請用此 Handle URI 來引用此文件：
http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/44444完整後設資料紀錄
| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 諶玉真 | |
| dc.contributor.author | Wei-Hsuan Chang | en |
| dc.contributor.author | 張維軒 | zh_TW |
| dc.date.accessioned | 2021-06-15T02:57:58Z | - |
| dc.date.available | 2012-08-14 | |
| dc.date.copyright | 2009-08-14 | |
| dc.date.issued | 2009 | |
| dc.date.submitted | 2009-08-02 | |
| dc.identifier.citation | Reference of Ch. 1
[1] F. S. Bates, G. H. Fredrickson, Annu. Rev. Phys. Chem. 1990, 41, 525. [2] M. Hillmyer, Curr. Opin. Solid State Mater. Sci. 1999, 4, 559. [3] I. W. Hamley, 'Developments in Block Copolymer Science and Technology', John Wiley & Sons, Ltd, 2004. [4] D. G. Bucknall, H. L. Anderson, Science 2003, 302, 1904. [5] M. Lee, B. K. Cho, W. C. Zin, Chem. Rev. 2001, 101, 3869. [6] F. S. Bates, Science 1991, 251, 898. [7] L. Leibler, Macromolecules 1980, 13, 1602. [8] R. D. Groot, T. J. Madden, J. Chem. Phys. 1998, 108, 8713. [9] L. F. Zhang, A. Eisenberg, Science 1995, 268, 1728. [10] L. F. Zhang, A. Eisenberg, J. Am. Chem. Soc. 1996, 118, 3168. [11] D. E. Discher, A. Eisenberg, Science 2002, 297, 967. [12] B. D. Olsen, R. A. Segalman, Mater. Sci. Eng. R-Rep. 2008, 62, 37. [13] F. J. M. Hoeben, P. M. Jonkheijm, E. W., A. P. H. Schenning, J. Chem. Rev. 2005, 105, 1491. [14] J.-H. Ryu, M. Lee, J. Am. Chem. Soc. 2005, 127, 14170. [15] M. Sayar, S. I. Stupp, Macromolecules 2001, 34, 7135. [16] S. Lin, N. Numasawa, T. Nose, J. Lin, Macromolecules 2007, 40, 1684. [17] J.-M. Lehn, Science 2002, 295, 2400. [18] H.-A. Klok, S. Lecommandoux, Adv. Mater. 2001, 13, 1217. [19] S. A. Jenekhe, X. L. Chen, Science 1998, 279, 1903. [20] X. L. Chen, S. A. Jenekhe, Macromolecules 2000, 33, 4610. [21] S. A. Jenekhe, X. L. Chen, J. Phys. Chem. B 2000, 104, 6332. [22] X. L. Chen, S. A. Jenekhe, Langmuir 1999, 15, 8007. [23] S. A. Jenekhe, X. L. Chen, Science 1999, 283, 372. [24] L.-L. Chua, J. Zaumseil, J.-F. Chang, E. C.-W. Ou, P. K.-H. Ho, H. Sirringhaus, R. H. Friend, Nature 2005, 434, 194. [25] J.-F. Wang, J.-K. Feng, A.-M. Ren, X. D. Liu, Y.-G. Ma, P. Lu, H.-X. Zhang, Macromolecules 2004, 37, 3451. [26] A. D. Becke, J. Chem. Phys. 1993, 98, 5648. [27] B. Miehlich, A. Savin, H. Stoll, H. Preuss, Chem. Phys. Lett. 1989, 157, 200. [28] D. Marsitzky, M. Klapper, K. Mullen, Macromolecules 1999, 32, 8685. [29] C. L. Chochos, P. K. Tsolakis, V. G. Gregoriou, J. K. Kallitsis, Macromolecules 2004, 37, 2502. [30] Y.-C. Tung, W.-C. Wu, W.-C. Chen, Macromol. Rapid Commun. 2006, 27, 1838. [31] C.-H. Lin, Y.-C. Tung, J. Ruokolainen, R. Mezzenga, W.-C. Chen, Macromolecules 2008, 41, 8759. [32] C. D. H. Alarcon, S. Pennadam, C. Alexander, Chem. Soc. Rev. 2005, 34, 276. [33] E. S. Gil, S. A. Hudson, Prog. Polym. Sci. 2004, 29, 1173. [34] Y. Zhao, S. Y. Bai, K. Asatryan, T. Galstian, 13, 781., Adv. Funct. Mater. 2003, 13, 781. [35] R. Shenhar, H. Xu, B. L. Frankamp, T. E. S. Mates, A., O. Uzun, V. M. Rotello, J. Am. Chem. Soc. 2005, 127, 16318. [36] D. Y. Chen, M. Jiang, Accounts Chem. Res. 2005, 38, 494. [37] Y. Bae, S. Fukushima, A. Harada, K. Kataoka, 42, 4640., Angew. Chem. Int. Ed. 2003, 42, 4640. [38] H. G. Schild, 17, 163., Prog. Polym. Sci. 1992, 17, 163. [39] M. Yamato, M. Utsumi, A. Kushida, C. Konno, A. Kikuchi, T. Okano, Tissue Eng. 2001, 7, 473. [40] M. E. Callow, J. A. Callow, L. K. Ista, S. E. Coleman, A. C. Nolasco, G. P. Lopez, Appl. Environ. Microbiol. 2000, 66, 3249. [41] L. K. Ista, V. H. Perez-Luna, G. P. Lopez, Appl. Environ. Microbiol. 1999, 65, 1603. [42] G. P. Chen, Y. Imanishi, Y. Ito, J. Biomed. Mater. Res. 1998, 42, 38. [43] F. J. Schmitt, C. S. Park, J., H. Ringsdorf, J. Israelachvili, Langmuir 1998, 14, 2838. [44] X. Chen, X. Ding, Z. Zheng, Y. Peng, Colloid Polym. Sci. 2005, 283, 452. [45] M. Mertoglu, S. Garniera, A. Laschewsky, K. Skrabania, J. Storsberg, Polymer 2005, 46, 7726. [46] C. Li, N. J. Buurma, I. Haq, C. Turner, S. P. Armes, Langmuir 2005, 21, 11026. [47] E. Hasan, M. Zhang, M. A. H. E., C. B. Tsvetanov, J. Macromol. Sci. Part A-Pure Appl. Chem. 2004, A41, 467. [48] Y. Cao, N. Zhao, K. Wu, X. X. Zhu, Langmuir 2009, 25, 1699. [49] D. E. Discher, A. Eisenberg, Science 2002, 297, 967. [50] X. Guo, F. C. Szoka, Accounts Chem. Res. 2003, 36, 335. [51] S. Qin, Y. Geng, D. E. Discher, S. Yang, Adv. Mater. 2006, 18, 2905. [52] M. Hales, C. Barner-Kowollik, T. P. Davis, M. H. Stenzel, Langmuir 2004, 20, 10809. [53] Y. Zhang, S. Luo, S. Liu, Macromolecules 2005, 38, 9813. [54] B. S. Lokitz, A. J. Convertine, R. G. Ezell, A. Heidenreich, Y. Li, C. L. McCormick, Macromolecules 2006, 39, 8594. [55] L. E. Bromberg, E. S. Ron, Adv. Drug Deliv. Rev. 1998, 31, 197. [56] M. Malmsten, B. Lindman, Macromolecules 1992, 25, 5446. [57] Z. Zhang, A. Khan, Macromolecules 1995, 28, 3807. [58] K. Mortensen, S. Perdersen, Macromolecules 1993, 26, 805. [59] P. Alexandridis, J. F. Holzwarth, T. A. Hatton, Macromolecules 1994, 27, 2414. [60] O. Glatter, Macromolecules 1994, 27, 6046. [61] P. Dimitrov, S. Rangelov, A. Dworak, C. B. Tsvetanov, Macromolecules 2004, 37, 1000. [62] P. Dimitrov, S. Rangelov, A. Dworak, N. Haraguchi, A. Hirao, C. B. Tsvetanov, Macromol. Symp. 2004, 215, 127. [63] S. Halacheva, S. Rangelov, C. B. Tsvetanov, Macromolecules 2006, 39, 6845. [64] S. Aoshima, S. Sugihara, J. Polym. Sci. Pol. Chem. 2000, 38, 3962. [65] S. Sugihara, S. Kanaoka, S. Aoshima, J. Polym. Sci. Pol. Chem. 2004, 42, 2601. [66] S. Sugihara, S. Kanaoka, S. Aoshima, Macromolecules 2005, 38, 1919. [67] F. Hua, X. Jiang, B. Zhao, Macromolecules 2006, 39, 3476. [68] Y. Maeda, T. Nakamura, I. Ikeda, Macromolecules 2002, 35, 217. [69] N. A. Yanul, Y. E. Kirsh, S. Verbrugghe, E. J. Goethals, F. E. Du Prez, Macromol. Chem. Phys. 2001, 202, 1700. [70] S. T. Milner, Science 1991, 251, 905. [71] A. Halperin, M. Tirrell, T. P. Lodge, Adv. Polym. Sci. 1992, 100, 31. [72] I. Szleofer, M. A. Carignano, Adv. Chem. Phys. 1996, 94, 165. [73] B. Zhao, W. J. Brittain, Prog. Polym. Sci. 2000, 25, 677. [74] Q. Niu, J. Fre’chet, Angew Chem, Int Ed Engl 1998, 37, 667. [75] R. Singhvi, A. Kumar, G. Lopez, G. Stephanopoulos, D. Wang, G. Whitesides, D. Ingber, Science 1996, 273, 892. [76] C. Chen, M. Mrksich, S. Huang, G. Whitesides, D. Ingber, Science 1997, 276, 1425. [77] A. Balazs, C. Singh, E. Zhulina, D. Gersappe, G. Pickett, MRS Bull 1997, 16, 1. [78] E. Raphae‥l, P. de Gennes, J Phys Chem 1992, 96, 4002. [79] H. Ji, P. de Gennes, Macromolecules 1993, 26, 520. [80] M. Amiji, K. Park, Biomater. Sci. Polym. Ed. 1993, 4, 217. [81] J. Van Zanten, Macromolecules 1994, 27, 6796. [82] J.-F. Joanny, Langmuir 1992, 8, 989. [83] Y. Takei, T. Aoki, K. Sanui, N. Ogata, Y. Sakurai, T. Okano, Macromolecules 1994, 27, 6163. [84] Y. Ito, Y. Ochiai, Y. Park, Y. Imanishi, J. Am. Chem. Soc. 1997, 119, 1619. [85] Y. Ito, Y. Park, Y. Imanishi, J. Am. Chem. Soc. 1997, 119, 2739. [86] Y. Ito, S. Nishi, Y. Park, Y. Imanishi, Macromolecules 1997, 30, 5856. [87] U. Velten, R. Shelden, W. Caseri, U. Suter, Y. Li, Macromolecules 1999, 32, 3590. [88] V. U, T. S, S. RA, C. WR, S. UW, H. R, M. M, Langmuir 1999, 15, 6940. [89] K. Soga, M. Zuckermann, H. Guo, Macromolecules 1996, 29, 1998. [90] P. Mansky, Y. Liu, E. Huang, T. Russell, C. Hawker, Science 1997, 275, 1458. [91] B. Zhao, W. Brittain, J. Am. Chem. Soc. 1999, 121, 3557. [92] E. Parsonage, M. Tirrell, H. Watanabe, R. Nuzzo, Macromolecules 1987, 24, 1987. [93] J. Marra, M. Hair, Colloids Surf. 1989, 34, 215. [94] D. Guzonas, D. Boils, M. Hair, Macromolecules 1991, 24, 3383. [95] G. Fytas, S. Anastasiadis, R. Seghrouchni, D. Vlassopoulos, J. Li, B. Factor, W. Theobald, C. Toprakcioglu, Science 1996, 274, 2041. [96] J. Field, C. Toprakcioglu, R. Ball, H. Stanley, L. Dai, W. Barford, J. Penfold, G. Smith, W. Hamilton, Macromolecules 1992, 25, 434. [97] H. Motschmann, M. Stamm, C. Toprakcioglu, Macromolecules 1991, 24, 3681. [98] T. Kelley, P. Schorr, K. Johnson, M. Tirrell, C. Frisbie, Macromolecules 1998, 31, 4297. [99] E. B. Zhulina, C. Singh, A. C. Balazs, Macromolecules 1996, 29, 6338. [100] E. B. Zhulina, C. Singh, A. C. Balazs, Macromolecules 1996, 26, 8254. [101] S. Minko, J. Macromol. Sci. Part C-Polym. Rev. 2006, 46, 397. [102] B. Zhao, W. J. Brittain, W. Zhou, S. Z. D. Chemg, J. Am. Chem. Soc. 2000, 122, 2407. [103] B. Zhao, W. J. Brittain, W. S. Zhou, S. Z. D. Cheng, Macromolecules 2000, 33, 8821. [104] B. Zhao, W. J. Brittain, Macromolecules 2000, 33, 8813. [105] E. M. Sevick, D. R. M. Williams, Colloid Surf. A-Physicochem. Eng. Asp. 1997, 130, 387. [106] W.-C. Wu, Y. Tian, C.-Y. Chen, C.-S. Lee, Y.-J. Sheng, W.-C. Chen, A. K.-Y. Yen, Langmuir 2007, 23, 2805. Reference of Ch. 2 [1] R. D. Groot, P. B. Warren, J. Chem. Phys. 1997, 107, 4423. [2] R. D. Groot, Lect. Notes Phys. 2004, 640, 5. [3] P. J. Hoogerbrugge, J. M. V. A. Koelman, Europhys. Lett. 1992, 19, 155. [4] J. M. V. A. Koelman, P. J. Hoogerbrugge, Europhys. Lett. 1993, 21, 363. [5] Y. Kong, C. W. Manke, W. G. Madden, A. G. Schlijper, Int. J. Thermophys 1994, 15, 1093. [6] A. G. Schlijper, P. J. Hoogerbrugge, C. W. Manke, J. Rheol 1995, 39, 567. [7] P. Espanol, P. B. Warren, Europhys. Lett. 1995, 30, 191. [8] M. P. Allen, D. J. Tildesley, 'Computer Simulation of Liquids', Oxford, Clarendon, 1987. [9] Y. K. Levine, A. E. Gomes, A. F. Martins, A. Polimeno, J. Chem. Phys. 2005, 122, 144902. [10] A. AlSunaidi, W. K. d. Otter, J. H. R. Clarke, Phil. Trans. R. Soc. Lond. A 2004, 362, 1773. [11] M. Kranenburg, M. Venturoli, B. Smit, J. Phys. Chem. B 2003, 107, 11491. Reference of Ch. 3 [1] S. T. Lin, Y. C. Tung, W. C. Chen, J. Mater. Chem. 2008, 18, 3985. [2] W.-C. Wu, Y. Tian, C.-Y. Chen, C.-S. Lee, Y.-J. Sheng, W.-C. Chen, A. K.-Y. Yen, Langmuir 2007, 23, 2805. [3] Y.-C. Tung, W.-C. Wu, W.-C. Chen, Macromol. Rapid Commun. 2006, 27, 1838. [4] C. L. Chochos, P. K. Tsolakis, V. G. Gregoriou, J. K. Kallitsis, Macromolecules 2004, 37, 2502. [5] A. Bug, M. Cates, S. Safran, T. Witten, J. Chem. Phys. 1987, 87, 1824. [6] J. Marra, M. Hair, Colloids Surf. 1989, 34, 215. [7] D. Guzonas, D. Boils, M. Hair, Macromolecules 1991, 24, 3383. [8] G. Fytas, S. Anastasiadis, R. Seghrouchni, D. Vlassopoulos, J. Li, B. Factor, W. Theobald, C. Toprakcioglu, Science 1996, 274, 2401. [9] J. Field, C. Toprakcioglu, R. Ball, H. Stanley, L. Dai, W. Barford, J. Penfold, G. Smith, W. Hamilton, Macromolecules 1992, 25, 434. [10] H. Motschmann, M. Stamm, C. Toprakcioglu, Macromolecules 1991, 24, 3681. [11] C.-H. Lin, Y.-C. Tung, J. Ruokolainen, R. Mezzenga, W.-C. Chen, Macromolecules 2008, 8759. [12] D. Marsitzky, M. Klapper, K. Mullen, Macromolecules 1999, 32, 8685. Reference of Ch. 4 [1] W.-C. Wu, Y. Tian, C.-Y. Chen, C.-S. Lee, Y.-J. Sheng, W.-C. Chen, A. K.-Y. Yen, Langmuir 2007, 23, 2805. [2] L. Ren, S. Agarwal, Macromol. Chem. Phys. 2007, 208, 245. [3] J.-C. Ruiz, G. Burillo, E. Bucio, Macromol. Mater. Eng. 2007, 292, 1176. [4] M. Heskins, J. E. Guillet, J. Macromol. Sci. Chem. 1968, A2, 1441. [5] B. Sun, Y. Lin, P. Wu, H. W. Siesler, Macromolecules 2008, 41, 1512. [6] H. Cheng, L. Shen, C. Wu, Macromolecules 2006, 39, 2325. [7] Y. Ding, X. Ye, G. Zhang, Macromolecules 2005, 38, 904. [8] W. Zhang, N. Zhou, Z. Cheng, J. Zhu, X. Zhu, Polymer 2008, 49, 4569. [9] D. Neher, Macromol. Rapid Commun. 2001, 22, 1365. [10] V. N. Bliznyuk, S. A. Carter, J. C. Scott, G. Klaerner, R. D. Miller, D. C. Miller, Macromolecules 1999, 32, 361. Reference of Appendix [1] K. Matyjaszewski, J. Xia, Chem. Rev. 2001, 101, 2921. [2] M. Fukuda, K. Sawada, K. Yoshino, Jpn. Appl. Phys. 1989, 28, L1433. [3] T. Yamamoto, T. Maruyama, Z.-h. Zhou, T. Ito, T. Fukuda, Y. Yoneda, F. Begum, T. Ikeda, S. Sasaki, H. Takezoe, A. Fukuda, K. Kubota, J. Am. Chem. Soc. 1994, 116, 4832. [4] Q. B. Pei, Y. Yang, J. Am. Chem. Soc. 1996, 118, 7416. [5] H.-G. Nothofer, A. Meisel, T. Miteva, D. Neher, M. Forster, M. Oda, G. Lieser, D. Sainova, A. Yasuda, D. Lupo, W. Knoll, U. Scherf, Macromol. Symp. 2000, 154, 139. [6] U. Scherf, E. J. W. List, Adv. Mater. 2002, 14, 477. [7] N. Miyaura, A. Suzuki, Chem. Rev. 1995, 95, 2457. [8] M. Ranger, M. Leclerc, Macromolecules 1997, 30, 7686. [9] M. T. Bernius, M. Inbasekaran, J. O'Brien, W. S. Wu, Adv. Mater. 2000, 12, 1737. [10] A. J. Cadby, P. A. Lane, H. Mellor, S. J. Martin, M. Grell, C. Giebeler, D. D. C. Bradley, M. Wohlgenannt, C. An, Z. V. Vardeny, Phys. Rev. B 2000, 62, 15604. | |
| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/44444 | - |
| dc.description.abstract | 本研究利用理論預測及實驗操作交互驗證的方式來研究共軛性硬桿-溫感性柔軟嵌段共聚高分子刷之表面結構。根據以耗散粒子動力學為基礎的模擬結果，我們發現這類溫度敏感性的高分子刷表面結構會受溫度刺激、高分子刷表面接枝密度與硬桿/柔軟嵌段長度比例的影響而有所改變。在溫度低時，會出現由硬桿所聚集而成的半圓球形聚集結構。隨著溫度的提高，這些聚集結構會轉換成島狀、蟲狀甚至是連結網狀的型態，其型態變化與高分子刷表面接枝密度相關。同時，這些由硬桿所組成的聚集體在溫度低時會受軟鏈保護而沉入軟鏈中，但隨著溫度的提升又會暴露於表面，聚集體受保護的程度則會受軟鏈長度的不同而改變。
爲了驗證此理論模擬的準確性，本研究合成了兩種不同硬桿/柔軟嵌段長度比例的聚芴-聚(氮-異丙基丙烯醯胺)嵌段共聚高分子，並利用物理吸附方法製備這兩種嵌段共聚高分子的高分子刷表面。藉由原子力顯微鏡的鑑定，吾人發現此高分子刷的表面結構會隨著溫度呈現可逆性變化。同時，接觸角測試結果顯示表面在升溫處理後變的稍加疏水，此即驗證了硬桿聚集體暴露於表面的現象。對應於光電性質，吾人發現因芴系分子聚集所產生之額外螢光放光峰確實存在，同時其波峰強度會隨溫度的變化而有所增強或削減。本研究顯示吾人可利用溫度來調控高分子刷的表面結構及其對應的光電性質，而這些結果皆與理論模擬相互呼應。 | zh_TW |
| dc.description.abstract | A combined theoretical and experimental investigation is performed to study the surface morphology of conjugated rod-coil block copolymer brushes. Based on dissipative particle dynamics, the surface structures of thermoresponsive polymer brushes are found to alter significantly in response to the effects of thermal stimuli, grafting density, and rod-coil block ratio of the polymer brushes. Small, hemispherical domains of the aggregation of rod-blocks are formed at low temperature. As the temperature increases, the conformations transform to isolated islands, worm-like structures, or even network-like morphologies depending on the grafting density. Furthermore, the aggregations tend to submerge into coil block at first and float on the top as the temperature increases. The degree of submergence depends on rod-coil block ratio of the polymer brushes. In the experimental part, two Poly[2,7-(9,9-dihexylfluorene)]-b-poly[N-isopropylacrylamide] (PF-b-PNIPAAm) rod-coil block copolymer with different block ratios are synthesized and used to prepare corresponding polymer brushes on the quartz glass by physisorption. The morphology on the top of the surface is characterized by atomic force microscopy image. The results show a thermoresponsive transformation via temperature variation and are consistent with theoretical predictions. In addition, the surface is verified to be more hydrophobic after temperature treatment by contact angle measurements, suggesting the flotation of the rod aggregative domain on the top. The photophysical properties of PF-b-PNIPAAm polymer brushes are also found to vary by thermal stimuli. The PL spectra reveals that emission peaks originated from the aggregation and/or excimer formation of PF blocks and the intensity slightly changes through temperature variation. Our study demonstrates that the surface morphology of polymer brush and its corresponding photophysical property can be tuned by thermal stimuli. | en |
| dc.description.provenance | Made available in DSpace on 2021-06-15T02:57:58Z (GMT). No. of bitstreams: 1 ntu-98-R96549004-1.pdf: 6882907 bytes, checksum: 2667deb80821f51193f989a3babf8752 (MD5) Previous issue date: 2009 | en |
| dc.description.tableofcontents | 致謝 I
摘要 III Abstract IV Content VI Table Captions VIII Scheme Captions IX Figure Captions X Introduction 1 1-1 Block Copolymers 1 1-2 Π-Conjugated Rod-Coil Block Copolymer 4 1-2-1 Chemical Structures of Π-conjugated Systems 6 1-2-2 Self-Assembly Principles of Π-conjugated Systems 7 1-2-3 Self-assembly of Π-conjugated Rod-coil Block Copolymer in Solution 9 1-3 Stimuli-responsive Block Copolymers 16 1-4 Block Copolymer Brushes 26 1-5 Research Objectives 36 Reference 38 Theoretical Analysis 43 2-1 Dissipative Particle Dynamics (DPD) Simulation Method 43 2-2 Basic of DPD Simulation Method 45 2-3 Model and Parameters for Rod-Coil Block Copolymer Brushes 53 Reference 58 Experimental Section 59 3-1 Material 59 3-2 Synthesis of PF-b-PNIPAAm Rod-Coil Diblock Copolymers 59 3-3 Preparation of PF-b-PNIPAAm of Diblock Coplymer Brushes 60 3-4 Thermal Stimuli on the PF-b-PNIPAAm Diblock Coplymer Brushes 61 3-5 Characterization 61 Reference 64 Results and Discussion 65 4-1 Theoretical Prediction on the Rod-Coil Block Copolymer Brushes 65 4-1-1 Effect of Thermal Stimuli on the Surface Structure 65 4-1-2 Effect of Grafting Density on the Surface Structure 70 4-1-3 Effect of Block Ratio on the Surface Structure 74 4-1-4 Polymer Brushes Based on Physiosorption 78 4-2 Experimental Results of PF-b-PNIPAAm Diblock Coplymer Brushes 82 4-2-1 Synthesis and Characterization 82 4-2-2 Characterization of Modified Substrate and Polymer Brushes Prepared 86 4-2-3 Surface Structure of PF-b-PNIPAAm Polymer Brushes 90 4-2-4 Temperature Effect on the Surface Structure of PF-b-PNIPAAm Polymer Brushes 90 4-2-5 Photophysiscal Properties of PF-b-PNIPAAm Polymer Brushes 103 Reference 113 Conclusion 114 Appendix 116 Appendix I: Basic of Atom transfer radical polymerization 116 Appendix II: Synthesis of Polyfluorene 118 Appendix III: Other Simulation Results 122 Appendix IV: Other Experiment Results 128 Reference 131 | |
| dc.language.iso | en | |
| dc.subject | 光電性質 | zh_TW |
| dc.subject | 芴系高分子 | zh_TW |
| dc.subject | 溫感性高分子 | zh_TW |
| dc.subject | 硬桿-軟鏈嵌段式共聚物 | zh_TW |
| dc.subject | 高分子刷 | zh_TW |
| dc.subject | 表面結構 | zh_TW |
| dc.subject | polymer brush | en |
| dc.subject | photophysical property | en |
| dc.subject | surface structure | en |
| dc.subject | polyfluorene | en |
| dc.subject | thermoresponsive polymer | en |
| dc.subject | rod-coil block copolymer | en |
| dc.title | 芴系硬桿及溫感性軟鏈之嵌段式共聚物 (PF-b-PNIPAAm) 高分子刷表面結構之研究 | zh_TW |
| dc.title | Theoretical and Experimental Studies on the Surface Structure of PF-b-PNIPAAm Rod-Coil Block Copolymer Brushes | en |
| dc.type | Thesis | |
| dc.date.schoolyear | 97-2 | |
| dc.description.degree | 碩士 | |
| dc.contributor.coadvisor | 陳文章 | |
| dc.contributor.oralexamcommittee | 曹恆光,林祥泰,陸駿逸 | |
| dc.subject.keyword | 芴系高分子,溫感性高分子,硬桿-軟鏈嵌段式共聚物,高分子刷,表面結構,光電性質, | zh_TW |
| dc.subject.keyword | polyfluorene,thermoresponsive polymer,rod-coil block copolymer,polymer brush,surface structure,photophysical property, | en |
| dc.relation.page | 131 | |
| dc.rights.note | 有償授權 | |
| dc.date.accepted | 2009-08-03 | |
| dc.contributor.author-college | 工學院 | zh_TW |
| dc.contributor.author-dept | 高分子科學與工程學研究所 | zh_TW |
| 顯示於系所單位： | 高分子科學與工程學研究所 | |
文件中的檔案：
| 檔案 | 大小 | 格式 | |
|---|---|---|---|
| ntu-98-1.pdf 未授權公開取用 | 6.72 MB | Adobe PDF |
系統中的文件，除了特別指名其著作權條款之外，均受到著作權保護，並且保留所有的權利。