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| ???org.dspace.app.webui.jsptag.ItemTag.dcfield??? | Value | Language |
|---|---|---|
| dc.contributor.advisor | 陳立仁 | |
| dc.contributor.author | Chi-Hung Lin | en |
| dc.contributor.author | 林奇宏 | zh_TW |
| dc.date.accessioned | 2021-06-15T01:31:32Z | - |
| dc.date.available | 2014-07-27 | |
| dc.date.copyright | 2009-07-27 | |
| dc.date.issued | 2009 | |
| dc.date.submitted | 2009-07-20 | |
| dc.identifier.citation | Adisasmito, S., Frank, R. J., Sloan, E. D., Journal of Chemical and Engineering Data, 36, 68(1991).
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| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/42984 | - |
| dc.description.abstract | 氣體水合物為類似冰塊之固態結晶物，由水分子所形成之立體結構空隙中，藉由填入甲烷、乙烷、二氧化碳等氣體分子以達到穩定狀態。本研究之研究動機即針對氣體水合物建立熱力學理論計算模型，藉由計算模型準確預測氣體水合物之氣相-液態水相-水合物相三相平衡。
在本研究所建立之理論計算模型，選擇以van der Waals and Platteeuw (vdW-P) Model來描述水合物相之相行為，並分別以Peng-Robinson-Stryjek-Vera Equation of State (PRSV EoS)與Cubic Plus Association Equation of State (CPA EoS)計算氣相與液態水相之相行為。在vdW-P Model中，藉由Langmuir吸附行為模型來描述氣體填入水合物結構之過程，過去相關研究中，多以球形對稱位能函數來估算Langmuir常數，本研究藉由一包含兩個參數之溫度函數來估算Langmuir常數，以簡化理論計算模型之計算流程。 本研究之熱力學理論計算模型可準確計算單一氣體水合物之相平衡，並可進一步應用於混合氣體水合物與添加醇類等抑制劑與促進劑之氣體水合物系統，預測其相平衡條件與相平衡狀態下系統組成，均具有相當高的準確性。 | zh_TW |
| dc.description.abstract | Gas hydrates are ice-like crystalline solids in which water molecules form a three-dimensional structure that is stabilized by the encapsulation of small gas molecules like methane, ethane and carbon dioxide. The motivation of this work is to develope a calculation model to predict vapor-liquid-hydrate-three-phase equilibrium condition with a better degree of predictability.
In this study, the van der Waals and Platteeuw (vdW-P) model is applied to describe the hydrate phase and both Peng-Robinson-Stryjek-Vera (PRSV) equation of state (EoS) and Cubic Plus Association equation of state (CPA EoS) are chosen to describe the vapor and liquid phases. In the vdW-P model, the Langmuir adsorption behavior is assumed to model the adsorption of gas molecules in the hydrate cages and the Langmuir constant is defined as a function of spherically symmetric cell potential function. In this study, the Langmuir constant is described by a two-parameter temperature-dependent function. It is found that the vapor-liquid-hydrate-three-phase equilibria can be well described by this simple model. And the model also can be applied to predict the competition of different gases when forming binary-guest gas hydrate and predict the phase equilibrium condition of gas hydrate with inhibitor. | en |
| dc.description.provenance | Made available in DSpace on 2021-06-15T01:31:32Z (GMT). No. of bitstreams: 1 ntu-98-R96524005-1.pdf: 6296821 bytes, checksum: 7ac64aa4b3d5d4c59879555d7c0ad86b (MD5) Previous issue date: 2009 | en |
| dc.description.tableofcontents | 口試委員會審定書 I
誌謝 II 摘要 III Abstract IV 目錄 V 圖目錄 VIII 表目錄 XI 第一章 緒論 1 第二章 文獻回顧 3 2.1 天然氣水合物簡介 3 2.1.1 天然氣水合物分佈位置與蘊藏量 3 2.1.2 天然氣水合物的結構 4 2.2 天然氣水合物之相關研究 7 2.2.1 氣體水合物相平衡研究 7 2.2.2 理論計算模型的應用 8 2.3 氣相-液態水相-水合物相三相平衡之理論計算模型 12 2.3.1 Peng-Robinson-Stryjek-Vera Equation of State (PRSV EOS) 12 2.3.2 Cubic Plus Association Equation of State (CPA EOS) 13 2.3.3 特性參數與多成份系統之混合規則（Mixing rule） 18 2.3.4 van der Waal and Platteeuw Model 19 第三章 研究目的暨研究方法 31 3.1 研究目的 31 3.2 研究方法-建立理論計算模型 31 3.2.1 Peng-Robinson-Stryjek-Vera Equation of State 31 3.2.2 Cubic Plus Association Equation of State 33 3.2.3 van der Waal & Platteeuw Model 37 3.3 理論計算模型之計算流程 41 3.3.1 氣液兩相平衡計算 41 3.3.2 氣相-液態水相-水合物相之三相平衡計算 42 第四章 結果與討論 47 4.1 純物質氣液兩相平衡計算 47 4.1.1 不同狀態方程式計算純水氣液兩相平衡之結果比較 47 4.1.2 CPA EOS純物質參數 49 4.2 雙成份混合物系統-氣液兩相平衡 50 4.2.1 水+甲烷雙成份混合物系統 50 4.2.2 水+乙烷雙成份混合物系統 52 4.2.3 水+丙烷雙成份混合物系統 53 4.2.4 水+二氧化碳雙成份混合物系統 54 4.2.5 kij參數 55 4.3 三成份混合物系統—氣液兩相平衡之預測 56 4.4 雙成份混合物系統—氣相-液態水相-水合物相之三相平衡 58 4.4.1 甲烷水合物之相平衡計算 58 4.4.2 乙烷水合物之相平衡計算 61 4.4.3 丙烷水合物之相平衡計算 63 4.4.4 二氧化碳水合物之相平衡計算 64 4.4.5 Langmuir常數數值 66 4.5 混合氣體水合物系統—氣相-液態水相-水合物相之三相平衡 67 4.5.1 甲烷+二氧化碳混合氣體水合物之相平衡預測 67 4.5.2 甲烷+乙烷混合氣體水合物之相平衡預測 69 4.6 添加抑制劑之氣體水合物相平衡系統—氣相-液態水相-水合物相之三相平衡 71 4.6.1 甲烷水合物添加抑制劑之相平衡預測 71 4.6.2 乙烷水合物添加抑制劑之相平衡預測 73 4.6.3 丙烷水合物添加抑制劑之相平衡預測 74 4.6.4 二氧化碳水合物添加抑制劑之相平衡預測 75 第五章 結論 127 符號說明 130 參考文獻 132 | |
| dc.language.iso | zh-TW | |
| dc.subject | 氣體水合物 | zh_TW |
| dc.subject | CPA EOS | zh_TW |
| dc.subject | PRSV EOS | zh_TW |
| dc.subject | van der Waals and Platteeuw Model | zh_TW |
| dc.subject | Langmuir常數 | zh_TW |
| dc.subject | PRSV EOS | en |
| dc.subject | Gas hydrate | en |
| dc.subject | Langmuir constnat | en |
| dc.subject | van der Waals and Platteeuw Model | en |
| dc.subject | CPA EOS | en |
| dc.title | 藉理論計算模型預測水合物相平衡行為 | zh_TW |
| dc.title | Modeling Gas Hydrates Using the Equation of State and the vdW-P Model | en |
| dc.type | Thesis | |
| dc.date.schoolyear | 97-2 | |
| dc.description.degree | 碩士 | |
| dc.contributor.oralexamcommittee | 林祥泰,陸駿逸 | |
| dc.subject.keyword | 氣體水合物,PRSV EOS,CPA EOS,van der Waals and Platteeuw Model,Langmuir常數, | zh_TW |
| dc.subject.keyword | Gas hydrate,PRSV EOS,CPA EOS,van der Waals and Platteeuw Model,Langmuir constnat, | en |
| dc.relation.page | 136 | |
| dc.rights.note | 有償授權 | |
| dc.date.accepted | 2009-07-20 | |
| dc.contributor.author-college | 工學院 | zh_TW |
| dc.contributor.author-dept | 化學工程學研究所 | zh_TW |
| Appears in Collections: | 化學工程學系 | |
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