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| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 余政靖 | |
| dc.contributor.author | Wan-Jen Hung | en |
| dc.contributor.author | 洪婉仁 | zh_TW |
| dc.date.accessioned | 2021-06-13T16:26:51Z | - |
| dc.date.available | 2005-07-21 | |
| dc.date.copyright | 2005-07-21 | |
| dc.date.issued | 2005 | |
| dc.date.submitted | 2005-07-15 | |
| dc.identifier.citation | [1] 黃士哲，「丙酸丁酯的反應蒸餾系統」，國立台灣科技大學化學
工程研究所碩士論文 (2002). [2] 趙桓易，「醋酸去水與異丙醇去水製程之非均勻相共沸蒸餾模擬 與控制」，國立台灣科技大學化學工程研究所碩士論文 (2002). [3] 白雲祥，「利用酯化反應之反應性蒸餾塔回收廢水中所含醋酸: 溶劑設計」，國立台灣大學化學工程研究所碩士論文 (2003). [4] 陳毅偉，「異相反應蒸餾系統的設計與控制」，國立台灣大學化 學工程研究所碩士論文 (2004). [英文] [5] Abella, L. C.; Gaspillo, P. D.; Itoh, H.; Goto, S., “Dehydration of tert-Butyl Alcohol in Reactive Distillation”, J. Chem. Eng. Jpn., 32(6), 742 (1999). [6] Abufares, A. A.; Douglas, P. L., “Mathematical Modeling and Simulation of an MTBE Catalytic Distillation Process Using Speedup and Aspenplus”, Chem. Eng. Res. Des., 73, Part A, 3 (1995). [7] Agreda, V. H.; Partin, L. R.; Heise, W. H., “High Purity Methyl Acetate via Reactive Distillation”, Chem. Eng. Prog., 86, 40 (1990). [8] Al-Arfaj, M. A.; Luyben, W. L., “Effect of Number of Fractionating Trays on Reactive Distillation Performance”, AIChE J., 46, 2417 (2000). [9] Al-Arfaj, M. A.; Luyben, W. L., “Comparison of Alternative Control Structures for an Ideal Two-Product Reactive Distillation Column”, Ind. Eng. 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| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/38134 | - |
| dc.description.abstract | 本研究的目的主要是探討稀釋（Dilute）醋酸水溶液的回收再利用問題，而我們所研究的稀釋醋酸濃度範圍大約是介於30~100 wt%之間。主要的研究方式是經由在反應性蒸餾塔中的酯化反應將回收後的廢酸轉變為具有利用價值的酯類產品，藉以取代單純利用蒸餾技術將廢酸中的醋酸與水予以分離。基本上，此一類型的研究主要會牽涉到以下三個問題：（1）針對酯化反應而言，我們需考量選擇何種醇類反應物來回收廢酸較具經濟效益（選用的醇類物質範圍為甲醇~戊醇）：一溶劑選擇的問題；（2）採用單一的反應性蒸餾塔處理濃度較為稀釋的廢酸，是否可以維持採用反應性蒸餾技術所帶來的經濟效益（判斷標準主要是根據年總成本）？在此，我們可藉由與另一處理廢酸回收問題製程（例如：利用共沸蒸餾系統處理廢酸取得高純度的醋酸，然後利用反應性蒸餾系統取得高純度的酯類產品）的比較得知其結果；（3）經由最適化設計地反應性蒸餾系統對於廢酸進料流率及進料濃度的改變是否具有可操作性？
針對溶劑選擇的問題，我們研究的主題主要是對反應性蒸餾塔結構進行定性上的分析(均相及異相反應性蒸餾系統比較)，以及藉由定量的年總成本（TAC）分析結果，依照廢酸中所含水組成比例的不同，決定廢酸的入料位置。結果證明當廢酸中所含醋酸的比例愈來愈稀釋時，廢酸的入料位置扮演了決定性的角色，本篇主要由第一年之結果，甲醇和戊醇則是對於廢酸回收製程較具經濟效益的反應溶劑。接下來我們針對反應性蒸餾製程提出一系統化的設計方法，經由年總成本的比較結果得知採用單一反應性蒸餾塔處理廢酸回收的製程，遠較利用共沸蒸餾系統對廢酸做提純（Purification），然後利用反應性蒸餾系統取得高純度酯類產品的製程具有經濟效益。 最後，我們將經由系統化的設計步驟所設計出之最適化的反應性蒸餾系統套用一控制架構進行動態模擬。模擬結果證明在合理地濃度範圍及流量擾動之下，我們能夠獲得較佳的控制結果。 | zh_TW |
| dc.description.provenance | Made available in DSpace on 2021-06-13T16:26:51Z (GMT). No. of bitstreams: 1 ntu-94-R92524050-1.pdf: 3356590 bytes, checksum: 4e0c47ee86d772ed1469a5c4205acd98 (MD5) Previous issue date: 2005 | en |
| dc.description.tableofcontents | 致 謝 I
摘 要…………………………………………………………………………….....II ABSTRACT IIII 目 錄 IV 圖索引 VI 表索引 VIII 1 緒論（INTRODUCTION） 1 1.1 前言 1 1.2 文獻回顧 3 1.3 研究動機與目的 5 1.4 組織章節 6 2 化學路徑（PROCESS CHEMISTRIES） 9 2.1 程序選擇 9 2.2 乙酸甲酯製程 10 2.2.1 液相使用之熱力學模式 11 2.2.2 氣相使用之熱力學模式 12 2.2.3 兩相區分布之探討 13 2.2.4 乙酸甲酯反應系統之蒸餾曲線圖分析 14 2.2.5 乙酸甲酯反應系統之動力學分析 17 2.3 乙酸戊酯系統製程 19 2.3.1 液相使用之熱力學模式 20 2.3.2 氣相使用之熱力學模式 20 2.3.3 兩相區分布之探討 21 2.3.4 乙酸戊酯反應系統之蒸餘曲線圖分析 22 2.3.5 乙酸戊酯反應系統動力學模式分析 27 3 穩態設計（STEADY STATE DESIGN） 30 3.1 程序設計選擇性 (DESIGN ALTERNATIVES) 30 3.2 穩態設計之最適化步驟 31 3.3 乙酸甲酯製程 33 3.3.1 無前處理過程 (WITHOUT PRETREATMENT) 之最適化設計 33 3.3.2 前處理過程 (WITH PRETREATMENT) 之最適化設計 35 3.4 乙酸戊酯製程 37 3.4.1 無前處理過程 (WITHOUT PRETREATMENT) 之最適化設計 37 3.4.1.1 100 WT% 濃度醋酸入料之穩態設計結果 38 3.4.1.2 75 WT% 濃度醋酸入料之穩態設計結果 40 3.4.1.3 50 WT% 濃度醋酸入料之穩態設計結果 42 3.4.1.4 30 WT% 濃度醋酸入料之穩態設計結果 44 3.4.2 乙酸戊酯製程無前處理過程之最適化設計探討 46 3.4.3 前處理過程 (WITH PRETREATMENT) 之最適化設計 51 3.4.4 乙酸戊酯製程之無前處理過程與前處理過程之討論與比較 56 4 動態控制模擬（DYNAMICS AND CONTROL） 57 4.1 程序特性 57 4.2 控制系統設計 62 4.3 乙酸戊酯製程之動態控制模擬 64 4.3.1 雙溫度控制 64 4.3.1.1 溫度靈敏度測試分析 65 4.3.1.2 非方形相對增益 67 4.3.1.3 控制器參數協調方法 68 4.3.1.4 雙溫度控制動態模擬結果 70 4.3.2 一溫度及一組成控制 78 4.3.2.1 一溫度及一組成控制動態模擬結果 79 4.3.3 非線性分析結果與討論 83 5 結論 85 參 考 文 獻 87 附錄 A 95 | |
| dc.language.iso | zh-TW | |
| dc.subject | 反應蒸餾 | zh_TW |
| dc.subject | reactive distillation | en |
| dc.title | 利用反應性蒸餾系統進行稀醋酸之酯化反應：化學路徑、程序設計與控制 | zh_TW |
| dc.title | Process Chemistries, Design Alternatives and Control for Recovery of Dilute Acetic Acid through Esterification in Reactive Distillation | en |
| dc.type | Thesis | |
| dc.date.schoolyear | 93-2 | |
| dc.description.degree | 碩士 | |
| dc.contributor.oralexamcommittee | 黃孝平,陳誠亮,錢義隆,周宜雄 | |
| dc.subject.keyword | 反應蒸餾, | zh_TW |
| dc.subject.keyword | reactive distillation, | en |
| dc.relation.page | 97 | |
| dc.rights.note | 有償授權 | |
| dc.date.accepted | 2005-07-15 | |
| dc.contributor.author-college | 工學院 | zh_TW |
| dc.contributor.author-dept | 化學工程學研究所 | zh_TW |
| 顯示於系所單位： | 化學工程學系 | |
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