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完整後設資料紀錄
DC 欄位 | 值 | 語言 |
---|---|---|
dc.contributor.advisor | 莊東漢 | |
dc.contributor.author | Wei-ChihC hen | en |
dc.contributor.author | 陳韋志 | zh_TW |
dc.date.accessioned | 2021-06-14T17:14:09Z | - |
dc.date.available | 2008-08-05 | |
dc.date.copyright | 2008-08-05 | |
dc.date.issued | 2008 | |
dc.date.submitted | 2008-07-25 | |
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Guo, “Microstructure Evolution of SnAgCuEr Lead-free Solders Under High Temperature Aging”, Journal of Electronic Materials, 2008, Vol. 37, No. 1, pp.2–8 50. C.M.T. Law, C.M.L. Wu, D.Q. Yu, and M. Li, Senior Member, IEEE, and D. Z. Chi, “Interfacial microstructure and strength of lead-free Sn-Zn-RE BGA solder bumps”, IEEE TRANSACTIONS ON ADVANCED PACKAGING, 2005, VOL. 28, NO. 2, pp.252–258 51. W. Dong, Y. Shi, Z. Xia, Y. Lei, and F. Guo, “Effects of Trace Amounts of Rare Earth Additions on Microstructure and Properties of Sn-Bi-Based Solder Alloy”, Journal of Electronic Materials, 2008, accepted March 19 52. C.M.T. Law, and C.M.L. Wu, “Microstructure evolution and shear strength of Sn-3.5Ag-RE lead-free BGA solder balls”, High Density Microsystem Design and Packaging and Component Failure Analysis, 2004. HDP '04. Proceeding of the Sixth IEEE CPMT Conference on, 2004, 30–June–3 July, pp.60–65 53. C.M.L.Wu, D.Q. Yu, C.M.T. 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Xia, “Properties of Sn3.8Ag0.7Cu Solder Alloy with Trace Rare Earth Element Y Additions”, Journal of Electronic Materials, 2007, Vol. 36 , No. 7, pp. 766–774 69. F.J. Wang, F. Gao, X. Ma and Y.Y. Qian, “Depressing Effect of 0.2wt. % Zn Addition into Sn-3.0Ag-0.5Cu Solder Alloy on the Intermetallic Growth with Cu Substrate during Isothermal Aging”, Journal of Electronic Materials, 2006, Vol.35, n.10, pp.1818–1824 | |
dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/41054 | - |
dc.description.abstract | 本研究分為兩部分,第一部分主要針對Sn-xAg-0.5Cu-0.04Ni(x = 0.1, 1, 2, 3wt%)不同Ag含量之銲錫合金與化金(Au/Ni-P/Cu)基板做接合,經過時效處理後,觀察其界面反應金相與接點強度及銲錫機械性質之研究。隨著Ag含量越多,銲錫基地中之Ag3Sn介金屬量越多,且接點強度亦隨Ag含量的增加而提高。在拉伸試驗方面,隨著Ag含量越多且分散於基地中,具有散佈強化之作用,進而提升強度值;此外,延展性則因Ag3Sn介金屬量增加影響差排移動,隨著Ag含量的增加使得延展性下降。在接點界面反應方面,Ag含量的多寡並不影響界面介金屬的型態以及成長速率。
第二部分則是在低Ag含量之Sn-1Ag-0.5Cu-0.04Ni銲錫中添加0.5wt%Ce的稀土元素及添加完Ce稀土元素後再添加0.2wt%Zn,分別以此三種銲錫與化金基板做接合,針對接點之界面反應與銲錫特性做研究。研究結果顯示:不論添加0.5wt%Ce稀土元素或是0.2wt%Zn過渡元素皆不會對Sn-1Ag-0.5Cu-0.04Ni銲錫合金之熔點產生影響。在觀察Sn-1Ag-0.5Cu-0.04Ni-0.5Ce銲錫微結構,可以看到粗大的CeSn3介金屬化合物,這些CeSn3介金屬化合物因為過於粗大而導致銲錫接點強度下降。雖然粗大的CeSn3介金屬化合物會使銲錫的機械強度下降,但卻可使銲錫合金的延展性獲得提升,推測這是因為破裂模式的轉變所造成。另外在Sn-1Ag-0.5Cu-0.04Ni-0.5Ce銲錫添加0.2wt%Zn可以細化銲錫中的CeSn3介金屬,使得銲錫接點強度與銲錫合金的抗拉強度皆獲得提升。再接點之界面反應方面,不論添加Ce或是Zn對接點之介金屬的成長皆有抑制的效果,而介金屬成長機制皆屬於擴散控制。 | zh_TW |
dc.description.abstract | This research is divided into two parts, the main focus of first part is the effect of different Ag content on the physical and mechanical performance, such as melting points, microstructure, interfacial reactions, bonding strength, tensile properties, between Sn-Ag-Cu-Ni solder and electroless nickel-immersion gold-plated Cu substrate during aging. As Ag content being the more, the more Ag3Sn intermetallic compound in the solder matrix, and the strength of joint is also improved with increasing of Ag content. In tensile test, the strength of the solder alloy increases with increasing of Ag content. In addition, the dislocation migration is resisted by Ag3Sn intermetallic compound, and the ductility of solders decreases with increasing of Ag content. In interface reaction, the number of Ag content does not influence the interfacial reaction type and growth speed of intermetallic compound.
Second part of this thesis is the effect of the adding of Ce element on the physical and mechanical performance, such as melting points, microstructure, interfacial reactions, bonding strength, tensile properties, between Sn-1Ag-0.5Cu-0.04Ni solder and electroless nickel-immersion gold-plated Cu substrate. The result of study reveals: No matter adding 0.5wt%Ce rare-earth element or 0.2wt%Zn element will not influence the melting point of Sn-1Ag-0.5Cu-0.04Ni solder. The thick CeSn3 intermetallic compound is observed in the microstructure of Sn-1Ag-0.5Cu-0.04Ni-0.5Ce solder. Because these CeSn3 intermetallic compounds is too thicker to decrease the strength of solder joint. Although the thick CeSn3 intermetallic compounds decrease the mechanical strength, the ductility is enhanced. In addition, adding 0.2wt%Zn into Sn-1Ag-0.5Cu-0.04Ni-0.5Ce solder alloy can not only refine the CeSn3 intermetallic compound but also improve the mechanical properties and bonding strength of solder joints. The addition of Ce and Zn into Sn-1Ag-0.5Cu-0.04Ni solder alloy can inhibit intermetallic compound layer growth of the joint. All the mechanism of intermetallic compound layer growth is diffusion controlled. | en |
dc.description.provenance | Made available in DSpace on 2021-06-14T17:14:09Z (GMT). No. of bitstreams: 1 ntu-97-R95527059-1.pdf: 13560595 bytes, checksum: 016fd010b0a1e38a06440240a6d3f6b4 (MD5) Previous issue date: 2008 | en |
dc.description.tableofcontents | 1. 前言 1
2. 理論與文獻回顧 4 2.1. 無鉛銲錫所需具備之特性 4 2.2. Sn-Ag-Cu無鉛銲錫文獻回顧 5 2.2.1. Ag含量對Sn-Ag-Cu無鉛銲錫的影響 6 2.2.2. Cu含量對Sn-Ag-Cu無鉛銲錫的影響 8 2.2.3. 添加其他元素對Sn-Ag-Cu無鉛銲錫的影響 10 2.2.4. 其他Sn-Ag-Cu無鉛銲錫文獻回顧 13 2.3. 添加稀土元素對無鉛銲錫的影響 16 2.3.1. 添加稀土元素對無鉛銲錫之微結構的影響 17 2.3.2. 添加稀土元素對無鉛銲錫熔點行為及潤濕性的影響 20 2.3.3. 添加稀土元素對銲錫介金屬化合物的影響 21 2.3.4. 添加稀土元素對無鉛銲錫機械性質的影響 23 2.4. 界面成長動力學 28 3. 實驗方法 30 3.1. 研究簡介 30 3.2. Sn-xAg-0.5Cu-0.04Ni(x = 0.1, 1, 2, 3wt%)添加稀土元素之球格陣列化金基板構裝研究 30 3.2.1. 銲錫材料的配製 30 3.2.2. 銲錫與化金基板界面反應及接點強度之研究 31 3.3. 銲錫特性之研究 33 3.3.1. 示差掃描熱分析儀(differential scanning calorimetry,DSC) 33 3.3.2. 銲錫微結構觀察 33 3.3.3. 拉伸試驗 33 4. 結果與討論 44 4.1. 銲錫材料特性之研究 44 4.1.1. 銲錫材料之熱分析 44 4.1.2. 銲錫材料之微結構觀察 49 4.2. 銲錫在化金基板球格陣列構裝接點性能之研究 53 4.2.1. 銲錫與化金基板之界面反應 53 4.2.2. 銲錫在化金基板之接點強度試驗 72 4.3. 銲錫材料拉伸試驗 86 4.3.1. 室溫拉伸試驗 86 4.3.2. 高溫慢速拉伸試驗 90 5. 結論 93 6. 參考文獻 95 | |
dc.language.iso | zh-TW | |
dc.title | Sn-XAg-0.5Cu-0.04Ni-0.5Ce 銲錫球格陣列構裝界面反應研究 | zh_TW |
dc.title | Studies on the Interfacial Reaction in
Sn-XAg-0.5Cu-0.04Ni-0.5Ce Solder BGA | en |
dc.type | Thesis | |
dc.date.schoolyear | 96-2 | |
dc.description.degree | 碩士 | |
dc.contributor.oralexamcommittee | 吳春森,賴宏仁,洪健龍,王彰盟 | |
dc.subject.keyword | 稀土元素,Ag含量,無鉛銲錫,界面反應,介金屬化合物, | zh_TW |
dc.subject.keyword | rare-earth element,Ag content,Pb-free solder,interfacial reaction,intermetallic compound, | en |
dc.relation.page | 102 | |
dc.rights.note | 有償授權 | |
dc.date.accepted | 2008-07-28 | |
dc.contributor.author-college | 工學院 | zh_TW |
dc.contributor.author-dept | 材料科學與工程學研究所 | zh_TW |
顯示於系所單位: | 材料科學與工程學系 |
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