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完整後設資料紀錄
DC 欄位 | 值 | 語言 |
---|---|---|
dc.contributor.advisor | 楊燿州 | |
dc.contributor.author | Yi-Chung Lan | en |
dc.contributor.author | 藍奕中 | zh_TW |
dc.date.accessioned | 2021-06-15T04:17:24Z | - |
dc.date.available | 2014-09-20 | |
dc.date.copyright | 2011-09-20 | |
dc.date.issued | 2011 | |
dc.date.submitted | 2011-08-17 | |
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dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/45386 | - |
dc.description.abstract | 本論文是以介電泳技術為基礎對奈米碳管進行集束組裝,並探討奈米碳管束的衍伸應用,奈米碳管在交流電場下會被電偶極化,並且於介電力的作用下會立即轉向於外加電場的方向,隨後朝向電場強度強的地方泳動,最後傾向於順著外加電場的方向進行排列,隨著溶液的蒸發,表面張力亦會形成束縛力對已轉向且平行於電場方向的奈米碳管進行捕捉,最終形成奈米碳管束。此外,本研究還利用混入奈米銀及在碳管束外層介電泳奈米銀層以增加奈米碳管束的導電性能,最後再以焦耳加熱退火處理,進一步的降低其電阻值,奈米碳管束混入奈米銀粒子,可以用於改善碳管與碳管接合處間的接觸電阻,並且用以填充碳管間多餘的空隙,奈米銀層則可以提供另條絕佳的導電路徑,而焦耳加熱退火處理則可以改善奈米碳管束與電極間的接觸電阻,使奈米碳管的電阻值獲得再進一步的改善。本研究以四點探針法進行電阻的量測及分析,每一步驟奈米碳管束的電阻改良都有很詳細的紀錄,其最終所形成的奈米碳管束的電阻值約為1 ohm左右,最後我們再進行奈米碳管束陣列式集束組裝的初步驗證,由實驗結果證實我們可以有效的控制單根奈米碳管束介電泳組裝的範圍,進而由單一的奈米碳管束組裝推廣至奈米碳管束的陣列組裝。 | zh_TW |
dc.description.abstract | In this work, we propose a method of assembling carbon nanotubes (CNT) into a cluster by using dielectrophoresis. Multiwalled carbon nanotubes (MWCNTs), which have been acid-treated, are dispersed into ethanol solution. As the electric field is applied, the MWCNTs rotate to align with the external field direction by dielectrophoresis force, and then MWCNTs are attracted to the region of high field intensity. As ethanol solution evaporates, the surface tension act as a binding force to tie up MWCNTs, which are aligned with the external field direction, and form a MWCNTs cluster. Furthermore, we improved the conductivity of the MWCNTs cluster by dispersing silver nanoparticles into the MWCNTs cluster. Annealing process was also performed by using local joule heating. The resistance of the MWCNT clusters were measured by using four-point probe technique. The repeated experiment shows that measured electrical resistance of the assembled MWCNTs cluster is about 1 ohm. In addition, the method of forming array-type MWCNTs clusters was also proposed. The preliminary experimental results were also provided. | en |
dc.description.provenance | Made available in DSpace on 2021-06-15T04:17:24Z (GMT). No. of bitstreams: 1 ntu-100-R98522705-1.pdf: 9437173 bytes, checksum: d46930e0b17389cc16145a64616f61f1 (MD5) Previous issue date: 2011 | en |
dc.description.tableofcontents | 誌謝 I
摘要 III Abstract IV 目錄 V 圖目錄 VIII 表目錄 XIII 第一章 緒論 1 1.1. 前言 1 1.2. 研究動機及目的 2 1.3. 文獻回顧 4 1.3.1. 奈米碳管的導電性 4 1.3.2. 生長奈米碳管作為interconnector的應用 6 1.3.3. 介電泳組裝奈米碳管 9 1.3.4. 降低奈米碳管的接觸阻抗 13 1.4 . 論文架構 17 第二章 理論基礎 18 2.1. 超音波震洗分散原理 18 2.2. 介電泳組裝 19 2.2.1. 介電泳效應 19 2.2.2. 介電泳原理 20 2.2.3. 奈米碳管介電泳組裝 22 2.2.4. 垂直式的介電泳 23 2.2.5. 兩點探針及四點探針電阻量測 24 第三章 奈米碳管的酸處理與分散 27 3.1. 奈米碳管的分散 27 3.2. 奈米碳管的酸處理 28 3.3. 奈米碳管在原子力顯微鏡下掃描 30 3.3.1. 奈米碳管的掃描試片製備 30 3.3.2. 奈米碳管的掃描觀察 30 第四章 介電泳組裝奈米碳管束 35 4.1. 研究規劃 35 4.2. 製程設計與原理 36 4.3. 介電泳設備的架設 38 4.4. 分散液的製備 41 4.5. 介電泳組裝奈米碳管束 44 4.6. 介電泳奈米銀層 45 4.7. 焦耳加熱退火處理 46 第五章 量測結果與討論 48 5.1. 介電泳組裝之結果與討論 48 5.2. 奈米碳管束電阻量測 53 5.3. 焦耳加熱退火處理實驗量測 61 第六章 陣列式之製程架構與初步驗證 65 6.1. 製程設計 65 6.2製程步驟 66 6.3. 製作成果 73 6.4. 四點探針法電阻量測 76 第七章 結論與未來展望 77 7.1. 結論 77 7.2. 未來展望 78 附錄A 介電泳組裝奈米碳管束作為呼吸感測器的應用 80 參考資料 100 | |
dc.language.iso | zh-TW | |
dc.title | 利用介電泳組裝奈米碳管成束及其應用探討 | zh_TW |
dc.title | Dielectrophoretic Assembly of Multiwall Carbon Nanotubes for Creating CNT Clusters | en |
dc.type | Thesis | |
dc.date.schoolyear | 99-2 | |
dc.description.degree | 碩士 | |
dc.contributor.oralexamcommittee | 陳國聲,蘇裕軒 | |
dc.subject.keyword | 奈米材料,奈米碳管,介電泳組裝,微奈米機電製程技術, | zh_TW |
dc.subject.keyword | Carbon Nanotube,Nano materials,Micro and Nano Fabrication,Dielectrophoretic Assembly, | en |
dc.relation.page | 108 | |
dc.rights.note | 有償授權 | |
dc.date.accepted | 2011-08-17 | |
dc.contributor.author-college | 工學院 | zh_TW |
dc.contributor.author-dept | 機械工程學研究所 | zh_TW |
顯示於系所單位: | 機械工程學系 |
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