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完整後設資料紀錄
DC 欄位 | 值 | 語言 |
---|---|---|
dc.contributor.advisor | 張文亮 | |
dc.contributor.author | Chiao-Wen Lin | en |
dc.contributor.author | 林巧雯 | zh_TW |
dc.date.accessioned | 2021-06-15T03:52:41Z | - |
dc.date.available | 2020-07-22 | |
dc.date.copyright | 2010-07-12 | |
dc.date.issued | 2010 | |
dc.date.submitted | 2010-07-07 | |
dc.identifier.citation | 1.丁健原,1987,重金屬鉻之土壤污染及其溶質吸附移動模擬研究,國立台灣大學農業工程學研究所碩士論文。
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C., 2006. “A novel approach to an advanced tertiary wastewater treatment:Combination of a membrane bioreactor and an oyster - zeolite column.”, Desalination, Vol. 190. pp. 243–255. 16. Kirkham D. and W. L. Powers, 1972, “Advanced Soil Physics”, John Wiley & Sons, Inc., New York, pp. 379-427. 17. Korte, N. E., Skopp, J., Fuller, W. H., Niebla, E. E., Alesii, B. A., 1976. “Trace Element Movement in Soils: Influence of Soil Physical and Chemical Properties.”, Soil Science, Vol. 122. pp. 350-359. 18. Kwon, H. B., Lee, C. W., Jun, B. S., Yun, J. D., Weon, S. Y., Koopman, B.,2004. “Recycling waste oyster shells for eutrophication control.” , Resources, Conservation & Recycling, Vol.41. pp. 75–82. 19. Lee, S. H., Vigneswaran, S., Chung Y., 1997. “A Detailed Investigation of Phosphorus Removal in Soil and Slag Media.”, Environmental Technology, Vol.18. pp. 699-710. 20. Lee, S. H., Vigneswaran, S., Moon, H., 1997. “Adsorption of phosphorus in saturated slag media columns.”, Separation and Purification Technology,Vol.12. pp. 109-118. 21. Mann, R. A., 1997, “Phosphorus adsorption and desorption characteristics of constructed wetland gravels and steelworks by-products.”, Australian Journal of Soil Research, Vol. 35. pp. 375-384. 22. Mansell, R. S., McKenna, P. J., Flaig, E., Hall, M., 1985. “Phosphate Movement in Columns of Sandy Soil From A Wastewater-Irrigated Site.”, Soil Science, Vol. 140. pp. 59-68. 23. Namasivayam, C., Sakoda A., Suzuki M., 2005. “Removal of phosphate by adsorption onto oyster shell powder - kinetic studies.”, Journal of Chemical Technology and Biotechnology, Vol.80. pp. 356–358. 24. Nielsen, D. R., and Biggar, J. W., 1961. “Miscible Displacement in Soils: I. Experimental Information.”, Soil Science Society of America Proceedings, Vol. 25. pp. 1-5. 25. Nielsen, D. R., and Biggar, J. W., 1962b. “Miscible Displacement : III. Theoretical Considerations.”, Soil Science Society of America Proceedings, Vol. 26. pp. 216-221. 26. Nielsen, D. R., and Biggar, J. W., 1963a. “Miscible Displacement: IV. Mixing in Glass Beads.”, Soil Science Society of America Proceedings, Vol. 27.pp. 10-13. 27. Odoemelam, S. A., Eddy, N. O., 2009. “Studies on the Use of Oyster, Snail and Periwinkle Shells as Adsorbents for the Removal of Pb2+ from Aqueous Solution.”, E-Journal of Chemistry, Vol. 6(1). pp. 213-222. 28. Olsen, S. R. and Watanabe, F. S., 1957. “A Method to Determine a Phosphorus Adsorption Maximum of Soils as Measured by the Langmuir Isotherm.”, Soil Science Society of America Proceedings, Vol.21. pp. 144-149. 29. Ozacar, M., 2003. “Adsorption of phosphate from aqueous solution onto alunite.”, Chemosphere, Vol.51. pp. 321-327. 30. Park, W. H., 2009. “Integrated constructed wetland systems employing alum sludge and oyster shells as filter media for P removal.”, Ecological Engineering , Vol. 35. pp. 1275-1282. 31. Passioura, J. B. and Rose, D. A., 1971. “Hydrodynamic Dispersion in Aggregated Media: 2. Effects of Velocity and Aggregate Size.”, Soil Science, Vol. 3. pp. 345-351. 32. Seo, D. C., Cho, J. S., Lee, H. J., and, Heo, J. S., 2005. “Phosphorus retention capacity of filter media for estimating the longevity of constructed wetland.”, Water Research, Vol.39. pp. 2445–2457. 33. Veith, J. A. and Sposito, G., 1977. “On the Use of the Langmuir Equation in the Interpretation of 'Adsorption' Phenomena.”, Soil Science Society of America, Vol.41. pp. 697-702. 34. Yang, E. I., Yi, S.T., Leem Y. M., 2005. “Effect of oyster shell substituted for fine aggregate on concrete characteristics: Part I. Fundamental properties.”, Cement & Concrete Research, Vol. 35. pp. 2175-2182. 35. Yoon, G. L., Kim, B. T., Kim, B. O., Han, S. H., 2003. “Chemical–mechanical characteristics of crushed oyster-shell.”, Waste Management, Vol.23. pp. 825-834. 36. Yoon H., Park S., Lee K., Park J., 2004. “Oyster shell as substitute for aggregate in mortar.”, Waste Management & Research, Vol. 22. pp. 158-170. 37. Zhang, G., Liu, H., Liu, R., Qu, J., 2009. “Removal of phosphate from water by a Fe-Mn binary oxide adsorbent.”, Journal of Colloid and Interface Science, Vol.335. pp. 168-174. | |
dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/44674 | - |
dc.description.abstract | 牡蠣為台灣西南沿海常見的養殖生物,其副產物牡蠣殼卻造成相當嚴重的廢棄物問題。若可利用牡蠣殼成為現地處理中,吸附污水中磷的介質,不但可減少牡蠣殼過多的數量問題,也可降低水中磷的濃度,改善水質優養化。
本研究主要探討不同粒徑間,三種粒徑的牡蠣殼粉(0.42~0.84mm),透過Langmuir等溫吸附實驗設計,求取牡蠣殼對磷的最大吸附量,並與其他吸附材料做比較。另外,以混合取代(Miscible Displacement)的實驗,研究磷在三種粒徑的牡蠣殼粉孔隙中動力傳輸的情形,並計算磷在三種粒徑的牡蠣殼粉的延散係數(Dispersion Coefficient)。最後,分析牡蠣殼化學成分,主要分析重金屬的含量。希望藉由以上研究,建立牡蠣殼吸附磷的能力和相關參數,供日後牡蠣殼移除污水中磷之應用。 其結果顯示,牡蠣殼對磷的吸附與Langmuir isotherm的假設接近。粒徑為0.42 mm,0.59 mm,0.84 mm,其最大吸附量(qm)分別為:200 mg/kg,166.67 mg/kg,125 mg/kg,最大吸附量隨著粒徑減小而增加。和不同種類的土壤和常用於吸附磷的材料比較,牡蠣殼也能夠成為吸附磷的介質,其效果相似。 另外,根據混合取代理論,求得磷在牡蠣殼的延散係數為0.42mm:17.05 cm2/s;0.59mm:0.90 cm2/s;0.84mm:0.21 cm2/s,隨著粒徑減小有增大的趨勢。 | zh_TW |
dc.description.provenance | Made available in DSpace on 2021-06-15T03:52:41Z (GMT). No. of bitstreams: 1 ntu-99-R97622013-1.pdf: 1162822 bytes, checksum: 5f2e09663f82cceb9eeba40486252f7a (MD5) Previous issue date: 2010 | en |
dc.description.tableofcontents | 目 錄
中文摘要 I 英文摘要 II 目錄 IV 圖目錄 VI 表目錄 VII 第一章 前言 1 1.1文獻回顧 1 1.2研究目的 2 第二章 理論與模式 4 2.1 Langmuir等溫吸附模式 (Langmuir Isotherm) 4 2.2 混合取代理論 (Miscible Displacement) 7 第三章 材料與方法 12 3.1 Langmuir等溫吸附實驗 12 3.1.1牡蠣殼 12 3.1.2磷溶液的配製 12 3.1.3實驗步驟 12 3.1.4牡蠣殼釋放的磷 13 3.2混合取代實驗 14 3.2.1實驗步驟 14 3.2.2繪製突破曲線 16 3.2.3計算導水係數(K) 16 3.3牡蠣殼化學成分分析 17 第四章 結果與討論 18 4.1 Langmuir等溫吸附實驗 18 4.1.1三種粒徑的牡蠣殼粉對磷的吸附量(q)和初始濃度(C)的關係 18 4.1.2三種粒徑的牡蠣殼粉在不同時間下的最大吸附量(qm)和Kads 22 4.1.3與其他材料比較qm值 27 4.1.4牡蠣殼釋放的磷 32 4.2混合取代實驗 33 4.3牡蠣殼化學成分分析結果 41 第五章 結論與建議 42 5.1結論 42 5.2建議 43 參考文獻 44 附錄 49 附錄A 公式符號對照表 49 附錄B Langmuir等溫吸附實驗原始數據 51 附錄C 混合取代實驗原始數據 69 附錄D 牡蠣殼重金屬分析 76 圖目錄 圖2-1 Langmuir等溫吸附模式中q和C的關係圖 6 圖2-2 線性回歸的Langmuir等溫吸附模式 6 圖2-3 突破曲線 11 圖3-1 錐形瓶置放於等溫震盪器 13 圖3-2 混濁的牡蠣殼溶液 13 圖3-3 過濾裝置過濾牡蠣殼溶液 13 圖3-4 透明無色的KH2PO4溶液 13 圖3-5定水頭裝置實圖 14 圖3-6 ΔH、L、d位置圖 14 圖4-1 0.42 mm 2hr∼24hr q與C關係圖 19 圖4-2 0.59 mm 2hr∼24hr q與C關係圖 20 圖4-3 0.84 mm 2hr∼24hr q與C關係圖 21 圖4-4 0.42 mm 2hr~24hr Langmuir Isotherm線性回歸圖 24 圖4-5 0.59 mm 2hr~24hr Langmuir Isotherm線性回歸圖 25 圖4-6 0.84 mm 2hr~24hr Langmuir Isotherm線性回歸圖 26 圖4-7 三種粒徑牡蠣殼的突破曲線圖 36 圖4-8 0.42 mm濃度移除率和累積時間關係圖 38 圖4-9 0.59 mm濃度移除率和累積時間關係圖 38 圖4-10 0.84 mm濃度移除率和累積時間關係圖 39 圖4-11 0.42 mm導水係數(K)和累積時間關係圖 39 圖4-12 0.59 mm導水係數(K)和累積時間關係圖 40 圖4-13 0.84 mm導水係數(K)和累積時間關係圖 40 表目錄 表4.1 牡蠣殼在不同研磨粒徑不同時間的qm和Kads值 22 表4.2 牡蠣殼與吸附劑其他材料的比較 29 表4.3 10g牡蠣殼在不同研磨粒徑不同時間釋放的磷和所佔全部 含磷量的比例 32 表4.4 牡蠣殼在不同研磨粒徑之混合取代實驗結果 33 表4.5牡蠣殼與其他材料平均孔隙流速和延散係數的比較 37 表4.6 牡蠣殼所含重金屬的成分含量表 41 | |
dc.language.iso | zh-TW | |
dc.title | 牡蠣殼粉移除水中磷之等溫吸附與混合取代研究 | zh_TW |
dc.title | Phosphorus Removal from Aqueous Solution Using Oyster Shell Powder–Adsorption Isotherm and Miscible Displacement Studies | en |
dc.type | Thesis | |
dc.date.schoolyear | 98-2 | |
dc.description.degree | 碩士 | |
dc.contributor.oralexamcommittee | 張尊國,張倉榮,游進裕 | |
dc.subject.keyword | 牡蠣殼,磷,Langmuir等溫吸附,混合取代理論,延散係數, | zh_TW |
dc.subject.keyword | oyster shell,phosphorus,Langmuir isotherm,miscible displacement,dispersion coefficient, | en |
dc.relation.page | 76 | |
dc.rights.note | 有償授權 | |
dc.date.accepted | 2010-07-07 | |
dc.contributor.author-college | 生物資源暨農學院 | zh_TW |
dc.contributor.author-dept | 生物環境系統工程學研究所 | zh_TW |
顯示於系所單位: | 生物環境系統工程學系 |
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