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  1. NTU Theses and Dissertations Repository
  2. 理學院
  3. 化學系
Please use this identifier to cite or link to this item: http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/42957
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???org.dspace.app.webui.jsptag.ItemTag.dcfield???ValueLanguage
dc.contributor.advisor邱勝賢(Sheng-Hsien Chiu)
dc.contributor.authorTzu-Huan Wongen
dc.contributor.author翁梓桓zh_TW
dc.date.accessioned2021-06-15T01:30:24Z-
dc.date.available2019-12-31
dc.date.copyright2009-07-28
dc.date.issued2009
dc.date.submitted2009-07-21
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dc.identifier.urihttp://tdr.lib.ntu.edu.tw/jspui/handle/123456789/42957-
dc.description.abstract運用實驗室先前發展出來之CTV為基礎的分子容器合成策略,合成以dibenzo-30-crown-10為架構之CTV分子容器。將分子容器與適當之客體分子做錯合的研究,從NMR氫譜上可以看到明顯之化學位移改變,可推測我們的分子容器對此客體分子有錯合之作用。zh_TW
dc.description.abstractWe have synthesized the cyclotirveratrylene molecular container based on dibenzo-30-crown-10 using the method we developed before. We studied the complex character between the molecular container and appropriate guest molecule. It showed that the chemical shift of the 1H-NMR spectra moved obviously. We supposed there were some interaction between our molecular container and the guest molecule.en
dc.description.provenanceMade available in DSpace on 2021-06-15T01:30:24Z (GMT). No. of bitstreams: 1
ntu-98-R96223141-1.pdf: 3817641 bytes, checksum: 5d301d10872f40f1be8a54450cdf2959 (MD5)
Previous issue date: 2009
en
dc.description.tableofcontents謝誌 ..............................................................I
中文摘要 .........................................................III
英文摘要 .........................................................IV
目錄 ............................................................. V
圖表 ............................................................VII
流程 ............................................................. X
表格 ............................................................ XI
壹、 導論 ...................................................... 1
1.1前言 ......................................................... 1
1.2超分子化學的發展與冠醚的起源 ................................. 3
1.3超分子系統 ................................................... 7
1.3.1 主客化學 (Host -guest chemistry)  ........................... 7
1.3.2 杯芳烴 (Calixarene) ....................................... 8
1.3.3 分子監獄 (Carcerand )  .................................... 9
1.3.4 準車輪烷 (Psudortaxane)  ................................. 10
1.4 環三聚藜烴 ( Cyclotriveratrylene )  ............................... 15
1.5 環三聚藜烴衍生物之應用 ....................................... 17
貳、 結果與討論 ................................................ 25
2.1研究動機 ......................................................25
2.2目標分子的合成 .................................................27
2.3錯合測試 ......................................................29
參、 結論 ...................................................... 39
肆、 實驗部分 .................................................. 40
伍、 參考文獻 .................................................. 47
陸、 附錄 ...................................................... 53
dc.language.isozh-TW
dc.subject分子容器zh_TW
dc.subject超分子化學zh_TW
dc.subject環三聚藜烴zh_TW
dc.subjectSupramolecular Chemistryen
dc.subjectMolecular Containeren
dc.subjectcyclotirveratryleneen
dc.title以CTV為基礎之籠狀分子與銨鹽的錯合研究zh_TW
dc.titleThe Complexation of a CTV-Based Molecular Container to Tetra-alkyl Ammonium Saltsen
dc.typeThesis
dc.date.schoolyear97-2
dc.description.degree碩士
dc.contributor.oralexamcommittee徐秀福(Hsiu-Fu Hsu),賴建成(Chien-Chen Lai)
dc.subject.keyword超分子化學,環三聚藜烴,分子容器,zh_TW
dc.subject.keywordSupramolecular Chemistry,cyclotirveratrylene,Molecular Container,en
dc.relation.page53
dc.rights.note有償授權
dc.date.accepted2009-07-21
dc.contributor.author-college理學院zh_TW
dc.contributor.author-dept化學研究所zh_TW
Appears in Collections:化學系

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