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http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/39450完整後設資料紀錄
| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 林金福 | |
| dc.contributor.author | Chao-Song Chang | en |
| dc.contributor.author | 張照松 | zh_TW |
| dc.date.accessioned | 2021-06-13T17:28:49Z | - |
| dc.date.available | 2004-11-19 | |
| dc.date.copyright | 2004-10-11 | |
| dc.date.issued | 2004 | |
| dc.date.submitted | 2004-10-05 | |
| dc.identifier.citation | 1. (a)N. S. Sariciftci, D. Braun, C. Zhang, V.I. Srdanov, A.J. Heeger, G. Stucky, and F. Wudl, Appl. Phys. Lett.,62,585 (1993).、(b) N.S. Sariciftci, L. Smilowitz, A. J. Heeger, and R. Wudl, Synth. Met.,59, 333 (1993).
2. H. Antoniadis, B. R. Hsieh, M. A. Abkowitz, S. A. Jenekhe, and M. Stolka, Synth. Met.,62,265-271 (1994). 3. (a) B. R. Hsieh, H. Antoniadis, M. A. Abkowitz, and M. Stolka, Polym. Prepr. (Am. Chem. SOc., Div. Polym. Chem.)33,414-415 (1992).、(b) H. Antoniadis, B. R.Hsieh, M. A. Abkowitz, S. A. Jenekhe, and M. Stolka, Mol. Cryst. Liq. Cryst.,256,381 (1994).、(c) H. Antoniadis, M. A. Abkowitz, and B. R. Hsieh, Appl. Phys. Lett.,65,2030 (1994).、 (d) H. Antoniadis, M. A. Abkowitz, B. R. Hsieh, S. A. Jenekhe, and M. Stolka, Mater. Res. Soc. Symp. Proc.,328,377 (1994).、(e) M. A. Abkowitz, H. Antoniadis, J. S. Facci, B. R. Hsieh, and M. Stolka, Synth.Met.,67,187-191 (1994). 4. (a) H. Koezuka, A. Tsumura, H. Fuchigami, and K. Kuramoto, Appl. Phys. Lett.,62,1794-1796 (1993). (b) H. Fuchigami, A. Tsumura, and H. Koezuka, Appl. Phys. Lett.,63,1372-1374 (1993). 5. F. Garnier, R. Hajlaoui, A. Yassar, and P. Srivastava, Science,265,1684 (1994). 6. A. Dodabalapur, L. Torsi, and H. E. Katz, Science,268,270 (1995). 7. Y. Yang, and A. J. Heeger, Nature,372,344 (1994). 8. Q. Pei, G. Yu, C. Zhang, Y. Yang, and A. J. Heeger, Science,269,1086 (1995). 9. A. D.MacDiarmid, H. L. Wang, F. Huang, J. K. Avlyanov, P. C. Wang, T. M. Swager, Z. Huang, A. J. Epstein, Y. Wang, D. D. Gebler, R. Shashidhar, J. M. Calvert, R. J. Crawford, T. G. Vargo, G. M. Whitesides, and B. R. Hsieh, MRS Proc., (1996). 10. J. H. Burroughes, D. D. C. Bradley, A. R. Brown, R. N. Marks, R.H. Friend, P. L. Burn and A. B. Holems, Light-emitting diodes based on conjugated polymers, Nature,347,539 (1990). 11. A. R. Brown, D. D. Bradley, J. H. Burroughes, R. H. Friend, N. C. Greenham, P. L. Burn, A. B. Holmes and A. Kraft, Poly(ρ-phenylene vinylene) light-emitting diodes : Enhanced electroluminescent efficiency through charge carrier confinement, Appl. Phys. Lett.,61,2793 (1992). 12. G. J. Lee, D. Kim, J. I. Lee, H. K. Shim, Y. W. Kim and J. C. Jo, Effect of alkoxy substitution on photophysical properties of poly(ρ-phenylene vinylene), Jpn. J. Appl. Phys.,35,114 (1996). 13. J. I. Jin, Y. H. Lee and B. K. Nam, Synthesis and characterization of poly(2-methoxy-5-(2-(4-nitrophenyl)ethenyl)-1,4-phenylene vinylene) and a series of copolymers containing 1,4-phenylenevinylene units, Polymer,36,193 (1995). 14. L. H. Wang, Z. K. Chen, E. T. Kang, H. Meng, and W. Huang, Synthesis, spectroscopy and electrochemistry study on a novel di-silyl substituted poly(ρ-phenylenevinylene), Syn. Met.,105,85 (1999). 15. D. M. Johansson, M. Theander, G. Srdanov, G. Yu, O. Inganas, and M. R. Andersson, Influence of polymerization temperature on molecular weight, photoluminescence, and electroluminescence for a phenyl-substituted poly(ρ-phenylenevinylene), Macromolecules, (2001). 16. C. B. Yoon, and H. K. Shim, New light emitting poly(1,4-phenylenevinylene) derivative containing trifluoromethylstibene group in the side chain, Syn. Met.,111-112, 469 (2000). 17. S. H. Lee, B. B. Jang, and T Tsutsui, Sterically hindered fluorenyl-substituted poly(ρ-phenylenevinylene) for light-emitting diodes, Macromolecules,35,1356 (2002). 18. N. H. S. Lee, Z. K. Chen, S. J. Chua, Y. H. Lai, and W. Huang, Synthesis and characterization of a novel poly (ρ-phenylenevinylene) derivative carrying an oxadiazole side chain with improved electron affinity, Thin Solid Films,363,106 (2000). 19. H. Peter, V. Horst, P. Joern, M. Rainer and G. Andreas, Blue light emitting polymer with phenylenevinylene segments in the side-chain, Adv. Mater.,7,388 (1995). 20. F. Cacialli, R. H. Friend, N. Haylett, R. Daik, W. J. Feast, D. A. dos Santos and J. L. Bredas, Efficient green light-emitting diodes from a phenylated derivative of poly(ρ-phenylene vinylene), Appl. Phys. Lett.,69, 3794 (1996). 21. Y. Xiao, W. L. Yu, J. Pei, Z. Chen, W. Huang, and A. J. Heeger, Conjugated copolymers of 2-methoxy-5-2’-ethyl-hexyloxy-1,4- phenylenevinylene and 2,5-dicyano-1,4,-phenylenevinylene as material for polymer light-emitting diodes, Synth. Met.,106,165 (1999). 22. Y. Xiao, W. L. Yu, Z. K. Chen, N. H. S. Lee, Y. H. Lai, and W. Huang, Synthesis and characterization of a novel light-emitting copolymer with improved charge-balancing property, Thin Solid Films,363,102 (2000). 23. I. H. Cho, E. J. Oh, J. S. Suh, S. J. Park, and K. W. Lee, Synthesis and optical characterization of poly[1,8-octanedioxy- 1,4-phenylene -1,2-ethylene-1,4-phenylene] and its copolymer derivatives, Thin Solid Films,363,138 (2000). 24. H. Wang, L. Duan, Y. Qiu, X. Wang, and D. Liu, Synthesis and electroluminescence properties of a novel poly(ρ-phenylene vinylene)-based copolymer with tri(ethylene oxide) segments on the backbone, J. Appl. Polymer Science,83,2195 (2002). 25. F. Liu and G. Liu, Poly(solketal methacrylate)-block- poly(2- cinnamoyloxyethyl methacrylate)-block-poly(allyl methacrylate)：Synthesis and micelle formation, Macromolecules, 34,1302 (2001). 26. J. Morgado, F. Cacialli, R. H. Friend, B. S. Chuah, H. Rost, and A. B. Holmes, Light-emitting devices based on a poly(ρ-phenylenevinylene) statistical copolymer with oligo (ethylene oxide) side groups, Macromolecules, (2001). 27. G. Yu, H. Nishino, A. J. Heeger, T. A. Chen and R. D. Rieke, Enhanced electroluminescence from semiconducting polymer blends, Syn. Met.,72,249 (1995). 28. G. C. Bazan, Y. J. Miao, M.L. Renak and B. J. Sun, Fluorescence quantum yield of poly(ρ-phenylene vinylene) prepared via the paracyclophene route：effect of chain length and interchain contacts, J. Am. Chem. Soc.,118,2618 (1996). 29. W. P. Chang and W. T. Whang, A study of the relationship between the electroluminescence characteristics and compositions of PPV-PVA-based polymer, Polymer,37,3493 (1996). 30. J. M. Machado, F. E. Karasz and R. W. Lenz, Electrically conducting polymer blends, Polymer,29,1412 (1988). 31. J. A. Osaheni and S.A. Jenekhe, New red light-emitting conjugated rigid-rod polymer : poly(benzobisthiazole- 1,4-phenylene bisvinylene), Macromolecules,06,4726 (1993). 32. J. Brabec, V. Dyakonov, N. S. Sariciftci, W. Graupner, G. Leising, and J. C. Hummelen, Investigation of photoexcitations of conjugated polymer/fullerene composites embedded in conventional polymers, J. Chem. Phys.,109,1185 (1998). 33. M. Hamaguchi and K. Yoshino, Color-variable electro luminescence form multiplayer polymer films, Appl. Phys. Lett.,69,143 (1996). 34. F. Cacialli, R. H. Friend, N. Haylett, R. Daik, W. J. Feast, D. A. dosSantos and J. L. Bredas, Efficient green light-emitting diodes from a phenylated derivative of poly(ρ-phenylene vinylene), Appl. Phys. Lett.,69,3794 (1996). 35. J. I. Jin, J. C. Kim and H. K. Shim, Synthesis and electrical properties of poly(2-bromo-5-methoxy-1,4-phenylenevinylene) and copolymers, Macromolecules,25,5519 (1992). 36. J. B. Schlenoff, J. M. Machado, P. J. Glatkowski and F. E. Karasz, Chemical and electrochemical doping in poly(ρ-phenylene vinylene) blends, J. Polym. Sci., Polym. Phys.,26,2247 (1988). 37. J. M. Machado, J. B. Schlenoff and F. E. Karasz, Morphology, dopingand electrical properties of poly(ρ-phenylene vinylene) / poly(ethylene oxide) blends, Macromolecules,22,1964 (1989). 38. B. R. Hsieh, Polym. Mater. Sci. Eng.,67,252 (1992). 39. B. R. Hsieh, et al. U.S. Patent Application. 40. B. R. Hsieh, H. Antoniadis, D. C. Bland,Feld, and W. A. Adv.Mater.,7,36-39 (1995). 41. B. R. Hsieh, H. Razafitrimo, Y. Gao, and W. A. Feld, Polym.Mater. Sci. Eng.,73,557-558 (1995). 42. B. R.Hsieh, H. Razafitrimo, Y. Gao, and W. A. Feld, Polym.Prepr. (Am. Chem. Soc., Div. Polym. Chem.) ,36(2),85-86 (1995). 43. S. Son, A. Dodabalapur, A. J. Lovinger, and M. E. Galvin, Science,269,376 (1995). 44. B. R. Hsieh,et. al. Proc. IS&T, in press. 45. United States Patent 5,189,136. 46. Y. Xiao, W. L. Yu, J. Pei, Z. Chen, W. Huang, and A. J. Heeger, Synth. Met.,106,165 (1999). 47. B. H. Sohn, K. Kim, D. S. Choi, Y. K. Kim., S. C. Jeoung, and J. I. Jin, Macromolecules,35,2876 (2002). 48. L. S. Park, Y. S. Han, S. D. Kim, and D. U. Kim, Synth. Met.,117, 237 (2001). 49. B. R. Hsieh, H .Antoniadis, D.C. Bland, and W.A. Feld, Adv.Mater.,7(1),36 (1995). 50. H. Antoniadis, D. Roitman, B. R. Hsieh and W. A. Feld, Poly for Adv.Tech.,8,392 (1996). 51. W. C. Wan, and B. R. Hsieh, Halogen Precursor Route to Poly [(2,3-diphenyl-ρ-phenylene)vinylene](DP-PPV)：synthesis, Photoluminescence, Electroluminescence, and Photoconductivity. Macromolecules,30, 6567-6574 (1997). 52. U. Bartuch, U. Peschel, T. Gabler, R. Waldhausl, and H. H. Hohold, Optics Communication,134,49 (1997). 53. B. R. Hsieh, Y. Yu, E. W. Forsythe, G. M. Schaaf, and W. A. Feld A New Family of Highly Emissive Soluble Poly(p-phenylene vinylene) Derivatives. A Steptoward Fully Conjugated Blue-Emitting Poly(p-phenylene vinylenes) J. Am. Chem. Soc.,120,231-232 (1998). 54. A. K. Li, S. S. Yang, W. Y. Jean, C. S. Hsu, and B. R. Hsieh, Chem. of Mater.,12(9),2741 (2000). 55. S. M. Chang, P. K. Su, G. J. Lin, and T. J. Wang, Syn. Met.,137,1025 (2003). 56. J. B. Schlenoff, J. M. Machado, P. J. Glatkowski and F. E. Karasz, J. Polym.Sci., Polym. Phys.,26,2247 (1988). 57. J. M. Machado, J. B. Schlenoff and F. E. Karasz, Macromolecules, 22,1964 (1989). 58. L. Smilowitz, A. Hays, A. J. Heeger, G. Wang and J. E. Bowers, J. Chem. Phys.,98,6504 (1993). 59. G. Yu, H. Nishino, A. J. Heeger , T. A. Chen and R. D. Rieke, Syn. Met.,72, 249 (1995). 60. W. P. Chang and W. T. Whang, Polymer,37,3493 (1996). 61. I. N. Kang, D. H. Hwang, H. K. Shim, T. Zyung and J. J. Kim, Macromolecules,29,165 (1996). 62. G. He , Y. F. Li, J. Liu, Y. Yang, App. Phy. Lett.,80,4247 (2002). 63. 張祿坤,國立台灣大學材料科學與工程學研究所,碩士論文. 64. E. Buchwald, M. Meier, S. Karg, H. W. Schmidt, P. Strohriegl, W. Riess, and M. Schwoerer, Adv. Mater.,7,839 (1995) 65. E. Bellmann, S. E. Shaheen, S. Thayumanavan, S. Barlow, R. H. Grubbs, S. R. Marder, B. Kippelen, and N. Peyghambarian, Chem. Mater. 1998,10,1668 (1998). 66. W. Li, et al. Covalently interlinked organic LED transport layers via spin-coating/siloxane condensation. Adv. Mater.,11,730–734 (1999). 67. J. P. Chen, et al. Efficient, blue light-emitting diodes using cross-linked layers of polymeric arylamineand fluorene. Synth. Met.,107,129–135 (1999). 68. J. P. Chen, G. Klaerner, J. I. Lee, D. Markiewicz, V. Y. Lee, R. D. Miller, and J. C. Scott, Syn. Met.,107,129 (1999). 69. X. C. Li, T. M. Yong, J. Grfiner, and A. B. Holmes, Syn. Met.,84,437 (1997). 70. E. Bellmann, S. E. Shaheen, S. Thayumanavan, S. Barlow, R. H. Grubbs, S. R. Marder, B. Kippelen, and N. Peyghambarian, Chem. Mater.,10,1668 ( 1998). 71. W. Li, Q. Wang, J. Cui, H. Chou, S. E. Shaheen, G. E. Jabbour, J. Anderson, P. Lee, B. Kippelen, N. Peyghambarian, N. R. Armstrong, and T. J. Marks, Adv. Mater.,11,730 (1999). 72. A. Bacher, C. H. Erdelen, W. Paulus, H. Ringsdorf, H. W. Schmidt, and P. Schuhmacher, Macromolecules,32,4551 (1999). 73. C. D. Muller, A. Falcou, N. Reckefuss, M. Rojahn, V. Wiederhirn, P. Rudati, H. Frohne, O. Nuyken, H. Becker, and K. Meerholz, Letter to Nature,42,829 (2003). 74. S. H. Qin, D. Q. Qin, and K. Y. Qin, A novel photo atom transfer radical polymerization of methyl methacrylate, New J. Chem.,25, 893-895 (2001). 75. B. R. Hsieh, Y. Yu, A. C. Vanlaeken, and H. Lee, General Methodology toward Soluble Poly(p-phenylenevinylene) Derivatives, Macromolecules,30,8094-8095 (1997). | |
| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/39450 | - |
| dc.description.abstract | 本研究主要是在探討反應型polyphenylenevinylene (PPV)之合成、結構與光物理性質。我們利用Gilch route的方法在聚合MEHPPV及DPOPPV的同時使高分子的末端接上，可提供後續做交聯反應的反應性官能基，4-vinylbenzyl chloride，再利用光催化的方法，使末端基交聯(crosslinking)，然後得到結構穩定的共軛高分子。
我們藉由控制單體與單官能基分子的比例，成功合出了不同分子量的聚合物，而且隨著單官能基分子比例的增加，所得之聚合物分子量也會遞減。接著，利用單官能基所具有的反應雙鍵，照UV光進行光起始交聯反應。我們發現交聯後與未經交聯的聚合物相比，更難溶於有機溶劑中。另外在光電性質方面，我們也發現以DPOPPV單體與單官能基分子二比一的比例共聚合所得到的聚合物，以及部分MEHPPV摻合DPOPPV的系列，其螢光光譜經交聯後，發光強度有增強5~10%的趨勢。 | zh_TW |
| dc.description.provenance | Made available in DSpace on 2021-06-13T17:28:49Z (GMT). No. of bitstreams: 1 ntu-93-R91527056-1.pdf: 4044269 bytes, checksum: 4a60008563ac1ca351f067fb47f690a2 (MD5) Previous issue date: 2004 | en |
| dc.description.tableofcontents | 目錄
摘要……………………………………………………………….I Abstract…………………………………………………………..II 目錄……………………………………………………….III 圖索引……………………………………………………VI 第一章 緒論.................................................................1 1-1 前言……………………………………………………….1 1-2 文獻回顧…………………………………………………2 1-3 研究動機……………………..…………………………..6 第二章 實驗…………………………………………………..9 2-1 試藥……………………………………………………………..9 2-2 實驗合成方法…………………………………………………10 2-2-1 MEH-PPV單體之合成………………………………10 2-2-2 含末端碳碳雙鍵之MEH-PPV之合成………………11 2-2-3 含末端NH2 MEH-PPV之合成……………………...12 2-2-4 DPO-PPV單體之合成………………………………..12 2-2-5 含末端碳碳雙鍵DPO-PPV之合成………………….14 2-3 交聯……………………………………………………..……..14 2-4 性質測試………………………………………………..……..14 2-4-1 凝膠滲透層析儀……………………………………...14 2-4-2 核磁共振光譜儀……………………………………...15 2-4-3 傅立葉轉換紅外線光譜……………………………...15 2-4-4 紫外可見光吸收光譜儀……………………………...15 2-4-5 螢光光譜儀…………………………………………...16 2-4-6 溶解度測試…………………………………………...16 第三章 結果與討論...................................................18 3-1 反應機制的探討………………………………………………18 3-1-1 含末端碳碳雙鍵及胺基之MEHPPV………………..18 3-1-2 DPOPPV單體的合成………………………………...18 3-1-3 含末端碳碳雙鍵之DPOPPV………………………...19 3-2 GPC圖譜分析………………………………………………….19 3-2-1 MEHPV聚合以4-vinylbenzyl chloride做為end cap…19 3-2-2 DPOPV聚合以4-vinylbenzyl chloride做為end cap…20 3-3 NMR圖譜分析………………………………………………...20 3-3-1 含末端碳碳雙鍵之MEHPPV…..……………………20 3-3-2 含末端碳碳雙鍵之DPOPPV………………………...21 3-3-3 含末端胺基之MEHPPV……………………………..21 3-4 IR圖譜分析…………………………………………………….22 3-4-1 含末端碳碳雙鍵之MEHPPV………………………..22 3-4-2 含末端碳碳雙鍵之DPOPPV………………………...22 3-4-3 含末端胺基之MEHPPV……………………………..23 3-5 UV-Vis光譜與PL光譜(固態薄膜)之分析……………………23 3-5-1 含末端碳碳雙鍵之MEHPPV………………………..23 3-5-2 含末端碳碳雙鍵之DPOPPV………………………...24 3-5-3 MEHPPV與 DPOPPV摻合 ………………………..25 3-6 溶解性測試……………………………………………………26 3-6-1 MEHPPV系列………………………………………..26 3-6-2 DPOPPV系列………………………………………...26 3-6-3 摻合系列……………………………………………...27 第四章 結論………………………………………………….28 參考文獻……………………………………………………….29 附圖…………………………………………………………...…39 圖索引 圖一、MEHPPV單體合成示意圖...........................................................39 圖二、含末端胺基之MEH-PPV合成示意圖…………………………40 圖三、DPO-PPV合成流程圖……………………………………….….41 圖四、含末端碳碳雙鍵之DPO-PPV合成示意圖…………………….42 圖五、DMPA的光起始機制……………………………………………43 圖六、含末端官能基MEHPPV的反應機制………………………….44 圖七、合成化合物(1) 2.5-dicarbethoxy-3,4-diphenylcyclopenta dienone的Aldol condensation反應機制…………………....45 圖八、合成化合物(2) Diethyl 2,3-diphenyl-5-octyl terephthalate的Diels-Alder反應機制………………………………………..46 圖九、含末端碳碳雙鍵DPOPPV的反應機制…………………….….47 圖十、含末端碳碳雙鍵MEHPPV之GPC……………………………48 圖十一、含末端碳碳雙鍵DPOPPV之GPC………………………….49 圖十二、純MEHPPV之1H NMR……………………………………..50 圖十三、MC41之1H NMR…………………………………………….51 圖十四、MC21之1H NMR…………………………………………….51 圖十五、MC11之1H NMR…………………………………………….52 圖十六、MC12之1H NMR…………………………………………….52 圖十七、Chemdraw模擬之末端碳碳雙鍵1H NMR…………………..53 圖十八、純DPOPPV之1H NMR………………………………………54 圖十九、DC41之1H NMR…………………………………………….55 圖二十、DC21之1H NMR……………………………………………..55 圖二十一、DC11之1H NMR…………………………………………..56 圖二十二、DC12之1H NMR…………………………………………...56 圖二十三、Chemdraw模擬之DPOPPV末端碳碳雙鍵1H NMR…….57 圖二十四、含末端NO2之MEHPPV 1H NMR………………………..58 圖二十五、含末端NH2之MEHPPV 1H NMR………………………..58 圖二十六、Chemdraw模擬之MEHPPV末端胺基1H NMR…………59 圖二十七、4-vinylbenyl chloride之IR吸收圖譜…………………….60 圖二十八、MEHPPV與含末端碳碳雙鍵之MEHPPV IR吸收圖譜…61 圖二十九、DPOPPV與含末端碳碳雙鍵之DPOPPV IR吸收圖譜…..62 圖三十、MEHPPV、MEHPPV-NO2、MEHPPV-NH2之IR吸收圖譜..63 圖三十一、 MEHPPV系列未照光之(a)UV光譜(b)PL光譜…….….64 圖三十二、 MEHPPV照光0~10秒之UV光譜(a)(b)、PL光譜(c)(d)…65 圖三十三、 MC41照光0~10秒之UV光譜(a)(b)、PL光譜(c)(d)……..66 圖三十四、 MC21照光0~10秒之UV光譜(a)(b)、PL光譜(c)(d)……..67 圖三十五、 MC11照光0~10秒之UV光譜(a)(b)、PL光譜(c)(d)……..68 圖三十六、 MC12照光0~10秒之UV光譜(a)(b)、PL光譜(c)(d)……..69 圖三十七、 DPOPPV系列未照光之(a)UV光譜(b)PL光譜…………70 圖三十八、 DPOPPV照光0~10秒之UV光譜(a)(b)、PL光譜(c)(d)….71 圖三十九、 DC41照光0~10秒之UV光譜(a)(b)、PL光譜(c)(d)….…72 圖四十、 DC21照光0~10秒之UV光譜(a)(b)、PL光譜(c)(d)……….73 圖四十一、 DC11照光0~10秒之UV光譜(a)(b)、PL光譜(c)(d)…...74 圖四十二、 DC12照光0~10秒之UV光譜(a)(b)、PL光譜(c)(d)…….75 圖四十三、 MEHPPV系列摻合DPOPPV系列未照光之(a)UV光譜(b)PL光譜............................................................................76 圖四十四、 MEHPPV摻合DPOPPV照光0~10秒之UV光譜(a)(b)、PL光譜(c)(d)……………………………………………..77 圖四十五、 MC41摻合DC41照光0~10秒之UV光譜(a)(b)、PL光譜(c)(d)…………………………………………………...78 圖四十六、 MC21摻合DC21照光0~10秒之UV光譜(a)(b)、PL光譜(c)(d)…………………………………………………...79 圖四十七、 MC11摻合DC11照光0~10秒之UV光譜(a)(b)、PL光譜(c)(d)………………………………………………...80 圖四十八、 MC12摻合DC12照光0~10秒之UV光譜(a)(b)、PL光譜(c)(d)…………………………………………………...81 圖四十九、 MEHPPV照UV光前的溶解測試………………………82 圖五十、 MEHPPV+DVB+DMPA照UV光10秒後的溶解測試….83 圖五十一、 MC41照UV光前的溶解測試……………………………84 圖五十二、 MC41+DVB+DMPA照UV光10秒後的溶解測試………85 圖五十三、 DPOPPV照UV光前的溶解測試…….………………….86 圖五十四、 DPOPPV+DVB+DMPA照UV光10秒後的溶解測試…87 圖五十五、 DC21照UV光前的溶解測試……………………………88 圖五十六、 DC21+DVB+DMPA照UV光10秒後的溶解測試………89 圖五十七、 MEHPPV摻合DPOPPV照UV光前的溶解測試………90 圖五十八、 MEHPPV摻合DPOPPV+DVB+DMPA照UV光10秒後的溶解測試………………………………………………91 圖五十九、 MC11摻合DC11照UV光前的溶解測試………………92 圖六十、 MC11摻合DC11+DVB+DMPA照UV光10秒後的溶解測試……………………………………………………………93 | |
| dc.language.iso | zh-TW | |
| dc.subject | 反應性官能基 | zh_TW |
| dc.subject | 光電高分子 | zh_TW |
| dc.subject | 合成 | zh_TW |
| dc.subject | conjugated polymer | en |
| dc.subject | end cap | en |
| dc.subject | reactively funtional group | en |
| dc.title | 含反應性官能基光電高分子之合成與其性質之研究 | zh_TW |
| dc.type | Thesis | |
| dc.date.schoolyear | 93-1 | |
| dc.description.degree | 碩士 | |
| dc.contributor.oralexamcommittee | 王立義,陳文章 | |
| dc.subject.keyword | 合成,反應性官能基,光電高分子, | zh_TW |
| dc.subject.keyword | end cap,reactively funtional group,conjugated polymer, | en |
| dc.relation.page | 93 | |
| dc.rights.note | 有償授權 | |
| dc.date.accepted | 2004-10-05 | |
| dc.contributor.author-college | 工學院 | zh_TW |
| dc.contributor.author-dept | 材料科學與工程學研究所 | zh_TW |
| 顯示於系所單位： | 材料科學與工程學系 | |
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