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| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 林嘉明 | |
| dc.contributor.author | Hui- Ju Hsieh | en |
| dc.contributor.author | 謝蕙如 | zh_TW |
| dc.date.accessioned | 2021-06-13T03:14:04Z | - |
| dc.date.available | 2006-09-18 | |
| dc.date.copyright | 2006-09-18 | |
| dc.date.issued | 2006 | |
| dc.date.submitted | 2006-08-04 | |
| dc.identifier.citation | 王正雄，1999，淺談環境荷爾蒙-干擾動物內分泌之化學物質，環境檢驗通訊雜誌24，http://www.niea.gov.tw/analysis/publish/month/DefaultMonthly.asp。
王正雄，2000，壬基苯酚環境荷爾蒙對環境生態之影響，環境檢驗通訊雜誌39，http://www.niea.gov.tw/analysis/publish/month/DefaultMonthly.asp。 呂育諭，2002，藉由高效能液相層析儀配合螢光偵測器同時分析食物中烷基酚和烷基酚乙氧基醇之濃度，國立陽明大學環境衛生研究所碩士論文。 袁紹英，2001，值得注意的環境荷爾蒙－壬基苯酚環境分佈與調查初探，環境檢驗通訊雜誌39，http://www.niea.gov.tw/analysis/publish/month/DefaultMonthly.asp。 黃世昌，2005，有機黏土對對硝基酚、酚及苯胺之吸附，國立台灣大學環境衛生研究所碩士論文。 黃龍泰，2002，以稻穀和花生殼製備高表面積之活性碳與其應用，國立台灣科技大學化學工程系研究所碩士論文。 陳弘彬，2002，孟宗竹炭與活性碳之研製，屏東科技大學林林系碩士論文。 曹功勳，2001，改質黏土吸附酚類化合物之平衡與動力學，元智大學化學工程學研究所碩士論文。 賴玄金、汪偉杰、吳仁傑，2006，實驗室裡的身家調查--竹碳物化特性簡介，科學月刊37(3)，180-183。 劉曾旭，1998，活性碳製造技術及應用，產業調查與技術127，84-97。 潘泰安，2003，以農業廢棄物為原料合成微孔吸附劑之資源化研究，國立高雄第一科技大學環境與安全衛生工程所碩士論文。 經濟部統計處，2002，台灣地區化學工業生產統計月報123，33。 Abe I.; Teuchi T.; Shinohara, Osamu S.; Iwasaki S.; Kawasaki N., and Tanada, S., 2002, Removal of 4-nonylphenol by carbonaceous materials produced from cottonseed shell as organic by-products, Environmental Science 13(5): 580-585. Alter G., 2002, Using organoclays to enhance carbon filtration, Waste Management 22: 507-513. Ball H.A., Reinhard M., and McCarty P., 1989, Biotransformation of halogenated and nonhalogenated octylphenol polyethoxylate residues under aerobic and anaerobi conditions, Environmental Science and Technology 23: 951-961 Biniak S., Pakula M., Szymanski G.S., and Swiatkowski A., 1991, Effect of activated carbon surface oxygen- and/or nitrogen-containing groups on adsorption of copper (II) ions from aqueous solution, Langmuir 15: 6117-6112. Boyd S.A., Lee J.F., and Mortland M.M., 1988, Attenuating organic contaminant mobility by soil modification, Nature 333: 345-347. Brunauer S., Deming L.S., Deming W.S., and Teller E.J., 1940, On a theory of the van der Waals adsorption of gases, Journal of the American Chemical society 62: 1723 Cheng C.Y., and Ding W.H., 2002, Determination of nonylphenol polyethoxylates in household detergents by high-performance liquid chromatography, Journal of Chromatography A 968: 143-150. Choi K.J., Kim S.G., Kim C.W., and Kim S.H., 2005, Effects of activated carbon types and service life on removal of endocrine disrupting chemicals: amitrol, nonylphenol, and bisphenol-A, Chemosphere 58(11): 1535-1545 Iwasaki S., Fukuhara T., Abe I., Yanagi J., Mouri M., Iwashima Y., Tabuchi T. and Shinohara O., 2001, Adsorption of alkylphenols onto microporous carbons prepared from coconut shell, Synthetic Metals 125(2): 207-211 Johnson A.C., Aerni H.R., Gerritsen A., Gibert M., Giger W., Hylland K., Jurgens M., Nakari T., Pickering A., Suter M.J.F., Svenson A., and Wettstein F.E., 2003, Comparing steroid estrogen, and nonylphenol content across a range of European sewage plants with different treatment and management practices, Water Research 39: 47-58. Kim S.G., Choi K.J., and Oh K.J., 2002, Fate of endocrine disruptor in water treatment processes. IWA World Congress. Kolpin D.W., Furlong E.T., Meyer M.T., Thurman L.B., and Buxton H.T., 2002, Pharmaceuticals, hormones, and other organic waste contaminants in U.S. streams, 1999-2000: A national reconnaissance, Environmental Science and Technology 36: 1202-1211. Lee P.C., 1998, Disruption of male reproductive tract development by administration of the xenoestrogen, nonylphenol, to male newborn rats, Endocrine 9: 105-111. Mortland M.M., Shaobai S., and Boyd S.A., 1986, Clay-organic complexes as adsorbents for phenol and chlorophenols, Clays & Clay Mineral 34: 591-585. Muller S., Schmid P., and Schlatter C., 1998, Pharmacokinetic behavior of 4-nonylphenol in humans, Environmental Toxicology and Pharmacology 5: 257-265. Naylor C.G., Mieure J.P., Adams W.J., Weeks J.A., Castaldi F.J., Ogle L., and Romano R.R., 1992, Alkylphenol ethoxylates in the environment, Journal of the American Oil Chemists’ Society 69: 695-703. Nevskaia D.M., and Guerrero-Ruiz A., 2001, Comparative study of the adsorption from aqueous solutions and the desorption of phenol and nonylphenol substrates on activated carbons, Journal of Colloid and Interface Science 234: 316-321. Roefer P., Snyder S., Zegers R.E., Rexing D.J., and Fronk J.L., 2000, Endocrine-disrupting chemicals in a source water, Journal of AWWA 92(8): 52-58. Rudel R.A., Melly S.J., Geno P.W., Sun G., and Brody J.G., 1998, Identification of alkyphenols and other estrogenic phenolic compounds in wastewater, septage, and groundwater on Cape Cod. Massachusetts. Environmental Science and Technology 37(7): 861-867. Shane A.S., Paul W., Yeomin Y., and David L.S., 2003, Pharmaceuticals, personal care products, and endocrine disruptors in water: implications for the water industry, Environmental Engineering Science 20: 449-469 Sole M., Lopez de Alda M.J., Castillo M., Porte C., Ladegaard-Pedersen K., and Barcelo D., 2000, Estrogenicity determination in sewage treatment plants and surface waters from the Catalonian area (NE Spain), Environmental Science and Technology 34: 5076-5083. Soto A.M., Justicia H., Wray J.W. and Sonnenschein C., 1991, p-Nonylphenol: an estrogenic xenobiotic released from modified polystyrene, Environmental Health Perspectives 92: 167-173. Staples C.A., Williams J.B., Blessing R.L. and Varineau P.T., 1999, Measuring the biodegradability of nonylphenol ether carboxylates, octylphenol ether carboxylates, and nonylphenol, Chemosphere 38(9): 2029-2039 Suzuki, M., 1990, Adsorption Engineering, Kodansha, Tokyo. Tanghe T., Devriese G., and Verstraete W., 1999, Nonylphenol and estrogenic activity in aquatic environmental samples, Journal of Environmental Quality 28: 702-709. | |
| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/31514 | - |
| dc.description.abstract | 壬基苯酚（nonylphenol）屬內分泌干擾物質，在低濃度(<10 μg/L)下即會干擾生物體體內荷爾蒙之作用，導致生殖、發育等危害甚至引發惡性腫瘤。全球目前普遍都受到此類化合物之污染，可是傳統水處理單元對於去除此類化合物之效果有限，而利用吸附劑吸附可能是一種有效的處理方法。近年來在台灣逐漸熱門的新興材料-竹碳及有機黏土，皆是具有高比表面積之多孔物質。因此本研究探討有機黏土及竹製活性碳對水中壬基苯酚之吸附現象。
本研究之等溫吸附試驗是在25℃下，使用0.3 mg吸附劑對100 mL水中壬基苯酚進行15個小時的吸附，以比較有機黏土及竹碳去除水中壬基苯酚的效果；並且對於吸附效果較好的有機黏土Cloisite R 15A及竹碳MOB2進行動力吸附試驗之觀察。試驗結果：有機黏土Cloisite R 15A去除效果最佳，去除效果之95%信賴區間為74.38 4.31%；竹碳MOB2之去除率95%信賴區間為54.92 14.59%；竹碳MOB3之去除率95%信賴區間為53.31 14.59%；竹碳MOB1之去除率95%信賴區間為24.25 11.05%；竹碳MOB4則沒有可察覺之去除效果。擬合Freundlich等溫吸附模式，除竹碳MOB4無法擬合外，其他吸附劑之擬合程度介於0.73~0.99之間。動力吸附試驗結果顯示有機黏土Cloisite R 15A在第4個小時後達平衡；竹碳MOB2在第15個小時後達平衡。故認為有機黏土15A不論是吸附達平衡所需時間或是去除效率而言，皆較適合實場應用去除水中壬基苯酚之吸附劑。 | zh_TW |
| dc.description.abstract | Nonylphenol is an endocrine disruptor that is able to interfere the functions of endocrines resulting in reproductive, developmental and/or carcinogenic effects. It is a globe-wide environmental contaminant and can not effectively removed by the routine water treatment. Its removal from water by adsorption has expected to be one of the promising ways. Thus, this study looked into the adsorption of 4-nolyphenol in water by adsorbents. One organic clay and four bamboo charcoals were tested just because they are proposed to be the porous materials with great specific surface areas and are getting more and more popular in Taiwan.
Adsorption isotherm test for each adsorbent was performed at 25℃ for 15 hours by adding 0.3 mg adsorbent into 100 mL aqueous solution containing five levels of 4-nonylphenol. The kinetic of adsorption for the adsorbents with good performance, that are Cloisite®15A and bamboo charcoal MOB2 were also observed. The results show that the Cloisite®15A had the best removed rate with 95% confidence interval of 74.38 4.31%, while the others had 54.92 14.59%, 53.31 14.59%, and 24.25 11.05% for bamboo charcoal MOB2, bamboo charcoal MOB3 and bamboo charcoal MOB1, respectively. Only the bamboo charcoal MOB4 did not demonstrate its adsorption capability of removing nonylphenol. The adsorption well fit the Freundlich isotherm with R2 in 0.73 - 0.99. The kinetic of adsorption indicated that the equilibrium was reached after 4 hours for the system with the Cloisite®15A, compared with 15 hours for the one with the bamboo charcoal MOB2. It is concluded that the Cloisite®15A is a more efficient adsorbent for application on the removal of 4-nonylphenol in water than bamboo charcoals. | en |
| dc.description.provenance | Made available in DSpace on 2021-06-13T03:14:04Z (GMT). No. of bitstreams: 1 ntu-95-R93844011-1.pdf: 410995 bytes, checksum: b6cf2120079aaa084df7880eddd3bb8e (MD5) Previous issue date: 2006 | en |
| dc.description.tableofcontents | 摘要 I
Abstract II 誌謝 III 目錄 IV 表目錄 VII 圖目錄 VIII 第一章 前言 1 1-1 研究緣起 1 1-2 研究目的 1 第二章 文獻探討 2 2-1 壬基苯酚 2 2-1-1 來源及用途 2 2-1-2 物化特性 4 2-1-3 生物毒性 4 2-1-4 環境流佈狀況 5 2-2 水體中內分泌干擾物質之移除 6 2-3 吸附材介紹 7 2-3-1 有機黏土 9 2-3-1-1 黏土之分類與性質 10 2-3-1-2 黏土的改質 11 2-3-1-3 有機黏土對酚類化合物的吸附效果 11 2-3-2 活性碳 12 2-3-2-1 活性碳之特性 12 2-3-2-2 活性碳之種類 13 2-3-3 有機黏土與活性碳吸附之比較 14 2-4 吸附理論 15 2-4-1 吸附現象 15 2-4-2 等溫吸附模式 15 2-4-2-1 Freundlich之等溫吸附式 16 2-4-2-2 Langmuir吸附理論 17 2-4-3 影響吸附之因素 18 2-4-3-1 吸附劑的性質 18 2-4-3-2 吸附質特性 19 2-4-3-3 環境因子 19 第三章 材料與方法 21 3-1 材料 21 3-1-1 吸附劑 21 3-1-2 吸附質 21 3-1-3 試藥 22 3-1-4 儀器 22 3-2 方法 22 3-2-1 標準品及檢量線製備 22 3-2-2 等溫吸附試驗 23 3-2-3 動力吸附試驗 23 3-2-4 高效能液相層析法 24 3-2-5 數據整理分析 24 第四章 結果與討論 25 4-1 壬基苯酚的分析 25 4-2 等溫吸附試驗 27 4-2-1 壬基苯酚在有機黏土Cloisite®15A之等溫吸附結果 27 4-2-2 壬基苯酚在竹碳MOB1之等溫吸附結果 30 4-2-3 壬基苯酚在竹碳MOB2之等溫吸附結果 31 4-2-4 壬基苯酚在竹碳MOB3之等溫吸附結果 33 4-2-5 壬基苯酚在竹碳MOB4之等溫吸附結果 34 4-2-6 等溫吸附結果之綜合討論 35 4-3 等溫吸附方程式擬合結果討論 38 4-4 動力吸附試驗 39 4-4-1 動力吸附試驗結果之比較 41 第五章 結論 42 參考文獻 43 附錄…………………………………………………………………48 表目錄 表2-1 活性碳吸附水中壬基苯酚之文獻整理…………………………..….8 表3-1 不同製程生產之竹碳……………………………………………….21 表4-1 壬基苯酚檢量結果(濃度範圍9.9-64.8 μg/L)…..…………..……....26 表4-2 壬基苯酚檢量結果(濃度範圍1.0-9.9 μg/L)……..………….….......26 表4-3 壬基苯酚分別在有機黏土及竹碳的等溫吸附結果….……………28 表4-4 水中壬基苯酚分別在有機黏土及竹碳之去除效果與壬基 苯酚起始濃度的關係………...……………….................................37 表4-5 等溫吸附之擬合方程式…………………………....……………....39 圖目錄 圖2-1 APEOs經生物降解形成壬基苯酚之過程…………..……………….3 圖2-2 四面體之結構………………...………………………………………9 圖2-3 八面體之結構…………………………………………………....….10 圖2-4 等溫吸附曲線基本型態示意圖 ………...……………………….....17 圖4-1 壬基苯酚之HPLC/fluorescence分析圖譜….………...…………...25 圖4-2 壬基苯酚之檢量線(濃度範圍9.9-64.8 μg/L)………...……………26 圖4-3 壬基苯酚之檢量線(濃度範圍1.0-9.9μg/L)…………………..……27 圖4-4 壬基苯酚在有機黏土Cloisite®15A之等溫吸附 ……...…..……..29 圖4-5 壬基苯酚在有機黏土Cloisite®15A之Freundlich 等溫吸附模式擬合……...…………………………………………30 圖4-6 壬基苯酚在竹碳MOB1之等溫吸附…………………………….…30 圖4-7 壬基苯酚在竹碳MOB1之Freundlich等溫吸附模式 擬合………………………………………………………...………31 圖4-8 壬基苯酚在竹碳MOB2之等溫吸附.…………….………………...32 圖4-9 壬基苯酚在竹碳MOB2之Freundlich等溫吸附模式 擬合……………………………………...………………....……....33 圖4-10 壬基苯酚在竹碳MOB3之等溫吸附………..…..………………....33 圖4-11 壬基苯酚在竹碳MOB3之Freundlich等溫吸附模式 擬合…………………………………………………………….......34 圖4-12 壬基苯酚在竹碳MOB4之等溫吸附……….………………….…..35 圖4-13 吸附劑對水中壬基苯酚之去除率(%)與壬基苯酚起始濃度 的關係 .……………………………………………………………38 圖4-14 壬基苯酚在有機黏土Cloisite®15A之動力吸附…….………….…40 圖4-15 壬基苯酚在竹碳MOB2之動力吸附………………………….…...40 | |
| dc.language.iso | zh-TW | |
| dc.subject | 竹碳 | zh_TW |
| dc.subject | 有機黏土 | zh_TW |
| dc.subject | 等溫吸附 | zh_TW |
| dc.subject | 壬基苯酚 | zh_TW |
| dc.subject | nonylphenol | en |
| dc.subject | bamboo charcoals | en |
| dc.subject | adsorption | en |
| dc.subject | organic clay | en |
| dc.title | 應用有機黏土及竹碳吸附水中4-壬基苯酚(4-nonylphenol) | zh_TW |
| dc.title | Adsorption of 4-Nonylphenol in Water by Organic Clay and Bamboo Charcoal | en |
| dc.type | Thesis | |
| dc.date.schoolyear | 94-2 | |
| dc.description.degree | 碩士 | |
| dc.contributor.oralexamcommittee | 洪益夫,柯淳涵 | |
| dc.subject.keyword | 壬基苯酚,等溫吸附,有機黏土,竹碳, | zh_TW |
| dc.subject.keyword | nonylphenol,adsorption,organic clay,bamboo charcoals, | en |
| dc.relation.page | 51 | |
| dc.rights.note | 有償授權 | |
| dc.date.accepted | 2006-08-04 | |
| dc.contributor.author-college | 公共衛生學院 | zh_TW |
| dc.contributor.author-dept | 環境衛生研究所 | zh_TW |
| 顯示於系所單位： | 環境衛生研究所 | |
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