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完整後設資料紀錄
DC 欄位 | 值 | 語言 |
---|---|---|
dc.contributor.advisor | 林清富(Ching-Fuh Lin) | |
dc.contributor.author | Chieh-Yu Hsiao | en |
dc.contributor.author | 蕭傑予 | zh_TW |
dc.date.accessioned | 2021-06-15T00:54:09Z | - |
dc.date.available | 2013-08-14 | |
dc.date.copyright | 2008-08-14 | |
dc.date.issued | 2008 | |
dc.date.submitted | 2008-08-07 | |
dc.identifier.citation | [1] 法蘭茲.阿爾特(F. Alt)著,王琪,唐小莉,與陳紅德等人譯,太陽電力公
司:新能源.新就業機會(新自然主義股份有限公司, 2005)。 [2] German Advisory Council on Global Change, 2003. [3] S. E. Shaheen, R. Radspinner, N. Peyghambarian, and G. E. Jabbour, “Fabrication of bulk heterojunction plastic solar cell by screen printing,” Appl. Phys. Lett. 79, 2996 (2001). [4] J. Bharathan, Y. Yang, “Polymer electroluminescent device processed by inkjet printing: 1.polymer light emitting logo,” Appl. Phys. Lett. 72, 2660 (1998). [5] C. J. Brabec, F. Padinger, J. C. Hummelen, R. A. Janssen, and N. S. Saricifrtci, “Realization of large area flexible fullerene-conjugated polymer photocells: A route to plastic solar cells,” Synth. Met. 102, 861 (1999). [6] 徐明生, 季振國, 闕瑞麟, “有機太陽能電池研究進展”, 材料科學與工程 18(3), 92-100 (2002). [7] P. Peumans, S. Uchida, and S. R. Forrest, “Efficient bulk heterojunction photovoltaic cells using small-molecular-weight organic thin films,” Nature 425, 158-162 (2003). [8] Y. Kang, N. G. Park, and D. Kim, “Hybrid solar cells with vertically aligned CdTe nanorods and a conjugated polymer,” Appl. Phys. Lett. 86, 113101 (2005). [9] Y. Kang and D. Kim, “Well-aligned CdS nanorod/conjugated polymer solar cells,” Sol. Energy Mater. Sol. Cells 90, 166-174 (2006). [10] W. U. Huynh, J. J. Dittmer, and A. P. Alivisatos, “Hybrid nanorod-polymer solar cells,” Science 295, 2425-2427 (2002). [11] D. C. Olson, J. Piris, R. T. Collins, S. E. Shaheen, D. S. Ginley, “Hybrid photovoltaic devices of polymer and ZnO nanofiber composites,” Thin Solid Films 496, 26-29 (2006). [12] K. Takanezawa, K. Hirota, Q. S. Wei, K. Tajima, and K. Hashimoto, “Efficient charge collection with ZnO nanorod array in hybrid photovoltaic devices,” J. Phys. Chem. C 111, 7218-7223 (2007). [13] T. W. Zeng, Y. Y. Lin, H. H. Lo, C. W. Chen, C. H. Chen, S. C. Liou, H. Y. Huang, and W. F. Su, “A large interconnecting network within hybrid MEH-PPV/TiO2 nanorod photovoltaic devices,” Nanotechnology 17, 5387-5392 (2006). [14] S. O. Kasap, “Optoelectronics”, Prentice Hall, 1999. [15] C. Kittel, “Introduction to Solid State Physics”, Chapter 11, John Wiley & Sons, New York (1996). [16] Franco Cacialli, “Organic semiconductors for the mew millennium,” Phil. Trans. R. Soc. Lond. A 358, 173-192 (2000). [17] J. Peet, J. Y. Kim, N. E. Coates, W. L. Ma, D. Moses, A. J. Heeger, and G. C. Bazan, “Efficiency enhancement in low-bandgap polymer solar cells by processing with alkane dithiols,” Nat. Mater. 6, 497-500 (2007). [18] J. J. Dittmer, E. A. Marseglia, and R. H. Friend, “Trapping in dye/ polymer blend photovoltaic Cells,” Adv. Mater. 12(17), 1270-1274 (2000). [19] P. Peumans, A. Yakimov, and S. R. Forrest, “Small molecular weight organic thin-film photodetectors and solar cells,” J. Appl. Phys. 93, 3693-3723 (2003). [20] 張正華,李陵嵐,葉楚平,楊平華,“有機與塑膠太陽能電池”,五南圖書出版公司。 [21] S. R. Forrest, “The limits to organic photovoltaic cell efficiency,” MRS Bull. 30, 28-32 (2005). [22] 陳壽安,導電高分子:新時代光電材料,物理雙月刊23卷2期,312-321 (2001)。 [23] J. H. Burroughes, D. D. C. Bradley, A. R. Brown, R. N. Marks, K. Mackay, R. H. Friend, P. L. Burns, and A. B. Holmes, “Light-emitting diodes based on conjugated polymers,” Nature 347, 539-541 (1990). [24] X. Y. Deng, W. M. Lau, and K. Y. Wong, “High efficiency low operating voltage polymer light-emitting diodes with aluminum cathode,” Appl. Phys. Lett. 84, 3522-3524 (2004). [25] Y. D. Park, D. H. Kim, Y. Jang, M. Hwang, J. A. Lim, and K. Cho, “Low-voltage polymer thin-film transistors with a self-assembled monolayer as the gate dielectric,” Appl. Phys. Lett. 87, 243509 (2005). [26] Y. Kim, S. A. Choulis, J. Nelson, Donal D. C. Bradley, S. Cook, and J. R. Durrant, “Device annealing effect in organic solar cells with blends of regioregular poly(3-hexylthiophene) and soluble fullerene,” Appl. Phys. Lett. 86, 063502 (2005). [27] L. B. Smilowitz, “Conjugated polymers: modern electronic materials,” IEEE Circ. Dev. Mag. 10(1), 19-23 (1994). [28] 謝崇偉, 雙二噻吩環戊烷衍生物的合成與性質探討, 國立中央大學化學研究所碩士論文, 2005. [29] L. Bozano and S. A. Carter, “Temperature- and Field-dependent electron and hole mobilities in polymer light-emitting diodes,” Appl. Phys. Lett. 74(8), 1132-1134 (1999). [30] D. Wohrle and D. Meissner, “Organic solar cells,” Adv. Mater. 3(3), 129-138 (1991). [31] H. Kallmans and M. Pope, “Photovoltaic effect in organic crystals,” J. Chem. Phys. 30, 585-586 (1958). [32] J. Nelson, “Organic photovoltaic films,” Curr. Opin. Solid State Mater. Sci. 6, 87-95 (2002). [33] K. M. Coakley and M. D. McGehee, “Conjugated polymer photovoltaic cells,” Chem. Mater. 16, 4533-4542 (2004). [34] C. W. Tang, “Two-layer organic photovoltaic cell,” Appl. Phys. Lett. 48, 183-185 (1986). [35] J. J. M. Halls, K. Pichler, and R. H. Friend, “Exciton diffusion and dissociation in a poly(p-phenylenevinylene)/C60 heterojunction photovoltaic cell,” Appl. Phys. Lett. 68, 3120-3122 (1996). [36] 鄭弘彬, 有機無機混合太陽電池製程之研究, 國立清華大學電子工程研究 所碩士論文, 2006. [37] N. S. Sariciftci, L. Smilowitz, A. J. Heeger, and F. Wudl, “Photoinduced electron transfer from a conducting polymer to buckminsterfullerene,” Science 258, 1474-1476 (1992). [38] G. Yu, J. Gao, J. C. Hummelen, F. Wudl, and A. J. Heeger, “Polymer photovoltaic cells: Enhanced efficiencies via a network of internal donor-acceptor heterojunctions,” Science 270, 1789-1791 (1995). [39] S. E. Shaheen, C. J. Brabec, and N. S. Sariciftci, “2.5% efficient organic plastic solar cells,” Appl. Phys. Lett. 78(6), 841-843 (2001). [40] F. Padinger, R. S. Rittberger, and N. S. Sariciftci, “Effects of Postproduction Treatment on Plastic Solar Cells,” Adv. Funct. Mater. 13(1), 85-88 (2003). [41] G. Li, V. Shrotriya, Y. Yao, and Y. Yang, “Investigation of annealing effects and film thickness dependence of polymer solar cells based on poly(3-hexylthiophene),” J. Appl. Phys. 98, 043704 (2005). [42] G. Li, V. Shrotriya, J. Huang, Y. Yao, T. Moriarty, K. Emery, and Y. Yang, “High-efficiency solution processable polymer photovoltaic cells by self-organization of polymer blends,” Nat. Mater. 4, 864-868 (2005). [43] I. W. Hwang, C. Soci, D. Moses, Z. Zhu, D. Waller, R. Gaudiana, C. J. Brabec, and A. J. Heeger, “Ultrafast electron transfer and decay dynamics in a small band gap bulk heterojunction material,” Adv. Mater. 19, 2307-2312 (2007). [44] N. C. Greenham, X. Peng, and A. P. Alivisatos, “Charge separation and transport in conjugated-polymer/semiconductor-nanocrystal composites studied by photoluminescence quenching and photoconductivity,” Phys. Rev. B 54(24), 17628-17637 (1996). [45] A. D. Pasquier, Daniel D. T. Mastrogiovanni, L. A. Klein, T. Wang, and E. Garfunkel, “Photoinduced charge transfer between poly(3-hexylthiophene) and germanium nanowires,” Appl. Phys. Lett. 91, 183501 (2007). [46] N. Tokranova, I. Levitsky, B. Xu, J. Castracane, and W. Euler, “Hybrid solar cells based organic material embedded into porous silicon”, Proc. of SPIE 5724, 183-190 (2005). [47] K. M. Coakley, Y. Liu, C. Goh, and M. D. McGehee, “Ordered organic-inorganic bulk heterojunction photovoltaic cells,” MRS Bull. 30, 37-40 (2005). [48] V. D. Mihailetchi, P. W. M. Blom, J. C. Hummelen, and M. T. Rispens, “Cathode dependence of the open-circuit voltage of polymer:fullerene bulk heterojunction solar cells,” J. Appl. Phys. 94, 6849-6854 (2003). [49] 黃則凱, 有機無機混掺薄膜太陽能電池之光電特性研究, 國立臺灣大學材 料科學與工程學研究所碩士論文, 2007. [50] A. W. Hains and T. J. Marks, “High-efficiency hole extraction/electron-blocking layer to replace poly(3,4-ethylenedioxythiophene):poly(styrene sulfonate) in bulk-heterojunction polymer solar cells,” Appl. Phys. Lett. 92, 023504 (2008). [51] J. Liu, Y Shi, and Y. Yang, “Solvation-induced morphology effects on the performance of polymer-based photovoltaic devices,” Adv. Funct. Mater. 11(6), 420-424 (2001). [52] T. Martens, T. Munters, L. Goris, J. D’Haen, K. Schouteden, M. D’Olieslaeger, L. Lutsen, D. Vanderzande, W. Geens, J. Poortmans, L. De Schepper, J. V. Manca, “Nanostructured organic pn junctions towards 3D photovoltaics,” Appl. Phys. A 79, 27-30 (2004). [53] K. Kim, J. Liu, Manoj A. G. Namboothiry, and D. L. Carroll, “Roles of donor and acceptor nanodomains in 6% efficient thermally annealed polymer photovoltaics,” Appl. Phys. Lett. 90, 163511 (2007). [54] J. Huang, G. Li, and Y. Yang, “Influence of composition and heat-treatment on the charge transport properties of poly (3-hexylthiophene) and [6,6]-phenyl C61-butyric acid methyl ester blends,” Appl. Phys. Lett. 87, 112105 (2005). [55] C. J. Ko, Y. K. Lin, F. C. Chen, and C. W. Chu, “Modified buffer layers for polymer photovoltaic devices,” Appl. Phys. Lett. 90, 063509 (2007). [56] A. Hayakawa, O. Yoshikawa, T. Fujieda, K. Uehara, and S. Yoshikawa, “High performance polythiophene/fullerene bulk-heterojunction solar cell with a TiOx hole blocking layer,” Appl. Phys. Lett. 90, 163517 (2007). [57] M. Adachi and D. J. Lockwood, “Self-Organized Nanoscale Materials,” Chap. 3, 101-158, Springer, New York, 2006. [58] F. Wang, A. Dong, J. Sun, R. Tang, H. Yu, and W. E. Buhro, “Solution-liquid-solid growth of semiconductor nanowires,” Inorg. Chem. 45, 7511-7521 (2006). [59] R. S. Wagner and W. C. Ellis, “Vapor-liquid-solid mechanism of single crystal growth,” Appl. Phys. Lett. 4(5), 89 (1964). [60] Th. Stelzner, G. Andrä, F. Falk, E. Wendler, W. Wesch, R. Scholz, and S. Christiansen, “Silicon nanowire synthesis on metal implanted silicon substrates,” Nucl. Instr. and Meth. in Phys. Res. B 257, 172-176 (2007). [61] P. Mohan, J. Motohisa, and T. Fukui, “Controlled growth of highly uniform, axial/radial direction-defined, individually addressable InP nanowire arrays,” Nanotechnology 16, 2903-2907 (2005). [62] E. Tutuc, S. Guha, and J. O. Chu, “Morphology of germanium nanowires grown in presence of B2H6,” Appl. Phys. Lett. 88, 043113 (2006). [63] J. R. Morber, Y. Ding, M. S. Haluska, Y. Li, J. P. Liu, Z. L. Wang, and R. L. Snyder, “PLD-assisted VLS growth of aligned ferrite nanorods, nanowires, and nanobelts-synthesis, and properties,” J. Phys. Chem. B 110(43), 21672-21679 (2006). [64] Q. Wan, E. N. Dattoli, W. Y. Fung, W. Guo, Y. Chen, X. Pan, and W. Lu, “High-performance transparent conducting oxide nanowires,” Nano Lett. 6(12), 2909-2915 (2006). [65] Y. Tian, G. Meng, S. K. Biswas, P. M. Ajayan, S. Sun, and L. Zhang, “Y-branched Bi nanowires with metal-semiconductor junction behavior,” Appl. Phys. Lett. 85(6), 967-969 (2004). [66] L. Li, Y. Yang, X. Huang, G. Li, and L. Zhang, “Fabrication and characterization of single-crystalline ZnTe nanowire arrays,” J. Phys. Chem. B 109, 12394-12398 (2005). [67] C. L. Xu, H. Li, G. Y. Zhao, and H. L. Li, “Electrodeposition and magnetic properties of Ni nanowire arrays on anodic aluminum oxide/Ti/Si substrate,” Appl. Surf. Sci. 253, 1399-1403 (2006). [68] Y. Zhou, J. Huang, C. Shen, and H. Li, “Synthesis of highly ordered LiNiO2 nanowire arrays in AAO templates and their structural properties,” Mater. Sci. Eng. A 335, 260-267 (2002). [69] C. C. Chen, Y. Bisrat, Z. P. Luo, R. E. Schaak, C. G. Chao, and D. C. Lagoudas, “Fabrication of single-crystal tin nanowires by hydraulic pressure injection,” Nanotechnology 17, 367-374 (2006). [70] Q. Zhang, Y. Li, D. Xu, and Z. Gu, “Preparation of silver nanowire arrays in anodic aluminum oxide templates,” J. Mater. Sci. Lett. 20, 925-927 (2001). [71] Y. Bisrat, Z. P. Luo, D. Davis, and D. Lagoudas, “Highly ordered uniform single-crystal Bi nanowires: fabrication and characterization,” Nanotechnology 18, 395601 (2007). [72] J. S. Huang and C. F. Lin, “Influences of ZnO sol-gel thin film characteristics on ZnO nanowire arrays prepared at low temperature using all solution-based processing,” J. Appl. Phys. 103, 014304 (2008). [73] N. Beermann, L. Vayssieres, S. E. Lindquist, and A. Hagfeldt, “Photoelectrochemical studies of oriented nanorod thin films of hematite,” J. Electrochem. Soc. 147(7), 2456-2461 (2000). [74] K. Peng, Y. Xu, Y. Wu, Y. Yan, S. T. Lee, and J. Zhu, “Aligned single-crystalline Si nanowire arrays for photovoltaic application,” Small 1, 1062-1067 (2005). [75] Y. H. Chang, T. H. Hsueh, F. I Lai, C. W. Chang, C. C. Yu, H. W. Huang, C. F. Lin, H. C. Kuo, and S. C. Wang, “Fabrication and micro-photoluminescence investigation of Mg-doped gallium nitride nanorods,” Jpn. J. Appl. Phys. 44(4B), 2657-2660 (2005). [76] L. Tsakalakos, J. Balch, J. Fronheiser, B. A. Korevaar, O. Sulima, and J. Rand, “Silicon nanowire solar cells,” Appl. Phys. Lett. 91, 233117 (2007). [77] A. P. Goodey, S. M. Eichfeld, K. K. Lew, J. M. Redwing, and T. E. Mallouk, “Silicon nanowire array photoelectrochemical cells,” J. Am. Chem. Soc. 129, 12344-12345 (2007). [78] A. Alec Talin, L. L. Hunter, F. Leonard, and R. Rokad, “Large area, dense silicon nanowire array chemical sensors,” Appl. Phys. Lett. 89, 153102 (2006). [79] W. Chen, H. Yao, C. H. Tzang, J. Zhu, M. Yang, and S. T. Lee, “Silicon nanowires for high-sensitivity glucose detection,” Appl. Phys. Lett. 88, 213104 (2006). [80] Y. Cui, Z. Zhong, D. Wang, W. U. Wang, and C. M. Lieber, “High performance silicon nanowire field effect transistors,” Nano Lett. 3(2), 149-152 (2003). [81] H. J. Fan, P. Werner, and M. Zacharias, “Semiconductor nanowires: from self organization to patterned growth,” Small 2, 700-717 (2006). [82] I. Lombardi, A. I. Hochbaum, P. Yang, C. Carraro, and R. Maboudian, “Synthesis of high density, size-controlled Si nanowire arrays via porous anodic alumina mask', Chem. Mater. 18, 988-991 (2006). [83] D. Gopireddy, C. G. Takoudis, D. Gamota, J. Zhang, and P. W. Brazis, “Fabrication of silicon nanowires using atomic layer deposition,” Nanotech 2, 515-518 (2005). [84] A. M. Morales and C. M. Lieber, “A laser ablation method for the synthesis of crystalline semiconductor nanowires,” Science 279, 208 (1998). [85] B. M. Kayes, M. A. Filler, M. C. Putnam, M. D. Kelzenberg, N. S. Lewis, and H. A. Atwater, “Growth of vertically aligned Si wire arrays over large areas (>1 cm2) with Au and Cu catalysts,” Appl. Phys. Lett. 91, 103110 (2007). [86] K. Q. Peng, Y. J. Yan, S. P. Gao, and J. Zhu, “Synthesis of large-area silicon nanowire arrays via self-assembling nanoelectrochemistry,” Adv. Mater. 14(16), 1164-1167 (2002). [87] K. Peng, Y. Yan, S. Gao, and J. Zhu, “Dendrite-assisted growth of silicon nanowires in electroless metal deposition,” Adv. Funct. Mater. 13(2), 127-132 (2003). [88] K. Peng, J. Hu, Y. Yan, Y. Wu, H. Fang, Y. Xu, S. Lee, and J. Zhu, “Fabrication of single-crystalline silicon nanowires by scratching a silicon surface with catalytic metal particles,” Adv. Funct. Mater. 16, 387-394 (2006). [89] H. Yu and W. E. Buhro, “Solution-liquid-solid growth of soluble GaAs nanowires,” Adv. Mater. 15(5), 416-419 (2003). [90] L. Tonks and I. Langmuir, “A general theory of the plasma of an arc,” Phys. Rev. 34, 876-922(1929). [91] 洪昭南,電漿反應器,化工技術,第三卷,第三期,124,1995。 [92] M. A. Liberman and A. J. Lichtenberg, “Principles of Plasma Discharges and Materials Processing,” Wiley New York, 1994. [93] 黃昭睿,矽奈米結構與矽發光效率之關係研究,國立台灣大學光電工程學研 究所碩士論文,2004. [94] Y. Zhao, Z. Xie, Y. Qu, Y. Geng, and L. Wang, “Solvent-vapor treatment induced performance enhancement of poly(3-hexylthiophene):methanofullerene bulk-heterojunction photovoltaic cells,” Appl. Phys. Lett. 90, 043504 (2007). [95] F. Yang, M. Shtein, and S. R. Forrest, “Controlled growth of a molecular bulk heterojunction photovoltaic cell,” Nat. Mater. 4, 37-41 (2005). [96] Y. Saito, T. Kitamura, Y. Wada, and S. Yanagida, “Application of poly(3,4-ethylenedioxythiophene) to counter electrode in dye-sensitized solar cells,” Chem. Lett. 31(10), 1060-1061 (2002). [97] S. S. Li and W. R. Thurber, “The dopant density and temperature dependence of electron mobility and resistivity in n-type silicon,” Solid-State Electron. 20, 609-616 (1977). [98] A. H. Jayatissa,” Preparation of gallium-doped ZnO films by oxidized ZnS films,” Semicond. Sci. Technol. 18(6), L27-L30 (2003). | |
dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/42229 | - |
dc.description.abstract | 有機共軛高分子太陽能電池具有低成本、低溫製程、可撓、容易大面積製造等等優點,近年來引起廣大的注意。爲了增加有機共軛高分子太陽能電池之光電轉換效率,一般都採用本體異質結構,此結構由施體如poly(3-hexylthiophene) (P3HT)和受體如[6,6]-phenyl-C61-butyric acid methyl ester (PCBM)混合組成一層。本體異質結構元件是施體和受體材料互相交錯形成,提供大面積的界面讓照光所產生的激子能有效分離成電子電洞。然而施體和受體材料互相交錯則不容易形成。除此之外有機材料不是很適合載子傳輸,因此有機共軛高分子太陽能電池之光電轉換效率受限於低激子的分離機率和沒有效率的跳躍式載子傳輸。
因此我們結合單晶矽奈米線與有機材料去克服有機共軛高分子太陽能電池的缺點,利用排列整齊單晶之矽奈米線結合P3HT:PCBM本體異質結構去製作排列整齊單晶矽奈米線混成太陽能電池,這排列整齊的矽奈米線是被製造從矽晶圓,並且轉移到P3HT:PCBM所覆蓋的玻璃基板,此矽奈米線提供電子未被打擾的傳導路徑、加強光的吸收和增加激子分離的界面面積。我們的結果展示矽奈米線是有潛力地提升混成太陽能電池效率,藉由增加短路電流從7.17 mA/cm2到11.61 mA/cm2。 | zh_TW |
dc.description.abstract | Conjugated polymer-based organic solar cells have attracted considerable attention in recent years because they have many advantages, such as low-cost, processing with low temperature, flexible, large area production and so on. To increase the power conversion efficiency of organic solar cells, the most common strategy is so-called bulk heterojunction, in which donors such as poly(3-hexylthiophene) (P3HT) and acceptors like [6,6]-phenyl-C61-butyric acid methyl ester (PCBM) are blended to form one mixed layer. The bulk heterojunction devices were characterized by an interpenetrating network of donor and acceptor materials, providing a large interface area where photo-induced excitons could efficiently dissociate into separated electrons and holes. However, the interpenetrating network cannot be easily formed in the blended mixture. In addition, the organic materials are not good in carrier transport. Thus the power conversion efficiency is still limited by the low dissociation probability of excitons and the inefficient hopping carrier transport.
Therefore, we combined single-crystalline Si nanowires with P3HT:PCBM to overcome the drawbacks of the conjugated polymer-based organic solar cells. The well-aligned SiNWs are fabricated from Si wafer and transferred onto the glass substrate with the P3HT:PCBM. Such SiNWs provide an uninterrupted conduction path for electron transport, enhance the optical absorption to serve as an interesting candidate of the absorber, and increase the surface area for exciton dissociation. Our investigations show that SiNWs are promising for hybrid organic photovoltaic cells with improved performance by increasing the short-circuit current density from 7.17 to 11.61 mA/cm2. | en |
dc.description.provenance | Made available in DSpace on 2021-06-15T00:54:09Z (GMT). No. of bitstreams: 1 ntu-97-R95941014-1.pdf: 2588654 bytes, checksum: 94b387a2415fbf8694275eab99874c73 (MD5) Previous issue date: 2008 | en |
dc.description.tableofcontents | 致謝 I
摘要 II Abstract III 圖目錄 VI 表目錄 X 第一章 緒論 1 1-1 簡介 1 1-2 研究動機 5 1-3 論文導覽 7 第二章 共軛高分子太陽能電池 8 2-1 太陽能電池理論 9 2-1-1 太陽光頻譜 9 2-1-2 無機太陽能電池原理 10 2-1-3 有機太陽能電池原理 12 2-1-4 理想太陽能電池分析 18 2-1-5 實際太陽能電池分析 19 2-2 共軛高分子的簡介 22 2-3 共軛高分子太陽能電池架構介紹 28 2-3-1 單層結構 28 2-3-2 雙層異質結構 29 2-3-3 本體異質結構 30 2-3-4 有序本體異質結構 34 2-4 共軛高分子太陽能電池特性分析 36 2-4-1 開路電壓分析 36 2-4-2 短路電流分析 37 2-4-3 填充因子分析 38 第三章 矽奈米線和砷化鎵奈米線的製備與研究 40 3-1 奈米線之簡介 41 3-2 矽奈米線 45 3-2-1 簡介 45 3-2-2 無電極沉積濕蝕刻製備矽奈米線之原理 45 3-2-3 矽奈米線的製備流程 46 3-2-4 探討蝕刻時間對矽奈米線的關係 47 3-3 砷化鎵奈米線 48 3-3-1 電漿和感應耦合式電漿介紹 48 3-3-2 感應耦合式電漿蝕刻的機制簡介 52 3-3-3 砷化鎵奈米線的製備和討論 53 第四章 單晶排列整齊的矽奈米線之混成太陽能電池 57 4-1 簡介 57 4-2 製作單晶排列整齊的矽奈米線之混成太陽能電池 60 4-3 探討轉移前後矽奈米線的情形 66 4-4 吸收光譜量測與討論 68 4-5 電流電壓特性曲線分析 70 第五章 總結 78 5-1 論文回顧 78 5-2 建議與未來展望 80 參考文獻 81 | |
dc.language.iso | zh-TW | |
dc.title | 無機奈米線與有機材料混成太陽能電池之研究 | zh_TW |
dc.title | Study of Inorganic Nanowire and Organic Hybrid Solar Cells | en |
dc.type | Thesis | |
dc.date.schoolyear | 96-2 | |
dc.description.degree | 碩士 | |
dc.contributor.oralexamcommittee | 林浩雄(Hao-Hsiung Lin),陳奕君(I-Chun Cheng) | |
dc.subject.keyword | 矽奈米線,砷化鎵奈米線,高分子,混成太陽能電池,本體異質結構, | zh_TW |
dc.subject.keyword | silicon nanowire,gallium arsenide nanowire,polymer,hybrid solar cells,bulk heterojunction structure, | en |
dc.relation.page | 90 | |
dc.rights.note | 有償授權 | |
dc.date.accepted | 2008-08-07 | |
dc.contributor.author-college | 電機資訊學院 | zh_TW |
dc.contributor.author-dept | 光電工程學研究所 | zh_TW |
顯示於系所單位: | 光電工程學研究所 |
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