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完整後設資料紀錄
DC 欄位 | 值 | 語言 |
---|---|---|
dc.contributor.advisor | 林唯芳 | |
dc.contributor.author | Tsung-Wei Zeng | en |
dc.contributor.author | 曾琮瑋 | zh_TW |
dc.date.accessioned | 2021-06-15T00:29:36Z | - |
dc.date.available | 2014-02-03 | |
dc.date.copyright | 2009-02-03 | |
dc.date.issued | 2009 | |
dc.date.submitted | 2009-01-19 | |
dc.identifier.citation | Chapter 1
[1] M. A. Green, “Third generation photovoltaics: Advanced solar energy conversion,” Springer (2003). [2] W. U. Huynh, “Nanocrystal-polymer solar cells,” University of California, Berkeley (2002). [3] K. Petritsch, “Organic solar cell architectures,” University of Cambridge (2000). [4] M. Grätzel,“Photoelectrochemical cells,” Nature 414, 338 (2001). [5] B. O’Regan, M. Grätzel,” A low-cost, high-efficiency solar cell based on dye-sensitized colloidal TiO2 films,” Nature 353, 737 (1991). [6] M. Grätzel, “Dye–sensitized solid–state heterojunction solar cells,” MRS BULLETIN 30, 23 (2005). [7] V. Saxena, B.D. Malhotra, “Prospects of conducting polymers in molecular electronics,” Current Applied Physics 3 293 (2003). [8] J. Y. Kim, K. Lee, N. E. Coates, D. Moses, T.-Q. Nguyen, M. Dante, A. J. Heeger, “Efficient tandem polymer solar cells fabricated by all-solution processing,” Science 317, 222 (2007). [9] K. Kim, J. Liu, M. A. G. Namboothiry, D. L. Carroll, “Roles of donor and acceptor nanodomains in 6% efficient thermally annealed polymer photovoltaics,” Appl. Phys. Lett. 90, 163511 (2007). [10] W. Ma, C. Yang, X. Gong, K. Lee, A. J. Heeger, “Thermally stable, efficient polymer solar cells with nanoscale control of the interpenetrating network morphology,” Adv. Func. Mater. 15, 1617 (2005). [11] S.-S. Sun, N. S. Sariciftci, “Organic photovoltaics mechanisms, materials, and devices,” CRC Press, Boca Raton (2005). [12] A. Moliton, J.-M. Nunzi, “How to model the behaviour of organic photovoltaic cells,” Polym Int. 55, 583 (2006). [13] K. M. Coakley, M. D. McGehee, “Conjugated polymer photovoltaic cells,” Chem. Mater. 16, 4533 (2004). [14] A. Goetzbergera, C. Heblinga, H.-W. Schockb, “Photovoltaic materials, history, status and outlook,” Mater. Sci. Eng. R 40, 1 (2003). [15] H. Hoppe, N. S. Sariciftci, “Organic solar cells: An overview,” J. Mater. Res. 19, 1924 (2004). [16] G. Yu, J. Gao, J. C. Hummelen, F. Wudl, A. J. Heeger, “Polymer photovoltaic cells: Enhanced efficiencies via a network of internal donor-acceptor heterojunctions,” Science 270, 1789 (1995). [17] S. E. Shaheen, C. J. Brabec, N. S. Sariciftci, F. Padinger, T. Fromherz and J. C. Hummelen, “2.5% efficient organic plastic solar cells,” Appl. Phys. Lett. 78, 841 (2001). [18] F. Padinger, R.S. Rittberger, N.S. Sariciftci, “Effects of postproduction treatment on plastic solar cells,” Adv. Funct. Mater., 13, 85 (2003). [19] R. A. J. Janssen, J. C. Hummelen, N. S. Sariciftci, “Polymer-fullerene bulk heterojunction solar cells,” MRS BULLETIN 30, 33 (2005). [20] N. C. Greenham, X. Peng, A. P. Alivisatos, “Charge separation and transport in conjugated-polymer/semiconductor-nanocrystal composites studied by photoluminescence quenching and photoconductivity,” Phys. Rev. B 54, 17628 (1996). [21] W. U. Huynh, J. J. Dittmer, A. P. Alivisatos, “Hybrid nanorod-polymer solar cells,” Science 29, 2425 (2002). [22] D. J. Milliron, I. Gur, A. P. Alivisatos, “Hybrid organic–nanocrystal solar cells,” MRS BULLENTIN 30, 41 (2005). [23] K. M. Coakley, M. D. McGehee, “Photovoltaic cells made from conjugated polymers infiltrated into mesoporous titania,” Appl. Phys. Lett. 79, 2058 (2003). [24] K. M. Coakley, Y. Liu, C. Goh, M. D. McGehee, “Ordered organic–inorganic bulk heterojunction photovoltaic cells,” MRS BULLETIN 30, 37 (2005). [25] Z. B. Xie , B. M. Henry, K. R. Kirov, D. A. R. Barkhouse, V. M. Burlakov, H. E. Smith, C. R. M. Grovenor, H. E. Assender, G. A. D. Briggs, M. Kano, Y. Tsukahara, “Correlation between photoconductivity in nanocrystalline titania and short circuit current transients in MEH-PPV/titania solar cells,” Nanotechnology 18, 145708 (2007). [26] A. C. Arango, L. R. Johnson, V. N. Bliznyuk, Z. Schlesinger, S. A. Carter, H. H. Hörhold, “Efficient titanium oxide/conjugated polymer photovoltaics for solar energy conversion,” Adv. Mater. 12, 1689 (2000). [27] A. J. Breeze, Z. Schlesinger, S. A. Carter, P. J. Brock, “Charge transport in TiO2/MEH-PPV polymer photovoltaics,” Phys. Rev. B 64, 1252051 (2001). [28] K. Y. Cheung, C. T. Yip, A. B. Djurisic, Y. H. Leung, W. K. Chan, “Long K-doped titania and titanate nanowires on Ti foil and fluorine-doped tin oxide/quartz substrates for solar-cell applications,” Adv. Funct. Mater., 17, 555 (2007). [29] K. Takanezawa, K. Hirota, Q.-S. Wei, K. Tajima, K. Hashimoto, “Efficient charge collection with ZnO nanorod array in hybrid photovoltaic devices,” J. Phys. Chem. C 111, 7218 (2007). [30] J. Bouclé, P. Ravirajan, J. Nelson, “Hybrid polymer–metal oxide thin films for photovoltaic applications,” J. Mater. Chem. 30, 3141 (2007). [31] W. J. E. Beek, M. M. Wienk, M. Kemerink, X. Yang, R. A. J. Janssen, “Hybrid zinc oxide - conjugated polymer bulk heterojunction solar cells,” J. Phys. Chem. B 109, 9505 (2005). [32] C. Y. Kwong, W. C. H. Choy, A. B. Djurisic, P. C. Chui, K. W. Cheng, W.K. Chan, “Poly(3-hexylthiophene):TiO2 nanocomposites for solar cell applications,” Nanotechnology, 15, 1156 (2004). [33] J. S. Salafsky, W. H. Lubberhuizen, R. E. I. Schropp, “Photoinduced charge separation and recombination in a conjugated polymer-semiconductor nanocrystal composite,” Chem. Phys. Lett. 290, 297 (1998). [34] J. S. Salafsky, “Exciton dissociation, charge transport, and recombination in ultrathin, conjugated polymer-TiO2 nanocrystal intermixed composites,” Phys. Rev. B 59, 10885 (1999). [35] A. C. Arango, S. A. Carter, P. J. Brock, “Charge transfer in photovoltaics consisting of interpenetrating networks of conjugated polymer and TiO2 nanoparticles,” Appl. Phys. Lett. 74, 1698 (1999). [36] A. Petrella, M. Tamborra, M. L. Curri, P. Cosma, M. Striccoli, P. D. Cozzoli, A. Agostiano, “Colloidal TiO2 nanocrystals/MEH-PPV nanocomposites: Photo(electro)chemical study,” J. Phys. Chem. B 109, 1554 (2005). [37] Y.-T. Lin, T.-W. Zeng, W.-Z. Lai, C.-W. Chen, Y.-Y. Lin, Y.-S. Chang, W.-F. Su, “Efficient photoinduced charge transfer in TiO2 nanorod/conjugated polymer hybrid materials,” Nanotechnology 17, 5781 (2006). [38] T.-W. Zeng, Y.-Y. Lin, H.-H. Lo, C.-W. Chen, C.-H. Chen, S.-C. Liou, H.-Y. Huang, W.-F. Su, “A large interconnecting network within hybrid MEH-PPV/TiO2 nanorod photovoltaic devices,” Nanotechnology 17, 5387 (2006). [39] Y.-Y. Lin, C.-W. Chen, T.-H. Chu, W.-F. Su, C.-C. Lin, C.-H. Ku, J.-J. Wu, C.-H. Chen, “Nanostructured metal oxide/conjugated polymer hybrid solar cells by low temperature solution processes,” J. Mater. Chem. 17, 4571 (2007). [40] Y.-Y. Lin, T.-H. Chu, C.-W. Chen, W.-F. Su, “Improved performance of polymer/TiO2 nanorod bulk heterojunction photovoltaic devices by interface modification,” Appl. Phys. Lett., 92, 053312(2008). [41] H. Hoppe and N. S. Sariciftci, “Morphology of polymer/fullerene bulk heterojunction solar cells,” J. Mater. Chem. 16, 45 (2006). [42] S. Günes, H. Neugebauer, N. S. Sariciftci, “Conjugated polymer-based organic solar cells,” Chem. Rev. 107, 1324 (2007). [43] C. J. Brabec, J. A. Hauch, P. Schilinsky, C. Waldauf, “Production aspects of organic photovoltaics and their impact on the commercialization of devices,” MRS BULLENTIN 30, 50 (2005). [44] M. C. Scharber, D. Mühlbacher, M. Koppe, P. Denk, C. Waldauf, A. J. Heeger, C. J. Brabec, “Design rules for donors in bulk-heterojunction solar cells - Towards 10 % energy-conversion efficiency,” Adv. Mater. 18, 789 (2006). [45] L. J. A. Koster, V. D. Mihailetchi, P. W. M. Blom, “Ultimate efficiency of polymer/fullerene bulk heterojunction solar cells,” Appl. Phys. Lett. 88, 093511 (2006). [46] S. E. Shaheen, D. S. Ginley, G. E. Jabbour,” Organic-based photovoltaics,” MRS BULLENTIN 30, 10 (2005). [47] V. Palermo, M. Palma and P. Samorì, “Electronic characterization of organic thin films by Kelvin probe force microscopy,” Adv. Mater. 18, 145 (2006). [48] A. Liscio, V. Palermo, D. Gentilini, F. Nolde, K. Müllen and P. Samorì, “Quantitative measurement of the local surface potential of π-conjugated nanostructures: A kelvin probe force microscopy study,” Adv. Func. Mater. 16, 1407 (2006). [49] V. Palermo, G. Ridolfi, A. M. Talarico, L. Favaretto, G. Barbarella, N. Camaioni and P. Samorì, “Kelvin probe force microscopy study of the photogeneration of surface charges in all-thiophene photovoltaic blends,” Adv. Func. Mater. 17, 472 (2007). [50] M. Chiesa, L. Bürgi, J.-S. Kim, R. Shikler, R. H. Friend, and H. Sirringhaus, “Correlation between surface photovoltage and blend morphology in polyfluorene-based photodiodes,” Nano Lett., 5, 559 (2005). [51] H. Hoppe, T. Glatzel, M. Niggemann, A. Hinsch, M. Ch. Lux-Steiner, and N. S. Sariciftci,“Kelvin probe force microscopy study on conjugated polymer/fullerence bulk heterojunction organic solar cells,” Nano Lett. 5, 269 (2005). [52] Andrea Liscio, Giovanna De Luca, Fabian Nolde, Vincenzo Palermo, Klaus Müllen, and Paolo Samorì, “Photovoltaic Charge Generation Visualized at the Nanoscale: A Proof of Principle,” J. Am. Chem. Soc. 130, 780 (2008). Chapter 2 [1] W. Ma, C. Yang, X. Gong, K. Lee, A. J. Heeger, “Thermally stable, efficient polymer solar cells with nanoscale control of the interpenetrating network morphology,” Adv. Func. Mater. 15, 1617 (2005). [2] J. Y. Kim, K. Lee, N. E. Coates, D. Moses, T.-Q. Nguyen, M. Dante, A. J. Heeger, “Efficient tandem polymer solar cells fabricated by all-solution processing,” Science 317, 222 (2007). [3] K. Kim, J. Liu, M. A. G. Namboothiry, D. L. Carroll, “Roles of donor and acceptor nanodomains in 6% efficient thermally annealed polymer photovoltaics,” Appl. Phys. Lett. 90, 163511 (2007). [4] N. C. Greenham, X. Peng, A. P. Alivisatos, “Charge separation and transport in conjugated-polymer/semiconductor-nanocrystal composites studied by photoluminescence quenching and photoconductivity,” Phys. Rev. B 54, 17628 (1996). [5] W. U. Huynh, J. J. Dittmer, A. P. Alivisatos, “Hybrid nanorod-polymer solar cells,” Science 29, 2425 (2002). [6] A. C. Arango, L. R. Johnson, V. N. Bliznyuk, Z. Schlesinger, S. A. Carter, H. H. Hörhold, “Efficient titanium oxide/conjugated polymer photovoltaics for solar energy conversion,” Adv. Mater. 12, 1689 (2000). [7] W. J. E. Beek, M. M. Wienk, M. Kemerink, X. Yang, R. A. J. Janssen, “Hybrid zinc oxide - conjugated polymer bulk heterojunction solar cells,” J. Phys. Chem. B 109, 9505 (2005). [8] A. J. Breeze, Z. Schlesinger, S. A. Carter, P. J. Brock, “Charge transport in TiO2/MEH-PPV polymer photovoltaics,” Phys. Rev. B 64, 1252051 (2001). [9] K. M. Coakley, M. D. McGehee, “Photovoltaic cells made from conjugated polymers infiltrated into mesoporous titania,” Appl. Phys. Lett. 79, 2058 (2003). [10] K. M. Coakley, Y. Liu, C. Goh, M. D. McGehee, “Ordered organic–inorganic bulk heterojunction photovoltaic cells,” MRS BULLETIN 30, 37 (2005). [11] Z. B. Xie , B. M. Henry, K. R. Kirov, D. A. R. Barkhouse, V. M. Burlakov, H. E. Smith, C. R. M. Grovenor, H. E. Assender, G. A. D. Briggs, M. Kano, Y. Tsukahara, “Correlation between photoconductivity in nanocrystalline titania and short circuit current transients in MEH-PPV/titania solar cells,” Nanotechnology 18, 145708 (2007). [12] J. Bouclé, P. Ravirajan, J. Nelson, “Hybrid polymer–metal oxide thin films for photovoltaic applications,” J. Mater. Chem. 30, 3141 (2007). [13] C. Y. Kwong, W. C. H. Choy, A. B. Djurisic, P. C. Chui, K. W. Cheng, W.K. Chan, “Poly(3-hexylthiophene):TiO2 nanocomposites for solar cell applications,” Nanotechnology, 15, 1156 (2004). [14] A. Petrella, M. Tamborra, P. D. Cozzoli, M. L. Curri, M. Striccoli, P. Cosma, G. M. Farinola, F. Babudri, F. Naso, A. Agostiano, “TiO2 nanocrystals – MEH-PPV composite thin films as photoactive material,” Thin Solid Films 451/452, 64 (2004). [15] A. Petrella, M. Tamborra, M. L. Curri, P. Cosma, M. Striccoli, P. D. Cozzoli, A. Agostiano, “Colloidal TiO2 Nanocrystals/MEH-PPV Nanocomposites: Photo(electro)chemical Study,” J. Phys. Chem. B 109, 1554 (2005). [16] Y.-T. Lin, T.-W. Zeng, W.-Z. Lai, C.-W. Chen, Y.-Y. Lin, Y.-S. Chang, W.-F. Su, “Efficient photoinduced charge transfer in TiO2 nanorod/conjugated polymer hybrid materials,” Nanotechnology 17, 5781 (2006). Chapter 3 [1] P. D. Cozzoli, A. Kornowski, H. Weller, “Low-temperature synthesis of soluble and processable organic-capped anatase TiO2 nanorods,” J. Am. Chem. Soc. 125, 14539 (2003). [2] W. U. Huynh, “Nanocrystal-polymer solar cells,” University of California, Berkeley (2002). [3] J. Joo, S. G. Kwon, T. Yu, M. Cho, J. Lee, J. Yoon, T. Hyeon, “Large-scale synthesis of TiO2 nanorods via nonhydrolytic sol-gel ester elimination reaction and their application to photocatalytic inactivation of E. coli,” J. Phys. Chem. B 109, 15297 (2005). [4] S.-S. Sun, N. S. Sariciftci, “Organic photovoltaics mechanisms, materials, and devices,” CRC Press, Boca Raton (2005). [5] A. L. Linsebigler, G. Lu, J. T. Yates, “Photocatalysis on TiO2 surfaces:Principles,mechanisms, and selected results,” Chem. Rev. 95, 735 (1995). [6] A. Hagfeldtt, M. Grätzel, “Light-induced redox reactions in nanocrystalline systems,” Chem, Rev. 95, 49 (1995). [7] C. Y. Yang, C. Soci, D. Moses, A. J. Heeger, “Aligned rrP3HT film: Structural order and transport properties,” Synthetic Metals 155, 639 (2005). [8] K. M. Coakley, M. D. McGehee, “Conjugated polymer photovoltaic cells,” Chem. Mater. 16, 4533 (2004). Chapter 4 [1] W. U. Huynh, J. J. Dittmer, A. P. Alivisatos, “Hybrid nanorod-polymer solar cells,” Science 29, 2425 (2002). [2] W. Ma, C. Yang, X. Gong, K. Lee, A. J. Heeger, “Thermally stable, efficient polymer solar cells with nanoscale control of the interpenetrating network morphology,” Adv. Func. Mater. 15, 1617 (2005). [3] S. E. Shaheen, C. J. Brabec, N. S. Sariciftci, F. Padinger, T. Fromherz and J. C. Hummelen, “2.5% efficient organic plastic solar cells,” Appl. Phys. Lett. 78, 841 (2001). [4] X. Yang, J. Loos, S. C. Veenstra, W. J. H. Verhees, M. M. Wienk, J. M. Kroon, M. A. J. Michels, R. A. J. Janssen, “Nanoscale morphology of high-performance polymer solar cells,” Nano Lett. 5 579 (2005). [5] M. Granström , K. Petritsch, A. C. Arias, A. Lux , M. R. Andersson, R. H. Friend, “Laminated fabrication of polymeric photovoltaic diodes,” Nature 395, 257 (1998). [6] N. C. Greenham, X. Peng, A. P. Alivisatos, “Charge separation and transport in conjugated-polymer/semiconductor-nanocrystal composites studied by photoluminescence quenching and photoconductivity,” Phys. Rev. B 54, 17628 (1996). [7] W. J. E. Beek, M. M. Wienk, M. Kemerink, X. Yang, R. A. J. Janssen, “Hybrid zinc oxide - conjugated polymer bulk heterojunction solar cells,” J. Phys. Chem. B 109, 9505 (2005). [8] C. Y. Kwong, W. C. H. Choy, A. B. Djurisic, P. C. Chui, K. W. Cheng, W. K. Chan, “Poly(3-hexylthiophene):TiO2 nanocomposites for solar cell applications,” Nanotechnology, 15, 1156 (2004). [9] W. U. Huynh, J. J. Dittmer, W. C. Libby, G. L. Whiting, A. P. Alivisatos, “Controlling the morphology of nanocrystal-polymer composites for solar cells,” Adv. Func. Mater. 13, 73 (2003). [10] B. Sun, E. Marx, N. C. Greenham, “Photovoltaic devices using blends of branched CdSe nanoparticles and conjugated polymers,” Nano Lett. 3, 961 (2003). [11] J. Jiu, S. Isoda, F. Wang, M. Adachi, “Dye-sensitized solar cells based on a nanorod film,” J. Phys. Chem. B 110, 2087 (2006). [12] A. J. Breeze, Z. Schlesinger, S. A. Carter, P. J. Brock, “Charge transport in TiO2/MEH-PPV polymer photovoltaics,” Phys. Rev. B 64, 1252051 (2001). [13] Q. Fan, B. McQuillin, D. D. C. Bradley, S. Whitelegg, A. B. Seddon, “A solid state solar cell using sol–gel processed material and a polymer,” Chem. Phys. Lett. 347, 325 (2000). [14] H. Wang, C. C. Oey, A. B. Djurišic, K. K. Y. Man, W. K. Chan, M. H. Xie, Y. H. Leung, P. C. Chui, A. Pandey, J.-M. Nunzi, “Titania bicontinuous network structures for solar cell applications,” Appl. Phys. Lett. 87, 023507 (2005). [15] C. C. Oey, A. B. Djurišic, H. Wang, K. K. Y. Man, W. K. Chan, M. H. Xie, Y. H. Leung, A. Pandey, J.-M. Nunzi, P. C. Chui, “Polymer–TiO2 solar cells: TiO2 interconnected network for improved cell performance,” Nanotechnology 17, 706 (2006). [16] R. Ravirajan, D. D. C. Bradley, J. Nelson, S. A. Haque, J. R. Durrant, H. J. P. Smith , J. M. Kroon, “Efficient charge collection in hybrid polymer/TiO2 solar cells using poly(ethylenedioxythiophene)/polystyrene sulphonate as hole collector,” Appl. Phys.Lett. 86 143101 (2005). [17] P. A. van Hal, M. M. Wienk, J. M. Kroon, W. J. Verhees, L. H. Sloof, W. J. H. Van Gennip, P. Jonkheijm, R. A. J. Janssen, “Photoinduced electron transfer and photovoltaic response of a MDMO-PPV:TiO2 bulk heterojunction,” Adv. Mater. 15, 118 (2003). [18] K. M. Coakley, M. D. McGehee, “Photovoltaic cells made from conjugated polymers infiltrated into mesoporous titania,” Appl. Phys. Lett. 79, 2058 (2003). [19] Y. Liu, M. A. Summers, C. Edder, J. M. J. Fréchet, M. D. McGehee, “Using resonance energy transfer to improve exciton harvesting in organic-inorganic hybrid photovoltaic cells,” Adv. Mater.17, 2960 (2005). [20] Q. Qiao, J. T. McLeskey, “Water-soluble polythiophene/nanocrystalline TiO2 solar cells,” Appl. Phys. Lett. 86, 153501 (2005). [21] A. Petrella, M. Tamborra, P. D. Cozzoli, M. L. Curri, M. Striccoli, P. Cosma, G. M. Farinola, F. Babudri, F. Naso, A. Agostiano, “TiO2 nanocrystals – MEH-PPV composite thin films as photoactive material,” Thin Solid Films 451/452, 64 (2004). [22] A. Petrella, M. Tamborra, M. L. Curri, P. Cosma, M. Striccoli, P. D. Cozzoli, A. Agostiano, “Colloidal TiO2 Nanocrystals/MEH-PPV Nanocomposites: Photo(electro)chemical Study,” J. Phys. Chem. B 109, 1554 (2005). [23] P. D. Cozzoli, A. Kornowski, H. Weller, “Low-temperature synthesis of soluble and processable organic-capped anatase TiO2 nanorods,” J. Am. Chem. Soc. 125, 14539 (2003). [24] Y. Y. Lin, C. W. Chen, J. Chang, T. Y. Lin, I. S. Liu, W. F. Su, “Exciton dissociation and migration in enhanced order conjugated polymer/nanoparticle hybrid materials,” Nanotechnology 17, 1260 (2006). [25] M. Thelakkat, C. Schmitz, H.-W. Schmidt,“Fully vapor-deposited thin-layer titanium dioxide solar cells, ” Adv. Mater. 14, 577 (2002). [26] J. Y. Kim, S. H. Kim, H.-H. Lee, K. Lee, W. Ma, X. Gong, A. J. Heeger, “New architecture for high-efficiency polymer photovoltaic cells using solution-based titanium oxide as an optical spacer,” Adv. Mater. 18, 572 (2006). [27] A. A. R. Watt, D. Blake, J. H. Warner, E. A. Thomsen, E. L. Tavenner, H. Rubinsztein-Dunlop, P. Meredith, “Lead sulfide nanocrystal: conducting polymer solar cells,” J. Phys. D: Appl. Phys. 38, 2006 (2005). Chapter 5 [1] W. Ma, C. Yang, X. Gong, K. Lee, A. J. Heeger, “Thermally stable, efficient polymer solar cells with nanoscale control of the interpenetrating network morphology,” Adv. Func. Mater. 15, 1617 (2005). [2] J. Y. Kim, K. Lee, N. E. Coates, D. Moses, T.-Q. Nguyen, M. Dante, A. J. Heeger, “Efficient tandem polymer solar cells fabricated by all-solution processing,” Science 317, 222 (2007). [3] M. Granström , K. Petritsch, A. C. Arias, A. Lux , M. R. Andersson, R. H. Friend, “Laminated fabrication of polymeric photovoltaic diodes,” Nature 395, 257 (1998). [4] W. U. Huynh, J. J. Dittmer, A. P. Alivisatos, “Hybrid nanorod-polymer solar cells,” Science 29, 2425 (2002). [5] P. Wang, A. Abrusci, H. M. P. Wong, M. Svensson, M. R. Andersson, N. C. Greenham, “Photoinduced charge transfer and efficient solar energy conversion in a blend of a red polyfluorene copolymer with CdSe nanoparticles Nano Lett. 6 1789 (2006). [6] W. J. E. Beek, M. M. Wienk, M. Kemerink, X. Yang, R. A. J. Janssen, “Hybrid zinc oxide - conjugated polymer bulk heterojunction solar cells,” J. Phys. Chem. B 109, 9505 (2005). [7] R. Ravirajan, D. D. C. Bradley, J. Nelson, S. A. Haque, J. R. Durrant, H. J. P. Smith , J. M. Kroon, “Efficient charge collection in hybrid polymer/TiO2 solar cells using poly(ethylenedioxythiophene)/polystyrene sulphonate as hole collector,” Appl. Phys.Lett. 86 143101 (2005). [8] D. C. Olson, J. Piris, R. T. Collins, S. E. Shaheen, D. S. Ginley, “Hybrid photovoltaic devices of polymer and ZnO nanofiber composites,” Thin Solid Films, 496, 26 (2006). [9] D. C. Olson, S. E. Shaheen, M. S. White, W. J. Mitchell, M. F. A. M. van Hest, R. T. Collins, D. S. Ginley, “Band-offset engineering for enhanced open-circuit voltage in polymer-oxide hybrid solar cells,” Adv. Funct. Mater. 17, 264 (2007). [10] J. Bouclé, P. Ravirajan, J. Nelson, “Hybrid polymer–metal oxide thin films for photovoltaic applications,” J. Mater. Chem. 30, 3141 (2007). [11] A. J. Breeze, Z. Schlesinger, S. A. Carter, P. J. Brock, “Charge transport in TiO2/MEH-PPV polymer photovoltaics,” Phys. Rev. B 64, 1252051 (2001). [12] K. M. Coakley, M. D. McGehee, “Photovoltaic cells made from conjugated polymers infiltrated into mesoporous titania,” Appl. Phys. Lett. 79, 2058 (2003). [13] H. Wang, C. C. Oey, A. B. Djurišic, K. K. Y. Man, W. K. Chan, M. H. Xie, Y. H. Leung, P. C. Chui, A. Pandey, J.-M. Nunzi, “Titania bicontinuous network structures for solar cell applications,” Appl. Phys. Lett. 87, 023507 (2005). [14] Q. Wei, K. Hirota, K. Tajima, K. Hashimoto, “Design and synthesis of TiO2 nanorod assemblies and their application for photovoltaic devices,” Chem. Mater. 18 , 5080 (2006). [15] Y.-Y. Lin, C.-W. Chen, T.-H. Chu, W.-F. Su, C.-C. Lin, C.-H. Ku, J.-J. Wu, C.-H. Chen, “Nanostructured metal oxide/conjugated polymer hybrid solar cells by low temperature solution processes,” J. Mater. Chem. 17, 4571 (2007). [16] C. Y. Kwong, W. C. H. Choy, A. B. Djurisic, P. C. Chui, K. W. Cheng, W. K. Chan, “Poly(3-hexylthiophene):TiO2 nanocomposites for solar cell applications,” Nanotechnology, 15, 1156 (2004). [17] T.-W. Zeng, Y.-Y. Lin, H.-H. Lo, C.-W. Chen, C.-H. Chen, S.-C. Liou, H.-Y. Huang, W.-F. Su, “A large interconnecting network within hybrid MEH-PPV/TiO2 nanorod photovoltaic devices,” Nanotechnology 17, 5387 (2006). [18] A. Petrella, M. Tamborra, M. L. Curri, P. Cosma, M. Striccoli, P. D. Cozzoli, A. Agostiano, “Colloidal TiO2 nanocrystals/MEH-PPV nanocomposites: Photo(electro)chemical study,” J. Phys. Chem. B 109, 1554 (2005). [19] Y.-T. Lin, T.-W. Zeng, W.-Z. Lai, C.-W. Chen, Y.-Y. Lin, Y.-S. Chang, W.-F. Su, “Efficient photoinduced charge transfer in TiO2 nanorod/conjugated polymer hybrid materials,” Nanotechnology 17, 5781 (2006). [20] P. D. Cozzoli, A. Kornowski, H. Weller, “Low-temperature synthesis of soluble and processable organic-capped anatase TiO2 nanorods,” J. Am. Chem. Soc. 125, 14539 (2003). [21] N. C. Greenham, X. Peng, A. P. Alivisatos, “Charge separation and transport in conjugated-polymer/semiconductor-nanocrystal composites studied by photoluminescence quenching and photoconductivity,” Phys. Rev. B 54, 17628 (1996). [22] S. A. Choulis, Y. Kim, J. Nelson, and D. D. C. Bradley M. Giles, M. Shkunov, I. McCulloch, “High ambipolar and balanced carrier mobility in regioregular poly(3-hexylthiophene),” Appl. Phys. Lett. 85, 3890 (2004). [23] R. J. Kline, M. D. McGehee, E. N. Kadnikova, J. Liu, J. M. J. Fréchet, M. F. Toney, “The dependence of regioregular poly(3-hexylthiophene) film morphology and field effect mobility on molecular weight,” Macromolecule 38, 3312 (2005) . [24] M.-C. Wu, C.-H. Chang, H.-H. Lo, Y.-S. Lin, Y.-Y. Lin, W.-C. Yen, W.-F. Su, Y.-F. Chen, C.-W. Chen, “Nanoscale morphology and performance of molecular-weight-dependent poly(3-hexylthiophene)/TiO2 nanorod hybrid solar cells,” J. Mater. Chem. 18, 4097 (2008). [25] C. Goh, S. R. Scully, M. D. McGehee, “Effects of molecular interface modification in hybrid organic-inorganic photovoltaic cells,” J. Appl. Phys. 101, 114503 (2007). [26] Y.-Y. Lin, T.-H. Chu, C.-W. Chen, W.-F. Su, “Improved performance of polymer/TiO2 nanorod bulk heterojunction photovoltaic devices by interface modification,” Appl. Phys. Lett., 92, 053312(2008). [27] J. Bouclé, P. Ravirajan, J. Nelson, “Hybrid polymer–metal oxide thin films for photovoltaic applications,” J. Mater. Chem. 30, 3141 (2007). [28] K. M. Coakley, Y. Liu, C. Goh, M. D. McGehee, “Ordered organic–inorganic bulk heterojunction photovoltaic cells,” MRS BULLETIN 30, 37 (2005). [29] W. U. Huynh, “Nanocrystal-polymer solar cells,” University of California, Berkeley (2002). [30] W. U. Huynh, J. J. Dittmer, A. P. Alivisatos, “Hybrid nanorod-polymer solar cells,” Science 29, 2425 (2002). [31] D. J. Milliron, I. Gur, A. P. Alivisatos, “Hybrid organic–nanocrystal solar cells,” MRS BULLENTIN 30, 41 (2005). Chapter 6 [1] W. Ma, C. Yang, X. Gong, K. Lee, A. J. Heeger, “Thermally stable, efficient polymer solar cells with nanoscale control of the interpenetrating network morphology,” Adv. Func. Mater. 15, 1617 (2005). [2] H. Hoppe, T. Glatzel, M. Niggemann, A. Hinsch, M. Ch. Lux-Steiner, and N. S. Sariciftci,“Kelvin probe force microscopy study on conjugated polymer/fullerence bulk heterojunction organic solar cells,” Nano Lett. 5, 269 (2005). [3] M. Chiesa, L. Bürgi, J.-S. Kim, R. Shikler, R. H. Friend, and H. Sirringhaus, “Correlation between surface photovoltage and blend morphology in polyfluorene-based photodiodes,” Nano Lett., 5, 559 (2005). [4] V. Palermo, G. Ridolfi, A. M. Talarico, L. Favaretto, G. Barbarella, N. Camaioni and P. Samorì, “Kelvin probe force microscopy study of the photogeneration of surface charges in all-thiophene photovoltaic blends,” Adv. Func. Mater. 17, 472 (2007). [5] A. Liscio, V. Palermo, D. Gentilini, F. Nolde, K. Müllen and P. Samorì, “Quantitative measurement of the local surface potential of π-conjugated nanostructures: A kelvin probe force microscopy study,” Adv. Func. Mater. 16, 1407 (2006). [6] V. Palermo, M. Palma and P. Samorì, “Electronic characterization of organic thin films by Kelvin probe force microscopy,” Adv. Mater. 18, 145 (2006). [7] B. Pérez-García, J. Abad, A. Urbina, J. Colchero and E. Palacios-Lidón, Nanotechnology, 19, 065709 (2008). [8] N. C. Greenham, X. Peng, A. P. Alivisatos, “Charge separation and transport in conjugated-polymer/semiconductor-nanocrystal composites studied by photoluminescence quenching and photoconductivity,” Phys. Rev. B 54, 17628 (1996). [9] W. U. Huynh, J. J. Dittmer, A. P. Alivisatos, “Hybrid nanorod-polymer solar cells,” Science 29, 2425 (2002). [10] B. Sun, H. J. Snaith, A. S. Dhoot, S. Westenhoff, and N. C. Greenham, “Vertically segregated hybrid blends for photovoltaic devices with improved efficiency,” J. Appl. Phys. 97, 014914 (2005). [11] B. Sun and N. C. Greenham, “Improved efficiency of photovoltaics based on CdSe nanorods and poly(3-hexylthiophene) nanofibers,” Phys. Chem. Chem. Phys., 8, 3557 (2006). [12] W. J. E. Beek, M. M. Wienk, M. Kemerink, X. Yang, R. A. J. Janssen, “Hybrid zinc oxide - conjugated polymer bulk heterojunction solar cells,” J. Phys. Chem. B 109, 9505 (2005). [13] T.-W. Zeng, Y.-Y. Lin, H.-H. Lo, C.-W. Chen, C.-H. Chen, S.-C. Liou, H.-Y. Huang, W.-F. Su, “A large interconnecting network within hybrid MEH-PPV/TiO2 nanorod photovoltaic devices,” Nanotechnology 17, 5387 (2006). [14] C. Yin, B. Pieper, B. Stiller, T. Kietzke, and D. Neher, “Charge carrier generation and electron blocking at interlayers in polymer solar cells, ” Appl. Phys. Lett. 90, 133502 (2007). [15] P. D. Cozzoli, A. Kornowski, H. Weller, “Low-temperature synthesis of soluble and processable organic-capped anatase TiO2 nanorods,” J. Am. Chem. Soc. 125, 14539 (2003). [16] Andrea Liscio, Giovanna De Luca, Fabian Nolde, Vincenzo Palermo, Klaus Müllen, and Paolo Samorì, “Photovoltaic Charge Generation Visualized at the Nanoscale: A Proof of Principle,” J. Am. Chem. Soc. 130, 780 (2008). Chapter 7 [1] W. Ma, C. Yang, X. Gong, K. Lee, A. J. Heeger, “Thermally stable, efficient polymer solar cells with nanoscale control of the interpenetrating network morphology,” Adv. Func. Mater. 15, 1617 (2005). [2] H. Hoppe, T. Glatzel, M. Niggemann, A. Hinsch, M. Ch. Lux-Steiner, and N. S. Sariciftci,“Kelvin probe force microscopy study on conjugated polymer/fullerence bulk heterojunction organic solar cells,” Nano Lett. 5, 269 (2005). [3] C. Goh, S. R. Scully, M. D. McGehee, “Effects of molecular interface modification in hybrid organic-inorganic photovoltaic cells,” J. Appl. Phys. 101, 114503 (2007). [4] L. J. A. Koster, V. D. Mihailetchi, P. W. M. Blom, “Ultimate efficiency of polymer/fullerene bulk heterojunction solar cells,” Appl. Phys. Lett. 88, 093511 (2006) Chapter 8 [1] J. Y. Kim, S. H. Kim, H.-H. Lee, K. Lee, W. Ma, X. Gong, A. J. Heeger, “New architecture for high-efficiency polymer photovoltaic cells using solution-based titanium oxide as an optical spacer,” Adv. Mater. 18, 572 (2006). [2] M. Thelakkat, C. Schmitz, H.-W. Schmidt, “Fully vapor-deposited thin-layer titanium dioxide solar cells,” Adv. Mater. 14, 577 (2002). [3] W. U. Huynh, “Nanocrystal-polymer solar cells,” University of California, Berkeley (2002). [4] W. Ma, C. Yang, X. Gong, K. Lee, A. J. Heeger, “Thermally stable, efficient polymer solar cells with nanoscale control of the interpenetrating network morphology,” Adv. Func. Mater. 15, 1617 (2005). [5] A. A. R. Watt, D. Blake, J. H. Warner, E. A. Thomsen, E. L. Tavenner, H. Rubinsztein-Dunlop, P. Meredith, “Lead sulfide nanocrystal: conducting polymer solar cells,” J. Phys. D: Appl. Phys. 38, 2006 (2005). [6] K. Petritsch, “Organic Solar Cell Architectures,” University of Cambridge (2000). | |
dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/41741 | - |
dc.description.abstract | 巨異質接面高分子太陽能電池由電子給體與受體的互穿網狀混合物構成,例如:共軛高分子混摻碳六十,共軛高分子混摻高分子,共軛高分子混摻無機奈米顆粒等等,已可以達到相當高的光電轉換效率。二氧化鈦奈米顆粒是一種環保材料,基於其優異物理與化學穩定性,具備高度潛力作為高分子太陽能電池的組成材料。二氧化鈦奈米顆粒可以在高分子太陽能電池中增加電荷分離,作為電子受體與電子傳導路徑。於文獻中,二氧化鈦奈米顆粒可應用於製作高分子太陽能電池已經被提出,共軛高分子混摻二氧化鈦奈米顆粒太陽能電池具備諸多優點。然而,共軛高分子混摻二氧化鈦奈米桿太陽能電池則尚未曾被製作並且評估效率。
本研究中,我們發掘將二氧化鈦奈米桿運用於共軛高分子混摻無機奈米顆粒太陽能電池的潛力。一維方向的奈米桿可以提供直線方向電荷傳導,因此適用於建構有效的電荷傳導網絡於巨異質接面高分子太陽能電池。 於第一部分研究中,巨異質接面光伏元件由聚〔2-甲氧基-5-(2'-乙基-己氧基)-1,4-苯乙烯〕與二氧化鈦奈米桿混摻材料製備。我們提出於元件中的光作用層與鋁電極之間插入一層二氧化鈦奈米桿。二氧化鈦奈米桿層可以作為電子傳導與電洞阻擋層,導致短路電流密度增為2.5倍。於565nm的單光照射下,能量轉換效率為2.2%,外部量子效率於430nm最大可以達到24%。於A.M. 1.5 模擬太陽光照下,轉換效率為0.5%。 於第二部分的研究,一種高電洞遷移率共軛高分子,聚(3-己烷噻吩),與二氧化鈦奈米桿被用於建構高效率巨異質接面高分子太陽能電池。混摻高電洞遷移率共軛高分子與二氧化鈦奈米桿具備形成有效率雙聯通的電子及電洞傳導相的潛力,以不同的元件製備條件進行嘗試以取得最佳化效率。對於巨異質接面影響電荷分離與電荷傳導的因素進行研究的結果指出,二氧化鈦奈米桿表面性質以及以旋轉塗佈製膜的溶劑都對於元件效率有很大的影響。 第三部分的研究中,凱文探針力顯微鏡被用以研討不同混摻比例聚(3-己烷噻吩)與二氧化鈦奈米桿高分子材料表面的奈米結構型態,高分子-奈米顆粒的聯通路徑,與光生電荷產生與分佈的狀態。我們並且探討聚(3,4-乙烯基二氧噻吩):聚(苯乙烯磺酸鹽)層與二氧化鈦奈米桿層在混摻聚(3-己烷噻吩)與二氧化鈦奈米桿高分子太陽能電池中的角色。直接的光生電荷轉移可以被量測到發生在奈米維度的聚(3-己烷噻吩)豐富區域及二氧化鈦奈米桿豐富區域之間。利用增加的聚(3,4-乙烯基二氧噻吩):聚(苯乙烯磺酸鹽)層或二氧化鈦奈米桿層,有效率的電子阻礙或收集作用亦被觀察到。聚(3-己烷噻吩)與二氧化鈦奈米桿混摻比例對於光生電荷的產生數目有決定性的影響。在混摻材料中具有高比例的二氧化鈦奈米桿可得到較細微的相分離與最多的光生電荷數。利用增加的聚(3,4-乙烯基二氧噻吩):聚(苯乙烯磺酸鹽)層與二氧化鈦奈米桿層,可以幫助電子較易於分佈於表面,有利於被鋁上電極收集。 | zh_TW |
dc.description.abstract | The bulk heterojunction polymer solar cells composed of a mixtures of electron donor-acceptor interpenetrating network, such as using the polymer:fullerene, polymer:polymer and polymer:nanocrystal have been achieved highly efficient photovoltaic conversion. TiO2 nanocrystal is an environmentally friendly material which possess great potential to be introduced into the in the polymer solar cells as a second component owing to its excellent physically and chemically stability. Usually, TiO2 serves as the electron acceptor after the charge separation at the hetero-interface and then conducts the electron in the polymer solar cells. The usage of the polymer- TiO2 isotropic nanocrystals blend in the polymer solar cells that has been proposed in the prior studies provides the advantages of ease of fabrication as well as good organic-inorganic interface. Also, prior studies on charge transfer in hybrid MEH-PPV:TiO2 nanorods suggest this material can be a promising material for photovoltaic conversion. However, the blended polymer:TiO2 nanorods photovoltaic device has not been fabricated and evaluated before.
In this work, we explore the potential of the usage of the titanium dioxide nanorods in the polymer:nanocrystal photovoltaic cells. The 1-dimensional nanorods are preferable due to the offering of direct path for charge conduction and therefore are suitable to be acting as a component for constructing an efficient charge transport network in the bulk heterojunction polymer solar cells that we proposed and fabricated. In the first part of this study, the bulk heterojunction devices made of MEH-PPV and titanium dioxide are fabricated. We propose to insert a thin layer of TiO2 nanorods between the photoactive material and the top Al electrode within the device. The TiO2 nanorods layer can serve as the electron-transporting-hole-blocking layer and leading to a 2.5 fold improvement in short circuit current density. The power conversion efficiency of 2.2 % under illumination at 565 nm and the maximum external quantum efficiency of 24 % at 430nm are achieved. A power conversion efficiency of ~0.5% is obtained under A.M. 1.5 illumination. A high mobility polymer, poly(3-hexylthiophene) (P3HT), in combination with TiO2 nanorods are used to construct highly efficient bulk heterojunction solar cells in the second part of this work. The blending of high mobility polymer and TiO2 nanorods offers the potential for formation efficient bi-continuous conduction phases for respective electron and hole transport. Various device fabrication parameters have been tested to obtain optimal efficiency. The factors that change the charge separation or charge transport within the bulk hetero-junction, such as the TiO2 surface ligand and the solvent for spin coating the active layer has shown to greatly affect the device efficiency. A power conversion efficiency of 0.83% has been achieved. In the third part, the Kelvin Probe Force Microscopy (KPFM) is applied to study the surface nano-structured morphology, the polymer-nanocrystal percolation paths as well as the light induced charge generation within the P3HT/TiO2 nanorod hybrid material in various D-A ratios which influence the interface area, conduction paths and film morphology. We also investigate the roles of PEDOT:PSS layer and TiO2 layer in a P3HT:TiO2 nanorods photovoltaic devices by KPFM. Directional photo-induced charge transfer in the nano-scale domains of P3HT rich and TiO2 nanorods rich regions and efficient electron blocking or collecting on the surface with additional layers are clearly seen. The blending ratios of P3HT with respective to TiO2 nanorods play an important role in determining the photo-induced charge generation. Finer scale of phase separation and highest numbers of charges are obtained within the film of high content TiO2 nanorods(72wt%). The inclusion of PEDOT:PSS and TiO2 nanorods layer in the device can facilitate the electron present on the surface to the Al electrode. | en |
dc.description.provenance | Made available in DSpace on 2021-06-15T00:29:36Z (GMT). No. of bitstreams: 1 ntu-98-D92527009-1.pdf: 3133570 bytes, checksum: 411237d7120ff6e41d7549496280d641 (MD5) Previous issue date: 2009 | en |
dc.description.tableofcontents | 摘要..........I
Abstract..........III Table of Contents..........VI List of Tables..........IX List of Figures..........X Chapter 1 Introduction..........1 1.1 Third Generation Solar Cell..........1 1.2 Dye-Sensitized Solar Cells..........2 1.3 Polymer Solar Cells..........3 1.4 Polymer Solar Cells Architectures..........5 1.4.1 Polymer Photovoltaic Cells Made from Single Layer or Bi-layer Structure..........5 1.4.2 Polymer: C60 Derivatives Bulk Heterojunciton Solar Cells..........6 1.4.3 Polymer-CdSe Nanocrystal Bulk Heterojunciton Photovoltaic Cell..........8 1.4.4 Polymer-Metal Oxide Hybrid Photovoltaic cells..........10 1.5 Loss Factors in Relation with the Various Photovoltaic Steps..........13 1.6 Concepts for Improvements of Bulk Heterojunction Photovoltaic Devices..........15 1.7 Prospects for Production Aspects of High-Efficiency Polymer Photovoltaic Cells..........17 1.8 Photovoltaic Characterization..........20 1.8.1 Power Conversion Efficiency..........20 1.8.2 External Quantum Efficiency..........21 1.9 Characterization of Photovoltaic Material Thin Films by Kelvin Probe Force Microscopy..........22 1.9.1 Introduction..........22 1.9.2 Kelvin Probe Force Microscopy Investigation on Organic Photovoltaic Materials..........26 1.10 References..........29 Chapter 2 Motivation and the Design of Conjugated Polymer:TiO2 Nanorods Photovoltaic Devices..........38 2.1 Motivation..........38 2.2 The Design of Polymer:TiO2 Nanorods Photovoltaic Device..........41 2.3 References..........42 Chapter 3 Materials in this Work..........46 3.1 Synthesis of the TiO2 Nanorods..........46 3.1.1 Fundamentals of TiO2 Nanorods Synthesis..........46 3.1.2 Preparation and Characterization of TiO2 Nanorods..........50 3.2 Inorganic nanocrystals..........54 3.2.1 Carrier Transport in Nanocrystals..........54 3.2.2 Charge Carrier Trapping..........54 3.2.3 Band Bending..........56 3.3 Organic Material in this Work..........58 3.3.1 Conjugated Polymers Properties..........58 3.3.2 Polymers –MEH-PPV and P3HT..........59 3.3.3 PEDOT:PSS..........61 3.4 References..........62 Chapter 4 A Large Interconnecting Network within Hybrid MEH-PPV/ TiO2 Nanorod Photovoltaic Devices..........64 4.1 Introduction..........64 4.2 Experimental details..........66 4.3 Results and discussion..........69 4.4 Conclusion..........81 4.5 References..........81 Chapter 5 Hybrid P3HT:TiO2 Nanorods Material for Photovoltaic Conversion..........87 5.1 Introduction..........87 5.2 Experimental details..........88 5.3 Results and discussion..........90 5.4 Conclusion..........101 5.5 References..........102 Chapter 6 Kelvin Probe Force Microscopy Study on Hybrid P3HT/Titanium Dioxide Nanorod Materials..........108 6.1 Introduction..........108 6.2 Experimental details..........111 6.3 Results and discussion..........111 6.4 Conclusion..........120 6.5 References..........120 Chapter 7 Recommendation..........124 7.1 TEM Images Investigations on the Nano-scale Control of the Morphology of the Donor-Acceptor Interpenetrating Networks..........124 7.2 Increase the Exciton Diffusion Length and Reduce Recombination..........124 7.3 Fine Tuning the LUMO and HOMO of the Materials..........125 7.4 Reference..........126 Chapter 8 Appendix..........128 8.1 TiO2 Nanorod Layer as an Optical Spacer..........128 8.2 Electric Properties of the Photovoltaic Cells..........131 8.2.1 Equivalent Circuit for a Photovoltaic Cell..........131 8.2.2 The Open Circuit Voltage deduced from Equivalent Circuit..........133 8.2.3 The Effect of Series Resistance, Shunt Resistance and Short Circuit Current Density on I-V Characteristics in a Photovoltaic Cell..........134 8.2.4 The Series Resistance and Shunt Resistance of our Photovoltaic Cells Extracted from the I-V Curves..........135 8.2.5 Electrodes and Transport for Photovoltaic Cells..........136 8.3 References..........137 Curriculum Vitae of Tsung-Wei Zeng..........139 | |
dc.language.iso | en | |
dc.title | 混摻導電高分子/二氧化鈦奈米桿太陽能電池 | zh_TW |
dc.title | Hybrid Solar Cells
Based on Conjugated Polymers and TiO2 Nanorods | en |
dc.type | Thesis | |
dc.date.schoolyear | 97-1 | |
dc.description.degree | 博士 | |
dc.contributor.oralexamcommittee | 陳俊維,林清富,戴子安,吳季珍,陳學禮 | |
dc.subject.keyword | 二氧化鈦,奈米桿,高分子,太陽能電池,光伏, | zh_TW |
dc.subject.keyword | titanium dioxide,nanorod,polymer,solar cell,photovoltaic, | en |
dc.relation.page | 142 | |
dc.rights.note | 有償授權 | |
dc.date.accepted | 2009-01-20 | |
dc.contributor.author-college | 工學院 | zh_TW |
dc.contributor.author-dept | 材料科學與工程學研究所 | zh_TW |
顯示於系所單位: | 材料科學與工程學系 |
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