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http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/37988完整後設資料紀錄
| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 謝國煌(Kuo-Huang Hsieh) | |
| dc.contributor.author | Cheng-Hsiu Ku | en |
| dc.contributor.author | 辜政脩 | zh_TW |
| dc.date.accessioned | 2021-06-13T15:55:07Z | - |
| dc.date.available | 2010-06-24 | |
| dc.date.copyright | 2008-06-24 | |
| dc.date.issued | 2008 | |
| dc.date.submitted | 2008-06-17 | |
| dc.identifier.citation | chapter 1
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| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/37988 | - |
| dc.description.abstract | 有機發光二極體將於下一個顯示器世代佔有一席之地，所以藉由不斷的材料改進與製程進步來提升此種顯示器的效率發光亮度以及壽命。本論文主要致力於合成良好的電洞注入及傳輸材料以提升發光元件的效能以及性質，並將此系列的電洞傳輸材料分子運用在有機電激發光元件中，試驗其作為電洞注入層及電洞傳輸層的性質並加以探討。且藉由不同製程方法提升元件表現 (1) 將所合成出的電洞傳輸單體利用表面修飾製程於玻璃基板上形成薄膜電洞傳輸層、(2) 利用真空蒸鍍的製程將所合成出的電洞傳輸層材料於共蒸鍍條件下形成電洞傳輸層以提升元件亮度、並利用共蒸鍍方法做為磷光與螢光發光材主體 (3) 藉由旋轉塗佈法均勻的修飾玻璃基板，將合成出的高分子材料是具有電洞傳輸性質的具羥基之卡唑衍生物和三苯基胺衍生物依不同比例以二異氰酸酯連接成聚氨酯型態，與以具羥基之卡唑衍生物以及具有電洞阻擋性質和電子傳輸性質的噁唑衍生物依不同比例以二異氰酸酯連接成聚氨酯型態共聚合物形成電洞傳輸層。聚氨酯本身結構即具有良好的電洞傳輸效果並於電激發光元件中，讓元件發光效率及亮度有效提升。 | zh_TW |
| dc.description.abstract | There are many kinds of pathway to improve the OLED or PLED device performance. In this thesis, hole-transporting materials were been focused subject and different routes were also been provided, including using surface modified method technology to do the modification on ITO glass surface by using oligo (phenylene vilyene) silane as hole transporting layer in chapter 2, synthesized the 9-(4-pentaphenylphenylphenyl)-9H-carbazole and co-evaporated with α-NPB function as hole transporting material and host in chapter 3 and functionalized Polyurethanes containing carbazole, OXD and Triphenylamine-derived for hole-transporting material in OLED device in chapter 4, 5. New polymers and organic materials were used as the hole transport layer (HTL) to improve the device performance. Such materials are not only reduced the driving voltage but also improve the current efficiency. We also observed that the current efficiency in the device is increased due to more carrier injection and better electron-hole balance. | en |
| dc.description.provenance | Made available in DSpace on 2021-06-13T15:55:07Z (GMT). No. of bitstreams: 1 ntu-97-D92549006-1.pdf: 3256093 bytes, checksum: 2a57df3a8e82136438ae2b210efe0f90 (MD5) Previous issue date: 2008 | en |
| dc.description.tableofcontents | 摘要...…………………….....…………………………………………………….…2
Abstract…...……………………………………………………………………..…..3 Chapter 1 Introduction of Organic Light Emitting Diode 1-1 Classification of Organic Light Emitting Device………………………….…..11 1-2 Principles of Organic electroluminescence and OLED device structure….…..12 1-3 Energy Transfer Mechanism in PLED……………………….………………..25 1-4 Hole-transporting and Injecting Materials……..……………. ...…………..…29 1-5 Reference of introduction…………………………………....………………..34 Chapter 2 Modification on ITO Glass Surface by Using Oligo (phenylene vinylene)silane as Hole Transporting Layer in Organic Light Emitting Diode Devices 2-1 Introduction……………………………………………………………….……38 2-2 Experimental part………………………………………………………...….…41 2-3 Results and discussion…………………………………………………….……46 2-4 Conclusion……………………………………………………………….……..56 2-5 Reference………………………………………………………………….……57 Chapter 3 Synthesis of 9-(4-pentaphenylphenylphenyl)-9H-carbazole for Hole-Transporting Material and Host in OLED Device 3-1 Introduction……………………………………………………………….……61 3-2 Experimental…………………………………………………………………...63 3-3 Results and discussion …………………………...……………………………67 3-4 Conclusion……………………………………………………….…………….84 3-5 Reference………………………………………………………………………84 Chapter 4 Carbazole Containing Polyurethanes as Hole-Transport Layer for Organic Light Emitting Diodes 4-1 Introduction……………………………………………………………….……87 4-2 Results and discussion…………………………………………………….……91 4-3 Conclusion……………………………………………………………………..116 4-4 Experimental Section…………………………………………………………..116 4-5 Reference………………………………………………………………………124 Chapter 5 Containing Triphenylamine-Derived Polyurethanes as Hole-Transporting Layers Exhibit High Current Efficiencies in PLED Devices 5-1 Introduction……………………………………………………………………130 5-2 Results and Discussion ..………………………………………………………133 5-3 Conclusion……………………………………………………………………..149 5-4 Experimental Section .…………………………………………………………149 5-4 Reference …..…………………………………………………………….…….158 Chapter 6 Tunable Color Devices of Fluorene-Based Polymers for Light Emitting Diodes 6-1 Introduction………………………………………………………………..…...161 6-2 Experimental Section……………………………………………………..……163 6-3 Results and Discussion…………………………………………………..……..172 6-4 Conclusion………………………………………………………………..…….188 6-5 Reference…………………………………………………………………..…...189 Appendix ………………………………………………………………………..…192 | |
| dc.language.iso | zh-TW | |
| dc.subject | 噁唑 | zh_TW |
| dc.subject | 有機發光二極體 | zh_TW |
| dc.subject | 聚氨酯 | zh_TW |
| dc.subject | 電洞傳輸 | zh_TW |
| dc.subject | 三苯基胺衍生物 | zh_TW |
| dc.subject | Polyurethanes | en |
| dc.subject | Triphenylamine | en |
| dc.subject | OLED | en |
| dc.subject | Carbazole | en |
| dc.subject | Hole-transporting | en |
| dc.title | 聚氨酯共聚高分子於電激發光元件之電洞傳輸層應用 | zh_TW |
| dc.title | Synthesis of Polyurethane Based Hole-Transporting Materials and Application for Organic Light Emitting Diode | en |
| dc.type | Thesis | |
| dc.date.schoolyear | 96-2 | |
| dc.description.degree | 博士 | |
| dc.contributor.coadvisor | 梁文傑(Man- Kit Leung) | |
| dc.contributor.oralexamcommittee | 王立義(Lee Yi WANG),李君浩(Jiun-Haw Lee),韓錦鈴(Jin-lin Han) | |
| dc.subject.keyword | 有機發光二極體,聚氨酯,電洞傳輸,三苯基胺衍生物,噁唑, | zh_TW |
| dc.subject.keyword | OLED,Polyurethanes,Hole-transporting,Triphenylamine,Carbazole, | en |
| dc.relation.page | 245 | |
| dc.rights.note | 有償授權 | |
| dc.date.accepted | 2008-06-17 | |
| dc.contributor.author-college | 工學院 | zh_TW |
| dc.contributor.author-dept | 高分子科學與工程學研究所 | zh_TW |
| 顯示於系所單位： | 高分子科學與工程學研究所 | |
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