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| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 謝國煌 | |
| dc.contributor.author | Hsin-Chung Ke | en |
| dc.contributor.author | 葛興中 | zh_TW |
| dc.date.accessioned | 2021-06-13T05:46:03Z | - |
| dc.date.available | 2009-07-27 | |
| dc.date.copyright | 2006-07-27 | |
| dc.date.issued | 2006 | |
| dc.date.submitted | 2006-07-11 | |
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| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/33782 | - |
| dc.description.abstract | 以9-(五苯代苯)卡唑為核心，利用Suzuki Coupling及Horner-Wadsworth-Emmons反應與不同單體聚合形成高分子P1~P8，並在高分子主鏈中分別掺混2mol%的1,4-bis(2-bromo-phenylenevinylene)benzene(簡稱OPV)與Benzothiadiazole，觀察其對高分子光電性質的影響；共聚高分子由於側鏈中含有五苯代苯而使的分子對稱性降低，轉動自由能提升，使玻璃轉換溫度有明顯的提升，在裂解溫度上也有不錯的表現。此外將合成的高分子進行有機電激發光二極體的元件製作並對其特性加以討論。 | zh_TW |
| dc.description.abstract | Copolymers of carbazole and fluorene with dendrimer side groups were synthesized using Suzuki Coupling and Horner-Wadsworth-Emmons reaction. Furthermore, 2mol% of benzothiadiazole and 1,4-bis(2-bromostyryl)benzene (OPV) were introduced into the copolymers. The effects of these two groups on optical and electrical properties of the copolymers were investigated. Copolymers with dendrimer side groups have higher Tg since the huge side groups make it difficult to rotate and move. At last, polymer light emitting diodes were fabricated and the performance of the devices was thoroughly investigated. | en |
| dc.description.provenance | Made available in DSpace on 2021-06-13T05:46:03Z (GMT). No. of bitstreams: 1 ntu-95-R93549006-1.pdf: 4591774 bytes, checksum: e9235be45508f8ec5a7c4a43c3ae1701 (MD5) Previous issue date: 2006 | en |
| dc.description.tableofcontents | 目錄………………………………………………………………………i
圖目錄…………………………………………………………………iv 表目錄………………………………………………………………viii 中文摘要……………………………………………………………ix 第一章 緒論 1-1 前言‥‥‥‥‥‥‥‥‥‥‥‥‥‥‥‥‥‥‥‥‥1 1-2 發光原理‥‥‥‥‥‥‥‥‥‥‥‥‥‥‥‥‥‥‥4 1-3 元件原理及結構‥‥‥‥‥‥‥‥‥‥‥‥‥‥‥‥5 1-4 有機電激發光材料‥‥‥‥‥‥‥‥‥‥‥‥‥‥‥7 1-4.1高分子發光主體材料‥‥‥‥‥‥‥‥‥‥‥ 7 1-4.2電子傳輸材料‥‥‥‥‥‥‥‥‥‥‥‥‥‥ 9 1-4.3電洞傳輸材料‥‥‥‥‥‥‥‥‥‥‥‥‥‥11 1-5 磷光材料及元件‥‥‥‥‥‥‥‥‥‥‥‥‥13 1-6 研究方向‥‥‥‥‥‥‥‥‥‥‥‥‥‥‥‥16 第二章 實驗部份 2-1 高分子之合成‥‥‥‥‥‥‥‥‥‥‥‥‥‥‥‥18 2-2 實驗儀器及藥品‥‥‥‥‥‥‥‥‥‥‥‥‥‥‥27 2-3 合成步驟‥‥‥‥‥‥‥‥‥‥‥‥‥‥‥‥‥‥30 第三章 結果與討論 3-1 高分子性質之探討‥‥‥‥‥‥‥‥‥‥‥‥‥‥52 3-1.1分子量分析‥‥‥‥‥‥‥‥‥‥‥‥‥‥52 3-1.2光學性質分析 ‥‥‥‥‥‥‥‥‥‥‥‥54 3-1.3熱性質分析‥‥‥‥‥‥‥‥‥‥‥‥‥‥64 3-1.4電化學分析‥‥‥‥‥‥‥‥‥‥‥‥‥‥66 3-2 元件製備與探討‥‥‥‥‥‥‥‥‥‥‥‥‥‥‥69 3-2.1 P1之單層元件製備‥‥‥‥‥‥‥‥‥‥‥71 3-2.2 P2之單層元件製備‥‥‥‥‥‥‥‥‥‥‥76 3-2.3 P3之單層元件製備‥‥‥‥‥‥‥‥‥‥‥83 3-2.4 P4之單層元件製備‥‥‥‥‥‥‥‥‥‥‥86 3-2.5 P5之單層元件製備‥‥‥‥‥‥‥‥‥‥‥91 3-2.6 P6之單層元件製備‥‥‥‥‥‥‥‥‥‥‥97 3-2.7 P7之單層元件製備‥‥‥‥‥‥‥‥‥‥102 3-2.8 P8之單層元件製備‥‥‥‥‥‥‥‥‥‥107 第四章 結論‥‥‥‥‥‥‥‥‥‥‥‥‥‥‥‥‥‥‥‥113 參考文獻‥‥‥‥‥‥‥‥‥‥‥‥‥‥‥‥‥‥‥‥‥115 附錄I:化合物的核磁共振光譜‥‥‥‥‥‥‥‥‥‥‥‥‥‥117 附錄II:P1~P8之CV圖‥‥‥‥‥‥‥‥‥‥‥‥‥‥‥‥‥‥148 附錄III:P1~P8之TGA及DSC圖‥‥‥‥‥‥‥‥‥‥‥‥‥‥158 附錄IV:各元件結構對照表‥‥‥‥‥‥‥‥‥‥‥‥‥‥‥167 | |
| dc.language.iso | zh-TW | |
| dc.title | 以9-(五苯代苯)卡唑為主體之有機電激發光二極體材料的合成與元件製備 | zh_TW |
| dc.title | Synthesis and PLED-Devices Fabrication of Carbazole-Fluorene Copolymer with Dendrimer Side Groups. | en |
| dc.type | Thesis | |
| dc.date.schoolyear | 94-2 | |
| dc.description.degree | 碩士 | |
| dc.contributor.oralexamcommittee | 梁文傑,李君浩 | |
| dc.subject.keyword | 五苯代苯,發光二極體,卡唑, | zh_TW |
| dc.subject.keyword | dendrimer side group,carbazole,PLED, | en |
| dc.relation.page | 169 | |
| dc.rights.note | 有償授權 | |
| dc.date.accepted | 2006-07-13 | |
| dc.contributor.author-college | 工學院 | zh_TW |
| dc.contributor.author-dept | 高分子科學與工程學研究所 | zh_TW |
| 顯示於系所單位： | 高分子科學與工程學研究所 | |
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