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完整後設資料紀錄
DC 欄位 | 值 | 語言 |
---|---|---|
dc.contributor.advisor | 謝國煌(Kuo-Huang Hsieh) | |
dc.contributor.author | Tsung-Han Ko | en |
dc.contributor.author | 葛宗翰 | zh_TW |
dc.date.accessioned | 2021-06-15T02:45:00Z | - |
dc.date.available | 2016-10-21 | |
dc.date.copyright | 2011-10-21 | |
dc.date.issued | 2011 | |
dc.date.submitted | 2011-08-16 | |
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dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/44208 | - |
dc.description.abstract | 在本研究中,藉由苯硼酸利用鈴木偶合反應在4,4´-二氟二苯碸上接枝含有苯環側鏈的新單體,接著在利用此新單體磺酸化後合成出新的側鏈磺酸化單體。
磺酸化單體利用親核性芳香取代反應合成出具有主鏈磺酸根之磺化聚醚碸與側鏈磺酸根之磺化聚醚碸P2。 藉由此二高分子可以製備出質子交換膜,且帶有側鏈的磺化聚醚碸在70°C時有57-183 mS/cm的高質子傳導度表現。 側鏈磺化聚醚碸在阻擋甲醇滲透方面的表現(0.35-1.368 cm2/s)也來的比Nafion好(1.45 cm2/s)。 綜合全部的數據指出,側鏈磺化聚醚碸表現出優異的電池效能,側鏈磺化聚醚碸於直接甲醇燃料電池的使用上也擁有相當高的潛力。 | zh_TW |
dc.description.abstract | In this studies,novel monomers containing two phenyl groups has been synthesized by bromination of bis(4-fluorophenyl) sulfone, via Suzuki coupling with benzeneboronic acid. The resulting monomers were converted to the corresponding sulfonated monomers having two pendent sulfonic acid groups.
Aromatic nucleophilic substitution (SNAr) polycondensation using the disulfonated monomers provided sulfonated poly(arylene ether sulfone) polymers P1 and P2. Flexible and tough membranes having high mechanical strength were obtained by solution casting of all two series of polymers. The polymers with two pendent sulfonic acid groups had high proton conductivities in the range of 57-183 mS/cm for P2-xx at 70°C, respectively. The methanol permeabilities of these polymers were in the range of (0.35-1.368 cm2/s), which is lower than Nafion (1.45 cm2/s). In proton exchange membrane fuel cell test, P2-70 membranes showed the good cell performance. This study suggests that the P2 membranes also have high potential for direct methanol fuel cell application. | en |
dc.description.provenance | Made available in DSpace on 2021-06-15T02:45:00Z (GMT). No. of bitstreams: 1 ntu-100-R98549030-1.pdf: 2435593 bytes, checksum: 115ff080f4776b02295076fcd5fd2ce3 (MD5) Previous issue date: 2011 | en |
dc.description.tableofcontents | 論文口試委員審定書 I
誌謝 II 中文摘要 II Abstract IV 目錄 V 圖次 VII 第一章 緒論 1 1-1前言 1 1-2 燃料電池的發展歷史與現況 4 1-3 研究目的與內容 5 第二章 理論與文獻探討 7 2-1 燃料電池的基本原理3, 10 7 2-2 燃料電池的種類 7 2-3 質子交換膜燃料電池(PEMFC)之介紹 9 2-4 質子交換膜發展及進展 11 2-5 Nafion(全氟磺酸樹酯)簡介12 13 2-6 磺化聚醚碸Sulfonated Poly(arylene ether sulfone)之發展簡介 16 2-7 側鏈磺酸化聚醚碸之發展簡介 18 第三章 實驗藥品與實驗儀器 19 3-1 實驗藥品 19 3-2 實驗儀器 22 3-3 合成步驟與數據 25 第四章 結果與討論 41 4-1合成鑑定與性質探討 41 4-1-1 單體合成 41 4-1-2 高分子合成 46 4-1-3 磺酸化聚醚碸熱穩定性質探討 47 4-2質子交換膜之物性分析 52 4-3 PEMFC效能分析 66 4-3-1 溫度的影響 67 4-3-2磺酸根含量的影響 69 第五章 結論 73 第六章 參考文獻 74 附錄I P2在6M濃度下之甲醇穿透率 80 附錄II NMR圖譜 82 附錄III MASS圖譜 96 | |
dc.language.iso | zh-TW | |
dc.title | 燃料電池質子交換膜用磺化聚醚碸之製備與性質研究 | zh_TW |
dc.title | Preparation of Sulfonated Poly(arylene ether sulfone)Membrane and The Performance for Proton Exchange Membrane Fuel Cell | en |
dc.type | Thesis | |
dc.date.schoolyear | 99-2 | |
dc.description.degree | 碩士 | |
dc.contributor.oralexamcommittee | 王怡仁,韓錦鈴,李其鴻 | |
dc.subject.keyword | 磺化聚醚碸,燃料電池,質子交換膜, | zh_TW |
dc.subject.keyword | Sulfonated Poly(arylene ether sulfone),fuel cell,proton exchange membrane, | en |
dc.relation.page | 99 | |
dc.rights.note | 有償授權 | |
dc.date.accepted | 2011-08-17 | |
dc.contributor.author-college | 工學院 | zh_TW |
dc.contributor.author-dept | 高分子科學與工程學研究所 | zh_TW |
顯示於系所單位: | 高分子科學與工程學研究所 |
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