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完整後設資料紀錄
DC 欄位 | 值 | 語言 |
---|---|---|
dc.contributor.advisor | 陳誠亮 | |
dc.contributor.author | Ying-Jyuan Ciou | en |
dc.contributor.author | 邱瑩鵑 | zh_TW |
dc.date.accessioned | 2021-06-14T17:16:06Z | - |
dc.date.available | 2008-07-30 | |
dc.date.copyright | 2008-07-30 | |
dc.date.issued | 2008 | |
dc.date.submitted | 2008-07-25 | |
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dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/41087 | - |
dc.description.abstract | 本論文旨在以數學規劃法分別探討批次製程中的質/能整合問題。
在不考慮生產排程問題的前題之下,雖然批次製程的生產週期及各程序流體的起始與結束時間均為已知,但流體的存續時間仍為設計批次製程網路的主要困難。此,相對於連續製程的質/能整合問題,在整合批次製程工廠中各程序流體之物質或能量時,除了濃度/溫度等限制條件依然必須考量之外,常必須藉由另行設置儲存槽的方式以暫存多餘的堪用流體,待與後續流體有整合的機會時再依需求釋出,以克服各程序流體的存續時間常有落差的限制。 論文的第一部份首先探討批次製程的質量整合問題。為了充分發揮數學規劃法的特點,也就是可先考量到所有可能狀況再整併出可行的最佳設計。本研究依據給定的生產週期及各程序流體的起始與結束時間,將整個批次製程生產週期區隔為數個操作區段。如此,個別操作區段內的質量整合問題均可視同連續製程的質量整合問題。本研究提出一個包括暫存槽且考量到所有操作可能性的質量交換器網路超結構,其中分別討論間歇性操作和連續性操作的質量交換網路。兩類操作模式的最佳網路合成問題都可基於最小化額外貧流之消耗或總年度成本為目標,分別制定為混合整數非線性規劃。最後再以一個文獻中的焦媒爐氣體的淨化問題為例,用以驗證對半連續程序所提出之質量網路結構整合方法的適用性。 本論文的第二個部分為針對批次工廠中間接熱能交換網路之合成與其能量儲存策略,提出一個能描述廣泛使用狀況的熱能交換器網路超結構。 首先使用一個原本存在於低溫槽的熱能轉移介質去吸收熱流中過剩的熱量,並且將已升高溫度的熱能轉移介質隨後暫時地存放在高溫儲槽中。其已累積相當熱能的熱能轉移介質隨後被使用在加熱後續的程序冷流,之後已被冷卻的熱能轉移介質將返回到原本的低溫儲槽中。藉由反覆循環在儲存槽間的熱能轉移介質,在批次工廠中與時間相關的熱/冷流的熱能交換限制因此可以被放寬,其中,儲存槽並包含兩種類型,即固定溫度/可變化質量之熱能儲存槽與可變化溫度/可變化質量之熱能儲存槽。依據所提出的熱能交換網路超結構,以最小化公用能源消耗與年度成本為設計目標,可分別制定兩個混合整數非線性規劃來描述使用不同類型熱儲存槽之間接性熱能交換網路合成問題。 最後,採用一數值例子來比較狹點分析/設計和所提之方法所得結果,並用兩個較複雜的程序驗證所提出的間接式熱能合成方法之適用性。 | zh_TW |
dc.description.abstract | This dissertation aims to confer the mass and heat integrated problems in batch processes by mathematical programming. Under the situation that does not consider the problem of production scheduling, although the production cycle and starting and ending times of each process stream in batch processes are both known, the existing time of streams is still the main difficulty for designing the networks in the batch processes. Hence, comparing with the mass and heat integrated problems in continuous processes, besides considering the composition/temperature limitation for synthesis the material or energy of process streams in batch plants, storage tanks are often used to overcome the constraint, the drop of the existing times for process streams.
The first part in this dissertation is to analyze the mass exchange network synthesis problem in batch processes. To exhibit amply the mathematical programming feature that is to ponder all possible conditions first and then to merge the feasible optimized design, the entire production cycle of batch process is divided into several operating periods according the given of production cycle and starting and ending times of each process. Therefore, the mass exchange network synthesis problem within each operating period resembles the mass integration problem of continuous process. This research presents a superstructure including storage tanks and mass exchange network (MEN) for all possible operations, where the mass exchange network is operating in intermittent and the continuous modes. The synthesis problems of two operating modes are formulated as mixed-integer nonlinear programs (MINLPs) based on the objectives of minimizing the external mass separating agents (MSAs) or the total annual cost (TAC). Finally, a coke oven gases (COGs) purification problem from the literature is used to demonstrate the applicability of the proposed MEN synthesis method for semi-continuous processes. The second part in this dissertation aims at proposing a generic superstructure of a heat exchange network (HEN) focusing on indirect heat integration and its associated thermal storage policy. The thermal storage uses a heat transfer medium (HTM) that initiated in a cold tank. It is then sent to absorb surplus heat from hot process streams and results at an elevated temperature, before it is to be temporarily stored in a hot tank. The accumulated hot HTM is then utilized to heat subsequent cold process streams, and the cooled HTM is circulated back into its source cold tank. By applying the re-circulated HTM storing in indirect thermal storages, the limitation of heat interchange between time-dependent hot/cold process streams in batch plants can be relaxed. The heat storage system consist of two types, the fixed temperature/variable-mass (FTVM) heat storage and the variable-temperature/variable-mass (VTVM) heat storage. Based on the proposed heat exchange network superstructure, the synthesis problems of indirect HENs for different types of thermal storages are formulated as two MINLPs, where the objective is to minimize the utility consumption and the total annual cost. One numerical example are analyzed to compare results from the pinch analysis technique and the newly proposed methods, and two complex processes are used to demonstrate the applicability of proposed indirect heat integration synthesis method. | en |
dc.description.provenance | Made available in DSpace on 2021-06-14T17:16:06Z (GMT). No. of bitstreams: 1 ntu-97-D93524013-1.pdf: 2759289 bytes, checksum: 9c918a0dd898cfbef89afd0837681b42 (MD5) Previous issue date: 2008 | en |
dc.description.tableofcontents | 口試委員審定書. . . . . . . . . . . . . . . . . . . . . . i
致謝. . . . . . . . . . . . . . . . . . . . . . . . . . iii 摘要. . . . . . . . . . . . . . . . . . . . . . . . . . . v Abstract. . . . . . . . . . . . . . . . . . . . . . . . vii List of Figures . . . . . . . . . . . . . . . . . . . .xvii List of Tables. . . . . . . . . . . . . . . . . . . .xxiii Nomenclature. . . . . . . . . . . . . . . . . . . . . . xxv 1 Introduction 1 1.1 Process Integration in Batch Plants . . . . . . . . . 1 1.1.1 Operational limitation in batch plant integration 2 1.1.2 Types of streams in batch processes . . . . . . . . 3 1.2 Mass Exchange Network in Batch Plants (BMEN) . . . . 4 1.2.1 Operating modes of MEN in batch plants . . . . . . 5 1.2.2 Literature survey for BMEN . . . . . . . . . . . . 6 1.2.3 Motivation for BMEN . . . . . . . . . . . . . . . . 9 1.3 Heat Exchange Network in Batch Plants (BHEN) . . . . 10 1.3.1 Heat integration modes in batch plants . . . . . . 11 1.3.2 Literature survey for BHEN . . . . . . . . . . . . 14 1.3.3 Motivation for BHEN . . . . . . . . . . . . . . . 17 1.4 Organization . . . . . . . . . . . . . .. . . . . . 19 2 Mass Exchanger Network in Batch Plants: Intermittent MEN Mode 21 2.1 Problem Statement for Intermittent MEN Mode . . . .. 21 2.2 Periodically Partitioned Stage-wise Superstructure for Intermittent MEN Mode . . . . . . . . . . . . . . . . . 24 2.3 Model Formulation for Intermittent MEN Mode . . . . 27 2.3.1 Overall mass balances for transferable components over the whole network . . . . . .. . . . . . . . . . . 27 2.3.2 Mass balances for transferable components in each stage . . . . . . 28 2.3.3 Mass balances for transferable components in each exchange unit . 29 2.3.4 Remaining mass for transferable components for each storage tank 29 2.3.5 Existence of each storage tank . . . . . . . . .. 30 2.3.6 Assignment of superstructure inlet/outlet compositions . . . . . . . 31 2.3.7 Feasibility of the transferable components . . . . 32 2.3.8 Logical constraints . . . . . . . . . . . . . . . 32 2.3.9 Feasibility constraints of the equilibrium relationships . . . . . . . 33 2.3.10 Bounds on variables . . . . . . . . . . . . . . . 34 2.3.11 Optional constraints . . . . . . .. . . . . . . . 34 2.3.12 Objective function and MINLP formulation . . . . 35 2.4 Example 2:1: Sweetening of COG . . . . . . . . . . . 35 2.4.1 Case 1: single operation without storage tanks . . 41 2.4.2 Case 2: single operation with storage tanks on rich streams . . . . . 45 2.4.3 Case 3: cyclic operations with storage tanks on rich streams . . . . 48 2.4.4 Case 4: single operation with storage tanks on process lean streams 50 2.4.5 Case 5: cyclic operation with storage tanks on process lean streams 52 3 Mass Exchanger Network in Batch Plants: Continuous MEN Mode 55 3.1 Problem Statement for Continuous MEN Mode . . . . . 55 3.2 Periodically Partitioned Stage-wise Superstructure for Continuous MEN Mode . . . . . . . . . . . . . . . . . . 56 3.3 Model Formulation for Continuous MEN Mode . . . . . 58 3.3.1 Modeling for continuous MEN (Design Phase I) . . .59 3.3.2 Modeling for storing policy (Design Phase I) . . .65 3.3.3 Sequential design objectives and MINLP formulations . . . . . . . 70 3.4 Example 3:1: Sweetening of COG . . . . . . . . . . 73 3.4.1 Case 1: continuousMEN synthesis for the original semi-consecutive COG process . . . . . . . . . . . 75 3.4.2 Case 2: modied COG process with three semi-consecutive streams 78 3.4.3 Case 3: two parallel COG plants with longer cyclic time . . . . . . 80 3.4.4 Case 4: two parallel COG plants with shorter cyclic time . . . . . . 83 3.4.5 Analysis of total annual costs (TACs) . . . . . . . . . . . . . . . . 83 4 Indirect Heat Exchanger Network in Batch Plants: FTVM Storage System 87 4.1 Conceptual Structure of Indirect Thermal Storage Systems . . . . . . . . . 87 4.2 Problem Statement for FTVM Storage System . . . . . 89 4.3 Superstructures for FTVM Storage System . . . . . . 91 4.4 Model Formulation for FTVM Storage System . . . . . 92 4.4.1 Overall heat balance on the recirculated heat transfer medium . . . 93 4.4.2 Heat balance around series type heat exchange units . . . . . . . . 93 4.4.3 Heat balance around parallel type heat exchange units . . . . . . . 95 4.4.4 Heat balance on recirculated HTM around units . . 95 4.4.5 Calculation of approach temperature . . . . . . . 96 4.4.6 Maximal number of tanks . . . . . . . . . . . . . 97 4.4.7 Temperature order of tanks . . . . . . . . . . . . 97 4.4.8 Remaining quantities in thermal storage tanks . . 99 4.4.9 Logical constraints on remaining quantities in tanks . . . . . . . . 100 4.4.10 Logical constraints on heat exchange units . . 101 4.4.11 Logical constraints on inlet/outlet of tanks . . 102 4.4.12 MINLP formulation for utility determination . . 103 4.4.13 MINLP formulation for minimizing storage tank size . . . . . . . . 104 4.5 Example 4:1: Simple Problem for Comparing Design Methods . . . . . . 105 4.6 Example 4:2: More Complex Single Product Batch Plant . . . . . . . . . . 111 4.6.1 Case 1: heat integration with two storage tanks . 115 4.6.2 Case 2: heat integration with three storage tanks . . . . . . . . . . 119 4.7 Example 4:3: A brewing process . . . . . . . . . . 124 5 Indirect Heat Exchanger Network in Batch Plants: VTVM Storage System 137 5.1 Problem Statement for VTVM Storage System . . . . . 137 5.2 Superstructures for VTVM Storage System . . . . . . 138 5.3 Model Formulation for VTVM Storage System . . . . . 141 5.3.1 Overall heat balance on the recirculated heat transfer medium . . . 141 5.3.2 Heat balance around series and parallel type heat exchanger . . . . 142 5.3.3 Heat balance on recirculated HTM around units . . 143 5.3.4 Heat balance around series type unit at time point . . . . . . . . . . 144 5.3.5 Calculation of approach temperature . . . . . . 145 5.3.6 Remaining mass and energy in energy reservoirs . 147 5.3.7 Logical constraints . . . . . . . . . . . . . 148 5.3.8 Sizing equation of heat exchanger . . . . .. . . 150 5.3.9 Costs of variable temperature storage system . . 152 5.3.10 Design Objectives and MINLP Formulations . . . . 153 5.4 Solution Strategy for Iterative Parameter, Rkp . . 156 5.5 Example 5:1: Simple Problem for Comparing FTVM Storage System . . . 162 5.5.1 Case 1: minimizing utility with two small tanks . . . . . . . . . . . 163 5.5.2 Case 2: minimizing utility with two large tanks . . . . . . . . . . . 167 5.5.3 Analysis of annual cost of a VTVM storage system, ACV T . . . . . 169 6 Conclusions 173 6.1 Main Contributions Achieved for BMEN . . . . . . . . . . . . . . . . . . 173 6.2 Main Contributions Achieved for BHEN . . . . . . . . . . . . . . . . . . 174 Appendix. A. . . .. . . . . . . . . . . . . . . . . . . 175 Bibliography. . . . . . . . . . . . . . . . . . . . . . 189 Autobiography. . .. . . . . . . . . . . . . . . . . . . 195 | |
dc.language.iso | en | |
dc.title | 應用數學規劃法作批次製程質/能交換器網路之合成與設計 | zh_TW |
dc.title | A Mathematical Programming Approach for Synthesis and
Design of Mass/Heat Exchanger Networks in Batch Plants | en |
dc.type | Thesis | |
dc.date.schoolyear | 96-2 | |
dc.description.degree | 博士 | |
dc.contributor.oralexamcommittee | 鄭西顯,黃世宏,張?庭,黃孝平,余政靖,符傳藝 | |
dc.subject.keyword | 批次程序,合成,質量交換器網路,能量交換器網路,超結構,混合整數非線性規劃, | zh_TW |
dc.subject.keyword | Batch process,Synthesis,Mass exchange network (MEN),Heat exchange network (HEN),Superstructure,Mixed-integer nonlinear programming (MINLP), | en |
dc.relation.page | 192 | |
dc.rights.note | 有償授權 | |
dc.date.accepted | 2008-07-28 | |
dc.contributor.author-college | 工學院 | zh_TW |
dc.contributor.author-dept | 化學工程學研究所 | zh_TW |
顯示於系所單位: | 化學工程學系 |
文件中的檔案:
檔案 | 大小 | 格式 | |
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ntu-97-1.pdf 目前未授權公開取用 | 2.69 MB | Adobe PDF |
系統中的文件,除了特別指名其著作權條款之外,均受到著作權保護,並且保留所有的權利。