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| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 鄭宗記(Tzong-Jih Cheng) | |
| dc.contributor.author | Hsin-Kai Hsu | en |
| dc.contributor.author | 徐信凱 | zh_TW |
| dc.date.accessioned | 2021-06-13T04:22:08Z | - |
| dc.date.available | 2006-07-24 | |
| dc.date.copyright | 2006-07-24 | |
| dc.date.issued | 2006 | |
| dc.date.submitted | 2006-07-22 | |
| dc.identifier.citation | 1. 李志剛。2003。幾丁聚醣複合薄膜的製備與抗菌測試。碩士論文。台北: 淡江大學化工程研究所。
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A., W. L. Salter, A. C. M. Wu and B. E. Perkins. 1978. Influence of manufacturing variables on the characteristics and effectiveness of chitosan products. I. Chemical composition, viscosity, and molecular-weight distribution of chitosan products. Biotechnol. Bioeng. 20: 1931-1939 14. Briones, A V., W. O. Ambal, R. R. Estrella, R. Pangilinan, C. J. D. Vera, R. L. Pacis, N. Rodriguez and M. A. Villanueva. 2004. Tensile and Tear Strength of Carragenan Film from Philippine Eucheuma Species. Marine Biotechnalocy. 6: 148-151. 15. Chen, P. C., B. C. Hsieh, R. L.C. Chen, T. Y. Wang, H. Y. Hsiao, T. J. Cheng. 2005. Characterization of natural chtiosan membranes from the carapace of the soldier crab Mictyris brevidactylus and its application to immobilize glucose oxidase in amperometric flow-injection biosensing system. Bioelectrochemistry. 68: 73-81. 16. Davis, D. H. and E. R. Hayes. 1988. Determination of the degree of acetylation of chitin and chitosan. Method in Enzymoloy. 161: 442-446. 17. Ignaciog, C., A. F. Robert and A. C. Paul. 1982. Bioconversion of shellfish chitin waste pretreatment, enzyme production, process design and economic analysis. J. Food Sic. 47: 901-908. 18. Hsiao, H. Y., C. C. Tsai, S. Chen, B. C. Hsieh, R. L.C. Chen. 2004. Spectrophotometric Determination of Deacetylation Degree of Chitosan Materials Dissolved in Phosphoric Acid. Macromolecular Bioscience, 4: 919-921. 19. Hsieh B. C., T. J. Cheng, T. Y. Wang and R. L. C. Chen. 2003. Use of Chitosan Membrane from the Carapace of the Soldier Crab Mictyris brevidactylus for Biosensor Construction. Marine Biotechnology, 5: 119-125. 20. Ikeda, I. S. M., K. Youshida, E. Sasaki, Y. Iwamoto and K. Hatano. 1993. Effects of chitosan hydrolysates on lipid absorption and on serum and liver lipid concernation in rats. J. Agric. Food Chem. 41: 431-435. 21. Jha, I. N., L. Iyenganr and A. V. S. Prabhakara Rao. 1988. Removal of cadmium using chitosan. J. Environ. Eng. 11: 962-966. 22. Jiang, X., L. Chen, W. Zhong. 2003. Carbonhydr. Polym. 54: 457. 23. Katherine, Y. W., A. M. Creber, B. Peppley, V. Tam Bui. 2002. Ionic conductivity of chitosan membranes. Polymer. 44: 1057-1065. 24. Knoor, D. 1982. Functional properties of chitin and chitosan. J. Food Sci. 47: 593-598. 25. Knoor, D. 1983. Dye binding properties of chitin and chitosan. J. Food Sci. 48: 36-41. 26. Knoor, D. 1984. Used of chitious polymers in food-A challenge for food research and development. Food Technology. 1: 85-97. 27. Krajewska, B.. 2005. Membrane-based processes performed with use of chitin/chitosan materials. Separation Purification Technology 41: 305-312. 28. Lang, E. R., C. A. Kienzle-Sterzer, D. Rodriqueiz-Sanchez, C. K. Rha. 1982. Rheological behavior of a typical random coil polyelectrolyte: Chitosan. In Chitin and Chintosan, Proceedings of the Second International Conference on Chitin and Chitosan. S. Hirano, and S. Tokura, (ed). The Japanese Society of Chitin and Chitosan. Plenum Press, Sapporo, Japan. pp: 34-38. 29. Lepri, L., P. G. Desideri, V. Coas. 1978. Separation and identification of water-soluble food dyes by ion-exchange and soap thin-layer chromatography. J Chromatogr. 161: 279-86. 30. Leuba, J. L. and P. Stossel. 1986. Chitosan and other polyamines: Antifungal activity and interaction with biological membranes. In Chitin in Nature and Technology . R. A. A. Muzzarelli, C. Jeuniaux, and G. W. Gooday. Pleunm Press, New York, USA. pp: 215-222. 31. Madihally, S. V., H. W. T. Matthew. 1999. Porous chitosan scaffolds for tissue engineering. Biomaterials 20: 1133-1142. 32. Mima, S., M, Miya, R. Iwamoto and S. Yoshikawa. 1983, Highly deacetylated chitosan and its properties. J. Appl. Polym. Sci. 28: 1909-1917. 33. Mitani, T., A. Moriyama and H. Ishii. 1992. Heavy metal uptake by swollen chitosan beads. Bioscience Biotechol. Biochem. 56: 985-991. 34. Nil. 1996. Market of chitin and chitosan. Biol. Industry 13(3): 52-61. 35. Peniche, C., W. Argüelles-Monal, H. Peniche , N. Acosta. 2003. Chitosan: An Attractive Biocompatible Polymer for Microencapsulation. Macromol. Biosci. 3: 511-520. 36. Ravindra, R., K. R. Krovvidi and A. A. Khan. 1988. Solubility parameter of chitin and chitosan. Carbohydrate Polymers 36: 121-127. 37. Roberts, G. A. F. 1992. Chitin Chemistry. Macmillian Press Ltd., London, UK. P: 350. 38. Roberts, G. A. F. 1995. Structure property relationships in chitin and chitosan . In Chitin and Chitosan – The Versatile Environmental Friendly Modern Materials. M. B. Zakaria, W. M. W. Muda and M. P. Abdullah(ed.). Penerbit University Kebangsaan. Malaysia Bangi. pp: 99-108. 39. Sannan, T., K. Kurita and Y. Iwakura. 1976. Studies on chitin 2: Effect of deacetylation on solubility. Makromolekulare Chemie. 177: 3589-3600. 40. Sato, H., S. I. Mizutani and S. Tsuge. 1998. Determination of the degree of acetylation of chitin/ chitosan by pyrolysis- gas chromatography in the presence of oxalic acid. Analytical Chemistry. 70(1): 7-12. 41. Shigemasa, Y., K. Saito, H. Sashiwa and H. Saimoto. 1994 . Enzymatic degradation of chitins and partially deacetylated chitins. Int. Biol. Macromol. 16: 43-49. 42. Shih, J. T. 1995. Population Densities and Annual Activities of Mictyris brevidactylus (Stimpson, 1858) in the Tanshui Mangrove Swamp of Northern Taiwan. Zoological Studies 34(2): 96-105. 43. Sinh, D. K., A. R. Ray. 1998. Characterization of grafted chitosan films. Carbohydrate Polymers 36: 251-255. 44. Soto-Peralta, N. V., H. Muller and D. Knorr. 1989. Effect of chitosan treatments on the clarity and color of apple. J. Food Sci. 54: 495-502. 45. Sugawara, K., T. Takano, H. Fukushi, S. Hoshi, K. Akatsuka, H. Kuramitz, S. Takana. 2000. Glucose sensing by a carbon-paste electrode containing chitin modified with glucose oxidase. J Electroanal Chem. 482: 81-86. 46. Tsai, G. J., W. H. Su and S. C. Chen. 2002. Antimicrobial activity of shrimp chitin and chitosan from different treatments and application to fish preservation. Fisheries Sci. 68: 170-177. 47. Vasconcelos, C. L., A. N. L. Rocha, M. R. Pereira and J. L. C. Fonseca. 2001. Electrolyte diffusion in a chitosan membrane. Society of Chemical Industry. Polymer International. 50: 309-312. 48. Wu, L. Q., A. P. Gadre, H. Yi, M. J. Kastantin, G. W. Rubloff, W. E. Bentley, G. F. Payne and R. Ghodssi. 2002. Voltage-Dependent Assembly of the Polysaccharide Chitosan onto an Electrode Surface. Langmuir. 18: 8620-8625. | |
| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/33019 | - |
| dc.description.abstract | 本研究針對幾丁聚醣（Chitosan）之物性量測進行探討，以和尚蟹（Mictyris brevidactylus）之皮膜為天然幾丁聚醣之來源，在不同去乙醯率（Degree of deacetylation）下，探討幾丁聚醣膜之拉力強度、含水率以及厚度間之關係，並與人工幾丁聚醣膜作比較。
結果發現，幾丁聚醣在去乙醯率48 % ∼ 55 % 時，具有最大膜厚及最小拉力強度。去乙醯率較低時，機械強度隨去乙醯率上升而減少；而去乙醯率較高時，機械強度隨去乙醯率提升而增加，而膜厚隨去乙醯率上升而減低。在不同去乙醯率下，膜厚與拉力強度之數值呈現高度負相關（R2 = 0.9547），且含水率與膜厚之數值呈正相關（R2 = 0.8665）。 | zh_TW |
| dc.description.abstract | In this study, measurement method and results for physical properties of chitosan membranes made from the carapace of the soldier crab Mictyris brevidactylus were discussed. Tensile strength, moisture and membrane thickness of chitosan membranes with various degree of deacelyation (DD) were measured. Besides, the physical properties of artificial chitosan membranes were further compared and discussed.
Experimental results showed that the maximal membrane thickness and the minimal tensile strength were obtained by using various chitosan membranes with DD value about 48 % ~ 55 %. In chitosan membranes with lower DD, strength of membrane decreased during DD increase. However, in the chitosan membranes with higher DD, strength of membrane increased during DD increase, but membrane thickness decreased during DD increase. With various DD, a high negative correlation (R2 = 0.9547) was obtained between membrane thickness and tensile strength of chitosan membrane, and a positive correlation (R2 = 0.8665) was obtained between moisture and membrane thickness of chitosan membrane, respectively. | en |
| dc.description.provenance | Made available in DSpace on 2021-06-13T04:22:08Z (GMT). No. of bitstreams: 1 ntu-95-R93631009-1.pdf: 1866663 bytes, checksum: 75ab90ff7a3d1e05b26f02f01f852301 (MD5) Previous issue date: 2006 | en |
| dc.description.tableofcontents | 目 錄
================= 頁數 致謝 i 摘要 ii Abstract iii 目錄 iv 圖目錄 vii 表目錄 viii 第一章 前言 1 第二章 文獻探討 3 2.1 和尚蟹 3 2.2 幾丁類物質 5 2.2.1 幾丁質與幾丁聚醣 5 2.2.2 幾丁聚醣之製備 8 2.2.3 幾丁類物質之溶解性質 9 2.2.4 幾丁聚醣薄膜之製備 11 2.2.5 和尚蟹幾丁聚醣皮膜 13 2.2.6 去乙醯率之測定 15 2.2.7 幾丁類物質之應用 17 2.3 膜厚量測 18 2.4 膨潤比 19 第三章 材料與方法 20 3.1 原料、藥品與儀器設備 20 3.1.1 實驗原料 20 3.1.2 實驗藥品 20 3.1.3 儀器設備 20 3.2 和尚蟹幾丁聚醣膜之製程與去乙醯率之量測 22 3.2.1 和尚蟹幾丁質之純化 22 3.2.2 去乙醯化作用 22 3.2.3 去乙醯率之量測 23 3.3 人工幾丁聚醣膜之製程 24 3.3.1 不同分子量之人工膜 24 3.3.2 不同厚度之人工膜 24 3.4 機械性質測試 25 3.4.1 機械性質之係數 25 3.4.2 測量方法 27 3.5 同一張皮膜在不同去乙醯率下之膜厚量測 31 3.6 含水率之量測 32 3.7 黏度計量測和尚蟹幾丁聚醣分子量 33 第四章 結果與討論 35 4.1 和尚蟹幾丁聚醣膜機械強度拉力實驗 35 4.1.1 軟體輸出介面 35 4.1.2 不同去乙醯率下和尚蟹幾丁聚醣膜之機械結構特性 36 4.2 不同去乙醯率下和尚蟹皮膜厚變化與量測工具之比較 41 4.3 不同去乙醯率之和尚蟹皮膜含水率與特性之關係 44 4.4 和尚蟹幾丁聚醣皮膜之分子量 50 4.5 人工幾丁聚醣膜之特性 52 4.5.1 不同分子量人工膜 52 4.5.2 不同厚度人工膜之特性 54 第五章 結論 57 參考文獻 58 圖 目 錄 ================= 頁數 圖 2-1 台灣產和尚蟹 4 圖 2-2 幾丁質、幾丁聚醣與纖維素之化學結構圖 7 圖 2-3 純化後和尚蟹幾丁質皮膜 14 圖 3-1 邊緣斷裂 28 圖 3-2 拉力試驗夾具位移與呈載受力關係之典型圖形 29 圖 3-3 玻璃黏度管 34 圖 4-1 Instron 公司萬能試驗機軟體輸出介面圖 35 圖 4-2 厚度與拉力強度對不同去乙醯率之皮膜之關係圖 38 圖 4-3 不同去乙醯率皮膜拉力強度－厚度關係圖 40 圖 4-4 厚度與含水率對不同去乙醯率幾丁聚醣之關係圖 46 圖 4-5 不同去乙醯率和尚蟹皮膜厚度－含水率關係圖 49 圖 4-6 不同分子量幾丁聚醣之黏度量測時間關係圖 51 表 目 錄 ================= 頁數 表 4-1 和尚蟹皮膜去乙醯化作用時間與去乙醯率量測數據 36 表 4-2 不同去乙醯率和尚蟹皮膜厚度及拉力試驗量測數據 37 表 4-3 和尚蟹皮膜去乙醯化作用時間與去乙醯率量測數據 40 表 4-4 以螺旋測微器及磁性感應式膜厚計對同一張皮膜在不同去乙醯率 情況下進行厚度量測值 43 表 4-5 不同去乙醯率皮膜之厚度及含水率量測數據 45 表 4-6 不同去乙醯率之和尚蟹皮膜之黏度係數量測數據 49 表 4-7 乾燥人工幾丁聚醣膜厚度與拉力量測結果 53 表 4-8 不同濃度製程之人工膜厚度及澎潤比量測結果 55 表 4-9 和尚蟹皮膜與人工膜厚度及拉力試驗量測結果 56 | |
| dc.language.iso | zh-TW | |
| dc.title | 和尚蟹皮膜與人工幾丁聚醣膜之物性研究 | zh_TW |
| dc.title | The Physical Properties of Mictyris brevidactylus
and Artificial Chitosan Membranes | en |
| dc.type | Thesis | |
| dc.date.schoolyear | 94-2 | |
| dc.description.degree | 碩士 | |
| dc.contributor.oralexamcommittee | 陳力騏(Richie Chen),陳林祈(Lin-Chi Chen) | |
| dc.subject.keyword | 幾丁聚醣,拉力強度,厚度,含水率, | zh_TW |
| dc.subject.keyword | Chitosan,Tensile strength,Membrane thickness,Moisture, | en |
| dc.relation.page | 64 | |
| dc.rights.note | 有償授權 | |
| dc.date.accepted | 2006-07-23 | |
| dc.contributor.author-college | 生物資源暨農學院 | zh_TW |
| dc.contributor.author-dept | 生物產業機電工程學研究所 | zh_TW |
| 顯示於系所單位： | 生物機電工程學系 | |
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