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| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 林江珍 | |
| dc.contributor.author | Yi-Lin Liao | en |
| dc.contributor.author | 廖一驎 | zh_TW |
| dc.date.accessioned | 2021-06-13T15:51:56Z | - |
| dc.date.available | 2013-07-24 | |
| dc.date.copyright | 2008-07-24 | |
| dc.date.issued | 2008 | |
| dc.date.submitted | 2008-06-24 | |
| dc.identifier.citation | [1]Okada, A.; Usuki, A. Mater. Sci. Eng. C. 1995, 3, 109.
[2]Okada, A.; Usuki, A. Macromol. Mater. Eng. 2006, 291, 1449. [3]LeBaron, P. C.; Wang, Z.; Pinnavaia, T. J. Appl. Clay Sci. 1999, 15, 11. [4]Alexandre, M.; Dubois, P. Mater. Sci. Eng. R-Rep. 2000, 28, 1. [5]Ray, S. S.; Okamoto, M. Prog. Polym. Sci. 2003, 28, 1539. [6]Utracki, L. A.; Sepehr. M.; Boccaleri, E. Polym. Adv. Technol. 2007, 18, 1. [7]Lin, J. J.; Cheng, I, J.; Wang, R.; Lee, R. J. Macromolecules 2001, 34, 8832. [8]Chou, C. C.; Shieu, F. S.; Lin, J. J. Macromolecules 2003, 36, 2187. [9]Lin, J. J.; Hsu, Y. C.; Chou, C. C. Langmuir 2003, 19, 5184. [10]Lin, J. J.; Chen, Y. M. Langmuir 2004, 20, 4261. [11]Chou, C. C.; Chang, Yu. Chung.; Chiang, M. L.; Lin, J. J. Macromolecules 2004, 37, 473. [12]Lin, J. J.; Juang, T. Y. Polymer 2004, 45, 7887. [13]Chang, Y. C.; Chou, C. C.; Lin, J. J. Langmuir 2005, 21, 7023. [14]Lin, J. J.; Chen, I. J.; Chou, C. C. Macromol. Rapid Commun. 2003, 24, 492 [15]Lin, J. J.; Chou, C. C.; Lin, J. L. Macromol. Rapid Commun. 2004, 25, 1109. [16]Lin, J. J.; Chang, Y. C.; Cheng, I. J. Macromol. Rapid Commun. 2004, 25, 508. [17]Chou, C. C.; Chiang, M. L.; Lin, J. J. Macromol. Rapid Commun. 2005, 26, 1841. [18]Lin, J. J.; Chen, Y. M.; Yu, M. H. Colloid Surf. A-Physicochem. Eng. Asp. 2007, 302 , 162. [19]Lin, J. J.; Chu, C. C.; Chiang, M. L.; Tsai, W. C. J. Phys. Chem. B. 2006, 110, 37. [20]Chiu, C. W.; Chu, C. C.; Cheng, W. T.; Lin, J. J. Eur. Polym. J. 2008, 44, 628. [21]Newman, S. P.; Jones, W. New J. Chem. 1998, 105. [22]Du, N.; Hou, W. G.; Song, S. E. J. Phys. Chem. B. 2007, 111, 13909. [23]Leroux, E.; Besse, J. P. Chem. Mater. 2001, 13, 3507. [24]Choy, J. H.; Kwak, S. Y.; Jeong, Y. J.; Park, J. S. Angew. Chem. Int. Ed. 2000, 39, 4041. [25]Choy, J. H.; Choi, S. J.; Oh, J. M.; Park, T. Appl. Clay Sci. 2007, 36, 122. [26]Giannelis, E. P.; Krishnamoorti, R.; Manias, E. Adv. Polym. Sci. 1999, 118, 108. [27]Wang, H.; Zhao, T.; Zhi, L.; Yan, Y.; Yu, Y. Macromol. Rapid Commun. 2002, 23, 44. [28]Tateyama, H.; Nishimura, S.; Tsunematsu, K.; Jinnai, K.; Adachi, Y.; Kimura, M. Clays and Clay Minerals, 1992, 40, 180. [29]Kodama, T.; Higuchi, T.; Shimizu, T.; Shimizu, K.; Komarneni, S.; Hoffbauer, W.; Schneider, H. J. Mater. Chem. 2001, 11, 2072. [30]Chaiko, D. J. Chem. Mater. 2003, 15, 1105. [31]Podsiadlo, P.; Kaushik, A. K.; Arruda, E. M.; Waas, A. M.; Shim, B. S.; Xu, J.; Nandivada, H.; Pumplin, B. G.; Lahann, J.; Ramamoorthy, A.; Kotov, N. A. Science. 2007, 318, 80. [32]Zur, F. W. Helv. Chim. Acta 1942, 25, 106. [33]Miyata, S.; Kumura, T. US Patent 3,796,792, 1974. [34]Kameda, T.; Satio, S.; Umetsu, Y. Sep. Purif. Technol. 2005, 47, 20. [35]Carlino, S. Solid State Ion. 1997, 98, 73. [36]Miyata, S.; Kumura, T. Chem. Lett, 1973, 843. [37]Reichle, W. T. J. Catal. 1985, 547, 94. [38]Kantam, M. L.; Ravindra, A.; Reddy, C. V.; Screedhar, B.; Choudary, B. M. Adv. Synth. Catal. 2006, 348, 569. [39]Wang, L.; Li, C.; Liu, M.; Evans, D. G.; Duan, Xue. Chem. Commun, 2007, 123. [40]Iyi, N.; Ebina, Y.; Sasaki, T. Langmuir, 2008, 24, 5591. | |
| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/37933 | - |
| dc.description.abstract | 本論文以聚醚胺(poly(oxypropylene)-amine)與馬來酸酐(maleic anhydride)合成插層劑poly(oxypropylene)-bis-amidoacids (POAs)，對人工合成的陰離子型黏土水滑石(LDH)進行改質，探討其反應機制，並與實驗室早期已發表的陽離子型黏土(蒙脫土、雲母)比較。
(1)一系列POAs插層水滑石，經由不同極性鏈段的POAs改質會有不同的性質的結果。隨著POP-amidoacids分子量的增加而層間距提升，最高可將水滑石層間撐開至XRD 94 Å之高層間距。 (2)隨著POP2000-2MA-2Na量的增加，水滑石層間變化會有個臨界點，超出此臨界點層間距會瞬間增大，利用此機制可輕易控制分子在層間的型態改變。 (3)經由POP2000-2MA-Na改質後的有機黏土具有雙性性質，為一新穎的有機無機界面活性劑，在臨界微胞濃度下(CMC=0.01wt%)可使甲苯/水的界面張力降低至4.5 mN/m。 (4)以同一類型插層劑對此三種不同類型黏土做比較，有別於傳統離子交換改質的黏土，新的改質機制包含氫鍵力及螯合分別作用在不同類型的黏土上(水滑石，蒙脫土和雲母)。 (5)有機改質的水滑石複材具有酸鹼應答特性，其層狀結構可在較低pH的環境下分解並釋放出層間有機物，此黏土複材同時具有溫度敏感特性，可在低溫下分散(5~10 oC)，高溫下聚集(＞20 oC)。結合上述特性，此有機水滑石可應用在藥物釋放等生醫工程上。 | zh_TW |
| dc.description.abstract | This thesis concerns the organic modification for the Mg–Al layered double hydroxides (LDHs), more specifically, the intercalation profile of the clay with a series of poly(oxypropylene)-bis-amidoacids (POAs).
A number of important issues are included in the thesis. (1)The intercalation of LDH by the POP-amidoacids and the spatial enlargement of the gallery up to 94 Å d spacing. (2)The critical intercalation of using the POP2000-2MA-2Na for expanding the LDH gallery. It provides a new way for manipulating nanomaterials and control of polymer conformations in the LDH confinement. (3)The amphiphilic property of POP2000-2MA-Na/LDH hybrid and their ability of lowering the toluene/water interfacial intension to 4.5 mN/m at the critical micelle concentration (CMC) of 0.01 wt%. (4)Newly discovered mechanisms that involving hydrogen-bonding and chelation. The different clays such as LDH, MMT and Mica are compared for the generality of the new mechanisms. (5)A pH dependence of the organo-LDH hybrids that particularly occurrence of layered structure collapse at low pH environment. The implication is an application of organic encapsulation and control release that could be developed for such a clay hybrid. In addition, the hybrids also possess thermal-sensitivity, that allows a fine dispersion at low temperature (5~10 oC) and aggregation at higher temperature (＞20 oC). | en |
| dc.description.provenance | Made available in DSpace on 2021-06-13T15:51:56Z (GMT). No. of bitstreams: 1 ntu-97-R95549001-1.pdf: 896049 bytes, checksum: afeb5a4f0db002766776ee08e4e39998 (MD5) Previous issue date: 2008 | en |
| dc.description.tableofcontents | 口試委員會審定書 i
Acknowledgement ii Abstract (English) iii Abstract (Chinese) v Chapter 1. Introduction 1 Chapter 2. Literature review 4 2-1. Layered silicate 4 2-2. Intercalation profile for organically modified layered silicate 6 2-3. Layered double hydroxides 12 2-3-1. Synthesis of organo-LDHs 13 2-3-2. Application of LDH complexes 15 Chapter 3. Experimental section 19 3-1. Materials 19 3-2. Experimental Process 21 3-2-1. Preparation of Mg2Al-NO3-LDH 21 3-2-2. Synthesis of Poly(oxyalkylene)-bis-amidoacids(POA) as intercalating agent 21 3-2-3. Intercalation of LDH by POA-xNa 23 3-2-4. Chelation of layered silicate by POA 23 3-3. Instrument 24 Chapter 4. Results and Discussion 25 4-1. Correlation between LDH basal spacing and intercalating agents 25 4-2. Critical conformation change of POP2000-2MA/LDH 28 4-3. Comparison between POP2000-2MA-Na/LDH and POE2000-2MA-Na/LDH in interfacial tensions 31 4-4. Correlation between LDH basal spacing and Basification Ratio of POP2000-2MA 33 4-5. Comparison of intercalation among LDH, MMT and Mica with the same intercalating agents 38 4-6. pH-sensitivity of POP2000-2MA/LDH, POP2000-2MA/MMT and POP2000-2MA/Mica 39 4-7. Thermal-sensitivity of POP2000-2MA/LDH in water 41 Chapter 5. Conclusion 44 Chapter 6. Reference 46 | |
| dc.language.iso | zh-TW | |
| dc.subject | 酸鹼溫度敏感性 | zh_TW |
| dc.subject | 水滑石 | zh_TW |
| dc.subject | 聚醚醯胺酸 | zh_TW |
| dc.subject | 插層 | zh_TW |
| dc.subject | 氫鍵 | zh_TW |
| dc.subject | poly(oxypropylene)-bis-amidoacids | en |
| dc.subject | Layered Double Hydroxides (LDH) | en |
| dc.subject | intercalation | en |
| dc.subject | hydrogen-bonding | en |
| dc.subject | pH- and thermal-sensitivity | en |
| dc.title | 聚醚醯胺酸插層之層狀水滑石與特性研究 | zh_TW |
| dc.title | Research of Poly(oxyalkylene)-bis-amidoacids Intercalated Layered Double Hydroxides | en |
| dc.type | Thesis | |
| dc.date.schoolyear | 96-2 | |
| dc.description.degree | 碩士 | |
| dc.contributor.oralexamcommittee | 何國川,謝國煌 | |
| dc.subject.keyword | 水滑石,聚醚醯胺酸,插層,氫鍵,酸鹼溫度敏感性, | zh_TW |
| dc.subject.keyword | Layered Double Hydroxides (LDH),poly(oxypropylene)-bis-amidoacids,intercalation,hydrogen-bonding,pH- and thermal-sensitivity, | en |
| dc.relation.page | 48 | |
| dc.rights.note | 有償授權 | |
| dc.date.accepted | 2008-06-25 | |
| dc.contributor.author-college | 工學院 | zh_TW |
| dc.contributor.author-dept | 高分子科學與工程學研究所 | zh_TW |
| 顯示於系所單位： | 高分子科學與工程學研究所 | |
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