dc.description.provenance | Made available in DSpace on 2021-06-15T05:04:27Z (GMT). No. of bitstreams: 1 ntu-99-R97541111-1.pdf: 1356665 bytes, checksum: 5090fc1f6e2086fc0566f9f3d27fcc0a (MD5) Previous issue date: 2010 | en |
dc.description.tableofcontents | 摘要 i
Abstract ii 目錄 iii 圖目錄 vi 表目錄 x Nomenclature xii 第一章 緒論 1 1.1 研究背景 1 1.2 研究目的 2 1.3 研究內容 2 第二章 文獻回顧 5 2.1 鄰苯二甲酸二甲酯 5 2.1.1 鄰苯二甲酸酯類之來源與應用 5 2.1.2 鄰苯二甲酸酯類之相關法規 6 2.1.3 鄰苯二甲酸酯類之特性與環境流布 9 2.1.4 鄰苯二甲酸酯類之主要分解作用 10 2.1.5 鄰苯二甲酸二甲酯相關處理文獻 14 2.2 電化學氧化法 19 2.2.1 直接電解氧化 21 2.2.2 間接電解氧化 21 2.2.3 電化學於廢水處理之應用 23 2.3 臭氧之基本性質與反應機制 27 2.3.1 臭氧之物理化學特性 27 2.3.2 臭氧在水中的自解反應 30 2.3.3 臭氧與有機物的反應 34 2.4 光化學氧化法 40 2.4.1 紫外光特性 42 2.4.2 光化學反應原理 42 2.5 高級氧化之原理與反應機制 45 2.5.1 H2O2/O3程序之理論與機制 45 2.5.2 EC/O3程序之理論與機制 47 2.5.3 H2O2/UV程序之理論與機制 47 2.5.4 O3/UV程序之理論與機制 49 2.5.5 H2O2/O3/UV程序之理論與機制 49 第三章 研究方法 52 3.1 實驗設備及分析儀器 52 3.1.1 反應系統 52 3.1.2 實驗設備 53 3.1.3 分析儀器 53 3.2 實驗藥品 55 3.2.1 試劑 55 3.2.2 氣體 56 3.2.3 樣品配置 57 3.2.4 緩衝溶液配置方法 57 3.3 實驗分析項目 57 3.3.1 分析項目 57 3.3.2 分析測定方法 59 3.4 實驗架構 61 3.5 實驗步驟 62 3.5.1 背景實驗 62 3.5.2 電化學氧化實驗 62 3.5.3 光電化學氧化實驗 62 3.5.4電化學臭氧化實驗 63 3.5.5 光電化學臭氧化實驗 63 第四章 結果與討論 65 4.1 背景實驗 65 4.1.1 反應系統氣-液質量傳送實驗 65 4.1.2 電解生成過氧化氫實驗 66 4.1.3 DMP背景試驗 81 4.1.4 DMP自解實驗 83 4.2 電化學氧化分解DMP 90 4.2.1電解質之影響 90 4.2.2 電壓強度對DMP分解之影響 93 4.2.3 溶液pH值之影響 93 4.2.4 不同DMP濃度之影響 96 4.2.5 電化學氧化DMP之機制 96 4.3 光電化學氧化分解DMP 99 4.3.1直接光解DMP 99 4.3.2 間接光解DMP 102 4.3.3 電化學結合UV光氧化分解DMP 109 4.4 電化學結合臭氧分解DMP 114 4.4.1 臭氧氧化實驗 114 4.4.2 電化學結合臭氧分解DMP 122 4.5 光電化學臭氧化分解DMP 136 4.5.1溶液pH值之影響 136 4.5.2 不同臭氧濃度光電化學氧化實驗 139 4.6 綜合討論 139 4.7 DMP之分解反應機制探討 142 4.7.1 EC及UV之DMP降解反應機制 148 4.7.2 臭氧輔助EC降解DMP之反應機制 148 第五章 結論與建議 151 5.1 結論 151 5.2 建議 152 參考文獻 154 附錄A. 方法偵測極限 A-1 附錄B. Calibration Curves B-1 附錄C. Raw Data C-1 | |
dc.language.iso | zh-TW | |
dc.title | 以電化學為基礎之高級氧化程序處理鄰苯二甲酸二甲酯之研究 | zh_TW |
dc.title | Application of Combined Electrochemical and Advanced Oxidation Processes on the Treatment of Dimethyl Phthalate | en |
dc.type | Thesis | |
dc.date.schoolyear | 98-2 | |
dc.description.degree | 碩士 | |
dc.contributor.oralexamcommittee | 張奉文,邱浚祐,張瓊芬 | |
dc.subject.keyword | DMP,電解,電化學氧化,臭氧,UV,高級氧化, | zh_TW |
dc.subject.keyword | DMP,electrolysis,electrochemical oxidation,ozone,UV,AOPs, | en |
dc.relation.page | 187 | |
dc.rights.note | 有償授權 | |
dc.date.accepted | 2010-07-27 | |
dc.contributor.author-college | 工學院 | zh_TW |
dc.contributor.author-dept | 環境工程學研究所 | zh_TW |
顯示於系所單位: | 環境工程學研究所 |
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