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| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 韋文誠 | |
| dc.contributor.author | Yen-Yu Chen | en |
| dc.contributor.author | 陳彥友 | zh_TW |
| dc.date.accessioned | 2021-06-15T04:57:50Z | - |
| dc.date.available | 2010-08-04 | |
| dc.date.copyright | 2010-08-04 | |
| dc.date.issued | 2010 | |
| dc.date.submitted | 2010-07-29 | |
| dc.identifier.citation | [1] National Hydrogen Energy Roadmap, issued by U.S. Department of Energy, 2002.
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| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/46201 | - |
| dc.description.abstract | 本研究採用兩種方法來製備釔安定化氧化鋯(YSZ)與釔摻雜氧化鈰(YDC)薄膜，用以改善陽極支撐型固態氧化物燃料電池的效率，包含溶膠鍍膜法(sol-state deposition)與膠粒鍍膜法(colloidal deposition)。使用這些方法製備的4-8 mol% 釔安定化氧化鋯薄膜可以達到無裂痕且緻密的要求，在600oC下測試，使用溶膠鍍膜法製備具有0.50 um的4 mol%釔安定化氧化鋯薄膜的單電池，其功率密度可達到477 mW/cm2，高於文獻報導具有數微米的8 mol%釔安定化氧化鋯薄膜的單電池；另外，使用膠體鍍膜法，單次鍍膜亦可成功製備出厚度2.5~8 um無裂痕的釔安定化氧化鋯(YSZ)薄膜。
為了避免釔安定化氧化鋯(YSZ)電解質與鑭鍶錳氧化物(LSM)陰極產生反應，本研究中，使用膠體鍍膜法製備釔摻雜氧化鈰(YDC)電解質薄膜層隔絕，並使用X光繞射儀(XRD)與高解析度穿透式電子顯微鏡(HRTEM)分析釔安定化氧化鋯(YSZ)與釔摻雜氧化鈰(YDC)材料的固溶反應現象，結果顯示反應溫度超過1200oC開始產生固溶反應，當反應溫度高於1600oC時達到完全固溶. 在1300oC時鈰離子擴散到氧化鋯的速度比鋯離子擴散到氧化鈰的速度快。 研究中針對製備單電池進行各項的電化學性質進行分析，包含開路電壓(OCV)、比表面積電阻(ASR)與單電池電效率(I-V-P)等。結果顯示，單電池組的功率可以藉由各項改良來提升，包含電流收集板(current collector)與陰極的接觸、陰極端鎳基多孔電流收集板的氧化、鑭鍶鈷鐵氧化物(LSCF)取代鑭鍶錳氧化物(LSM)陰極與使用新的層狀結構等。 | zh_TW |
| dc.description.abstract | Various thin yttria-stabilized zirconia (YSZ) and ceria (YDC) electrolytic films on anode-supported solid oxide fuel cell (SOFC) have been prepared to improve the performance of the made cells by either a sol-state deposition or colloidal deposition (CD) process. 4-8 mol% yttria-doped zirconia layer was prepared to reach the requirements of crack-free, dense and thin coats. The best half cell consisted of 4YSZ film with 0.5 um thickness showed a higher power density (477 mW/cm2) at 600oC than the cell with microns 8YSZ electrolyte layer. The CD method is also able to prepare crack-free and dense YSZ films in thickness of 2.5~8 um on porous anode substrate via one coating cycle.
YDC as the second electrolytic layer is prepared by colloidal deposition to prevent the reaction of YSZ/(La,Sr)MnOx (LSM). The solid solution reaction between YSZ and YDC has been analyzed. XRD and high resolution TEM results show that the reaction of YSZ and YDC layers starts at 1200oC, and becomes fully solid solution at 1600oC. The diffusion of Ce ions into YSZ grains is faster than the reversed migration of Zr ions into YDC at 1300oC. Electrochemical analysis on assembled cells has been conducted. By measuring the open circuit voltage (OCV), area specific resistance (ASR), and current-voltage-power (I-V-P), the power density of made gas-tight cells can be improved step-by-step in consideration of the interface contact between current collector/cathodes, oxidation of Ni-foam at cathode in oxidation condition, the replacement of LSM by LSCF cathode material, and new arrangement of layer configuration. | en |
| dc.description.provenance | Made available in DSpace on 2021-06-15T04:57:50Z (GMT). No. of bitstreams: 1 ntu-99-D90527007-1.pdf: 11843809 bytes, checksum: a5b756120ad9f2b8c8b739dc48e28ba7 (MD5) Previous issue date: 2010 | en |
| dc.description.tableofcontents | Chapter 1 Introduction 1
1.1 Motivation 2 1.2 Objectives of the research 4 Chapter 2 Literature Review 7 2.1 Fuel Cell 7 2.1.1 General consideration 7 2.1.2 Electrochemical reactions of fuel cells 8 2.1.3 Types of fuel cells 13 2.2 Solid Oxide Fuel Cell 22 2.2.1 Theories of ionic conduction of solid electrolyte 23 2.2.2 Materials for SOFC 30 2.3 Key issues for development of SOFC 49 2.3.1 Reliability of processing methods of electrode-supported SOFC 49 2.3.2 Improvement of triple phase boundary (TPB) at cathode 54 2.3.3 Diagnosis of SOFC mal-function by AC impedance 55 Chapter 3 Experimental 71 3.1 Design of Experiments 71 3.2 Materials 71 3.2.1 Anode materials 71 3.2.2 Electrolyte materials 72 3.2.3 Cathode materials 73 3.3 Sample Preparation 73 3.3.1 Anode substrate 73 3.3.2 Electrolyte layers 74 3.3.3 Cathode coating layer 77 3.4 Characterization 78 3.4.1 Phase Evolutions 78 3.4.2 Microstructural analysis 78 3.4.3 Electrochemical Properties 79 3.4.4 Other Properties 79 3.5 Configuration design for cell testing 81 Chapter 4 Processing and Characterization of Ultra-Thin Yttria Stabilized Zirconia (YSZ) Electrolytic Films for SOFC 88 4.1 Background 88 4.2 Results and Discussion 90 4.2.1 Characterization of NiO/YSZ anode substrate 91 4.2.2 Crystalline Phase Formation of YSZ 92 4.2.3 Characteristics of thin YSZ Coating 94 4.2.4 Cell Testing 96 4.3 Summary 97 Chapter 5 Fabrication and Characterization of Anode-supported YSZ Electrolyte Films by Colloidal Deposition (CD) Method 110 5.1 Background 110 5.2 Results and Discussion 111 5.2.1 NiO/YSZ anode composite 111 5.2.2 8YSZ electrolyte films by CD method 113 5.2.3 Cell Performance Testing 117 5.3 Summary 119 Chapter 6 Microstructure Analysis of the Interface of Yttria-Doped Ceria (YDC) and Yttria- Stabilized Zirconia (YSZ) 134 6.1 Background 134 6.2 Results 136 6.2.1 Properties of YDC Powder 136 6.2.2 Crystalline Phases of YSZ and YDC Composite 137 6.2.3 Microstructure of YDC/YSZ Composite 137 6.3 Discussion 139 6.4 Summary 143 Chapter 7 Assembly and Analysis of Multi-layered Cells 155 7.1 Background 155 7.2 Results and Discussion 156 7.2.1 Contact issue of cell 156 7.2.2 OCV Evaluation of SOFC 158 7.2.3 Test of multilayer cell assembly 160 7.2.4 Cells with different current collectors 162 7.3 Summary 164 Chapter 8 Conclusion 175 Reference 178 | |
| dc.language.iso | en | |
| dc.subject | 氧化鈰 | zh_TW |
| dc.subject | 電解質 | zh_TW |
| dc.subject | 薄膜 | zh_TW |
| dc.subject | 板狀電池 | zh_TW |
| dc.subject | 固態氧化物燃料電池 | zh_TW |
| dc.subject | 功率密度 | zh_TW |
| dc.subject | 釔安定化氧化鋯 | zh_TW |
| dc.subject | electrolyte | en |
| dc.subject | YSZ | en |
| dc.subject | SOFC | en |
| dc.subject | Power density | en |
| dc.subject | solid solution | en |
| dc.title | 陽極支撐型固態氧化物燃料電池之電解質薄膜製程與分析 | zh_TW |
| dc.title | Processing and Characterization of Electrolyte Thin Filmfor Anode-Supported Solid Oxide Fuel Cell | en |
| dc.type | Thesis | |
| dc.date.schoolyear | 98-2 | |
| dc.description.degree | 博士 | |
| dc.contributor.oralexamcommittee | 馬小康,王錫福,林志光,方冠榮,李堅雄 | |
| dc.subject.keyword | 電解質,釔安定化氧化鋯,固態氧化物燃料電池,功率密度,氧化鈰,薄膜,板狀電池, | zh_TW |
| dc.subject.keyword | electrolyte,YSZ,SOFC,Power density,solid solution, | en |
| dc.relation.page | 192 | |
| dc.rights.note | 有償授權 | |
| dc.date.accepted | 2010-07-29 | |
| dc.contributor.author-college | 工學院 | zh_TW |
| dc.contributor.author-dept | 材料科學與工程學研究所 | zh_TW |
| 顯示於系所單位： | 材料科學與工程學系 | |
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