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http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/42624完整後設資料紀錄
| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 連雙喜 | |
| dc.contributor.author | Wen-Sheng Wang | en |
| dc.contributor.author | 王文聖 | zh_TW |
| dc.date.accessioned | 2021-06-15T01:18:01Z | - |
| dc.date.available | 2014-07-30 | |
| dc.date.copyright | 2009-07-30 | |
| dc.date.issued | 2009 | |
| dc.date.submitted | 2009-07-27 | |
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Stringer, “Oxide scale adhesion and impurity segregation at the scale/metal interface”, Oxidation of Metals, Volume 38, 1992, p323-345. [30] B. Pint, “Experimental observations in support of the dynamic-segregation theory to explain the reactive-element effect”, Oxidation of Metals, Volume 45, 1996, p1-37. [31] W. J. Quadakkers, J. Piron-Abellan, V. Shemet and L. Singheiser, “Metallic interconnectors for solid oxide fuel cells - a review”,Materials at High Temperatures , Volume 20, May 2003, p115-127. [32] W.Z.Zhu, S.C.Deevi, “Opportunity of metallic interconnectors for solid oxide fuel cells: a status on contact resistance”, Materials Research Bulletin, Volume 38, Issue 6, 26 May 2003, p957-972. [33] T. Brylewski , K. Przybylski , J. Morgiel, “Microstructure of Fe-25Cr/(La, Ca)CrO3 composite interconnector in solid oxide fuel cell operating conditions”, Materials Chemistry and Physics, Volume 81, 2003, p434-437 [34] Y.D. Zhen, San Ping Jiang , Sam Zhang, Vincent Tan, “Interaction between metallic interconnect and constituent oxides of (La, Sr)MnO3 coating of solid oxide fuel cells”, Journal of the European Ceramic Society, Volume 26 Issue15, 2006 , p3253-3264. [35] Christopher Johnson, Randall Gemmen, Nina Orlovskaya, “Nano-structured self-assembled LaCrO3 thin film deposited by RF-magnetron sputtering on a stainless steel interconnect material”, Composites Part B: Engineering, Volume 35 Issue 2, 2004, p167-172. [36] Nina Orlovskaya , Anthony Coratolo , Mykola Lugovy ,Christopher Johnson, Randall Gemmen, “Structural evolution of La-Cr-O thin films: Part I. Microstructure and phase development”, Thin Solid Films, Volume 515 Issue 4, 2006, p1741-1747. [37] S. Fontana , R. Amendola, S. Chevalier , P. Piccardob, G. Caboche, M. Viviani, R. Molins , M. Sennour, “Metallic interconnects for SOFC: Characterisation of corrosion resistance and conductivity evaluation at operating temperature of differently coated alloys”, Journal of Power Sources, Volume 171 Issue 2 , 2007, p652-662. [38] Zigui Lu, Jiahong Zhu, Ye Pana, Naijuan Wu , Alex Ignatiev, “Improved oxidation resistance of a nanocrystalline chromite-coated ferritic stainless steel”, Journal of Power Sources, Volume 178 Issue1 , 2008, p282-290. [39] Nima Shaigan, Douglas G. Ivey,Weixing Chen, “Co/LaCrO3 composite coatings for AISI 430 stainless steel solid oxide fuel cell interconnects”, Journal of Power Sources, Volume 185 Issue1 , 2008, p331-337. [40] Y.D. Zhen, San Ping Jiang , Sam Zhang, Vincent Tan, “Interaction between metallic interconnect and constituent oxides of (La, Sr)MnO3 coating of solid oxide fuel cells”, Journal of the European Ceramic Society Volume 26 Issue 15, 2006, p3253-3264. [41] Zhenguo Yang , Guan-Guang Xia, Gary D. Maupin, Jeffry W. Stevenson, “Conductive protection layers on oxidation resistant alloys for SOFC interconnect applications”,Surface & Coatings Technology, Volume 201 Issue 7, 2006, p4476-4483. [42] Frank Tietz, Doris Sebold, “Interface reactions between electrically conductive ceramics and ferritic steel-I. The system Cr–22Fe–0.5Mn/Mn2O3/(La,Ca)(Cr,Co,Cu)O3”, Materials Science and Engineering: B, Volume 150 Issue 2, 2008, p135-140. [43] S.-H. SONG, Z.-X. YUAN, “Electrical properties of MnCr2O4 spinel”, Journal of Materials Science Letters, Volume 22, 2003, p755- 757. [44] Teruhisa Horita, Haruo Kishimoto, Katsuhiko Yamaji, Yueping Xiong, Natsuko Sakai,Manuel E. Brito, Harumi Yokokawa, “Effect of grain boundaries on the formation of oxide scale in Fe-Cr alloy for SOFCs”, Solid State Ionics, Volume 179, 2008, p1320-1324. [45] Nima Shaigan, Douglas G. Ivey,Weixing Chen, ‘Co/LaCrO3 composite coatings for AISI 430 stainless steel solid oxide fuel cell interconnects”, Journal of Power Sources, Volume 185, 2008, p331-337. [46] Zigui Lu, Jiahong Zhu, Ye Pan, Naijuan Wu, Alex Ignatiev, ‘Improved oxidation resistance of a nanocrystalline chromite-coated ferritic stainless steel”, Journal of Power Sources, Volume 178, 2008, p282-290. [47] T. Brylewsk, J. D¹bek and K. Przybylski, “OXIDATION KINETICS STUDY OF THE IRON-BASED STEEL FOR SOLID OXIDE FUEL CELL APPLICATION”, Journal of Thermal Analysis and Calorimetry, Volume 77, 2004, p207-216. | |
| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/42624 | - |
| dc.description.abstract | 為了發展適合固態氧化物燃料電池中的金屬連接板，抗高溫氧化合金是目前熱門的研究題目。其中鐵鉻錳合金是常見的金屬連接板材料。本論文將探討添加微量鈦、鉬、鈷、鑭元素對鐵鉻錳合金高溫性質所造成的影響。
實驗前預先以thermal-calc計算模擬合金相圖，並使用真空電弧熔煉爐配置所需的鐵-鉻-錳-鈦、鐵-鉻-錳-鉬、鐵-鉻-錳-鈷、以及鐵-鉻-錳-鑭合金。所得之合金先在900℃氬氣氣氛下均質化12小時，然後於850℃空氣氣氛下分別進行150小時與300小時不連續高溫氧化實驗。 高溫氧化實驗顯示添加鈷可以藉由減少鉻離子空位來改善抗氧化能力，反之添加鈦及鉬則會造成氧化加速進行。熱膨脹實驗結果顯示添加鈦、鉬、鈷皆可改善熱膨脹量。另外，電阻實驗結果顯示添加鈦和鈷可以大幅改善高溫電阻值，而鉬和鑭只能稍微改善高溫電阻值。 | zh_TW |
| dc.description.provenance | Made available in DSpace on 2021-06-15T01:18:01Z (GMT). No. of bitstreams: 1 ntu-98-R96527021-1.pdf: 13134771 bytes, checksum: 8979a4e718ee15b48265d5c7c7bf5a69 (MD5) Previous issue date: 2009 | en |
| dc.description.tableofcontents | 目錄
中文摘要 iii Abstract iv 目錄 v 表目錄 viii 圖目錄 ix 第一章 前言 1 第二章 文獻回顧 2 2.1 連接板需具備的條件 2 2.2 金屬連接板 4 2.2.1 合金選擇 5 2.2.2 表面處理 6 2.3 氧化機制 8 2.3.1 熱力學 8 2.3.2 動力學 10 2.3.3 其他影響擴散之因素 13 第三章 實驗步驟與方法 14 3.1合金相圖計算 15 3.2熔煉合金與後續處理 16 3.2.1 合金配置 16 3.2.2 氬氣保護電弧熔煉(arc-melting)製做合金鑄錠 17 3.2.3 後續合金熱處理 18 3.3合金性質分析 19 3.3.1 合金成分分析 19 3.3.2 合金金相與其他性質 19 3.3.3 合金熱膨脹分析 20 3.3.4 電阻分析 20 3.4 高溫氧化實驗 20 3.5 高溫氧化試片分析 21 3.5.1 氧化試片表面SEM與EDS分析 21 3.5.2 氧化試片表面XRD繞射分析 21 3.5.3 氧化試片橫截面EPMA分析 21 第四章 結果與討論 22 4.1 合金模擬與金相 22 4.1.1 合金設計模擬 22 4.1.2 金相與XRD結果 27 4.2 高溫氧化測試 36 4.2.1 FeCrMn 37 4.2.2 FeCrMnTi 39 4.2.3 FeCrMnMo 41 4.2.4 FeCrMnCo 43 4.2.5 FeCrMnLa 45 4.2.6 高溫氧化行為的綜合討論 47 4.3 氧化試片表面與橫截面觀察 52 4.3.1 FeCrMn 52 4.3.2 FeCrMnTi 67 4.3.3 FeCrMnMo 77 4.3.4 FeCrMnCo 87 4.3.5 FeCrMnLa 97 4.3.6 表面形貌觀察的綜合討論 107 4.4 熱膨脹實驗 108 4.5 電阻測試 111 第五章 結論 113 第六章 參考文獻 114 附錄：Thermal-calc程式碼 118 | |
| dc.language.iso | zh-TW | |
| dc.title | 添加微量鈦、鉬、鈷、鑭元素對鐵鉻錳合金高溫氧化行為之研究 | zh_TW |
| dc.title | Effects of minor Ti, Mo, Co, and La additions on the high temperature oxidation behavior of Fe-Cr-Mn alloy | en |
| dc.type | Thesis | |
| dc.date.schoolyear | 97-2 | |
| dc.description.degree | 碩士 | |
| dc.contributor.oralexamcommittee | 李瑞益,林金福,陳鈞 | |
| dc.subject.keyword | 燃料電池,金屬連接板,鐵鉻錳合金,thermal-calc,高溫氧化, | zh_TW |
| dc.subject.keyword | SOFC,metallic interconnect,Fe-Cr-Mn alloy,thermal-calc,high temperature oxidation, | en |
| dc.relation.page | 120 | |
| dc.rights.note | 有償授權 | |
| dc.date.accepted | 2009-07-27 | |
| dc.contributor.author-college | 工學院 | zh_TW |
| dc.contributor.author-dept | 材料科學與工程學研究所 | zh_TW |
| 顯示於系所單位： | 材料科學與工程學系 | |
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