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http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/46237完整後設資料紀錄
| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 何國川(Kuo-Chuan Ho) | |
| dc.contributor.author | Chia-Hui Wu | en |
| dc.contributor.author | 吳佳蕙 | zh_TW |
| dc.date.accessioned | 2021-06-15T04:59:22Z | - |
| dc.date.available | 2011-07-30 | |
| dc.date.copyright | 2010-07-30 | |
| dc.date.issued | 2010 | |
| dc.date.submitted | 2010-07-29 | |
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| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/46237 | - |
| dc.description.abstract | In this thesis, the optimization of a photoelectrochromic device (PECD) toward its electro-optical performance is discussed. This system is comprised of a poly(thiophene) derivative conducting polymer, poly(3,3,-diethyl-3,4-dihydro-2H-thieno-[3,4-b][1,4]dioxepine)(PProDOT-Et2) as the electrochromic layer, in conjuction with gel-type electrolytes.
At first, the optical performances of PECDs are comparred using the electrolyte based on succinonitrile (Electrolyte S) and poly-(vinylidene fluoridehexa- fluoropropylene) (PVDF-HFP) (Electrolyte P). Under the light illumination and short-circuit condition for darkening the device, the devices using either electrolyte spend ca. 3s for darkening and the transmittance attenuation (ΔT) is 40%. At open-circuit condition for bleaching the device, the device using Electrolyte S exhibits the bleaching time of ca. 3 min and the other one using Electrolyte P is ca. 2 min. The difference results from crystallinity degree of the electrolyte, and resulting in difference of the ionic mobility. Thus, the relationship between the crystallinity degree of the electrolyte and the response time of the device is discussed. It is found that the crystallinity degree can be suppressed by mixing the Electrolyte P and Electrolyte S. The ionic conductivity and diffusion coefficient are increased with the decreasing of crystallinity degree. So the response time of the PECD can be improved, i.e. the bleaching time is shortened to ca. 20 s. Afterward, the electro-optical performance of the PECD is attempted to improve by combining the electrochromic material, PProDOT-Et2, with Pt. We sputtered the Pt in between the interface of PProDOT-Et2 and electrolyte (electrolyte/Pt/PProDOT-Et2/conducting substrate) and in between the interface of PProDOT-Et2 and conducting substrate (electrolyte/PProDOT-Et2/ Pt/conducting substrate), respectively, to prepare the electrochromic layer in the PECD. According to the I-V characteristic of the device, the later configuration ,compared with the former, that sputters a small amount of Pt on conducting glass before the deposition of PProDOT-Et2 shows better power output result (Voc = 0.81 V, Jsc = 0.255 mA/cm2, and conversion efficiency ＝0.095%). Furthermore, it is also verified from the Scanning Electrochemical microscopy, SECM, that the later electrode provides higher electron transfer rate constant. In the last part, Br2 is added into the gel electrolyte to form Br3- ions by reacting with Br- ions, which is attempted to improve the optical response and the power output performance of the PECD. It is evidenced from the analysis of SECM that the redox reaction is occurred between the Br-/ Br3- ions and the PProDOT-Et2 conducting polymer without applying any voltage. The optical response of the PProDOT-Et2 electrochromic material is thus changed. By changing the addition amount of Br2, the optimal concentration is found at 1.0 mM Br2. It is because that the redox reaction between the redox couple and the PProDOT-Et2 approaches to equilibrium. After the optimization of this device system, the transmittance attenuation and the bleaching time is ca. 32% and ca. 30 s, respectively. This device can also supply power output with Voc = 0.74 V, Jsc = 0.339 mA/cm2, and conversion efficiency＝0.122%. | en |
| dc.description.provenance | Made available in DSpace on 2021-06-15T04:59:22Z (GMT). No. of bitstreams: 1 ntu-99-R97549021-1.pdf: 3273284 bytes, checksum: f9775f3f8f8cb02c1ca06eb4348dd5c0 (MD5) Previous issue date: 2010 | en |
| dc.description.tableofcontents | 致謝…………………………………..………..………….….…I
Abstract (中文摘要)……………..…………………….….….II Abstract (English)…………………………………….….….IV Table of Contents………………………………………..…..VII List of Tables…………………………………………….…..XI List of Figures……………………………………………….XIII Chapter 1 Introduction………………………………………………....1 1-1 Electrochromic Devices…………..…………………1 1-1-1 Classification of Electrochromic Devices....5 1-1-2 Electrochromic Materials…..……………………9 1-2 Solar Cells……………………………………………12 1-2-1 History of Solar Cells…………………………12 1-2-2 Working Principle of Dye-Sensitized Solar Cells…14 1-3 Photoelectrochromic Devices (PECD)……………………16 1-3-1 Development of PECDs……………………………………16 1-3-2 Structure and Working Principle of PECDs……………18 Chapter 2 Review and Research Motivation………………….20 2-1 Conducting Polymers………………………………………….20 2-1-1 Introduction………………………………………………..20 2-1-2 Conducting Mechanism……………………………………22 2-1-2-1 Band Theory…………………………………………...22 2-1-2-2 Conduction Mechanism of Conducting Polymers……….25 2-1-3 Polythiophene and Its Derivatives…………………...27 2-1-3-1 Characteristic of PProDOT-Et2………………………31 2-1-3-2 Applications of PProDOT-Et2 to PECD……………….33 2-2 Electrolytes………………………………………………...35 2-2-1 Succinonitrile……………………………………………35 2-2-2 Gel Electrolyte based on PVDF-HFP…………………..36 2-3 Motivation and Research Objectives……………………38 Chapter 3 Experimental…………………………………………40 3-1 Instruments………………………………………...…….40 3-2 Materials and Reagents……………………………………..41 3-3 Experimental Methods………………………………………42 3-3-1 Preparation of Conducting Glasses…………………42 3-3-2 Electrochromic Layer……………………………………42 3-3-3 Photoactive Layer………………………………………43 3-3-4 Electrolytes……………………………………………..43 3-3-5 Fabrication of PECD……………………………………45 3-4 Measurements and Analysis……………………………46 3-4-1 Measurement of Optical Properties of PECD…………46 3-4-2 Measurement of Photoelectrochemical Properties of PECD………….....................................46 3-4-3 XRD Analyses of Gel and Solid Electrolytes………47 3-4-4 EIS Analyses of Gel and Solid Electrolytes……..49 3-4-5 Measurement of Diffusion Coefficients of Gel and Solid Electrolyte...............................50 3-4-6 Scanning Electrochemical Microscopy Analysis……51 Chapter 4 Results and Discussions……………………………53 4-1 The Performances of PECDs based on Succinonitrile and PVDF-HFP….........................................53 4-2 The Effect of Crystallinity of Electrolyte…………59 4-2-1 The Ionic Conductivity and Diffusion Coefficient of the Electrolytes.................................61 4-2-2 The Performances of PECD..……………………………66 4-3 Switching Behaviors of Electrolytes with/without Br2................................................70 4-4 Incorporation of Pt in Electrochromic Layer…………76 4-4-1 Different Configurations of Pt in PECD………………76 4-4-2 Different Sputtering Times of Pt……………………..80 4-4-3 Combination of Br2 and Pt into PECDs…………………82 Chapter 5 Conclusions and Suggestions…………………….88 5-1 Conclusions…………………………………………………….88 5-1-1 The Gel-type PECD as Electrochromic Device…………88 5-1-2 The Gel-type PECD as Dye-Sensitized Solar Cell……91 5-2 Suggestions…………………………………………………...94 Chapter 6 References……………………………………….………95 Appendix A………………..……..…………...…………………111 Appendix B…………………………..……...……………………114 | |
| dc.language.iso | en | |
| dc.subject | 掃描式電化學顯微鏡。 | zh_TW |
| dc.subject | 結晶度 | zh_TW |
| dc.subject | 膠態電解質 | zh_TW |
| dc.subject | 光致電變色元件 | zh_TW |
| dc.subject | 響應時間 | zh_TW |
| dc.subject | response time | en |
| dc.subject | scanning electrochemical microscopy. | en |
| dc.subject | crystallinity | en |
| dc.subject | gel electrolyte | en |
| dc.subject | photoelectrochromic device | en |
| dc.title | 最適化含膠態電解質之快速響應光致電變色元件 | zh_TW |
| dc.title | On the Optimization of Fast-Response Photoelectrochromic Device Containing Gel Electrolytes | en |
| dc.type | Thesis | |
| dc.date.schoolyear | 98-2 | |
| dc.description.degree | 碩士 | |
| dc.contributor.oralexamcommittee | 周澤川(Tse-Chuan Chou),朱治偉(Chih-Wei Chu),林正嵐(Cheng-Lan Lin) | |
| dc.subject.keyword | 結晶度,膠態電解質,光致電變色元件,響應時間,掃描式電化學顯微鏡。, | zh_TW |
| dc.subject.keyword | crystallinity,gel electrolyte,photoelectrochromic device,response time,scanning electrochemical microscopy., | en |
| dc.relation.page | 115 | |
| dc.rights.note | 有償授權 | |
| dc.date.accepted | 2010-07-29 | |
| dc.contributor.author-college | 工學院 | zh_TW |
| dc.contributor.author-dept | 高分子科學與工程學研究所 | zh_TW |
| 顯示於系所單位： | 高分子科學與工程學研究所 | |
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