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| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 彭旭明(Shie-Ming Peng) | |
| dc.contributor.author | Yu-Lin Lo | en |
| dc.contributor.author | 羅鈺霖 | zh_TW |
| dc.date.accessioned | 2021-06-15T03:52:24Z | - |
| dc.date.available | 2013-07-16 | |
| dc.date.copyright | 2010-07-16 | |
| dc.date.issued | 2010 | |
| dc.date.submitted | 2010-07-08 | |
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| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/44656 | - |
| dc.description.abstract | Two series of the complex, which contain the novel linear pentanickel metal string complexes and a trinickel metal string complex, have been studied.
The asymmetric 2-(Phenylpyridyldiamino)- 1,8-naphthyridine (H2phpdany) ligand and its pentanickel metal string complex, (4,0)-[Ni5(phpdany)4Cl](PF6) (1) are synthesized. According to X-ray crystallography analysis, the metal ions of complex 1 are surrounded by four unsymmetrical ligands with (4,0) stereoisomer. Because of the steric hindrance of the bulky phenyl groups, there is only one axial ligand Cl-, which is coordinated to terminal naphthyridyl groups’ nickel ion. Magnetic measurements show that complex 1 is paramagnetic. The terminal naphthyridyl groups’ Ni2+ ion possess S = 1 and the others Ni ions are diamagnetic. Complex 1 undergoes redox reaction, which lead one-electron oxidation and reduction complexes (4,0)-[Ni5(phpdany)4Cl](PF6)2 (2) and (4,0)-[Ni5(phpdany)4Cl] (3). Complexes 2 and 3 are characterized by magnetism, EPR and UV/Vis-NIR spectra and compare with complex 1. In the second part, by using the precursor [Ni3(dpa)4Cl2] with nitrosonium tetrafluoroborate in acetonitrile, the reaction proceeded with nitration instead of originally proposed oxidation. [Ni3(dpa(NO2)2)4Cl2] has been synthesized successfully and studied. The nitropyridine formed in the reaction of pyridine with nitronium ion (NO2+). A linear trimetallic string of nickel(Ⅱ) atoms wrapped by dpa- ligand with two NO2 groups at the 3-positions of each pyridyl group. Magnetic measurements show that it exhibits antiferromagnetic coupling ( J = -196.25 cm-1 ). The terminal Ni2+ and center Ni2+ are S = 1 and S = 0 respectively. | en |
| dc.description.provenance | Made available in DSpace on 2021-06-15T03:52:24Z (GMT). No. of bitstreams: 1 ntu-99-R97223113-1.pdf: 27987170 bytes, checksum: e75f2f318c3616f4600b2dce10bc636b (MD5) Previous issue date: 2010 | en |
| dc.description.tableofcontents | 口試委員會審定書
謝誌 中文摘要 I 英文摘要 II 第一章 緒論 1 1-1 前言 1 1-2 分子金屬導線 1 1-3 金屬-金屬鍵結理論 6 1-3-1 直線型三核金屬錯合物之鍵結理論 7 1-3-2 直線型五核金屬錯合物之鍵結理論 8 1-4 多氮配基之簡介 10 1-4-1 多吡啶胺配基介紹 10 1-4-2 多萘啶胺配基介紹 11 1-4-3 吡啶萘啶胺混合與苯環修飾之多氮配基介紹 12 1-5 直線型金屬串簡介 13 1-5-1 對稱型配基之直線型金屬串介紹 13 1-5-2 不對稱型配基之直線型金屬串介紹 15 1-6 研究方向 18 第二章 實驗部分 20 2-1 試藥與儀器 20 2-1-1 試藥與溶劑 20 2-1-2 儀器 22 2-2 實驗步驟 24 2-2-1 配基之合成 24 2-2-2 金屬串錯合物之合成 29 第三章 不對稱型五氮配基H2phpdany及其鎳金屬串錯合物之合成與物理性質研究 35 3-1 配基之合成 35 3-2 直線型五核鎳金屬串錯合物之合成 37 3-3 結構分析與討論 39 3-4 磁性分析與EPR光譜 43 3-5 電化學與光譜電化學分析 51 3-6 UV/Vis與Near-IR光譜分析 56 第四章 三核鎳金屬串錯合物之合成與物理性質研究 58 4-1 配基之合成 58 4-2 直線型三核鎳金屬串錯合物之合成 59 4-3 結構分析與討論 60 4-4 磁性分析 63 第五章 總結 66 參考文獻 68 附錄 光譜與晶體數據 72 A. Mass, 1H NMR and IR spectra 73 B. Crystal data 84 | |
| dc.language.iso | zh-TW | |
| dc.title | 不對稱配基之新直線型五核鎳金屬串錯合物
的合成與性質研究 | zh_TW |
| dc.title | Syntheses and Studies of the Novel Linear Pentanickel Metal String Complexes with Asymmetric
H2phpdany Ligand | en |
| dc.type | Thesis | |
| dc.date.schoolyear | 98-2 | |
| dc.description.degree | 碩士 | |
| dc.contributor.oralexamcommittee | 陳俊顯(Chun-hsien Chen),王志傑(Chih-Chieh Wang),葉鎮宇(Chen-Yu Yeh) | |
| dc.subject.keyword | 鎳金屬串錯合物,分子金屬導線, | zh_TW |
| dc.subject.keyword | EMACs,Metal String Complexes, | en |
| dc.relation.page | 94 | |
| dc.rights.note | 有償授權 | |
| dc.date.accepted | 2010-07-08 | |
| dc.contributor.author-college | 理學院 | zh_TW |
| dc.contributor.author-dept | 化學研究所 | zh_TW |
| 顯示於系所單位： | 化學系 | |
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