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DC 欄位 | 值 | 語言 |
---|---|---|
dc.contributor.advisor | 徐治平 | |
dc.contributor.author | Ming-Jui Hsieh | en |
dc.contributor.author | 謝明叡 | zh_TW |
dc.date.accessioned | 2021-06-15T01:22:36Z | - |
dc.date.available | 2010-07-29 | |
dc.date.copyright | 2009-07-29 | |
dc.date.issued | 2009 | |
dc.date.submitted | 2009-07-23 | |
dc.identifier.citation | 第一章
[1] Hunter, R. J. Foundations of Colloid Science, Vol. I; Oxford University Press: Oxford, 2001. [2] Besra, L.; Liu, M. “A review on fundamentals and applications of electrophoretic deposition (EPD)” Prog. Mater. Sci. 2007, 52, 1-61. [3] Masliyah, J. H. Electrokinetic Transport Phenomena; AOSTRA, Edmonton, Albert: Canada, 1994. [4] Korolev, N.; Nordenskiöld, L. “Application of Polyelectrolyte Theories for Analysis of DNA Melting in the Presence of Na+ and Mg2+ Ions” Biophys. J. 1998, 75, 3041-3056. [5] Pfohl, T.; Li, Y.; Kim, J. H.; Wen, Z.; Wong, G. C. L.; Koltover, I.; Kim, M. W.; Safinya, C. R. “Biological polyelectrolyte complexes in solution and confined on patterned surfaces” Colloids Surf. A 2002, 198, 613-623. [6] Elliott, G. F.; Hodson, S. A. “Cornea, and the swelling of polyelectrolyte gels of biological interest” Rep. Prog. Phys. 1998, 61, 1325-1365. [7] Regini, J.W.; Elliott, G. F. “The effect of temperature on the Donnan potentials in biological polyelectrolyte gels: cornea and striated muscle” Int. J. Biol. Macromol. 2001, 28, 245-254. [8] Nagvekar, M.; Tihminlioglu, F.; Danner, R. P. “Colligative properties of polyelectrolyte solutions” Fluid Phase Equilibria 1998, 145, 15-41 [9] Reuss, F. F. “Sur un nouvel effet de l’electricite galvanique” Mém. Soc. Impérial Naturalistes de Moscow 1809, 2, 327-337. [10] Quincke, G. 'Über die Fortfüjung materielle Theilchen durch strömende Elektrictät” Poggendorf’s Ann. 1861, 113, 513-595. [11] Helmholtz, H. von “Studies of electric boundary layers” Wied. Ann. 1879, 7, 337-387. [12] von Smoluchowaski, M. Bull. Int. Acad. Sci. Cracovie 1903, p.184. [13] von Smoluchowaski, M. “Versuch einer mathematischen Theorie der Koagulationskinetik kolloider lösungen” Z. Phys. Chem. 1918, 92, 129-168. [14] Morrison, F. A. “Electrophoresis of a particle of arbitrary shape” J. Colloid Interface Sci. 1970, 34, 210-214. [15] Hückel, E.” Die Kataphoresese der Kugel” Physik. Z. 1924, 25, 204-210 其它章節 [1] von Smoluchowaski, M. “Versuch einer mathematischen Theorie der Koagulationskinetik kolloider lösungen” Z. Phys. Chem. 1918, 92, 129-168. [2] Zydney, A.L. “Boundary Effects on the Electrophoretic Motion of a Charged Particle in a Spherical Cavity” J. Colloid Interface Sci. 1995, 169, 476-485. [3] Lee, E.; Chu, J. W.; Hsu, J. P. “Electrophoretic Mobility of a Sphere in a Spherical Cavity” J. Colloid Interface Sci. 1998, 205, 65-76. [4] Hsu, J. P.; Hung, S. H. and Kao, C. Y. “Electrophoresis of a Sphere at an Arbitrary Position in a Spherical Cavity” Langmuir 2002, 18, 8897-8901. [5] Hsu, J. P; Hung, S. H.“Electrophoresis of a Spheroid in a Spherical Cavity” Langmuir 2003, 19, 7469-7473. [6] Hsu, J. P.; Yeh, L.H. and Chen, Z. S. “Effect of a charged boundary on electrophoresis: A sphere at an arbitrary position in a spherical cavity” J. Colloid Interface Sci. 2007, 310, 281-291. [7] Hsu, J. P. and Yeh, L.H. “Effect of a Charged Boundary on Electrophoresis in a Carreau Fluid: A Sphere at an Arbitrary Position in a Spherical Cavity” Langmuir, 2007, 23, 8637-8646. [8] Hsu, J. P. and Chen, C. Y. “Electrophoresis of a charge-regulated sphere at an arbitrary position in a charged spherical cavity” J. Colloid Interface Sci. 2008, 325, 516-525. [9] Hsu, J. P.; Chen, Z. S.; Ku, M. H. and Yeh, L. H. “Effect of charged boundary on electrophoresis: Sphere in spherical cavity at arbitrary potential and double-layer thickness” J. Colloid Interface Sci. 2007, 314, 256-263. [10] Imai, N.; Oosawa, F.” Counterion distribution around a highly charged spherical polyelectrolyte” Busseiron Kenkyu 1952, 52, 42-63. [11] Oosawa, F. Polyelectrolytes; Dekker: New York, 1971 [12] Ohshima, H. “Surface Charge Density/Surface Potential Relationship for a Spherical Colloidal Particle in a Salt-Free Medium” J. Colloid Interface Sci. 2002, 247, 18-23. [13] Ohshima, H. “Electrophoretic Mobility of a Spherical Colloidal Particle in a Salt-Free Medium” J. Colloid Interface Sci. 2002, 248, 499-503. [14] Ohshima, H. “Numerical calculation of the electrophoretic mobility of a spherical particle in a salt-free medium” J. Colloid Interface Sci. 2003, 262, 294-297. [15] Chiang, C. P.; Lee, E.; He, Y. Y., et al. “Electrophoresis of a spherical dispersion of polyelectrolytes in a salt-free solution” J. Phys. Chem. B 2006, 110, 1490-1498. [16] Kuwabara, S. “The forces experienced by randomly distributed parallel circular cylinders or spheres in a viscous flow at small Reynolds numbers” J. Phys. Soc. Jpn. 1959, 14, 527-532. [17] O’Brien, R. W.; White, L. R. ”Electrophoretic mobility of a spherical colloidal particle” J. Chem. Soc. Faraday 2 1978, 74, 1607-1626. [18] Hsu, J. P.; Yeh, L. H; Ku, M. H. “Evaluation of the electric force in electrophoresis” J. Colloid Interface Sci. 2007, 305, 324-329. [19] Hsu, J. P. and Yeh, L. H. “Comparison of Three Methods for the Evaluation of the Electric Force on a Particle in Electrophoresis” J. Chin. Inst. Chem. Eng. 2006, 37, 601-607. | |
dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/42767 | - |
dc.description.abstract | 本論文以有限元素分析法研究一橢球形粒子在充滿無鹽電解質溶液之球型孔洞中的任意位置電泳行為的影響,其中,無鹽電解質溶液即為溶液相中僅包含從粒子上官能基解離出的反離子而不含其它鹽類介質。
數值模擬的結果顯示,對粒子電泳的定性行為有重大影響的參數如下:粒子表面的總帶電量、分散在溶液當中的反離子價數、球型孔洞與粒子之間的相對大小、橢球粒子的縱橫軸長度比、粒子在球型孔洞中的位置。許多有趣的結果在此論文中被觀察到,例如:當粒子表面總帶電量固定時,大致上電泳動度的大小排序為:長橢球>球>扁橢球;反離子凝聚效應導致電泳動度依反離子價數的增加而遞減的情形;電泳動度對橢球粒子的縱橫軸長度比做圖出現極大值。 | zh_TW |
dc.description.abstract | The electrophoretic behavior of a spheroid at an arbitrary position in a spherical cavity is analyzed numerically under a salt-free condition, that is, the liquid phase contains only counterions which come from the dissociation of the functional groups of particle. The influences of the key parameters of the system under consideration, including the total amount of surface charge on the particle, the valence of the counterion, the relative size of the cavity, the aspect ratio of the particle and its position in the cavity. Several interesting results were observed. For example, if the total amount of surface charge is fixed, the magnitude of the electrophoretic mobility for various types of particle generally ranks as prolate>sphere>oblate. The effect of counterion condensation yields a small value of electrophoretic mobility in the case of high valence of the counterions. In addition, it exhibits a local maximum in the electrophoretic mobility as the aspect ratio of the particle varies. | en |
dc.description.provenance | Made available in DSpace on 2021-06-15T01:22:36Z (GMT). No. of bitstreams: 1 ntu-98-R96549023-1.pdf: 677547 bytes, checksum: 2489953389f3d0d73cabca4113495967 (MD5) Previous issue date: 2009 | en |
dc.description.tableofcontents | 摘要……………………………………………………………I
Abstract………………………………………………………II 目錄……………………………………………………………III 圖目錄…………………………………………………………IV 第一章 緒論…………………………………………………1 1.1膠體系統…………………………………………………1 1.2膠體穩定性與表面帶電…………………………………1 1.3電雙層理論 ………………………………………….2 1.4電動力學現象 ………………………………………….3 1.5不含鹽類的膠體分散系統 …………………………….4 1.6文獻回顧………………………………………………….5 References ……………………………………………….10 第二章Introduction………………………………………….12 第三章Theory…………………………………………………15 3.1. Governing equations…………………………….15 3.2. Boundary Conditions…………………………….19 3.3. Electrophoretic mobility…………………………….21 第四章Results and Discussion……………………………..24 第五章Conclusion……………………………………………..30 References……..………………………………………………32 Notations…………………………………………………………52 | |
dc.language.iso | en | |
dc.title | 橢球在充滿無鹽電解質溶液之球型孔洞內之電泳 | zh_TW |
dc.title | Electrophoresis of a Spheroid in a Spherical Cavity Filled with a Salt-Free Solution | en |
dc.type | Thesis | |
dc.date.schoolyear | 97-2 | |
dc.description.degree | 碩士 | |
dc.contributor.oralexamcommittee | 曾琇瑱,張有義,劉博滔,林松華 | |
dc.subject.keyword | 電泳,固定表面電荷密度,橢球粒子在球型孔洞中,無鹽電解質溶液,泳動度,牛頓流體,邊界效應, | zh_TW |
dc.subject.keyword | electrophoresis,constant surface charge density,spheroid in spherical cavity,salt-free solution,mobility,boundary effect, | en |
dc.relation.page | 56 | |
dc.rights.note | 有償授權 | |
dc.date.accepted | 2009-07-24 | |
dc.contributor.author-college | 工學院 | zh_TW |
dc.contributor.author-dept | 高分子科學與工程學研究所 | zh_TW |
顯示於系所單位: | 高分子科學與工程學研究所 |
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