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完整後設資料紀錄
DC 欄位 | 值 | 語言 |
---|---|---|
dc.contributor.advisor | 吳哲夫(Jeffrey D. Ward) | |
dc.contributor.author | Yu-Lung Kao | en |
dc.contributor.author | 高玉龍 | zh_TW |
dc.date.accessioned | 2021-06-15T05:04:08Z | - |
dc.date.available | 2010-07-28 | |
dc.date.copyright | 2010-07-28 | |
dc.date.issued | 2010 | |
dc.date.submitted | 2010-07-27 | |
dc.identifier.citation | [1]
Harmsen, G.J., 'Reactive distillation: The front-runner of industrial process intensification - A full review of commercial applications, research, scale-up, design and operation', Chem. Eng. Proc., 2007, 46, 774-780. [2] Robinson, C.S. and Gilliland, E.R., 'Elements of Fractional Distillation'4th edition, McGraw-Hill, 1950, New York. [3] Davidyan, A.G., V.N. Kiva, G.A. Meski, and M. Morari, 'Batch Distillation in a Column with a Middle Vessel', Chem. Eng. Sci., 1994, 49, 3033-3051. [4] Agreda, V.H., L.R. Partin, and W.H. Heise, 'High-Purity Methyl Acetate Via Reactive Distillation', Chem. Eng. Prog., 1990, 86, 40-46. [5] Cuille, P.E. and G.V. Reklaitis, 'Dynamic Simulation of Multicomponent Batch Rectification with Chemical-Reactions', Comput. Chem. Eng., 1986, 10, 389-398. [6] Ruiz, C.A., M.S. Basualdo, and N.J. Scenna, 'Reactive Distillation Dynamic Simulation', Chem. Eng. Res. Des., 1995, 73, 363-378. [7] Wajge, R.M., J.M. Wilson, J.F. Pekny, and G.V. Reklaitis, 'Investigation of numerical solution approaches to multicomponent batch distillation in packed', Ind. Eng. Chem. Res., 1997, 36, 1738-1746. [8] Mujtaba, I.M. and S. Macchietto, 'Optimal Operation of Multicomponent Batch Distillation Multiperiod Formulation and Solution', Comput. Chem. Eng., 1993, 17, 1191-1207. [9] Mujtaba, I.M. and S. Macchietto, 'Efficient optimization of batch distillation with chemical reaction using polynomial curve fitting techniques', Ind. Eng. Chem. Res., 1997, 36, 2287-2295. [10] Wajge, R.M. and G.V. Reklaitis, 'RBDOPT: a general-purpose object-oriented module for distributed campaign optimization of reactive batch distillation', Chem. Eng. J., 1999, 75, 57-68. [11] Giessler, S., S. Hasebe, and I. Hashimoto, 'Optimization aspects for reactive batch distillation', J. Chem. Eng. Jpn., 2001, 34, 312-318. [12] Guo, Z., M. Ghufran, and J.W. Lee, 'Feasible products in batch reactive distillation', AlChE J., 2003, 49, 3161-3172. [13] Guo, Z. and J.W. Lee, 'Feasible products in batch reactive extractive distillation', AlChE J., 2004, 50, 1484-1492. [14] Chin, J., J.W. Lee, and J. Choe, 'Feasible products in complex batch reactive distillation', AlChE J., 2006, 52, 1790-1805. [15] Steger, C., T. Lukacs, E. Rev, M. Meyer, and Z. Lelkes, 'A Generic Feasibility Study of Batch Reactive Distillation in Hybrid Configurations', AlChE J., 2009, 55, 1185-1199. [16] Chin, J. and J.W. Lee, 'Estimation of still trajectory for batch reactive distillation systems', Ind. Eng. Chem. Res., 2008, 47, 3930-3936. [17] Venimadhavan, G., M.F. Malone, and M.F. Doherty, 'A novel distillate policy for batch reactive distillation with application to the production of butyl acetate', Ind. Eng. Chem. Res., 1999, 38, 714-722. [18] Bruggemann, S., J. Oldenburg, P. Zhang, and W. Marquardt, 'Robust dynamic simulation of three-phase reactive batch distillation columns', Ind. Eng. Chem. Res., 2004, 43, 3672-3684. [19] Arellano-Garcia, H., I. Carmona, and G. Wozny, 'A new operation mode for reactive batch distillation in middle-vessel columns: Start-up and operation', Comput. Chem. Eng., 2008, 32, 161-169. [20] Tung, S.T. and C.C. Yu, 'Effects of relative volatility ranking to the design of reactive distillation', AlChE J., 2007, 53, 1278-1297. [21] Luyben, W.L., 'Some Practical Aspects of Optimal Batch Distillation Design', Ind. & Eng. Chem. Proc. Des. Dev., 1971, 10, 54-59. [22] Hanke, M. and P. Li, 'Simulated annealing for the optimization of batch distillation processes', Comput. Chem. Eng., 2000, 24, 1-8. | |
dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/46334 | - |
dc.description.abstract | 結合了反應蒸餾系統的優點以及批次蒸餾在操作上的彈性,批次反應蒸餾系統逐漸受到學術界及工業界的重視,成為程序強化中一重要議題。然而,過去多數研究主要探討系統上模式的建構與模擬、可行性分析、程序的設計與控制,但針對相同或不同系統,在程序設計上缺乏一系統化的整體概念性設計。 一般來說,批次蒸餾塔可依儲槽以及出料位置分為:(1)一般式批次蒸餾塔: 儲槽位於塔底,出料於塔頂;(2)逆轉式批次蒸餾塔: 儲槽位於塔頂,出料於塔底;(3)中槽式批次蒸餾塔: 儲槽置於塔的中央,出料則可於塔底以及塔頂。
Tung 與 Yu (AlChE J.,53, 1278-1297, 2007) 利用一理想反應系統來探討相對揮發度對連續式反應蒸餾系統在架構與設計上之影響,他們考慮一可逆放熱反應 A + B <=> C + D的四成份系統,將原本24 (4!) 個可能相對揮發度排序,歸納出6類。在此研究中,我們將針對這6類相對揮發度排序,探討其對3種基本批次蒸餾塔架構在設計及操作上的影響,我們以生產力因子(CAP)為目標函數,進行設計與操作的最適化,結果發現,當反應系統裡其中一產物為最輕成份時,一般式批次蒸餾塔可達到分離目標,另一方面,當反應系統裡其中一產物為最重成份時,逆轉式批次蒸餾塔可達到分離目標,而利用中槽式批次蒸餾塔,在大多數情況下可獲得更好的結果。 進一步,我們探討一種更一般性的批次蒸餾塔架構,在此架構中,儲存槽可連接於塔的任何位置,不再限制於塔的頂部、塔的中央、或是塔的底部。最後,對於每一個相對揮發度排序種類,提出一最適當的設計架構以及對應的操作策略以達到最高的生產力。 | zh_TW |
dc.description.abstract | Batch reactive distillation (BREAD) is an attractive process alternative which combines the advantages of reactive distillation and the flexibility of batch processes. There are three basic batch distillation column configurations: (1) Conventional batch distillation column (CBD): Feeds are charged at the bottom and products are taken out at the top. (2) Inverted batch distillation column (IBD): Feeds are charged at the top and products are taken out at the bottom. (3) Middle-vessel column (MVC): Feeds are charged in a middle-vessel of the column and products are withdrawn at the top and the bottom.
Tung and Yu (AlChE J., 53, 1278-1297, 2007) used an ideal system to study the effect of relative volatility ranking on the design of column configuration for continuous RD systems. A reversible reaction A+B <=> C+D is considered and constitutes a quaternary system which has 24(4!) possible rankings according to the relativity volatility among reactants and products. They further grouped these 24 possibilities into 6 (24/2!/2!) distinct categories since the two reactants and two products are interchangeable. In this work, these 6 distinct volatility rankings are applied to the 3 basic BREAD column configurations to study the effects of relative volatility ranking on BREAD process design. The process design focuses on the choice of column configuration and the optimal collection policy including when and where to collect products and off-cuts and the corresponding reflux profile. The designs are optimized based on the batch capacity (CAP) defined as the total quantity of products meeting the purity specification produced divided by the total batch time. The results indicate that if one of the reaction products is the lightest key, a CBD column can achieve the separation objective. On the other hand, if one of the reaction products is the heaviest key, an IBD column can achieve the separation objective. Moreover, a MVC with a proper collection policy shows better performances in most of the cases. Furthermore, we investigate a new column configuration: a modified MVC in which the location of the reaction vessel is not exactly in the middle of the column. We consider the general case where the reaction vessel can be connected to the column at any point. If the reaction vessel is connected all the way at the bottom, we recover the CBD process whereas if it is connected all the way at the top, we recover the IBD. Finally, for each relative volatility ranking, we propose the most suitable column configuration and the collection policy with corresponding reflux profile which give the highest CAP. | en |
dc.description.provenance | Made available in DSpace on 2021-06-15T05:04:08Z (GMT). No. of bitstreams: 1 ntu-99-R97524045-1.pdf: 1149309 bytes, checksum: a6559d2f628e99424c42906a9a05df1a (MD5) Previous issue date: 2010 | en |
dc.description.tableofcontents | 致謝 I
摘要 III Abstract V Table of Contents VII List of Figures IX List of Tables XIII 1. Introduction 1 1.1. Overview 1 1.2. Literature Review 2 1.3. Motivation 3 1.4. Thesis Organization 4 2. Boiling Ranking Classification and Ideal Reactive System Description 5 2.1. Overview 5 2.2. Reaction scheme classification 6 2.2.1. Type I : One-zone 8 2.2.2. Type II: Two-zone 8 2.2.3. Type III: Alternating 8 2.3. Ideal reactive distillation system description 9 2.3.1. System Kinetics 9 2.3.2. System Thermodynamics 10 3. Modeling and Constant Process Parameters 11 3.1. Modeling 11 3.1.1. CBD column 13 3.1.2. IBD column 14 3.1.3. MVC column 15 3.2. Constant process parameters 16 4. Optimization Problem of BREAD Process 18 4.1. Collection policy 18 4.2. BREAD Process Description 21 4.3. Operating Profile 22 4.4. Optimization Problem 23 4.5. Constant Reflux Ratio Test 25 4.6. Effect of the Number of Time Periods 29 5. Optimal Results of Basic Column Configurations for Different Relative Volatility Ranking Systems 31 5.1. Type I: One-Zone 31 5.1.1. Type Ip: LK + HK <=> LLK + HHK 31 5.1.2. Comparison of Type Ip System 43 5.2. Type II: Two-Zone 45 5.2.1. Type IIp: HK + HHK <=>LLK + LK 45 5.2.2. Type IIr: LLK + LK <=> HK + HHK 54 5.2.3. Comparison of Type II Systems 59 5.3. Type III: Alternating 61 5.3.1. Type IIIp: LK + HHK <=> LLK + HK 61 5.3.2. Type IIIr: LLK + HK <=>. LK + HHK 67 5.3.3. Comparison of Type III Systems 72 5.4. Comparison and Discussion 73 6. Optimal Results of a Modified MVC Configuration for Different Relative Volatility Ranking Systems 76 6.1. Type I: One-Zone 76 6.2. Type II: Two-Zone 77 6.3. Type III: Alternating 80 6.4. Comparison and Discussion 83 7. Conclusions 86 Nomenclature 87 Appendix A 88 References 90 | |
dc.language.iso | en | |
dc.title | 不同相對揮發度排序對批次反應性蒸餾系統設計與操作的影響 | zh_TW |
dc.title | Effect of Relative Volatility Ranking on the Design and
Operation of Batch Reactive Distillation Systems | en |
dc.type | Thesis | |
dc.date.schoolyear | 98-2 | |
dc.description.degree | 碩士 | |
dc.contributor.coadvisor | 余政靖 | |
dc.contributor.oralexamcommittee | 黃孝平(Hsiao-Ping Huang),周宜雄(Yi-Shyong Chou),王聖潔(San-Jang Wang) | |
dc.subject.keyword | 批次反應蒸餾,相對揮發度排序,程序設計,最適化,一般式批次蒸餾塔,逆轉式批次蒸餾塔,中槽式批次蒸餾塔, | zh_TW |
dc.subject.keyword | batch reactive distillation,relative volatility ranking,process design,optimization,conventional,inverted,middle-vessel, | en |
dc.relation.page | 92 | |
dc.rights.note | 有償授權 | |
dc.date.accepted | 2010-07-28 | |
dc.contributor.author-college | 工學院 | zh_TW |
dc.contributor.author-dept | 化學工程學研究所 | zh_TW |
顯示於系所單位: | 化學工程學系 |
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