請用此 Handle URI 來引用此文件:
http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/42842
完整後設資料紀錄
DC 欄位 | 值 | 語言 |
---|---|---|
dc.contributor.advisor | 牟中原(Chung-Yuan Mou) | |
dc.contributor.author | Ying-Chu Lai | en |
dc.contributor.author | 賴映竹 | zh_TW |
dc.date.accessioned | 2021-06-15T01:25:38Z | - |
dc.date.available | 2013-08-15 | |
dc.date.copyright | 2011-08-17 | |
dc.date.issued | 2011 | |
dc.date.submitted | 2011-08-15 | |
dc.identifier.citation | (1) Vartuli, J. C.; Kresge, C. T.; Leonowicz, M. E.; Chu, A. S.; McCullen, S. B.; Johnsen, I. D.; Sheppard, E. W. Chem. Mater. 1994, 6, 2070.
(2) Beck, J. S.; Vartuli, J. C.; Roth, W. J.; Leonowicz, M. E.; Kresge, C. T.; Schmitt, K. D.; Chu, C. T. W.; Olson, D. H.; Sheppard, E. W.; McCullen, S. B.; Higgins, J. B.; Schlenker, J. L. J. Am. Soc. Chem. 1992, 114, 10834. (3) Kresge, C. T.; Leonowicz, M. E.; Roth, W. J.; Vartuli, J. C.; Beck, J. S. Nature 1992, 359, 710. (4) Zhao, D. Y.; Feng, J. L.; Huo, Q. S.; Melosh, N.; Fredrickson, G. H.; Chmelka, B. F.; Stucky, G. D. Science 1998, 279, 548. (5) Zhao, D. Y.; Huo, Q. S.; Feng, J. L.; Chmelka, B. F.; Stucky, G. D. J. Am. Soc. Chem. 1998, 120, 6024. (6) Imperor-Clerc, M.; Davidson, P.; Davidson, A. J. Am. Chem. Soc. 2000, 122, 11925. (7) Kim T. W.; Ryoo R.; Kruk M.; Gierszal K. P.; Jaroniec M.; Kamiya S.; Terasaki O. J. Phys. Chem. B. 2004, 108, 11480. (8) Huo, Q; Leon, R.; Petroff, P. M.; Stucky, G. D. Science 1995, 268, 1324. (9) Huo, Q. S.; Margolese, D. I.; Stucky, G. D. Chem. Mater. 1996, 8, 1147. (10) Sayari, A.; Liu, P.; Jaroniec, M. Chem. Mater. 1997, 9, 2499. (11) Todros, T. F. Surfactant, Academic Press 1980. (12) Tranford, C. The hydrophobic effect: formation of micelles and biological membranes 1973. (13) Lindman, B. a. W., H Micelles: Amphiphile Aggregation in Aqueous solution, Springer–Verlag, Heidelberg 1980. (14) Naim, B. A Hydrophobic Interaction, Plnnum Press, New York 1980. (15) Mitchell, D. J. N., B. W. J. Chem. Soc. Farad. Trans. II 1981, 77, 601. (16) Natsume, Y. and Sakata H.Thin Solids Films 2000, 372, 30. (17) Emsile, A. G.; Bonner, F. T.; Peck, L. G. J. Appl.Phys. 1958, 29, 858. (18) Bornside, D. E.; Macosko, C. W.; Scriven, L. E. J. Imaging Tech. 1987, 13, 122. (19) Meyerhofer, D. J. Appl. Phys. 1978, 49, 3993. (20) Higgins, B. G. Phys. Fluids 1986, 29, 3522. (21) Hamley, I. W. The Physics of Block Copolymers, Oxford University Press: New York, 1998. (22) Hadjichristidis, N.; Pispas, S.; Floudas, G. Block Copolymers: Synthetic Strategies, Physical Properties, and Applications; John Wiley & Sons: New York, 2002. (23) Bates, F. S.; Fredrickson, G. H. Annu. ReV. Phys. Chem. 1990, 41, 525. (24) Bates, F. S.; Fredrickson, G. H. Phys. Today 1999, 52, 32. (25) Lodge, T. P. Macromol. Chem. Phys. 2003, 204, 265. (26) Ruzette, A.V.; Leibler, L. Nat. Mater. 2005, 4, 19. (27) Segalman, R. A. Mater. Sci. Eng. 2005, R48, 191. (28) Li, M.; Ober, C. K. Mater. Today 2006, 9, 30. (29) Hawker, C. J.; Russell, T. P. MRS Bull. 2005, 30, 952. (30) Li, M.; Coenjarts, C. A.; Ober, C. K. Adv. Polym. Sci. 2005, 190, 183. (31) Kim, S. H.; Misner, M. J.; Xu, T.; Kimura, M.; Russell, T. P. Adv. Mater. 2004, 16, 226. (32) Ho, R. M.; Tseng, W. H.; Fan, H. W.; Chiang, Y. W.; Lin, C. C.; Ko, B. T.; Huang, B. H. Polymer 2005, 46, 9362. (33) 陳慧英, 黃., 朱秦億 化工技術 1999, 7, 152. (34) Thurn-Albrecht, T.; DeRouchey, J.; Russell, T. P. Macromolecules 2000, 33, 3250. (35) Bodycomb, J.; Funaki, Y.; Kimishima, K.; Hashimoto, T. Macromolecules 1999, 32, 2075. (36) Stoykovich, M. P.; Mu¨ller, M.; Kim, S. O.; Solak, H. H.; Edwards, E. W.; de Pablo, J. J.; Nealey, P. F. Science 2005, 308, 1442. (37) Kim, G.; Libera, M. Macromolecules 1998, 31, 2569. (38) Lin, Z.; Kim, D. H.; Wu, X.; Boosahda, L.; Stone, D.; LaRose, L.; Russell, T. P. Adv. Mater. 2002, 14, 1373. (39) Hahm, J.; Sibener, S. J. Langmuir 2000, 16, 4766. (40) Thurn-Albrecht, T.; Schotter, T.; Kastle, G. A.; Emley, N.; Shibauchi, T.; Krusin-Elbaum, L.; Guarini, K.; Black, C. T.; Tuominen, M. T.; Russell, T. P.; Science 2000, 290, 2126. (41) Park, S.; Kim, B.; Wang, J.-Y.; Russell, T. P. Adv. Mater. 2008, 20, 681. (42) Faustini, M.; Vayer, M.; Marmiroli, B.; Hillmyer, M.; Amenitsch, H.; Sinturel, C.; Grosso, D. Chem. Mater., 2010, 22, 5687. (43) 洪伸錡 國立台灣大學博士論文 2004年 (44) Zhang, J.; Huang, F.; Lin, Z. Nanoscale 2010, 2, 18. (45) 陳壁彰 國立台灣大學碩士論文 2002年 (46) Lin, H. P.; Mou, C. Y. Acc. Chem. Res. 2002, 35, 927. (47) 葉奕琪 國立台灣大學博士預口試論文 2010年 (48) Pashley, D. W.; Menter, J. W.; Bassett, G. A. Nature 1957, 179, 752. (49) 林麗娟 工業材料 1994, 86, 100. (50) 鄭有舜 物理雙月刊 2004, 26, 416. (51) Hara, M.; Nagano, S.; Seki, T. J. Am. Soc. Chem. 2010, 132, 13654. (52) Doshi, D. A.; Gibaud, A.; Goletto, V.; Lu, M. C.; Gerung, H.; Ocko, B.; Han, S. M.; Brinker, C. J. J. Am. Chem. Soc. 2003, 125, 11646. (53) Dourdain, S.; Bardeau, J-F.; Colas, M. Appl. Phys. Lett. 2005, 86, 113108. (54) Smarsly, B.; Gibaud, A.; Ruland, W.; Sturmayr, D.; Brinker, C. J. Langmuir 2005, 21, 3858. (55) Klotz, M.; Albouy, P. A.; Ayral, A.; Menager, C.; Grosso, D.; Van der Lee, A.; Cabuil, V.; Babonneau, F.; Guizard, C. Chem. Mater. 2000, 12, 1721. (56) Freer, E. M.; Krupp, L. E.; Hinsberg, W. D.; Rice, P. M.; Hedrick, J. L.; Cha, J. N.; Miller, R. D.; Kim, H. C. Nano Lett. 2005, 5, 2014. (57) Gibaud, A.; Dosh, D.; Goletto, V.; Brinker, J.; Ocko, B. Abstract No. giba791 (58) Lee, B.; Park, I.; Yoon, J.; Park, S.; Kim, J.; Kim, K. W.; Chang, T.; Ree, M. Macromolecules 2005, 38, 4311. | |
dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/42842 | - |
dc.description.abstract | Mesoporous organic/inorganic hybrid films with vertically aligned channels were in high interest but scientifically challenging, since there was no clear guidance to attain the surface-mediated vertical alignment. Here we developed a facile route to prepare meosporous silica thin films with a ternary surfactant system- C16TAB, SDS and P123, the structure directing agent, via sol-gel process. The thin films were then spin coated on silicon wafers and glass slides, and/or dipped in the coating solution for potential applications, such as catalyst support films, separation technology, optoelectronics, and high-density memory storage.
In the first part of this thesis, we used triblock copolymer P123 (EO20PO70EO20) as template, through sol-gel method, the mesoporous silica SBA-15 platelet (⊥) could be synthesized. From TEM and microtome TEM, we confirmed that the plate possessed well-ordered hexagonal structure and perpendicular channels. By changing the synthesis condition, for example, pH value and aging time, we looked forward to discovering better mesoporous silica SBA-15 platelet (⊥) synthesis condition. In the second part of this thesis, we modified the surface properties of silicon wafers and glass slides with some functional groups to help induce the vertical orientation of mesoporous organic/inorganic hybrid film channels on substrates. By sol-gel process and spin coating technique, the vertically aligned channel with hexagonally arranged and large pore size mesoporous organic/inorganic hybrid films could be formed uniformly in large scale. The structural characterization of the thin films was evaluated by scanning electron microscopy (SEM) and transmission electron microscopy (TEM). In addition, grazing incidence small angle X-ray scattering (GISAXS) was used to investigate the structure and morphology of thin films. | en |
dc.description.provenance | Made available in DSpace on 2021-06-15T01:25:38Z (GMT). No. of bitstreams: 1 ntu-100-R98223138-1.pdf: 12249338 bytes, checksum: 62d276165c706b70e4122066dd990731 (MD5) Previous issue date: 2011 | en |
dc.description.tableofcontents | Contents
Chapter 1 Introduction 1.1 Introduction of mesoporous materials 1 1.1.1 Mesoporous materials 1 1.1.2 Mesoporous silica materials of SBA-n 3 1.2 Introduction of surfactants 5 1.2.1 Structure and classification of surfactants 5 1.2.2 Surfactant micellization 6 1.3 Preparation of mesoporous thin film materials 8 1.3.1 Spin coating 8 1.3.2 Solvent annealing 10 1.3.3 Dip coating 13 1.4 Applications of mesoporous thin film with perpendicular channels 14 1.5 Research Objects 18 Chapter 2 Experimental 2.1 Chemical reagents 20 2.2 Instruments 21 2.2.1 Scanning Electron Microscopy (SEM) 21 2.2.2 Grazing Incidence Small Angle X-ray Scattering (GISAXS) 21 2.2.3 Transmission Electron Microscopy (TEM) 21 2.2.4 Powder X-ray diffraction (XRD) 21 2.2.5 Nitrogen adsorption-desorption isotherm 22 2.2.6 Focus Ion Beam (FIB) 22 2.3 Synthesis 23 2.3.1 Synthesis of mesoporous silica SBA-15 platelet (⊥) 23 2.3.2 Substrates surface modification 23 2.3.3 Preparation of mesoporous silica SBA-15 platelet (⊥) on substrates 24 Chapter 3 Mesoporous silica SBA-15 platelet (⊥) synthesis 3.1 Synthesis of mesoporous silica platelet (⊥) under different silicate condensation pH values 25 3.2 Results and discussion of mesoporous silica platelet (⊥) synthesized under different silicate condensation pH values 25 Chapter 4 Preparation and characterization of mesoporous silica SBA-15 platelet (⊥) coating on substrates 4.1 Different substrates for mesoporous silica SBA-15 platelet (⊥) thin film coating 35 4.1.1 Experimental 35 4.1.2 Mesoporous silica SBA-15 platelet (⊥) coating on silicon wafers 36 4.1.3 Mesoporous silica SBA-15 platelet (⊥) coating on glass slides 51 4.2 Different coating methods for preparation of mesoporous silica SBA-15 platelet (⊥) thin film 54 4.2.1 Experimental of spin coating method plus dip in the coating solution 54 4.2.2 Spin coating plus dip in the coating solution for preparation of mesoporous silica SBA-15 platelet (⊥) thin film 55 4.2.3 Spin coating for preparation of mesoporous silica SBA-15 platelet (⊥) thin film 58 4.3 Different silica condensation pH values for mesoporous silica SBA-15 platelet (⊥) thin film coating 63 4.3.1 Experimental 63 4.3.2 Mesoporous silica SBA-15 platelet (⊥) thin film synthesis at pH 3 64 4.3.3 Mesoporous silica SBA-15 platelet (⊥) thin film synthesis at pH 2 68 Chapter 5 Conclusions 73 References 76 | |
dc.language.iso | en | |
dc.title | 具垂直通道之中孔洞氧化矽薄膜製備於基板與其性質研究 | zh_TW |
dc.title | Preparation and Characterization of Mesoporous Silica Thin Films with Vertically Aligned Channels on Substrates | en |
dc.type | Thesis | |
dc.date.schoolyear | 99-2 | |
dc.description.degree | 碩士 | |
dc.contributor.oralexamcommittee | 林弘萍(Hong-Ping Lin),鄭有舜(U-Ser, Jeng) | |
dc.subject.keyword | 中孔洞薄膜,垂直方向通道,有機無機複合材料,SBA-15氧化矽薄片,掠射小角度X光散射, | zh_TW |
dc.subject.keyword | mesoporous thin film,vertically aligned channels,organic/inorganic hybrid materials,SBA-15 silica platelet,grazing-incidence small angle X-ray scattering (GISAXS), | en |
dc.relation.page | 80 | |
dc.rights.note | 有償授權 | |
dc.date.accepted | 2011-08-16 | |
dc.contributor.author-college | 理學院 | zh_TW |
dc.contributor.author-dept | 化學研究所 | zh_TW |
顯示於系所單位: | 化學系 |
文件中的檔案:
檔案 | 大小 | 格式 | |
---|---|---|---|
ntu-100-1.pdf 目前未授權公開取用 | 11.96 MB | Adobe PDF |
系統中的文件,除了特別指名其著作權條款之外,均受到著作權保護,並且保留所有的權利。