請用此 Handle URI 來引用此文件:
http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/41414
完整後設資料紀錄
DC 欄位 | 值 | 語言 |
---|---|---|
dc.contributor.advisor | 陳文章 | |
dc.contributor.author | Chi-Ching Kuo | en |
dc.contributor.author | 郭霽慶 | zh_TW |
dc.date.accessioned | 2021-06-15T00:18:37Z | - |
dc.date.available | 2010-02-13 | |
dc.date.copyright | 2009-03-23 | |
dc.date.issued | 2009 | |
dc.date.submitted | 2009-03-12 | |
dc.identifier.citation | Chapter 1
References References 1 (a) D. Li and Y. Xia, Adv. Mater. 2005, 16, 1151. (b) T. Subbiah, G. S. Bhat, R. W. Tock, S. Parameswaran, S. S. Ramkumar, J. Appl. Polym. Sci. 2005, 96, 557. (c) K. M. Sawicka and P. Gouma, J. Nanopart. Res. 2006, 8, 769. (d) W. E. Teo and S. Ramakrishna, Nanotechnology 2006, 17, 89. (e)A. L. Yarin, E. Zussman, J. H. Wendorff and A. Greiner, J. Mater. Chem. 2007, 17, 2585. (f) I. S. Chronakis, J. Mater. Process. Tech. 2005, 167, 283. 2 A. Formalas, US patent 1975 5034, 1934. 3 G. I. Taylor, Proc Roy Soc London 1969, A313, 453. 4 J. M. Deitzel, J. Kleinmeyer, D. Harris and N.C.B. Tan, Polymer 2001, 42 261. 5 Y. M. Shin, M. M. Hohman, M. P. Brenner, G. C. Rutledge, Polymer 2001, 42, 9955. 6 (a) J. W. Strutt, Dublin Philos. Mag. 1882, 14, 184. (b) G. I. Taylor, J. Fluid Mech. 1965, 22, 1. (c) G. I. Taylor, Proc. R. Soc. Lond. Ser. A 1969, 313, 453. (d) C. D. Hendricks, AIAA J. 1964, 2, 733. (e) C. T. O’Konski and H. C. Thacher Jr, J. Phys. Chem. 1953, 57, 955. 7 (a) A. L. Yarin, S. Koombhongse, D. H. Reneker, I AppL Phys. 2001, 90, 4836. (b) I M. Shin, M. M. Hohman, M. P. Brenner, G C Rutledge, Polymer 2001, 42, 9955. (c) M. M. Hohman, M. Shin, G. C. Rutledge, M. P. Brenner, Phys. Fluidics 2001, 13, 2201. (d) M. M. Hohman, M. Shin, G. C Rutledge, M. P. Brenner, Phys. Fluidics 2001, 13, 2221. (e) S. V. Fridrikh, H. Yu, M. P. Brenner, G. C. Rutledge, Phys. Rev. Leff. 2003, 90, 144. 8 (a) D. H. Reneker and I. Chun, Nanotechnology 1996, 7, 216. (b) A. L. Yarin, S. Koombhongse, D. H. Reneker, J Appl Phys 2001, 89, 3018. (c) M. Cloupeau, B. Prunet-Foch, J of Electrostatics 1990, 25, 165. (d) J. M. Grace and J. C. Marijnissen, J of Aerosol Science 1994, 25, 1005. 9 (a) J. Doshi and D. H. Reneker, J Electrostatics 1995, 35, 151. (b) A. L. Yarin, S. Koombhongse, D. H. Reneker, J Appl Phys 2001, 89, 3018. (c) Y. M. Shin, M. M. Hohman, M. P. Brenner, G. C. Rutledge, Appl Phys Lett 2001, 78, 1149. (d) S. V. Fridrikh, J. H.Yu, M. P. Brenner, G. C. Rutledge, Physical Review Letters, 2003, 90, 144502. 10 (a) J. M. Deitzel, J. Kleinmeyer, Polymer 2001, 42, 261. (b) S. Megelski, J. S. Stephens, D. B. Chase, J. F. Rabolt, Macromolecules 2002, 35, 8456. (c) X. H. Zong, B. S. Hsiao, B. Chu, Polymer 2002, 43, 4403. 11 (a) M. Bognitzki, W. Czado, A. Greiner, H. Wendorff, Adv Mater 2001, 13, 70. (b) K. H. Lee, D. R. Lee, N. H. Sung, J Polym Sci: Part B: Polymer Physics 2002, 40, 2259. 12 C. J. Buchko, L. C. Chen, S. Yu, D. C. Martin, Polymer 1999, 40, 7397. 13 (a) Y. J. Ryu, H. I. Kim, K. H. Lee, H. C. Park, D. R. Lee, Eur Polym. J. 2003, 39, 1883. (b) Z. Chen, M. D. Foster, W. Zhou, H. Fong, D. H. Reneker, Macromolecules 2001, 34, 6156. (c) J. S. Stephens, D. B. Chase, J. F. Rabolt, Macromolecules 2004, 37, 877. (d) C. J. Buchko, L. C. Chen, S. Yu, D. C. Martin, Polymer 1999, 40, 7397. (e) K. J. Pawlowski, H. L. Belvin, D. L. Raney, I. S. Harrison, Polymer 2003, 44, 1309. 14 (a) K. W. Kim, K. H. Lee, M. S. Khil, Y. S. Ho, H. Y. Kim, Fiber Polym. 2004, 5, 122. (b) D. Li, Y. Wang, Y. Xia, Nano Lett. 2003, 3, 1167. (c) R. Inai, M. Kotaki, S. Ramakrishna, Nanotechnology 2005, 16, 208. (d) D. Li, Y. Wang, Y. Xia, Adv. Mater. 2004, 16, 361. (e) S. A. Theron, A. L. Yarin, E. Zussman, E, Kroll, Polymer 2005 46, 2889. (f) I. G. Loscertales, A. Barrero, M. Marquez, R. Spretz, G. Larsen, J. Am. Chem. Soc. 2004, 126, 5376. (g) G. Larsen, R. Spretz, R. Velarde-Ortiz, Adv. Mater. 2004, 16, 166. 15 (a) H. I. Jin, S. V. Fridrikh, G. C Rutledge, D. L. Kaplan, Biomacromolecules 2002, 3, 1233. (b) P. K. Kahol, N. I Pinto, Synth. Met. 2004, 140 ,269. (c) K. Kim, M. Yu, X. Zong, I. Chiu, D. Fang, Y.-S. Seo, B. S. Hsiao, B. Chu, M. Hadjiargyrou, Biomaterials 2003,24, 4977. 16 (a) W. Salalha, Y. Dror, R. Khalfin, Y. Cohen, A. Yarin, E. Zussman, CNs, Langmuir 2003, 19, 7012. (b) F. Ko, Y. Gogotsi, A. Ali, N. Naguib, H. Ye, G. Yang, C. Li, P. Willis, Adv. Mater. 2003, 15, 1161. (c) H. Ye, H. Lam, N. Titchenal, Y. Gogotsi, F. Ko, Appl. Phys. Lett. 2004, 85, 1775. 17 (a) M. Bognitzki, H. Hou, M. Ishaque, T. Frese, M. Hellwig, C. Schwarte, A. Shaper, J.H. Wendorff, A. Greiner, Adv. Mater. 2000, 12, 637. (b) C. Shao, H. Y. Kim, J. Gong, B. Ding, D. R. Lee, S. J. Park, Mater. Lett. 2003, 57, 1579. (c) G. Larsen, R. Velarde-Ortiz, K. Minchow, A. Barrero, I. G. Loscertales, J. Am. Chem. Soc. 2003, 125, 1154. (d) P. Viswanathamurthia, N. Bhattarai, H. Y. Kim, D.I. Cha, D. R. Lee, Mater. Lett. 2004, 58, 3368. (e) P. Viswanathamurthi, N. Bhattarai, H. Kim, D. Lee, S. Kim, M. Morris, Chem. Phys. Lett. 2003, 374, 79. 18 (a) V. Kalra, S. Mendez, J. H. Lee, Y. L. Joo, Adv. Mater. 2006, 18, 3299. (b) M. Ma, V. Krikorian, J. H. Yu, E. L. Thomas, G. C. Rutledge, Nano Letters 2006, 6, 2969. (c) M. Ma, R. M. Hill, J. L. Lowery, S. V. Fridrikh, G. C. Rutledge, Langmuir 2005, 21, 5549. (d)T. Ruotsalainen, J. Turku, A. Harlin, O. Ikkala, Adv. Mater. 2005, 17, 1048. 19 (a) E. Zussman, A. L. Yarin, A. V. Bazilevsky, R. Avrahami, M. Feldman, Adv. Mater., 2006, 18, 348. (B) D. Li, Y. Xia, Nano Lett. 2004, 4, 933. 20 (a) A. Theron, E. Zussman, A. L. Yarin, Nanotechnology 2001, 12, 384. (b)D. Li, Y. Wang, Y. Xia, Nano Letters 2003, 3, 1167. (c) D. Yang, B. Lu, Y. Zhao, X. Jiang, Adv. Mater. 2007, 19, 3702. 21 (a) H. Hou, D. H. Reneker, Adv. Mater. 2004, 16, 69. (b) M. Bashouti, W. Salalha, M. Brumer, E. Zussman, E. Lifshitz, Chemphyschem 2006, 7, 102. (c) M. Ma, M. Gupta, Z. Li, L. Zhai, K. K. Gleason, R. E. Cohen, M. F. Rubner, G. C. Rutledge, Adv. Mater. 2007, 19, 255. (d) G. M. Kim, R. Lach, G. H. Michler, Y. W. Chang, Macromol. Rapid Commun. 2005, 26, 728. 22 (a) M. M. Demir, M. A. Gulgun, M.G. Sulman, Macromolecules 2004, 37, 573. (b) X. Wang, C. Drew, S-H. Lee, K. I Senecal, I. Kumar, L. A. Samuelson, Nano Lett 2002, 2, 1273. (c) C. Kim, K. S. Yang, Appl. Phys. Lett. 2003, 83, 1216. (d) S. W. Choi, S. M. Jo, W. S. Lee, Y.-R. Kim, Adv. Mater. 2003, 15, 2027. (e)Y. Wang, J. J. Santigano-Aviles, J. Appl. Phys. 2003, 94, 1721. (f) Y. Zhou, M. Freitag, J. Hone, A. G. MacDiarmid, Appl. Phys. Lett. 2003, 83, 3800. 23 (a) W. J. Feast, J. Tsibouklis, K. L. Pouwer, L. Groenendaal, E. W. Meijer, Polymer 1996, 37, 5017. (b) R. D. McCullough, Adv. Mater. 1998, 10, 93. (c) M. Leclerc, K. Faïd, Adv. Mater. 1997, 9, 1087. 24 (a) J. H. Burroughes, D. D. C. Bradley, A. R. Brown, R. N Marks, K. Mackay, R. H. Friend, P. L. Burns, A. B. Holmes, Nature 1990, 347, 539. (b) Y. Yang, A. J. Heeger, Nature 1994, 372, 344. (c) G. Yu, J.Gao, J. C. Hummelen, F. Wudl., A. J. Heeger, Science 1995, 270, 1789. 25 H. A. M. van Mullekom, J. A. J. M. Vekemans, E. E. Havinga, E. W. Meijer, Mater Sci & Eng. 2001, 32, 1. 26 J. Roncali, Chem. Rev. 1997, 97, 173. 27 (a) A. J. Cadby, P. A. Lane, H. Mellor, S. J. Martin, M. Grell, Z. V. Vardeny, Phys. Rev. B 2000, 62, 15604. (b) M. Grell, D. D. C. Bradley, M. Soliman, Acta Polym. 1998, 49, 439.(c) S. Setayesh, A. C. Grimsdale,T. Weil, G. Leising, J. Am. Chem. Soc. 2001, 123, 946. 28 (a) M. Fukuda, K. Sawada, K.Yoshino, J. Polym. Sci. A: Polym. Chem. 1993, 31, 2465. (b) D. Neher, Macromol. Rapid Commun. 2001, 22, 1365. (c) A. W. Grice, D. D. C. Bradley, M. T. Bernius, M. Inbasekaran, W. W. Wu, E. P. Woo, Appl. Phys. Lett. 1998, 73, 629. 29 (a) J. I. Lee, G. Klaerner, R. D. Miller, Synth. Met. 1999, 101, 126. (b) G. Klaerner, R. D. Miller, Macromolecules 1998, 31, 2007.(c) V. N. Bliznyuk, S. A. Carter, J. C. Scott, G. Klaerner, D. C. Miller, Macromolecules 1999, 32, 361. 30 (a) N. Ananthakrishnan, G. Padmanaban, S. Ramarkrishnan, J. R. Reynolds, Macromolecules 2005, 38, 7660. (b) A. P. Kulkarni, S. A. Jenekhe, Macromolecules 2003 36, 5285. (c) H. P. Rathnayake, A. Cirpan, F. E. Karasz, Chem. Mater. 2006, 18, 560. (d)W. C. Wu, W. Y. Lee, C. L. Pai, W. C. Chen, C. S. Tuan, J. L. Lin, J. Polym. Sci. B:Polym. Phsics 2007, 45, 67. 31 (a) M. S. Lee, B. K. Cho, W. C. Zin, Chem. Rev. 2001, 101, 3869. (b) S. A. Jenekhe, X. L. Chen, Science 1998, 279, 1903. (c) S. A. Jenekhe, X. L. Chen, Science 1999, 283, 372-375. (d) X. L. Chen, S. A. Jenekhe, Langmuir 1999, 15, 8007. (e) U. Stalmach, B. Boer, C. Videlot, P. F. van Hutten, G. Hadziioannou, J. Am. Chem. Soc., 2000, 122, 5464. (f) J. Liu, E. Sheina, T. Kowalewski, R. D. McCullough, Angew. Chem., Int. Ed., 2002, 41, 329-332. (g) J. F. Hulvat, M. Sofos, K. Tajima, S. I. Stupp, J. Am. Chem. Soc., 2005, 127, 366. 32 (a) C. D. Dimitrakopolous, P. R. L. Malenfant, Adv. Mater. 2002, 14, 99. (b) D. Braun, Mater. Today 2002, 5, 32. (c). R. H. Friend, R. W. Gymer, A. B.Holmes, J. H. Burroughes, R.N.Marks, C. Taliani, D. D. C. Bradley, D. A. dos Santos, J. L.Bre´das, M. Lo¨glund, W. R.Salaneck, Nature 1999, 397, 121. (e) A. O. Patil, A. J. Heeger, F. Wudl, Chem. Rev. 1988, 88, 183. 33 (a) F. J. M. Hoeben, P. Jonkhijm, E. W. Meijer, A. P. H. J. Schenning, Chem. Rev. 2005, 105, 1491. (b) P. Lecle`re, E. Hennebicq, A. Calderone, P. Brocorens, A. C. Grimsdale, K. Mullen, J. L. Bre’das, R. Lazzaroni, Prog. Polym. Sci. 2003, 28, 55. (c) M.-S. Lee, B.-K. Cho, W.-C. Zin, Chem. Rev. 2001, 101, 3869. 34 (a) M. Surin, D. Marsitzky, A. C. Grimsdale, K. Mullen, R. Lazzaroni, P. Lecle`re, Adv. Funct. Mater. 2004, 14, 708. (b) S. Lu, T. Liu, L. Ke, D. G. Ma, S. J. Chua, W. Huang, Macromolecules 2005, 38, 8494. (c) C. L. Chochos, J. K. Kallitsis, P. E. Keivanidis, S. Baluschev, V. G. Gregoriou, J. Phys. Chem. B 2006, 110, 4657; (d) L. Rubatat, X. Kong, S. A. Jenekhe, J. Ruokolainen, M. Hojeij, R. Mezzenga, Macromolecules, 2008, 41, 1846. 35 (a) Y. C. Tung, W. C. Wu, W. C. Chen, Macromol. Rapid Commun. 2006, 27, 1838. (b) W. C. Wu, Y. Tian, C. Y. Chen, C. S. Lee, Y. J. Sheng, W. C. Chen, Alex K.-Y. Jen, Langmuir 2007, 23, 2805. (c) S. T. Lin, Y. C. Tung, W. C. Chen, J. Mater. Chem. 2008, 18, 3985. 36 B.D. Olsen, R.A. Segalman, Materials Science and Engineering, 2008, 63, 37 37 (a) A. G. MacDiarmid, W. E. Jr. Jones, M. Llaguno, Synth. Met. 2001, 119, 27. (b) H. Dong, V. Nyame, A. G. MacDiarmid, Jr. W. E. Jones, J. Polyms. Sci. Polym. Phys. 2004, 42, 3934. (c) M. Wei, J. Lee, B. Kang, J. Mead, Macromol. Rapid. Commun. 2005, 26, 1127. 38 (a) S. Madhugiri, A. Dalton, K. J. Jr. Balkus, J. Am. Chem. Soc. 2003, 125,14531. (b) X. Wang, Y. G. Kim, C. Drew, B. C. Ku, J. Kumar, L. A. Samuelson, Nano. Lett. 2004, 4, 331. (c) Y. Wang, J. S. Park, J. P. Leech, S. Miao, U. H. F. Bunz, Macromolecules 2007, 40, 1843. 39 (a) D. Li, A. Babel, S. A. Jenekhe, Y. Xia, Adv. Mater. 2004, 16, 2062. (b) A. Babel, D. Li, Y. Xia, S. A. Jenekhe, Macromolecules 2005, 38, 4705. (c) Y. Wang, J. S. Park, J. P. Leech, S. Miao, U. H. F. Bunz, Macromolecules 2007, 40, 1843. (d) G. Kwak, S. Fukap, M. Fujiki, T. Sakaguchi, T. Masuda, Chem. Mater. 2006, 18, 5537.(e) H. Liu, C. H. Reccius, H. G. Craighead, Appl. Phys. Lett. 2005, 87, 253016. (f) S. Y. Jang, V. Seshadri, M. S. Khil, A. Kumar, M. Marquez, P. T. Mather, G. A. Sotzing, Adv. Mater. 2005, 17, 2177. 40 (a) S. Y. Jang, V. Seshadri, M-S. Khil, A. Kumar, M. Marquez, P. Mather, G. A. Sotzing, Adv. Mater. 2005, 17, 2177. (b) X. Wang, C. Drew, S-H. Lee, K. Senecal, J. Kumar, L. A. Samuelson, Nano Lett. 2002, 2, 1273. (c) X. Wang, Y. G. Kim, C. Drew, J. Ku, J. Kumar, L. A. Samuelson, Nano Lett. 2004, 4, 331. (d) L. Wang, P. D. Topham, O. O. Mykhaylyk, J. R. Howse, W. Bras, R. A. J. Jones, A. J. Ryan, Adv. Mater. 2007, 19, 3544. (e) J. Yoon, S. K. Chae, J-M. Kim, J. Am. Chem. Soc. 2007, 129, 3038. Chapter 2 Reference 1 See Special Issue on Organic Electronics: Chem. Mater. 2004, 16, 4381-4846. 2 (a) J. H. Burroughes, D. D. C. Bradley, A. R. Brown, R. N. Marks, K. Mackay, R. H. Friend, P. L. Burns, A. B. Holmes, Nature 1990, 347, 539; (b) A. Kraft, A. C. Grimsdale, A. B. Holmes, Angew. Chem. Int. Ed. 1998, 37, 402 . 3 (a) L. L. Chua, J. Zaumseil, J. F. Chang, E. C. W. Ou, P. K.-H.Ho, R. H. Friend, Nature 2005, 434, 194. (c) M. M. Lin, Z. Bao, Chem. Mater. 2004, 16, 4824. 4 (a) G. Yu, J. Gao, J. C. Hummelen, F. Wudl, A. J. Heeger, Science 1995, 270, 1789; (b) M. C. Scharber, A. J. Heeger, C. J. Brabec, Adv. Mater. 2006, 18, 789. (c) G. Li, V. S hrotriya, J. Huang, T. K. Emery, Y. Yang, Nature Mater. 2005, 4, 864. 5 (a) M. Grell, D. D. C. Bradley, M. Inbasekaran, E. P. Woo, Adv. Mater. 1997, 9, 798. (b) D. Neher, Macromol. Rapid Commun. 2001, 22, 1365. (c) U. Schref, E. J. W. List, Adv. Mater. 2002, 14, 477 6 (a) Q. Peng, J. B. Peng, E. T. Kang, K. G. Neoh, Y. Cao, Macromolecules 2005, 38, 7292; (b) W. J. Lin, W. C. Chen, W. C. Wu, Y. H. Niu, A. K. Y. Jen, Macromolecules 2004, 37, 2335 (c) W. C. Wu, W. Y. Lee, W. C. Chen, Macromol. Chem. Phys. 2006, 207, 1131. (d) W. C. Wu, C. L. Liu, W. C. Chen, Polymer 2006, 47, 527. (e) C. Y. Chuang, P. I. Shih; C. H. Chieh, F. I. Wu, C. F. Shu, Macromolecules 2007, 40, 247. 7 (a) A. P. Kulkarni, S. A. Jenekhe, Macromolecules 2003, 36, 5285; (b) N. A. Iyengar, B. Harrison, R. S. Duran, K. S. Schanze, J. R. Reynolds, Macromolecules 2003, 36, 8978; (c) N. Ananthakrishnan, G. Padmanaban, J. R. Reynolds, Macromolecules 2005, 38, 7600; (d) H.. P. Rathnayake, A. Cirpan, P. M. Lahti, F. E. Karasz, Chem. Mater. 2006, 18, 560. 8 (a) D. Li, Y. Xia, Adv. Mater. 2004, 16, 1151. (b) D. H. Reneker, I. Chun, Nanotechnology 1996, 7, 216. (c) Z. M. Huang, Y. Z. Zhang, M. Kotaki, S. Ramakrishna, Compos. Sci. Technol. 2003, 63, 2223. (d) R. Dersch, M. Steinhart, U. Boudriot, J. H. Wendorff, Polym. Adv. Technol. 2005, 16, 276. 9 (a) S. V. Fridrikh, J. H. Yu, M. P. Brenner, G. C. Rutledge, Phys. Rev. Lett. 2003, 90, 144502-1. (b) C. Wang, C. H. Hsu, J. H. Lin, Macromolecules 2006, 39, 7662. (c) V. Kalra, P. A. Kakad, S. Mendez, T. Ivannikov, M. Kamperman, Y. L. Joo, Macromolecules 2006, 39, 5453. (d) M. Ma, V. Krikorian, J. H. Yu, E. L. Thomas, G. C. Rutledge, Nano. Lett. 2006, 6, 2969. (e) A. V. Bazilevsky, A. L. Yarin, C. M. Megaridis, Langmuir 2007, 23, 2311. (f) J. S. Choi, S. W. Lee, L. Leong, S. H. Bae, B. C. Min, J. H. Youk, W. H. Park, Int. J. Bio. Macromol. 2004, 34, 249. 10 (a) A. G. MacDiarmid, W. E. Jones, M. Synth. Met. 2001, 119, 27. (b) H. Dong, V. Nyame, A. G.. MacDiarmid,. J. Polyms. Sci. Polym. Phys. 2004, 42, 3934. (c) M. Wei, J. Lee, B. Kang, J. Mead, Macromol. Rapid. Commun. 2005, 26, 1127. (d) S. Y. Jang, V. Seshadri, M. S. Khil, A. Kumar, M. Marquez, P. T. Mather, G. A. Sotzing, Adv. Mater. 2005, 17, 2177. 11 (a) S. Madhugiri, A. Dalton, K. J. Jr. Balkus, J. Am. Chem. Soc. 2003, 125,14531. (b) X. Wang, Y. G. Kim,. L. A. Samuelson, Nano. Lett. 2004, 4, 331. (c) P. Supaphol, T. Srikhirin, T. Kerdcharoen, T. Osotchan, J. Polym. Sci. Polym. Phys. 2005, 43, 1881. (d) Y. Xin, Z. H. Huang, E. Y. Yan, W. Zhang, Q. Zhao, Appl. Phys. Lett. 2006, 89, 053101. (e) G. Kwak, S. Fukao, M. Fujiki, T. Sakaguchi, T. Masuda, Chem. Mater. 2006, 18, 5537. (f) Y. Wang, J. S. Park, J. P. Leech, S. Miao, U. H. F. Bunz, Macromolecules 2007, 40, 1843. 12 (a) D. Li, A. Babel, S. A. Jenekhe, Y. Xia, Adv. Mater. 2004, 16, 2062. (b) A. Babel, D. Li, Y. Xia, S. A. Jenekhe, Macromolecules 2005, 38, 4705. (c) H. Okuzaki, T. Takahaski, N. miyajima, Y. Suzuki, T. Kuwabara, Macromlecules 2006, 39, 4276. 13 A. Pedicine, R. J. Farris Polymer 2003, 44, 6857. 14 J. W. Y. Lam, B. Z. Tang, Acc. Chem. Res. 2005, 38, 745. 15 S. A. Jenekhe, J. A. Osaheni, Science 1994, 265, 765. Chapter 3 References 1 D. Neher, Macromol. Rapid Commun. 2001, 22, 1365. 2 U. Schref, E. J. W. List, Adv. Mater. 2002, 14, 477. 3 Q. Peng, J. B. Peng, E. T. Kang, K. G. Neoh, Y. Cao, Macromolecules 2005, 38, 7292. 4 W. J. Lin, W. C. Chen, W. C. Wu, Y. H. Niu, A. K. Y. Jen, Macromolecules 2004, 37, 2335. 5 W. C. Wu, W. Y. Lee, W. C. Chen, Macromol. Chem. Phys. 2006, 207, 1131. 6 W. C. Wu, C. L. Liu, W. C. Chen, Polymer 2006, 47, 527. 7 A. P. Kulkarni, S. A. Jenekhe, Macromolecules 2003, 36, 5285. 8 D. O’Carroll, I. Lieberwirth, G. Redmond, Nature Nanotechnol. 2007, 2, 180. 9 D. H. Reneker, I. Chun, Nanotechnology 1996, 7, 216. 10 M. Ma, V. Krikorian, J. H. Yu, E. L. Thomas, G. C. Rutledge, Nano Lett. 2006, 6, 2969. 11 J. E. Diaz, A. Barrero, M. Marquez, I. G. Loscertales, Adv. Funct. Mater. 2006, 16, 2110. 12 X. Y. Sun, R. Shankar, H. G. Borner, T. K. Ghosh, R. J. Spontak, Adv. Mater. 2007, 19, 87. 13 C. Wang, E. Y. Yan, Z. Y. Sun, Z. J. Jiang, Y. B. Tong, Y. Xin, Z. H. Huang, Macromol. Mater. Eng. 2007, 292, 949. 14 D. Li, Y. Xia, Nano Lett. 2004, 4, 933. 15 T. Ruotsalainen, J. Turku, P. Hiekkataipale, U. Vainio, R. Serimaa, G. T. Brinke, A. Harlin, J. Ruokolainen, O. Ikkala, Soft Matt. 2007, 3, 978. 16 Y. Zhu, J. Zhang, Y. Zheng, Z. Huang, L. Feng, L. Jiang, Adv. Funct. Mater. 2006, 16, 568. 17 S. Madhugiri, A. Dalton, K. J. Jr. Balkus, J. Am. Chem. Soc. 2003, 125, 14531. 18 Y. Wang, J. S. Park, J. P. Leech, S. Miao, U. H. F. Bunz, Macromolecules 2007, 40, 1843. 19 D. Li, A. Babel, S. A. Jenekhe, Y. Xia, Adv. Mater. 2004, 16, 2062. 20 A. Babel, D. Li, Y. Xia, S. A. Jenekhe, Macromolecules 2005, 38, 4705. 21 C. C. Kuo, C. H. Lin, W. C. Chen, Macromolecules 2007, 40, 6959. 22 Y. Huang, X. Duan, Q. Wei, C. M. Lieber, Science 2001, 291, 630. 23 F. Kim, S. Kwan, J. Akana, P. Yang, J. Am. Chem. Soc. 2001, 123, 4360. 24 N. A. Melosh, A. Boukai, F. Diana, B. Gerardot, A. Badolato, P. M. Petroff, J. R. Heath, Science 2003, 300, 112. 25 J. Kameoka, R. Orth, Y. N. Yang, D. Czaplewski, R. Mathers, G. W. Coates, H. G. Craighead, Nanotechnology 2003, 14, 1124. 26 J. Doshi, D. H. Reneker, J. Electrost. 1995, 35, 151. 27 A. Theron, E. Zussman, A. L. Yarin, Nanotechnology 2001, 12, 384. 28 D. Li, Y. Wang, Y. Xia, Nano Lett. 2003, 3, 1167. 29 D. Li, Y. Wang, Y. Xia, Adv. Mater. 2004, 16, 361. 30 M. V. Kakade, S. Givens, K. Gardner, K. H. Lee, D. B. Chase, F. J. Rabolt, J. Am. Chem. Soc. 2007, 129, 2777. 31 R. Dersch, T. Liu, A. K. Schaper, A. Greiner, J. H. Wendorff, J Polym Sci Part A: Polym Chem 2003, 41, 545. 32 D. Li, G. Ouyang, J. T. McCann, Y. Xia, Nano Lett. 2005, 5, 913. 33 Y. Xin, Z. Huang, J. Chen, C. Wang, Y. Tong, S. Liu, Materials Letters 2008, 62, 991. 34 Y. Ishii, H. Sakai, H. Murata, Materials Letters 2008, 62, 3370. 35 M. Campoy-Quiles, Ishii, H. Sakai, H. Murata, Appl. Phys. Lett. 2008, 92, 213305. 36 A. Pedicine, R. J. Arris, Polymer 2003, 44, 6857. 37 D. Li, Y. Xia, Adv. Mater. 2004, 16, 1151. 38 G. Kwak, S. Fukao, M. Fujiki, T. Sakaguchi, T. Masuda, Chem. Mater. 2006, 18, 5537. 39 J. W. Y. Lam, B. Z. Tang, Acc. Chem. Res. 2005, 38, 745. 40 C. C. Yang, Y. Tian, A. K. Y. Jen, W. C. Chen, J. Polym. Sci. Part A: Polym. Chem. 2006, 44, 5495. 41 M. Wei, B. Kang, C. Sung, J. Mead, Macromolecular Mater. Eng. 2006, 291, 1307 42 S. Megelski, J. S. Stephens, D. B. Chase, J. F. Rabolt, Macromolecules 2002, 35, 8456. 43 S. K. Chae, H. Park, J. Yoon, C. H. Lee, D. J. Ahn, J-M. Kim, Adv. Mater. 2007, 19, 521. 44 A. P. Kulkarni, S. A. Jenekhe, Macromolecules 2003, 36, 5285. 45 S. A. Jenekhe, J. A. Osaheni, Science 1994, 265, 765. 46 T-Q. Nguyen, J. Wu, V. Doan, B. J. Schwartz, S. H. Tolbert, Science 2000, 288, 652. 47 S-Y. Jang, V. Seshadri, M-S. Khil, A. Kumar, M. Marquez, P. Mather, G. A. Sotzing, Adv. Mater. 2005, 17, 2177. 48 X. Wang, C. Drew, S-H. Lee, K. Senecal, J. Kumar, L. A. Samuelson, Nano Lett. 2002, 2, 1273. 49 X. Wang, Y. G. Kim, C. Drew, J. Ku, J. Kumar, L. A. Samuelson, Nano Lett. 2004, 4, 331. 50 L. Wang, P. D. Topham, O. O. Mykhaylyk, J. R. Howse, W. Bras, R. A. J. Jones, A. J. Ryan, Adv. Mater. 2007, 19, 3544. 51 J. Yoon, S. K. Chae, J-M. Kim, J. Am. Chem. Soc. 2007, 129, 3038. Chapter 4 References 1 (a) F. J. M. Hoeben, P. Jonkhijm, E. W. Meijer, A. P. H. J. Schenning, Chem. Rev. 2005, 105, 1491; (b) P. Lecle`re, E. Hennebicq, A. Calderone, P. Brocorens, A. C. Grimsdale, K. Mullen, J. L. Bre’das, R. Lazzaroni, Prog. Polym. Sci. 2003, 28, 55. 2 (a) M.-S. Lee, B.-K. Cho, W.-C. Zin, Chem. Rev. 2001, 101, 3869; (b) S. A. Jenekhe, X. L. Chen, Science 1998, 279, 1903; (c) J. F. Hulvat, M. Sofos, K. Tajima, S. I. Stupp, J. Am. Chem. Soc. 2005, 127, 366. 3 (a) M. Surin, D. Marsitzky, A. C. Grimsdale, K. Mullen, R. Lazzaroni, P. Lecle`re, Adv. Funct. Mater. 2004, 14, 708; (b) S. Lu, T. Liu, L. Ke, D. G. Ma, S. J. Chua, W. Huang, Macromolecules 2005, 38, 8494; (c) C. L. Chochos, J. K. Kallitsis, P. E. Keivanidis, S. Baluschev, V. G. Gregoriou, J. Phys. Chem. B 2006, 110, 4657; (d) L. Rubatat, X. Kong, S. A. Jenekhe, J. Ruokolainen, M. Hojeij, R. Mezzenga, Macromolecules, 2008, 41, 1846. (e) X. Xiao, Y. Q. Fu, J. J. Zhou, Z. S. Bo, L. Li, C. M. Chan, Macromol. Rapid Commun. 2007, 28, 1003. 4 (a) Y. C. Tung, W. C. Wu, W. C. Chen, Macromol. Rapid Commun. 2006, 27, 1838; (b) W. C. Wu, Y. Tian, C. Y. Chen, C. S. Lee, Y. J. Sheng, W. C. Chen, Alex K.-Y. Jen, Langmuir 2007, 23, 2805; (c) S. T. Lin, Y. C. Tung, W. C. Chen, J. Mater. Chem. 2008, 18, 3985; (d) C. S. Li, W. C. Wu, Y. J. Sheng, W. C. Chen, J. Chem. Phys. 2008, 128, 154908. 5 (a) D. H. Reneker, I. Chun, Nanotechnology 1996, 7, 216. (b) D. Li, Y. Xia, Adv. Mater. 2004, 16, 1151. (c) C. Burger, B. S. Hsiao, B. Chu, Annu. Rev. Mater. Res. 2006, 36, 333. 6 (a) G. Kwak, G. H. Lee, S. H. Shim, K. B. Yoon, Macromol. Rapid Commun. 2008, 29, 815. (b) S. K. Chae, H. Park, J. Yoon, C. H. Lee, D. J. Ahn, J-M. Kim, Adv. Mater. 2007, 19, 521. 7 (a) S. Madhugiri, A. Dalton, K. J. Jr. Balkus, J. Am. Chem. Soc. 2003, 125, 14531. (b) A. Babel, D. Li, Y. Xia, S. A. Jenekhe, Macromolecules 2005, 38, 4705. (c) H. Dong, V. Nyame, A. G. Macdiarmid, W. E. Jones, J Polym. Sci. Part B: Polym. Phys. 2004, 42, 3934. (d) G. Kwak, S. Fukao, M. Fujiki, T. Sakaguchi, T. Masuda, Chem. Mater. 2006, 18, 5537. 8 (a) Y. Wang, J. S. Park, J. P. Leech, S. Miao, U. H. F. Bunz, Macromolecules 2007, 40, 1843. (b) C. C. Kuo, C. H. Lin, W. C. Chen, Macromolecules 2007, 40, 6959. (c) S. Chuangchote , T. Srikhirin , P. Supaphol, Macromol. Rapid Commun. 2007, 28, 651. 9 (a) M. Ma, V. Krikorian, J. H. Yu, E. L. Thomas, G. C. Rutledge, Nano Lett. 2005, 21, 5549. (b) V. Kalra, P. A. Kakad, S. Mendez, T. Ivannikov, M. Kamperman, Y. L. Joo, Macromolecules 2006, 39, 5453. 10 T. Ruotsalainen, J. Turku, P. Hiekkataipale, U. Vainio, R. Serimaa, G. T. Brinke, A. Harlin, J. Ruokolainen, O. Ikkala, Soft Matt. 2007, 3, 978. 11 D. T. McQuade, A. E. Pullen, T. M. Swager, Chem. Rev. 2000, 5, 123. 12 X. H. Zhou, J. C. Yan, J. Pei, Macromolecules. 2004, 37, 7078 13 D. L. Wang, X. Gong, P. S. Heeger, F. Rininsland, G. C. Bazan, A. J. Heeger, Proc. Natl. Acad. Sci. USA 2002, 99, 49 14 F. Le Floch, H. A. Ho, P. Harding-Lepage, M. Bedard, R. Neagu-Plesu, M. Leclerc, Adv. Mater. 2005, 17, 1251 15 J. S. Yang, T. M. Swager, J. Am. Chem. Soc. 1998, 120, 11864 16 L. H. Chen, D. W. Mcbranch, H. L. Wang, R. Helgeson, F. Wudl, D. G. Whitten, Proc. Natl. Acad. Sci. U.S.A. 1999, 96, 12287 17 C. Fan, K. W. Plaxco, A. J. Heeger, J. Am. Chem. Soc. 2002, 124, 5642 18 C. C. Kuo, C. H. Lin, W. C. Chen, Macromolecules 2007, 40, 6959 19 D. H. Reneker, I. Chun, Nanotechnology 1996, 7, 215 20 M. Lee, B. K. Cho, W. C. Zin Chem. Rev. 2001, 101, 3869 21 F. J. M. Hoeben, P. Jonkhijm, E. W. Meijer, A. P. H. J. Schenning, Chem. Rev. 2005, 105, 1491 22 S. A. Jenekhe, X. Zhang, X. L. Chen, V.E. Choong, Y. Gao, B. R. Hsieh, Chem. Mater. 1997, 9, 409 23 X. Zhang, A. S. Shetty, S. A. Jenekhe, Acta Polym. 1998, 49, 52 24 S. A. Jenekhe, X. L. Chen, Science, 1998, 279, 1903 25 S. A. Jenekhe, X. L. Chen, Science, 1999, 283, 372 26 L. Lu, and S. A. Jenekhe, Macromolecules 2001, 34, 6249 27 C. C. Kuo, C. T. Wang, W. C. Chen, Macromol. Mater. Eng. 2008, 293, 999. 28 C. C. Kuo, Y. C. Tung, C. H. Lin, W. C. Chen, Macromol.Rapid. Commun. 2008, 29, 1711 29 P. D. Sybert, W. H. Beever, J. K. Stille. Macromolecules 1981, 14, 493 30 S. A. Jenekhe, J. A. Osaheni, Science 1994, 265, 765 31 G. Kwak, S. Fukao, M. Fujiki, T. Sakaguchi, T. Masuda, Chem. Mater. 2006, 18, 5537 32 S. Megelski, J. S. Stephens, D. B. Chase, J. F. Rabolt, Macromolecules 2002, 35, 8456 33 J. Cornil, D. Beljonne, J. P. Calbert, J. L. Bredas, Adv. Mater. 2001, 13, 1053 34 S. Y. Jang, V. Seshadri, M. S. Khil, A. Kumar, M. Marquez, P. Mather, G. A. Sotzing, Adv. Mater. 2005, 17, 2177. 35 X. Wang, C. Drew, S-H. Lee, K. Senecal, J. Kumar, L. A. Samuelson, Nano Lett. 2002, 2, 1273. 36 X. Wang, Y. G. Kim, C. Drew, J. Ku, J. Kumar, L. A. Samuelson, Nano Lett. 2004, 4, 331. 37 L. Wang, P. D. Topham, O. O. Mykhaylyk, J. R. Howse, W. Bras, R. A. J. Jones, A. J. Ryan, Adv. Mater. 2007, 19, 3544. 38 J. Yoon, S. K. Chae, J. M. Kim, J. Am. Chem. Soc. 2007, 129, 30 Chapter 5 References 1 R. D. McCullough, Adv. Mater. 1998, 10, 93. 2 I. F. Perepichka, D. F. Perepichka, H. Meng, F. Wudl, Adv. Mater. 2005, 17, 2281. 3 G. Li, V. Shrotriya, J. Huang, Y. Yao, T. Moriarty, K. Emery, Y. Yang,. Nature Mater. 2005, 4, 864. 4 J. Liu, T. Tanaka, K. Sivula, A. P. Alivisatos, J. M. J. Frechet, J. Am. Chem. Soc. 2004, 126, 6550. 5 B. Li, G. Sauve, M. C. Iovu, D. N. Lambeth, Nano. Lett. 2006, 6, 1598. 6 H. Liu, C. H. Reccius, H. G. Craighead, Appl. Phys. Lett. 2005, 87, 253106. 7 D. Li, A. Babel, S. A. Jenekhe, Y. Xia, Adv. Mater. 2004, 16, 2062. 8 A. Babel, D. Li, Y. Xia, S. A. Jenekhe, Macromolecules 2005, 38, 4705. 9 D. H. Reneker, I. Chun, Nanotechnology 1996, 7, 216. 10 D. Li, Y. Xia, Adv. Mater. 2004, 16, 1151. 11 G. Kwak, G. H. Lee, S. H. Shim, K. B. Yoon, Macromol. Rapid Commun. 2008, 29, 815. 12 Y. Wang, J. S. Park, J. P. Leech, S. Miao, U. H. F. Bunz, Macromolecules 2007, 40, 1843. 11. 13 S. Madhugiri, A. Dalton, K. J. Jr. Balkus, J. Am. Chem. Soc. 2003, 125,14531. 14 H. Okuzaki, T. Takahaski, N. miyajima, Y. Suzuki, T. Kuwabara, Macromlecules 2006, 39, 4276. 15 M. Campoy-Quiles, Ishii, H. Sakai, H. Murata, Appl. Phys. Lett. 2008, 92, 213305. 16 C. C. Kuo, Y. C. Tung, C. H. Lin, W. C. Chen, Macromol. Rapid Commun. 2008, 29, 1711. 17 C. C. Kuo, C. H. Lin, W. C. Chen, Macromolecules 2007, 40, 6959. 18 A. G. MacDiarmid, W. E. Jones, M. Llaguno, Synth. Met. 2001, 119, 27. 19 H. Dong, V. Nyame, A. G.. MacDiarmid, W. E. Jones, J. Polyms. Sci. Polym. Phys. 2004, 42, 3934. 20 D. Li, Y. Xia, Nano. Lett. 2004, 4, 933. 21 J. H. Yu, S. V. Fridrikh, G. C. Rutledge, Adv. Mater. 2001, 13, 1053. 22 J. Yoon, S. K. Chae, J-M. Kim, J. Am. Chem. Soc. 2007, 129, 3038. 23 X. Wang, Y. G. Kim, C. Drew, J. Ku, J. Kumar, L. A. Samuelson, Nano Lett. 2004, 4, 331. 24 L. Wang, P. D. Topham, O. O. Mykhaylyk, J. R. Howse, W. Bras, R. A. J. Jones, A. J. Ryan, Adv. Mater. 2007, 19, 3544. 25 D. H. Kim, Y. Jang, Y. D. Park, K. Cho, j. Phys. Chem. B 2006, 110, 15763. 26 M. S. A. Abdou, S. Holdcroft, Macromolecules 1993, 26, 2954. 27 M. S. A. Abdou, F. P. Orfino, Y. Son, S. Holdcroft, J. Am. Chem. Soc. 1997, 119, 4518. | |
dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/41414 | - |
dc.description.abstract | 靜電紡絲是一種能夠將高分子材料製備成多功能性奈米纖維的新穎技術,所以近年來已廣泛地被探討。共軛高分子具有良好之導電及光電效率,可廣泛應用於光電元件上。其共軛高分子的光物理特性,可以藉由高分子混摻亦或是不同的合成方法來調控,以增強在元件應用上的特性,然而,目前的研究多是以共軛高分子薄膜的形態為主,較少探討共軛高分子奈米纖維的形態與光物理特性,主要的原因是對於靜電紡絲製程,共軛高分子有較低分子量與溶劑選擇的限制。因此,本論文的研究目標為設計靜電紡絲製程並操控其製程條件,製備出不同樣式的新穎共軛高分子靜電紡絲纖維(包含不織布、定向性或是核殼纖維的型態),研究其形態與光物理特性,並探討其在感測元件織物上的可能應用,舉凡pH值之酸靈敏感應、偏極光特性、DNA感測、環境檢測。上述的各項特性也與薄膜型態進行比較。
本文的第一個部分(第二章),我們利用單軸靜電紡絲系統,成功製備出以共軛性茀系衍生物之高分子(PFO, PFQ, PFBT, PFTP)混合非共軛高分子(聚甲基丙烯酸甲酯, PMMA)之靜電紡絲纖維。由SEM的結果顯示,PFO/PMMA可發光性之奈米纖維的纖維直徑為250-750nm。而由TEM的測試結果發現,共軛高分子PFO在PFO/PMMA纖維內是以類似纖維狀存在,隨著PFO在整體成份的比例提高,聚集尺度漸增,並且形成一個特殊的核殼結構(core-shell/ PFO-PMMA structure),我們推測這主要是因為相較於PMMA,PFO在氯仿中的溶解度較差,導致其會較快固化於整體纖維的中央。從共軛聚焦顯微鏡的觀察中,我們發現PFO在纖維內的聚集尺度遠小於PFO在薄膜型態的聚集尺度,故相較於薄膜,經由静電紡絲製程能夠降低共軛高分子的聚集,使得發光顏色較為藍移,並且有較高的發光量子效率。藉由混合入不同的茀-受體交替共聚高分子於PMMA中,我們可以製備出不同發光的奈米纖維,獨特的發光奈米纖維如PFO/PMMA, PFQ/PMMA, PFBT/PMMA, PFTP/PMMA,其最大放光波長/顏色分別如下: (443nm/藍色)、(483nm/綠色)、(539nm/黃色)、(628nm/紅色)。此部分的研究證實,我們利用共軛性茀系衍生物之高分子混合非共軛高分子,以靜電紡絲技術製備而得的靜電紡絲纖維,可以得到全光色之特殊的發光奈米纖維。 本文的第二個部份(第三章),我們利用單軸靜電紡絲系統再搭配自製的收集器,將共軛性茀系衍生物之高分子(PFO與PF+)分別與非共軛性高分子(聚甲基丙烯酸甲酯, PMMA)混合後,製備出具備高度定向的共軛高分子混合之靜電紡絲纖維。利用SEM觀察可發現不同收集器的中空寬度會影響纖維的定向程度,其中以寬度在0.5-1.5公分者為最佳,且其纖維具備高度定向性,而纖維直徑細度是250-500nm,纖維表面平滑不具備孔洞。利用TEM觀察出PFO的微相分離形態在纖維裡頭是平行整根纖維,而PF+則是呈現週期性的延纖維方向進行聚集。相較於不織布或是薄膜形式,這樣子的定向性纖維具備高達4倍的偏極光效果。除此之外,在PF+與PMMA混合的奈米纖維,由於比薄膜具備較高的比表面積,因此能夠有更靈敏的DNA質體感測效果。因此,此章節所研究製備的定向性纖維具備有偏極光以及感測質體DNA的特性,在光電元件與感測應用上具備潛力。 本文的第三個部份(第四章),分別將兩種團鏈共聚合高分子(rod-coil diblock copolymer): PF-b-PMMA或是PPQ-b-PS,利用單軸靜電紡絲系統,成功製備出新穎的共軛高分子之靜電紡絲纖維,並利用溶劑選擇效應,探討共聚合物高分子在纖維中的形態與光物理性質特性的不同。首先,我們將PF-b-PMMA共聚合物高分子,分別從三種不同THF/DMF混合的溶劑系統中製備成奈米纖維,從實驗的結果中發現,不同的溶劑系統會使得在纖維內的PF團鏈聚集的形態與尺度發生轉變,在THF中會形成尺度在5-10nm的點狀(dot-like),於THF/DMF (50/50)則是以尺度在10-20nm的線狀(line-like)存在,而在DMF中則是尺度在25-50nm的橢圓形狀(ellipse-like),隨著DMF在混合溶劑系統中的比例增加,不但使得纖維的直徑細度降低,並且由於DMF是PF團鏈的不佳溶劑(poor solvent),因此造成PF團鏈的聚集尺度增加,進而使得UV-vis吸收波長與光激發光波長(absorption or luminescence spectra)產生紅移的現象(red-shifting)。從我們的研究中証實,我們能夠成功製備出PF-b-PMMA放射藍光的奈米纖維,並經由溶劑選擇效應,藉由PF團鏈聚集形態與尺度的改變進而調控光色的變化。其次,我們亦將PPQ-b-PS共聚合物高分子,分別溶在三種不同的溶劑系統(dichloromethane, chlorobenzene, and chloroform)後,利用單軸靜電紡絲系統將其製備成奈米纖維,發現不同的溶劑會使得PPQ-b-PS產生不同程度的聚集,進而有不同的發光光色(綠、黃、橙色)。除此之外,更深入探討硬桿-柔軟嵌段共聚高分子的靜電紡絲纖維用於pH 感應器方面的應用。結果顯示不同溶劑製備的纖維,其對酸的感應程度隨著硬桿端高分子的聚集程度上升而下降。而由靜電紡絲製備的纖維會比其固態薄膜的感測性高。 本文的第四個部分(第五章),我們利用雙軸的系統,製備出具有感測環境能力的核(PMMA)殼(P3HT)雙成分奈米纖維。這樣子的核(PMMA)殼(P3HT)雙成分奈米纖維,經由SEM觀察發現其纖維的直徑為500-700nm,且其纖維的表面均勻覆蓋著類似P3HT的特徵形態(worm-like)。當纖維放置在室溫大氣可見光的環境之下,隨著時間的增加,纖維的發光顏色會從紅光轉變到橘光,到兩週後呈現綠光的顏色,這主要是由於發生高分子鏈段的降解,導致共軛長度減短所致。除此之外,由於P3HT/O2的複合物形成(charge transfer complex, CTC),使得兩週後的纖維在沒有進行doping下,發現具有導電的特性。然而,以上特殊的光電現象,則在薄膜的形態並沒有明顯地發現,故我們製備出的核(PMMA)殼(P3HT)雙成分奈米纖維是具備環境感測能力的潛力。 | zh_TW |
dc.description.abstract | Electrospinning (ES) has emerged as a new technique to produce various functional polymer nanofibers. Conjugated polymers have extensively studied for diverse electronic and optoelectronic devices due to the excellent electronic and optoelectronic properties. The photophysical properties of conjugated polymers could be tuned through the approaches of blending or different synthetic ways which result in the enhancement of device characteristics. However, most of the above studies are based on the thin film devices. The morphology and properties of conjugated polymers based ES nanofibers have not been fully explored yet. Only few ES nanofibers based on conjugated polymers were reported because of the limitation on molecular weight or solvents. In this thesis, the objectives are to produce diverse ES nanofibers (nonwoven, aligned, or core-shell type) based on various conjugated polymers and explore their morphology, photophysical properties, and applications, including distinguishing polarized characteristic and sensory devices and further those exhibited significant difference in comparison to the thin films.
In the first part of this thesis, Light-emitting electrospun (ES) nanofibers were successfully prepared through the binary blends of polyfluorene derivative/poly(methyl methacrylate)(PMMA) using a single-capillary spinneret. The studied poly(fluorene)s included poly(9,9-dioctylfluoreny-2,7-diyl)(PFO), poly [2,7-(9,9-dihexylfluorene)-alt-5,8-quinoxaline](PFQ), poly[2,7-(9,9-dihexyl-fluorene) -alt-4,7-(2,1,3-benzothiadiazole)](PFBT), and poly[2,7-(9,9-dihexyl-fluorene)-alt -5,7-(thieno[3,4-b]pyrazine)](PFTP). The TEM and SEM results suggested that PFO/PMMA ES fibers gradually formed a core-shell structure with a porous surface as the PFO blend ratio was increased. PFO has a poorer solubility in chloroform than PMMA and forced it to be solidified first in the fiber center to form the core-shell structure. The SEM and laser confocal images suggested that the PFO aggregation domain in the ES fibers was much smaller than that in the spin-coated films and resulted in higher photoluminescence efficiency. Uniform ES fibers produced from the binary blends of PFO/PMMA, PFQ/PMMA, PFBT/PMMA, and PFTP/PMMA exhibited the luminescence characteristics (peak maximum(nm); color) of (443; blue), (483; green), (539; yellow), and (628; red), respectively. The present study demonstrates that full color light-emitting ES nanofibers could be produced from the binary blends of polyfluorene derivative/PMMA. In the second part of this thesis, highly aligned luminescent electrospun (ES) nanofibers were successfully prepared from two binary blends of poly(9,9-dioctylfluoreny-2,7-diyl)(PFO)/ poly(methyl methacrylate)(PMMA) and poly(9,9-di(3,3-N,N-trimethyl-ammonium)-propylfluorenyl-2,7-diyl)-alt-(9,9-dioctylfluorenyl-2,7-diyl)diiodide salt (PF+)/ PMMA. The PFO/PMMA aligned ES fibers showed a core-shell structure but the PF+/PMMA exhibited periodic aggregate domains in the fibers. The aligned fibers had polarized steady-state luminescence with a polarized ratio as high as 4, much higher than the nonwoven ES fibers or spin-coated film. Besides, the PF+/PMMA aligned ES fibers showed an enhanced sensitivity on sensing plasmid DNA. Such aligned ES fibers could have potential applications in optoelectronic or sensory devices. In the third part of this thesis, Novel luminescent electrospun (ES) fibers were successfully prepared from a conjugated rod-coil block copolymer, poly[2,7-(9,9-dihexylfluorene)]-block-poly (methylmethacrylate) (PF-b-PMMA) using a single-capillary spinneret. The experiment results indicated that PF-b-PMMA ES fibers prepared from THF, THF/DMF (50/50) and DMF contained PF block aggregated structures of dot-link (5-10 nm), line-like (10-20 nm), and ellipse-like structure (25-50 nm), respectively. Such variation on the aggregation size led to the red-shifting on the absorption or luminescence spectra. Also, the fiber diameters decreased with enhancing the DMF content. Furthermore, functional ES fibers with a high sensitivity on acid or pH were successfully prepared from binary blends of poly(phenylquinoline)-block-polystyrene rod-coil diblock copolymers (PPQ-b-PS) /polystyrene (PS). The effect of pH on the fluorescence spectra for ES fibers and spin-coated thin film were investigated. The PPQ-b-PS /PS ES fibers showed high sensitivity in comparison with the spin-coated film. The present study demonstrates that blue light-emitting ES fibers were successfully prepared from conjugated rod-coil diblock copolymer and their aggregate morphology and photophysical properties could be tuned through selective solvent. Furthermore, it also suggested that the ES fibers prepared from rod-coil conjugated block copolymer could have potential applications in optoelectronic or sensory devices. In the fourth part of this thesis, new electrospun (ES) sensory fibers consisted of poly(methyl methacrylate) (PMMA) core and poly(3-hexylthiophene-2,5-diyl) (P3HT) shell were successfully prepared using a two-fluid coaxial electrospinning process. The studies showed that the prepared ES fibers had diameters of 500-700 nm and worm-like surface structure of P3HT on the fiber. Upon exposed to air under visible light for two weeks, significant blue-shifting on both absorption and luminescence spectra (from red, to orange, and to green PL emission). It was probably due to the chain scission occurred in the P3HT and led to the reduced conjugated length. The sensitivity of the ES fibers was much better than that of the spin-coated P3HT film from the comparison on the variation of photophysical properties. Besides, the EPR measurements suggested the formation of the P3HT.O2 charge transfer complex (CTC), leading to the fiber conductivity without an external doping. The present study demonstrates that conjugated polymer based ES core-shell fibers may have potential applications for oxygen-sensing devices. | en |
dc.description.provenance | Made available in DSpace on 2021-06-15T00:18:37Z (GMT). No. of bitstreams: 1 ntu-98-D94549009-1.pdf: 4975430 bytes, checksum: 852869d7a4f82dd17faeba5bdd50f510 (MD5) Previous issue date: 2009 | en |
dc.description.tableofcontents | Table of Contents
口試委員會審定書 i 誌謝 ii Abstract iii 中文摘要 vi Table of Contents ix List of Figures xiv List of Tables xxii 1. Electrospun Polymer Nanofibers 1 1.1 Introduction 1 1.2 Electrospinning: Setups, Theory, Process and Features 3 1.2.1 The Basic Setups for Electrospinning 3 1.2.2 The Fundanmental Theory and Process of Electrospinning 4 1.2.3 The Effect of Prarameters on Electrospun Nanofiber Morphology 6 1.2.3.1 Electrospinning Solution parameters and fiber morphology 7 1.2.3.2 Electrospinning Process parameters and fiber morphology 8 1.2.4 Some Remarkable and Unique Features of Electrospun Nanofibers 10 1.2.5 Various Electrospinning Design Set-ups and Nanofiber Assemblies 12 1.3 Electrospun Nanofibers: Structure, Function, and Application 14 1.3.1 Functional Polymers Blend Electrospun Nanofibers 14 1.3.2 Carbon nanotubes within nanofibers 15 1.3.3 Organic-inorganic Nanofibers (Hybrids) 15 1.3.4 Block Copolymer Nanofibers 16 1.3.5 Core-shell/ Hollow/ Porous Polymer Nanofibers 17 1.3.6 Aligned Electrospun Nanofibers 19 1.3.7 The Applications of Electrospun Nanofibers1a 21 1.4. Electrospun Conjugated Polymer Nanofibers 24 1.4.1 Conjugated Polymers 24 1.4.1.1 Conjugated Polyfluorenes 25 1.4.2 Conjugated Polymer Blends (Morphology/Photophysical Properties) 28 1.4.3 Rod-Coil Copolymers Based on Conjugated Rods 30 1.4.4 Electrospun Nanofibers based on Conjugated polymer 33 1.4.4.1 Morphology and Photophysical Properties 34 1.4.5 The Application of Electrospun Nanofibers based on Conjugated Polymers 37 1.4.5.1 Field-effect transistors 37 1.4.5.2 Electrochromic devicce 39 1.4.5.3 Sensor Application 39 1.5 Research objectives 42 References 45 Table and Figure 50 2. Morphology and Photophysical Properties of Light-Emitting Electrospun Nanofibers Prepared From Poly(fluorene) Derivative/PMMA Blends 77 2.1 Introduction 77 2.2 Experimental 80 2.2.1 Materials 80 2.2.2 Electrospinning Setup 80 2.2.3 Characterization 81 2.2.3.1 Morphology of Electrospun Fibers and Thin Films 81 2.2.3.2 Photophysical Properties 81 2.4 Results and Discussion 82 2.4.1 Morphology of Electrospun Fibers and Thin Films 82 2.4.1.1 The effect of adding salt on morphology of electrospun fibers 82 2.4.1.2 The morphology of electrospun fibers (FE-SEM images) 82 2.4.1.3 The morphology of electrospun fibers (TEM images) 83 2.4.1.4 The morphology of electrospun fibers and thin films (Confocal images) 84 2.4.2 Photophysical Properties of Electrospun Fibers and Thin Films 85 2.4.2.1 UV-Vis Absorption Spectra 85 2.4.2.2 Photoluminescence Spectra 86 2.4.2.3 Internal Quantum Efficiency 86 2.4.2.4 Full color ES fibers 87 2.5 Conclusions 89 Reference 90 Table and Figure 92 3. Highly Aligned Luminescent Electrospun Nanofibers Prepared From Polyfluorene /PMMA Blends: Fabrication, Morphology, Photophysical Properties, and Sensory Applications 105 3.1 Introduction 105 3.2 Experimental 108 3.2.1 Materials 108 3.2.2 Polymer Blend Compositions for ES Fiber 108 3.2.3 Electrospinning Setup 109 3.2.4 Spin-coated Film 109 3.3 Characterization 110 3.3.1 Morphology Characterization 110 3.3.2 Photophysical Properties 110 3.4 Results and Discussion 111 3.4.1 ES Process Design for Aligned Fibers 111 3.4.2 Fabrication and Morphology of Aligned PFO/PMMA ES Nanofibers 112 3.4.3 Fabrication and Morphology of Aligned PF+/PMMA Nanofibers 113 3.4.4 Photophysical Properties of ES fibers and Spin-coated Films 114 3.4.5 Polarized Luminescence Properties 115 3.4.6 Plasmid DNA Sensory Application 116 3.5 Conclusions 118 References 119 Table and Figure 122 4. Morphology and photophysical properties of electrospun conjugated rod-coil block copolymers 135 4.1 Introduction 135 4.2 Experimental 138 4.2.1 Materials 138 4.2.2 Synthesis of conjucated rod-coil block copolymer 138 4.2.3 Electrospinning Fiber and Spin-coated Film 140 4.2.4 Characterization 141 4.3 Results and discussion 143 4.3.1 Synthesis of methyl ketone-terminated polystyrene (PS) and rod-coil diblock polymers (PPQ-b-PS) 143 4.3.2 Thermal Analyses 143 4.3.3 Morphology of PF-b-PMMA ES fibers 144 4.3.4 Photophysical Properties of the PF-b-PMMA ES fibers 146 4.3.5 Phase morphologies and phtophysical properties of ES fibers and solid-state film based on PPQ-b-PS/ PS blend 148 4.3.6 pH-tunable sensing property 150 4.4 Conclusion 152 References 154 Table and Figure 157 5. Electrospun Poly(3-hexylthiophene)/Poly(methyl methacrylate) Core-Shell Fibers for Sensory Applications 171 5.1 Introduction 171 5.2 Experimental 173 5.2.1 Materials 173 5.2.2 Electrospinning Setup 173 5.2.3 Spin-coated Film 174 5.3 Characterization 174 5.4 Results and Discussion 175 5.4.1 Fabrication and Morphology of Core(PMMA)-Shell(P3FT) Electrospun Fibers 175 5.4.2 Photophysical Properties and Sensory Application 176 5.4.3 EPR and Electronic Properties 177 5.5 Conclusions 179 References 180 Table and Figure 182 6. Conclusion and Future Works 187 Autobiography 191 Publication Lists 192 | |
dc.language.iso | en | |
dc.title | 靜電紡絲製備共軛高分子奈米纖維之形態、光物理性質及應用 | zh_TW |
dc.title | Electrospun Conjugated Polymer Nanofibers: Morphology, Photophysical Properties, and Applications | en |
dc.type | Thesis | |
dc.date.schoolyear | 97-1 | |
dc.description.degree | 博士 | |
dc.contributor.oralexamcommittee | 邱文英,王紀,林唯芳,劉貴生,童世煌 | |
dc.subject.keyword | 靜電紡絲,共軛高分子,形態,光物理特性, | zh_TW |
dc.subject.keyword | electrospun,conjugated polymer,morphology,photophysical properties, | en |
dc.relation.page | 193 | |
dc.rights.note | 有償授權 | |
dc.date.accepted | 2009-03-13 | |
dc.contributor.author-college | 工學院 | zh_TW |
dc.contributor.author-dept | 高分子科學與工程學研究所 | zh_TW |
顯示於系所單位: | 高分子科學與工程學研究所 |
文件中的檔案:
檔案 | 大小 | 格式 | |
---|---|---|---|
ntu-98-1.pdf 目前未授權公開取用 | 4.86 MB | Adobe PDF |
系統中的文件,除了特別指名其著作權條款之外,均受到著作權保護,並且保留所有的權利。