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http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/4619完整後設資料紀錄
| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 廖英志 | |
| dc.contributor.author | Bo-Han Chen | en |
| dc.contributor.author | 陳柏翰 | zh_TW |
| dc.date.accessioned | 2021-05-14T17:44:12Z | - |
| dc.date.available | 2020-07-31 | |
| dc.date.available | 2021-05-14T17:44:12Z | - |
| dc.date.copyright | 2015-07-31 | |
| dc.date.issued | 2015 | |
| dc.date.submitted | 2015-07-30 | |
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| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/4619 | - |
| dc.description.abstract | 本論文利用一種簡單且迅速的噴墨直寫技術來製作多色彩可撓曲式圖樣化電致變色元件。此元件係利用一種電致變色超分子聚合物 (Metallo-supramolecular polymers, MEPE) 製成，相較於傳統電致變色材料，MEPE具有高對比度、高穩定性及高著色效率等特性。由於此聚合物為水溶性，因此可將其製作成墨水，並利用噴墨技術直接噴塗於導電基材上。
首先，為了製作出平整且緻密的變色材料薄膜，使用不同的液滴排列並探討其對薄膜樣態的影響。找出均勻噴塗的方式後，在透明導電基材ITO-PEN上製作薄膜並以循環伏安法及光譜儀測量其電化學與光學性質。與先前之文獻做比較，電致變色材料薄膜之吸收峰值與氧化還原電位並無因不同製程而改變。印製而成的變色薄膜接著與固態電解質搭配，組合成可撓曲式電致變色元件。此電解質是由高沸點之非揮發性離子液體 (EMIBTI) 與高分子 (PVDF-HFP) 製作而成。當改變施加的電壓時 (-3.0~3.0 V)，此元件可在兩秒鐘內著色並具有相當高的對比度以及著色效率。在580 nm之波長下，其穿透度變化為40.1%並且具有445 cm2C-1之高著色效率。當此元件彎曲時，其穿透度變化仍可達30.1%且著色時間不變，是相當好的展現。 接著，利用噴墨技術將兩種不同顏色之MEPE混合成一系列不同顏色以及圖樣化之電致變色薄膜。同樣地，利用光譜儀及循環伏安法探討混合後之特性。可發現兩者之吸收光譜會線性疊加，進而顯現不同的顏色。與先前文獻使用合成調整顏色不同的是：藉由噴墨技術混合的變色薄膜，其氧化還原電位並不會因兩種金屬離子的交互作用而偏移。最後，本論文利用噴墨技術可在不需遮罩的情形下精確噴印出所設計的圖樣之特點，搭配兩種變色材料製作圖樣化之電致變色元件，為此製程在軟性顯示器的應用提供進一步的可能性。 | zh_TW |
| dc.description.abstract | In this thesis, multi-colored electrochromic (EC) thin film devices were prepared by a direct-writing method. Metallo-supramolecular polymers (MEPE) solutions with two primary colors were inkjet-printed digitally on flexible electrodes. Uniform EC thin films are fabricated via inkjet printing. Further, by digitally controlling print dosages of each species, colors of the printed EC thin film patterns can be adjusted directly without pre-mixing or synthesizing new materials. The printed EC thin films were then laminated with a solid transparent thin film electrolyte and a transparent conductive thin film to form an electrochromic device (ECD). After applying a DC voltage, the printed ECDs exhibited a great contrast with a transmittance change (ΔT) of 40.1% and a high coloration efficiency of 445 cm2C-1 at 580 nm within a short darkening time of 2 s. The flexible ECDs can also be made base on ITO-PEN and showed same darkening time of 2 s and still have a high ΔT of 30.1% under bending condition. In summary, this study demonstrated the feasibility to fabricate display devices with different color set up by all-solution process, and can be further extended to other types of displays. | en |
| dc.description.provenance | Made available in DSpace on 2021-05-14T17:44:12Z (GMT). No. of bitstreams: 1 ntu-104-R02524059-1.pdf: 3242192 bytes, checksum: 9c22e429bee6de5751dab3f6aa6f9922 (MD5) Previous issue date: 2015 | en |
| dc.description.tableofcontents | 口試委員會審定書 #
Acknowledgements i 中文摘要 ii ABSTRACT iii Table of Contents iv List of Figures vii List of Tables ix Chapter 1 Introduction 1 1.1 Preface 1 1.2 Objective 2 1.3 Thesis structure 6 Chapter 2 Literature Review 7 2.1 Electrochromic 7 2.1.1 Transmittance Attenuation 12 2.1.2 Coloration Efficiency 12 2.1.3 Switching Speed 13 2.2 Flexible Electronics and Printing Technology 14 2.3 Classification of Inkjet Printing Technology 15 2.3.1 Continuous Mode[61-64] 15 2.3.2 Drop-on-demand Mode[61-65] 16 Chapter 3 Inkjet Printing EC device 18 3.1 Experimental 18 3.1.1 Materials 18 3.1.2 Preperation of EC Inks 19 3.1.3 Ink Deposition on Surfaces 21 3.1.4 Printing of EC Thin Film 21 3.1.5 Solid-State Electrolyte 25 3.1.6 Electrochromic Device 26 3.2 Results & Discussion 27 3.2.1 Ink Deposition on Substrates 27 3.2.2 Influence of Printing Mask Scheme 29 3.2.3 UV-vis Absorption 33 3.2.4 Cyclic Voltammetry Method 35 3.2.5 Solid-State Electrolyte 37 3.2.6 Transmittance Change 38 3.2.7 Coloration Efficiency 45 3.2.8 Long-Term Stability 51 Chapter 4 Multi-Color EC device 52 4.1 Experimental 52 4.1.1 Color Mixing Serious 52 4.1.2 Multi-Color EC Pattern 53 4.1.3 Electrochromic Device 54 4.2 Results & Discussion 55 4.2.1 Color Mixing Series 55 4.2.2 Multi-Color EC Pattern 56 4.2.3 UV-vis Absorption 57 4.2.4 Cyclic Voltammetry Method 58 4.2.5 Multi-Color EC Devices 60 Chapter 5 Conclusion 64 Chapter 6 Future Prospect 65 References...... 66 | |
| dc.language.iso | en | |
| dc.title | 可撓式電致變色元件之噴墨混色與圖樣化研究 | zh_TW |
| dc.title | Printed Multi-Color High-Contrast Flexible Electrochromic Devices | en |
| dc.type | Thesis | |
| dc.date.schoolyear | 103-2 | |
| dc.description.degree | 碩士 | |
| dc.contributor.oralexamcommittee | 何國川,林正嵐,衛子健,?口昌芳(Masayoshi Higuchi) | |
| dc.subject.keyword | 電致變色,印刷電子,噴墨技術,金屬配位超分子,顯示器, | zh_TW |
| dc.subject.keyword | Metallo-Supramolecular,Display,Electrochromic,Printing Electronics,Inkjet Printing, | en |
| dc.relation.page | 70 | |
| dc.rights.note | 同意授權(全球公開) | |
| dc.date.accepted | 2015-07-30 | |
| dc.contributor.author-college | 工學院 | zh_TW |
| dc.contributor.author-dept | 化學工程學研究所 | zh_TW |
| 顯示於系所單位： | 化學工程學系 | |
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