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  1. NTU Theses and Dissertations Repository
  2. 工學院
  3. 應用力學研究所
請用此 Handle URI 來引用此文件: http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/43970
完整後設資料紀錄
DC 欄位值語言
dc.contributor.advisor吳政忠(Tsung-Tsong Wu)
dc.contributor.authorYa-Shan Huangen
dc.contributor.author黃亞珊zh_TW
dc.date.accessioned2021-06-15T02:34:36Z-
dc.date.available2013-08-18
dc.date.copyright2009-08-18
dc.date.issued2009
dc.date.submitted2009-08-13
dc.identifier.citation[1] H. T. Wang, B. S. Kang, F. Ren, L. C. Tien, P. W. Sadik, D. P. Norton, S. J. Pearton, and J. Lin, 'Hydrogen-selective sensing at room temperature with ZnO nanorods,' Applied Physics Letters, vol. 86, pp. 243503-3, 2005.
[2] H. T. Wang, B. S. Kang, F. Ren, L. C. Tien, P. W. Sadik, D. P. Norton, S. J. Pearton, and J. Lin, 'Detection of hydrogen at room temperature with catalyst-coated multiple ZnO nanorods,' Applied Physics A: Materials Science & Processing, vol. 81, pp. 1117-1119, 2005.
[3] X. Lu, S. Wu, L. Wang, and Z. Su, 'Solid-state amperometric hydrogen sensor based on polymer electrolyte membrane fuel cell,' Sensors and Actuators B: Chemical, vol. 107, pp. 812-817, 2005.
[4] N. TasaltIn, F. Dumludag, M. A. Ebeoglu, H. Yuzer, and Z. Z. Ozturk, 'Pd/native nitride/n-GaAs structures as hydrogen sensors,' Sensors and Actuators B: Chemical, vol. 130, pp. 59-64, 2008.
[5] I. C. Yen, C. Chia-Ming, L. Wen-Chau, and C. Huey-Ing, 'A new Pd-InP Schottky hydrogen sensor fabricated by electrophoretic deposition with Pd nanoparticles,' Electron Device Letters, IEEE, vol. 26, pp. 62-65, 2005.
[6] L. F. Houlet, W. Shin, K. Tajima, M. Nishibori, N. Izu, T. Itoh, and I. Matsubara, 'Thermopile sensor-devices for the catalytic detection of hydrogen gas,' Sensors and Actuators B: Chemical, vol. 130, pp. 200-206, 2008.
[7] F. C. Huang, Y. Y. Chen, and T. T. Wu, “A room temperature surface acoustic wave hydrogen sensor with Pt coated ZnO nanorods,” Nanotechnology, vol. 20, pp. 065501, 2009.
[8] R. M. White and F. W. Voltmeter, “Direct Piezoelectric Coupling to Surface Elastic Waves,” Applied Physics Letter, vol. 7, pp. 314-316, 1965.
[9] P. H. Cole and R. Vaughn, “ELECTRONIC SURVEILLANCE SYSTEM,” United States Patent 3707711, 1972.
[10] X. Q. Bao, W. Burkhard, V. V. Varadan, and V. K. Varadan, ”SAW temperature sensor and remote reading system,” IEEE Ultrasonics Symposium, pp. 583-585, 1999.
[11] K. Yamanouchi, G. Shimizu, and K. Morishita, “2.5GHz SAW Propagation and Refltion Characteristics and Application to Passive Electronic Tag and Matched Filter,” IEEE Ultrasonics Symposium, pp 1267-1270, 1993.
[12] R. Steindl, A. Pohl, and F. Seifert, “Impedance Loaded SAW Sensors Offer a Wide Range of Measurement Opportunities,” IEEE Transactions on Microwave Theory and Techniques, vol. 47, pp. 2625-2629, 1999.
[13] R. D. Wang, “A Wireless SAW Hybrid Sensor for Simultaneous Temperature and Humidity Measurements,” Master thesis, the Institute of Applied Mechanics at the National Taiwan University, Taiwan, 2007.
[14] C. Liu and D. D. Macdonald, “An advanced Pd/Pt relative resistance sensor for the continuous monitoring of dissolved hydrogen in aqueous systems at high subcritical and supercritical temperatures,” The Journal of Supercritical Fluids, vol. 8, pp. 263-270, 1995.
[15] F. Favier, E. C. Walter, M. P. Zach, T. Benter, and R. M. Penner, “Hydrogen Sensors and Switches from Electrodeposited Palladium Mesowire Arrays,” Science, vol. 293, pp. 2227-2231, 2001.
[16] B. P. Abbott, “A Coupling-of-Modes Model For SAW Transducers With Arbitrary Reflectivity Weighting,” Ph. D dissertation, the Department of Electrical Engineering at the University of Central Florida Orlando, Florida, 1989.
[17] B. P. Abbott, C. S. Hartmann and D. C. Malocha, “A Coupling-of-Modes Analysis of Chirped Transducers Containing Reflective Electrode Geometries,” IEEE Ultrasonics Symposium, pp 129-134, 1989.
[18] B. P. Abbott, “A Derivation of the Coupling-of-Modes Parameters Based on the Scattering Analysis of SAW Transducers and Gratings,” IEEE Ultrasonics Symposium, pp 5-10, 1991.
[19] B. P. Abbott, C. S. Hartmann and D. C. Malocha, “Transduction Magnitude and Phase for COM Modeling of SAW Devices,” IEEE Transactions on Ultrasonics, Ferroelectrics, and Frequency Control, vol. 39, pp. 55-60, 1992.
[20] C. M. Shiu, “UHF Band SAW Based RFID Sensor System,” Master thesis, Institute of Applied Mechanics, National Taiwan University, Taipei, Taiwan, 2005.
[21] Y. Y. Chen, T. H. Chou, and T. T. Wu, “A high sensitivity nanomaterial based SAW humidity sensor,” Journal of Physics D: Applied Physics, vol. 41, pp. 085101, 2008
dc.identifier.urihttp://tdr.lib.ntu.edu.tw/jspui/handle/123456789/43970-
dc.description.abstract在面臨能源危機的時代,使用清潔能源的汽車已逐漸成為日後發展的主流,其中氫氣即為備受矚目的替代能源之一,然而氫氣具有無色無味的特性,且濃度在介於4%到75%時會有自燃或是爆炸的危險性,因此氫氣偵測的工作亦開始受到重視。在氫氣儲存和運送的過程中,即時地監測氫氣濃度對於環境保護及人身安全都非常的重要,在此使用具有無線傳輸能力的氫氣感測器便可提供極佳的便利性,此外無須電池的被動式氫氣感測器,更可免除更換電池的困擾且降低系統成本。因此為了提高量測便利性及減少成本的考量,便開啟了被動表面聲波式無線氫氣感測器的研發。
本文中使用了中心頻率為433MHz的128°YX-LiNbO3做為表面聲波識別標籤之基板,再附加一個電阻式氫氣感測器,已成功整合成阻抗加載型的被動表面聲波式感測器。此量測系統的優點如下:無線傳輸,被動式架構,以及為質輕微小之元件。
首先,本論文藉由耦合模型理論而設計出表面聲波識別標籤之相關參數,並模擬得知其所對應之頻率響應,再由快速傅立葉轉換得到識別標籤的時間域訊號。接下來則製作一電阻式感測器,其中感測材料需具有高穩定度、重複使用性以及製程簡便等優點,因此選定氧化鋅奈米柱,而為了讓本架構可在常溫下使用,故於奈米柱之上鍍白金作為催化劑。之後,將電阻式感測器和表面聲波識別標籤接合,以組合出阻抗加載型的被動表面聲波式感測器。最後,即結合感測器及量測腔體以完成實驗架設。由實驗結果可知:本感測器對於氫氣具有極佳的靈敏度,且有重覆使用性。
zh_TW
dc.description.abstractFor an energy crisis, the clean fuel is gradually taken seriously. Hydrogen is an alternative energy source, and now hydrogen vehicles are not a reality but a product on the market. Hydrogen gas is colorless, tasteless and flammable. When concentrations of hydrogen are between 4% and 75%, hydrogen is subject to combustion and explosion risk. During the process of hydrogen gas storage and transportation, monitoring the condition of hydrogen gas is important for environmental protection and human safety. Besides, it is convenient to use a hydrogen sensor, especially the passive wireless hydrogen sensor. A passive device doesn’t need a battery, and the cost will be reduced greatly. Hence, the passive wireless hydrogen SAW sensor is developed for its convenience and low cost.
In this thesis, an impedance-loaded SAW sensor is achieved by combining the SAW tag whose substrate is the 433MHz 128˚ YX-LiNbO3 and a resistive hydrogen sensor. First, the coupling-of-modes model is used to design the parameters of the SAW tag and predict the frequency response. Then, by employing the fast Fourier transform the signals in time domain can be obtained. The resistive hydrogen sensor whose sensing film is the Pt-coated ZnO nanorods has the advantages of high stability, repeatability and easy fabrication. Finally, the sensor is formed and measured to evaluate performances. The results show that this SAW sensor has good repeatability and high sensitivity, and its advantages are wireless transmission, passive mode and mini size.
en
dc.description.provenanceMade available in DSpace on 2021-06-15T02:34:36Z (GMT). No. of bitstreams: 1
ntu-98-R96543003-1.pdf: 2349016 bytes, checksum: fe68bb8bf4bf557a5374d88ca80c93fb (MD5)
Previous issue date: 2009
en
dc.description.tableofcontents誌謝 i
中文摘要 ii
Abstract iii
Notations iv
Table of Contents vii
List of Figures ix
List of Tables xi
Chapter 1 Introduction 1
1.1 Motivation 1
1.2 Classification of Hydrogen Sensors 2
1.3 Literature Review 3
1.4 Contents of the Chapters 5
Chapter 2 Theories and Analysis of SAW Tag 8
2.1 Coupling-of-Modes Model 8
2.1.1 First Order Wave Equations 9
2.1.2 Propagation Loss 11
2.1.3 Electrode Reflections 11
2.1.4 Transduction Coupling 15
2.1.5 [P] Matrix 17
2.2 Coupling-of- Modes Parameters 22
2.2.1 Average Surface Acoustic Wave Velocity Shift 22
2.2.2 Reflection Coefficient 24
2.2.3 Transduction Coefficient 25
2.2.4 Electrode Resistance and Capacitance 26
2.2.5 Attenuation Coefficient 27
2.3 Simulation of SAW Tag 28
2.3.1 IDT Type Reflectors 29
2.3.2 Impedance-Loaded Reflector 30
2.3.3 Frequency Response of SAW Tag 31
Chapter 3 Setup of a Wireless Hydrogen SAW Sensor System 43
3.1 Principle of a Wireless Hydrogen SAW Sensor 43
3.2 Sensor Fabrication 44
3.2.1 Fabrication of a SAW Tag 44
3.2.2 Electrodes of a Resistive Hydrogen Sensor Fabrication 46
3.3 Fabrication of Pt-coated ZnO Nanorods 47
3.4 Experimental Setups 48
3.4.1 Combination of a SAW Tag and Antenna by Impedance Matching 49
3.4.2 Wireless Transceiver System 49
3.4.3 Gas Flow System 50
Chapter 4 Measurement Results 62
4.1 Signal Processing Techniques 62
4.2 Measurement of Impedance-Loaded Sensor 63
4.2.1 Measurements of Sensor toward Various Hydrogen Concentrations 63
4.2.2 Responses to Various Relative Humidity and Different Temperature 65
4.3 Measurements of Wireless Hydrogen SAW Sensor 66
4.3.1 Response of Sensor to Various Hydrogen Concentrations 67
Chapter 5 Conclusions and Future Work 77
5.1 Conclusions 77
5.2 Future Work 78
References 79
dc.language.isoen
dc.subject白金zh_TW
dc.subject無線zh_TW
dc.subject氧化鋅奈米柱zh_TW
dc.subject氫氣感測器zh_TW
dc.subject被動表面聲波式zh_TW
dc.subject被動式zh_TW
dc.subjectSurface acoustic waveen
dc.subjectZnO nanorodsen
dc.subjectPten
dc.subjectHydrogen sensoren
dc.subjectPassiveen
dc.subjectWirelessen
dc.title室溫量測之被動式表面聲波無線氫氣感測器zh_TW
dc.titleA Room Temperature Passive Wireless Hydrogen SAW Sensoren
dc.typeThesis
dc.date.schoolyear97-2
dc.description.degree碩士
dc.contributor.oralexamcommittee郭茂坤,吳文方,陳永裕(Yung-Yu Chen)
dc.subject.keyword被動表面聲波式,無線,被動式,氫氣感測器,氧化鋅奈米柱,白金,zh_TW
dc.subject.keywordSurface acoustic wave,Wireless,Passive,Hydrogen sensor,Pt,ZnO nanorods,en
dc.relation.page81
dc.rights.note有償授權
dc.date.accepted2009-08-14
dc.contributor.author-college工學院zh_TW
dc.contributor.author-dept應用力學研究所zh_TW
顯示於系所單位:應用力學研究所

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