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| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 李君浩(Jiun-Haw Lee) | |
| dc.contributor.author | Chia-Hsun Chen | en |
| dc.contributor.author | 陳佳勳 | zh_TW |
| dc.date.accessioned | 2021-05-14T17:42:01Z | - |
| dc.date.available | 2020-08-21 | |
| dc.date.available | 2021-05-14T17:42:01Z | - |
| dc.date.copyright | 2015-08-21 | |
| dc.date.issued | 2015 | |
| dc.date.submitted | 2015-08-20 | |
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| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/4391 | - |
| dc.description.abstract | 本論文旨有其二，第一部分將介紹藉由合成四個新的施體材料運用於有機太陽能電池元件，其結構施體-施體-受體型小分子。7-(5-(di-p-tolylamino)thiophen-2-yl)benzo[c][1,2,5]thiadiazole-4-carbonitrile (DTCTB), 7-(4-(di-p-tolylamino)phenyl)benzo[c][1,2,5]thiadiazole-4-carbonitrile (DTCPB), 7-(5-(di-p-tolylamino)thiophen-2-yl)benzo[c][1,2,5]oxadiazole-4-carbonitrile (DTCTBO), 及7-(4-(di-p-tolylamino)phenyl)benzo[c][1,2,5]oxadiazole-4-carbonitrile (DTCPBO).，在一系列由混和濃度及膜厚變化之塊材異質混和界面架構下，利用與受體材料碳70混合，我們可得以四個小分子DTCPB, DTCTB, DTCPBO 及 DTCTBO所製成太陽能電池之最佳化功率轉換效率分別為6.55%, 4.40%, 5.98% 及4.65%。
二者， 我們使用暫態螢光之量測，來瞭解5,6,11,12-tetraphenylnaphthacene (rubrene)之單重態分裂(singlet fission)與三重態激子融合(triplet fusion)動態特性。在不同溫度及單重態-單重態滅絕可忽略之前提下，單重態分裂之活化動能可被決定。再者在膜厚較薄之薄膜中，由於空間局限之故，其會表現出較高機率之三重態激子融合速率。 | zh_TW |
| dc.description.abstract | There are two parts in this dissertation. In the first part, we employed four donor-donor-acceptor (D-A-A) configurations molecules, 7-(5-(di-p-tolylamino)thiophen-2-yl)benzo[c][1,2,5]thiadiazole-4-carbonitrile (DTCTB), 7-(4-(di-p-tolylamino)phenyl)benzo[c][1,2,5]thiadiazole-4-carbonitrile (DTCPB), 7-(5-(di-p-tolylamino)thiophen-2-yl)benzo[c][1,2,5]oxadiazole-4-carbonitrile (DTCTBO), and 7-(4-(di-p-tolylamino)phenyl)benzo[c][1,2,5]oxadiazole-4-carbonitrile (DTCPBO) as electron donor materials for organic solar cell applications. By a series of methodical optimization, the highest power conversion efficiencies are 6.55%, 4.40%, 5.98%, 4.65% for DTCPB, DTCTB, DTCPBO and DTCTBO respectively with bulk heterojunction configuration.
In the second part of this dissertation, the exciton dynamic of 5,6,11,12-tetraphenylnaphthacene (rubrene) was investigated by transient photoluminescence (TrPL) measurements. With low excitation energy (to avoid singlet-singlet annihilation) at different temperatures, the activation energy of singlet fission (SF) in rubrene thin film can be obtained. We also found that the thinner rubrene exhibited higher fusion rate, which may result from higher probability for non-germinate recombination. | en |
| dc.description.provenance | Made available in DSpace on 2021-05-14T17:42:01Z (GMT). No. of bitstreams: 1 ntu-104-R02941007-1.pdf: 4228074 bytes, checksum: f97fce808ca51eec1d6f897431196308 (MD5) Previous issue date: 2015 | en |
| dc.description.tableofcontents | 致謝 ii
摘要 iv Abstract v Content vi 1 Chapter 1 Introduction 1 1.1 Overview 1 1.2 Small molecule organic solar cells 2 1.2.1 Introduction of OSC 2 1.2.2 Bulk heterojunction configuration 4 1.2.3 D-A-A system organic materials 5 1.2.4 Recombination mechanisms of OSC 7 1.3 Singlet fission 9 1.3.1 Introduction 9 1.3.2 Exciton dynamics of aromatic based materials 11 1.3.3 Caging effect 14 1.4 Motivation 15 2 Chapter 2 Experiments 17 2.1 Introduction 17 2.2 Device fabrication and measurement systems for OSC 17 2.2.1 Substrate patterning 17 2.2.2 Device fabrication 18 2.2.3 Device performances measurement 19 2.2.4 Measurement of external quantum efficiency (EQE) 20 2.2.5 Absorption spectrum measurement 21 2.2.6 Measurement of optical constants 21 2.2.7 Sun variation system 22 2.3 Sample fabrication and measurement systems for exciton dynamics 23 2.3.1 Samples fabricated for exciton dynamic investigation 23 2.3 2 Steady state and time-resolve photoluminence (TrPL) at different temperatures 24 3 Chapter 3 Optimization of bulk heterojunction OSC for D-A-A configuration molecule with single cyano group as the electron donor material 27 3.1 Introduction 27 3.2 Photophysical properties of the four single cyano group electron donor materials 27 3.3 OSC optimization of four electron donor materials with single cyano substituent molecules 31 3.3.1 Comparison between PMHJ and BHJ of DTCTB devices 32 3.3.1.1 C60 based OSC 32 3.3.1.2 C70 based OSC 34 3.3.2 Optimization of different mixing ratio and thickness of active layer for DTCTB 36 3.3.2.1 C60 based OSC 37 3.3.2.2 C70 based OSC 39 3.3.2.3 Replacement of different blocking layer for DTCTB: C60 based OSC 42 3.3.3 Comparison between PMHJ and BHJ of DTCPB: C60 based OSC 46 3.3.4 Optimization of mixing ratio and thickness of active layer for DTCPB 48 3.3.4.1 C60 based OSC 48 3.3.4.2 C70 based OSC 52 3.3.4.3 Insertion of blocking layer for DTCPB: C60 based OSC 55 3.3.7 Optimization of mixing ratio and thickness of active layer for DTCTBO 65 3.3.7.1 C60 based OSC 65 3.4 Comparison of optimized device structures among four single cyano groups electron donor materials 70 3.5 Sun intensity variation measurements of OSCs with four single cyano groups electron donor materials 73 4 Chapter 4 Exciton dynamics in rubrene thin films 74 4.1 Introduction 74 4.2 Basic characteristics of amorphous rubrene thin films 75 4.3 TrPL of rubrene in toluene 76 4.4 TrPL of 100-nm rubrene thin film at 78 K with different excitation energy 78 4.5 TrPL of 100-nm rubrene thin film at room temperature with different excitation energy 79 4.6 TrPL of 100-nm rubrene thin film at different temperatures with ultra-low excitation energy 80 4.7 TrPL of rubrene thin film with different thickness and different excitation energy at room temperature 84 5 Chapter 5 Conclusion 89 5.1 Summary 89 5.2 Future work 89 Appendix 91 Appendix. I Morphology for four single cyano groups electron donor materials 91 Appendix. II Anisotropic characteristics of four single cyano groups electron donor materials 93 References 95 | |
| dc.language.iso | zh-TW | |
| dc.subject | 三重態融合 | zh_TW |
| dc.subject | 有機太陽能電池 | zh_TW |
| dc.subject | 塊材異質接面 | zh_TW |
| dc.subject | 激發光光譜量測系統 | zh_TW |
| dc.subject | 單重態分裂 | zh_TW |
| dc.subject | singlet fission | en |
| dc.subject | triplet fusion | en |
| dc.subject | organic solar cells | en |
| dc.subject | bulk heterojunction | en |
| dc.subject | transient photoluminescence | en |
| dc.title | 具腈基小分子有機太陽能電池之優化與紅螢烯薄膜激子動態特性之研究 | zh_TW |
| dc.title | Device optimization for small molecular organic solar cell with cyano groups and exciton dynamics of rubrene thin film | en |
| dc.type | Thesis | |
| dc.date.schoolyear | 103-2 | |
| dc.description.degree | 碩士 | |
| dc.contributor.oralexamcommittee | 邱天隆(Tian-Lung Chiu),陳錦地(Chin-Ti Chen),王俊凱(Juen-Kai Wang),汪根欉(Ken-Tsung Wong) | |
| dc.subject.keyword | 有機太陽能電池,塊材異質接面,激發光光譜量測系統,單重態分裂,三重態融合, | zh_TW |
| dc.subject.keyword | organic solar cells,bulk heterojunction,transient photoluminescence,singlet fission,triplet fusion, | en |
| dc.relation.page | 99 | |
| dc.rights.note | 同意授權(全球公開) | |
| dc.date.accepted | 2015-08-20 | |
| dc.contributor.author-college | 電機資訊學院 | zh_TW |
| dc.contributor.author-dept | 光電工程學研究所 | zh_TW |
| 顯示於系所單位： | 光電工程學研究所 | |
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