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| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 童世煌 | |
| dc.contributor.author | Hwai-Te Chiu | en |
| dc.contributor.author | 邱懷德 | zh_TW |
| dc.date.accessioned | 2021-06-15T04:04:48Z | - |
| dc.date.available | 2016-08-23 | |
| dc.date.copyright | 2011-08-23 | |
| dc.date.issued | 2011 | |
| dc.date.submitted | 2011-08-22 | |
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| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/45108 | - |
| dc.description.abstract | 本實驗利用不同分子量的超分子共聚物PS-b-P4VP(PDP)與奈米粒子混摻，對分子量大小造成奈米粒子不同的空間分布結果進行探討，實驗發現在分子量較小的超分子共聚物中，奈米粒子在P4VP(PDP)區間的分布會隨PDP的多寡而有顯著的影響；但對於大分子量的超分子共聚物而言，奈米粒子並不會隨著PDP的增加而有不同的分布，而是會在靠近P4VP(PDP)區間中間位置均勻分散。且奈米粒子會傾向存在於界面彎曲的區域當中。此外，我們將奈米柱加入超分子系統當中，發現PDP增加而產生的結晶會迫使奈米柱形成特殊的堆疊，此堆疊在超分子共聚物當中會使奈米柱以垂直PS-b-P4VP所形成的層狀方向排列而存在於P4VP(PDP)相當中。若PDP比例更高時，則會形成溶液中特有的液胞型態，且奈米粒子及奈米柱在此狀況下亦能選擇性地分散在P4VP(PDP)區間。
小分子扮演在此系統中扮演多重角色，不僅僅為奈米粒子及團聯式共聚物的混摻的媒介，亦可改變團聯式共聚物兩鏈段的體積分率而使超分子共聚物的型態改變，且在小分子比例很高時，小分子可扮演類似選擇性溶劑的角色而膨潤其中一鏈段，進而形成溶液中特有的液胞結構。這些多重的可調性功能使此系統具有廣泛的應用發展性。 | zh_TW |
| dc.description.abstract | It is confirmed that the incorporation of nanoparticles and nanorods into block copolymer-based supramolecules of poly(styrene-b-4-vinylpyridine) (PS-b-P4VP) possess well selective spatial distribution into P4VP(PDP) microdomain. In this study, we investigate the effect of molecular weight of block copolymer on the spatial distribution of nanoparticles controlled by small molecules. With small molecular weight block copolymer, the spatial distribution of nanoparticles varies with different amount of PDP. However, with large molecular weight block copolymer, nanoparticles disperse around the center of P4VP(PDP) domain regardless of the amount of PDP. Favorable incorporation of nanoparticles into bended lamella is observed. Moreover, Nanorods tend to orientate perpendicular to the lamella of PS-b-P4VP when forming special aggregations of nanorods in the presence of excess free PDP in P4VP(PDP) microdomain.
Small molecules not only tailor the incorporation of various nanoparticles into supramolecular assembly by favorable mixing properties, but direct the supramolecular assembly to various morphologies. Besides, small molecules with excess amount can swell the P4VP(PDP) domain in similar to the effect of selective solvent toward P4VP. | en |
| dc.description.provenance | Made available in DSpace on 2021-06-15T04:04:48Z (GMT). No. of bitstreams: 1 ntu-100-R98549025-1.pdf: 10704124 bytes, checksum: f711346f81be3211e2b84f4bf1f8c24f (MD5) Previous issue date: 2011 | en |
| dc.description.tableofcontents | 誌謝 II
摘要 III Abstract IV 目錄 V 圖目錄 VIII 表目錄 XIV 一、 緒論 1 二、 文獻回顧 2 2-1 功能性奈米混合材料 2 2-2團聯式共聚物及超分子共聚物 5 2-2-1 團聯式共聚物之微相分離型態 6 2-2-2 梳狀超分子共聚物之微相分離型態 13 2-3 奈米粒子的合成 19 2-4 奈米粒子與團聯式共聚物的混摻 23 2-4-1 同時還原法（In-situ） 23 2-4-2 異地還原法（Ex-situ） 26 2-4-3 奈米粒子在混合材料中的空間分布及排列 30 2-5 由小分子引導的奈米粒子與超分子共聚物的混摻 33 三、 實驗方法與儀器 37 3-1 材料 37 3-2 實驗步驟 39 3-2-1 Nanoparticles的合成 39 3-2-2 奈米柱的合成 40 3-2-3混合材料的製備 40 3-2-4薄膜的製備與側面TEM分析 41 3-3 儀器原理 42 3-3-1 穿透式電子顯微鏡（TEM） 42 3-3-2 濺鍍機 43 四、 實驗結果與討論 44 4-1 碘蒸氣染色對奈米粒子在超分子共聚物中混摻的影響 44 4-2 不同分子量的超分子共聚物及PDP比例對奈米粒子混摻的影響 50 4-3 奈米柱在混合材料當中的特殊排列 72 五、 結論 85 參考文獻 86 | |
| dc.language.iso | zh-TW | |
| dc.subject | 奈米柱 | zh_TW |
| dc.subject | 雙團聯式共聚物 | zh_TW |
| dc.subject | 奈米粒子 | zh_TW |
| dc.subject | 超分子共聚物 | zh_TW |
| dc.subject | supramolecule | en |
| dc.subject | block-copolymer | en |
| dc.subject | nanorod | en |
| dc.subject | nanoparticle | en |
| dc.title | 奈米粒子與奈米柱在超分子共聚物中的空間分布探討 | zh_TW |
| dc.title | The Spatial Distribution of Nanoparticles and Nanorods in Block Copolymer-Based Supramolecules of PS-b-P4VP | en |
| dc.type | Thesis | |
| dc.date.schoolyear | 99-2 | |
| dc.description.degree | 碩士 | |
| dc.contributor.oralexamcommittee | 廖文彬,邱文英 | |
| dc.subject.keyword | 雙團聯式共聚物,奈米粒子,奈米柱,超分子共聚物, | zh_TW |
| dc.subject.keyword | block-copolymer,supramolecule,nanoparticle,nanorod, | en |
| dc.relation.page | 92 | |
| dc.rights.note | 有償授權 | |
| dc.date.accepted | 2011-08-23 | |
| dc.contributor.author-college | 工學院 | zh_TW |
| dc.contributor.author-dept | 高分子科學與工程學研究所 | zh_TW |
| 顯示於系所單位： | 高分子科學與工程學研究所 | |
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