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完整後設資料紀錄
DC 欄位 | 值 | 語言 |
---|---|---|
dc.contributor.advisor | 邱文英 | |
dc.contributor.author | Kai-Chi Chang | en |
dc.contributor.author | 張凱齊 | zh_TW |
dc.date.accessioned | 2021-06-13T06:37:21Z | - |
dc.date.available | 2005-10-18 | |
dc.date.copyright | 2005-10-18 | |
dc.date.issued | 2005 | |
dc.date.submitted | 2005-10-08 | |
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2. A. Sultan Nasar, S. Subramani, Ganga Radhakrishnan “Journal of Polymer Science” Part A: Polymer Chemistry, Vol. 37, 1815–1821 (1999) 3. Sudipta Mohanty, N. Krishnamurti “Synthesis and thermal deblocking of blocked diisocyanate adducts” Eur. Polym. J. Vol. 34, No. 1, pp. 77-83, 1998. 4. Norbert Moszner, Frank Zeuner, Jorg Angermann, Urs Karl Fisher, Volker Rheinberger, ``Synthesis and Radical Polymerization of Hydrolytically Stable Crosslinking Monomers.”, Macromolecular Materials and Engineering, 2003, 288,621-628. 5. S.Lelu, C. Novat, C. Graillat, A. Guyot, and E.Bourgeat-Lami.``Encapsulation of an organic phthalocyanine blue pigment into polystyrene latex particles using a miniemulsion polymerization process’’, Polymer International, 542-547,(2003). 6. Decker, C., UV-radiation curing chemistry. Pigment & Resin Technology, 30(5): p.278-286. (2001) 7. 日本化學會編, 化學便覽, p.114.(1975) 8. 劉瑞祥 編譯, 光聚合性組成型, 感光性高分子, p. 256-295.(1992) 9. Martin, B., UV Curing: Science and Technology, Vol.II, p.109-140.(1985) 10. Allan, N.S., Chemistry & Technology of UV & EB Formulations for Coatings, Inks & Paints,Vol II, p.37-134.(1991) 11. J. P. Fouassier, J.F.R., Radiation Curing in Polymer Science and Technology Vol.2 Photoinitiating systems, p.1-58.(1993) 12. 石井孝雄, 塗裝與塗料, p. 135.(1975) 13. J. P. Fouassier, et al, Radiation Curing in Polymer Science and Technology Vol.3 Polymerisation Mechanisms, p.1-32.(1993) 14. J. P. Fouassier, et al, Radiation Curing in Polymer Science and Technology,Vol.1 Elsevier Applied Science, p. 186.(1993) 15. 陳暉, UV硬化技術入門(一),高分子工業, 34, p.65.(1985) 16. Pavia, D.L., Ch2.Infrared Spectroscopy. Introduction to Spectroscopy ,3rd ed, p. 13-101.(2001) 17. Cheatham, C.M., et al., Kinetics of trifluorovinyl ether cyclopolymerization via Raman spectroscopy. Polymer International, 46(4): p. 320-324.(1998) 18. Grunden, B.L. and C.S.P. Sung, Cure monitoring of an unsaturated polyester resin by near-infrared spectroscopy. Abstracts of Papers of the American Chemical Society, 215,p. U360-U361.(1998) 19. Abdel-Fattah, A.A., et al., Ultraviolet and infrared spectral analysis of irradiated polyethylene films: Correlation and possible application for large-dose radiation dosimetry. Journal of Applied Polymer Science, 67(11), p. 1837-1851.(1998) 20. Belfield, K.D. and S. Pichandi, FT-IR study of UV and visible photoinitiated polymerization of 4-methylenedioxolanes. Abstracts of Papers of the American Chemical Society, 215, p.U378-U378.(1998) | |
dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/34945 | - |
dc.description.abstract | 本實驗首先以具有黃色染料加入IPDI。染料上的一級胺基(-NH2)會與IPDI上的異氰酸基(-NCO)產生合成反應。再加入HEMA。HEMA上的氫氧基會和IPDI上剩下的異氰酸基繼續進行合成反應。第二部分以具有氫氧基(-OH)的epoxy acrylate加入IPDI進行反應,再接上黃色染料。經由這樣的過程,可以將原本的染料合成為具有碳碳雙鍵的反應性染料。由改變不同的反應物,來增加每分子反應性染料的官能基數,進而提高含反應性染料光阻劑在UV光硬化時的交聯度。
兩種反應性染料再搭配上oligomer、binder和光起始劑,配成含反應性染料光阻劑。藉由改變不同的配方、各配方不同的比例以及不同的曝後烤溫度,觀察對光阻劑之光硬化膜的色彩度、耐溶性、耐鹼性以及耐酸性的影響。 | zh_TW |
dc.description.abstract | In this research, we used yellow dye to add IPDI. The first amine group of dye was synthesized with the isocyanate group of IPDI, then add HEMA. The hydroxy group of HEMA was synthesized with the rest isocyanate group of IPDI. Second, we used epoxy acrylate to added IPDI. The isocyanate group of IPDI was synthesized with the hydroxy group of epoxy acrylate. It synthesized yellow dye later. In these processes, we can synthesize yellow dye to converse reactive dye that contains CC double bonds. With changing the reactant, the function groups of reactive dye were increased. That as well as can increase the functionality of photoresist with reactive dye after UV curing.
Afterward this reactive dye was diluted in monomer, oligomer, solvent, and photoinitiator to formulate color photo-resists. With changing the different composition, different ratio and the different temperature of post-baking, the color degree of the color photo-resists and the properties of chemical, basic and acidic resistance were observed. | en |
dc.description.provenance | Made available in DSpace on 2021-06-13T06:37:21Z (GMT). No. of bitstreams: 1 ntu-94-R92524079-1.pdf: 1480239 bytes, checksum: 6b6c63bae65445488f4cebc73eab638a (MD5) Previous issue date: 2005 | en |
dc.description.tableofcontents | 中文摘要 I
Abstract II 表目錄 VII 圖目錄 IX 第一章 緒論 1 第二章 文獻回顧 3 2-1 染料改質 3 2-2 紫外光硬化(UV curable)簡介 7 2-3 紫外光硬化樹脂之組成 8 2-4 紫外光的作用及用途 14 2-5 紫外光硬化反應機構 15 2-6 影響紫外光硬化之因素 18 第三章 實驗方法 20 3-1 實驗藥品 20 3-2 實驗儀器 24 3-3 實驗過程與製備流程 27 3-3.1合成反應一 27 3-3.2合成反應二 27 3-3.3 UV曝光 28 3-4 測試方法 29 3-4.1 FTIR量測 29 3-4.2層析試驗 29 3-4.3 耐溶、耐酸、耐鹼性測試 29 3-4.4 黏度測試 30 3-4.5 膜厚測試 30 第四章 結果與討論 31 4-1 使用染料Y1、IPDI和HEMA合成反應性染料 31 4-1.1染料Y1、IPDI和HEMA的合成反應 31 4-1.2 利用FTIR觀察反應情形 32 4-1.3 反應產物層析試驗 33 4-1.4 不同比例的洗滌液所得到的分離後產物比例 34 4-1.5 NMR分析 34 4-2 不同配方的含反應性染料光阻劑在光硬化成膜後的性質討論一 34 4-2.1不同比例的洗滌液對成膜性質的影響 35 4-2.2 增加Urethane acrylate 88對膜的性質產生的影響 37 4-2.3 改變不同的binder 38 4-2.4 增加光起始劑 39 4-2.5 使用不同oligomer的比較 40 4-2.6 TGA分析 42 4-2.7 使用反應性染料一號的結論 42 4-3使用Epoxy Acrylate、IPDI和染料Y1合成反應性染料 42 4-3.1 Epoxy Acrylate、IPDI和染料Y1的合成反應 42 4-3.2 利用FTIR觀察反應情形 44 4-3.3 洗滌分離 45 4-3.4 NMR分析 45 4-4 不同配方的含反應性染料光阻劑在光硬化成膜後的性質討論二 45 4-4.1 比較使用不同反應性染料對膜性質產生的影響 45 4-4.2 增加溶劑對膜性質產生的影響 47 4-4.3改變不同的溶劑對膜性質產生的影響 48 4-4.4 對照組試驗 49 4-4.5 增加反應性染料對膜性質產生的影響 51 4-4.6 改變不同的oligomer對膜性質產生的影響 52 4-4.7 改變不同的曝後烤溫度對膜性質產生的影響 53 4-4.8 改變不同的光起始劑對膜性質產生的影響 55 4-4.9 減少Urethane acrylate 88對膜性質產生的影響 57 4-4.10 改變光起始劑比例對膜性質產生的影響 58 4-4.11 TGA分析 60 4-4.12 GPC分析 60 4-4.13 含反應性染料光阻劑的黏度與膜厚的關係以及配方中的各種成份與黏度的關係 61 第五章 結論 64 第六章 參考文獻 66 | |
dc.language.iso | zh-TW | |
dc.title | 含反應性染料光阻劑之UV光硬化膜的製備
及性質探討 | zh_TW |
dc.title | Study on the preparation and property of UV curable film of reactive dye-containing photoresist | en |
dc.type | Thesis | |
dc.date.schoolyear | 94-1 | |
dc.description.degree | 碩士 | |
dc.contributor.oralexamcommittee | 謝國煌,戴子安 | |
dc.subject.keyword | 異氰酸基(isocyanate),FTIR,紫外光硬化(UV curable),彩色濾光片(color filter), | zh_TW |
dc.subject.keyword | isocyanate,FTIR,UV curable,color filter, | en |
dc.relation.page | 107 | |
dc.rights.note | 有償授權 | |
dc.date.accepted | 2005-10-12 | |
dc.contributor.author-college | 工學院 | zh_TW |
dc.contributor.author-dept | 化學工程學研究所 | zh_TW |
顯示於系所單位: | 化學工程學系 |
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