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完整後設資料紀錄
DC 欄位 | 值 | 語言 |
---|---|---|
dc.contributor.advisor | 林江珍 | |
dc.contributor.author | Siao-Cheng Shih | en |
dc.contributor.author | 施孝承 | zh_TW |
dc.date.accessioned | 2021-06-13T02:10:20Z | - |
dc.date.available | 2016-08-08 | |
dc.date.copyright | 2011-08-08 | |
dc.date.issued | 2011 | |
dc.date.submitted | 2011-08-01 | |
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dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/30618 | - |
dc.description.abstract | 在本研究中,我們合成了三種單體有卡唑(Carbazole)、噻吩(Thiophene)以及苯並噻二唑(Benzothiadiazole)分別為主體且在苯乙烯4-號即對位上做連接,並以free radical聚合法,成功合成一系列的單聚物(Homopolymer)與共聚物(Copolymer)。共聚物部分為本研究主軸,施體端(Donor)為具有良好電洞傳導性的卡唑,且在卡唑9-號氮上連接具有六個碳的正己烷來提升共聚物高分子之溶解度,第二個單體結構為兩個噻吩一起連接,並調整增加共軛長度使其能階符合前段可見光吸收範圍內,另一方面預期作為三個單體之共聚物的電子電洞雙向傳導架橋,第三個單體為強電子受體(Acceptor)苯並噻二唑,第三個單體我們額外在苯並噻二唑結構兩端連接了兩個噻吩,使其能階可吸收後段可見光範圍;我們預期透過調控三種單體比例可以改善共聚物可見光吸收範圍、能階以及溶解度。此外我們對成功合成出的一系列的高分子P1~P6利用凝膠滲透層析儀、熱重分析儀、微差掃描卡計、紫外光/可見光分光光譜儀、螢光光譜儀以及循環伏安儀來做光電性質分析與探討,進而應用於有機太陽能電池元件的製作與討論。 | zh_TW |
dc.description.abstract | In this study, we synthesized three type monomers : carbazole-containing、thiophene-containing、benzothiadiazole-containing. Carbazole was a great hole transporting material in OLED and OPV field. We expected that increasing of polymer solubility which was modified by n-Hexane on carbazole nitrogen site. We also used the Styrene (Para site) to connected with monomer via suzuki coupling reactions. All kind of polymers were synthesized via free radical polymerization. The homopolymers P1~P3 and the copolymers P4~P6 were successfully synthesized. All derivatives discovered good thermal stability, and 5% thermal degradation temperature over 350 oC. The optical properties showed that the absorption were red-shifted with the film state on absorption spectrum, It was indicated that copolymers P4~P6 had great interaction of π-πstacking molecular structure. The optical band gap of P4, P5 and P6 were 2.18 eV, 2.15 eV, 2.12 eV respectively. We also observed that the HOMO of these derivatives increased with increasing raio of carbazole unit. The preliminary bulk heterojunction solar cell devices were fabricated with poymer P1~P6. The highest power conversion efficiency were 0.22 %, containing weigh ratio with P6 : PCBM = 1:4 , VOC of 0.45 (V), ISC of 1.49 mA/cm2, and FF of 0.32 under AM 1.5G solar simulator. | en |
dc.description.provenance | Made available in DSpace on 2021-06-13T02:10:20Z (GMT). No. of bitstreams: 1 ntu-100-R98549027-1.pdf: 2386850 bytes, checksum: 8e290da12dbfb04ac1af98c7b076d9f9 (MD5) Previous issue date: 2011 | en |
dc.description.tableofcontents | 口試委員會審定書 #
謝誌 I 摘要 III ABSTRACT IV 目錄 V 圖目錄 VIII 表目錄 X Chapter 1 緒論 1 1.1 前言 1 1.2 太陽能電池的種類 3 1.3 有機太陽能電池基本知識 5 1.3.1 能量轉移機制 5 1.3.2 工作原理 6 1.3.3 電池元件結構 8 1.4 電池元件特性參數 10 1.4.1 等效電路 10 1.4.2 開環電壓(Open-circuit photovoltage, VOC) 12 1.4.3 短路電流(Short-circuit photocurrent, ISC) 12 1.4.4 充填因子(Fill factor, FF) 13 1.4.5 光電轉換效率(Power conversion efficiency, η) 13 1.4.6 外部量子效率(Incident photocurrent conversion efficiency, IPCE) 14 1.5 標準太陽光譜 15 Chapter 2 文獻回顧 17 2.1 全共軛系統之有機高分子太陽能電池 17 2.1.1 卡唑(Carbazole)系列 17 2.1.2 苯並噻二唑(Benzothiadiazole)系列 18 2.2 獨立系統之有機高分子太陽能電池 21 2.2.1 聚乙烯基卡唑(Polyvinyl carbazole)系列 21 2.2.2 苝類衍生物(Perylene derivatives)系列 23 2.3 研究動機 24 Chapter 3 實驗部分 25 3.1 實驗藥品與溶劑 25 3.2 實驗儀器 29 3.3 合成步驟及數據 32 Chapter 4 結果與討論 50 4.1 合成機制與結果探討 50 4.1.1 Suzuki-Miyaura Cross-Coupling Reaction 50 4.1.2 Free Radical Polymerization 52 4.1.3 高分子的分子量探討 54 4.2 熱化學性質 56 4.3 光物理性質 58 4.4 電化學性質 64 4.5 元件物理性質 70 4.5.1 有機高分子太陽能元件製程 70 4.5.2 單聚物P1~P3之元件性質 71 4.5.3 共聚物P4~P6之元件性質 73 4.5.4 共聚物P6之元件性質 76 Chapter 5 結論 78 參考文獻 79 附錄I 高分子P1~P6之GPC圖譜 85 附錄II 高分子P1~P6之DSC圖譜 89 附錄III 高分子P1~P6之1H與13C核磁共振光譜 93 | |
dc.language.iso | zh-TW | |
dc.title | 含苯並噻二唑及卡唑共聚高分子之合成及其應用在有機太陽能電池之研究 | zh_TW |
dc.title | Synthesis and Characterizations of Carbazole Benzothiadiazole-Containing Derivatives for Organic Solar Cell Applications | en |
dc.type | Thesis | |
dc.date.schoolyear | 99-2 | |
dc.description.degree | 碩士 | |
dc.contributor.coadvisor | 謝國煌 | |
dc.contributor.oralexamcommittee | 黃智楷 | |
dc.subject.keyword | 卡唑,噻,吩,苯並噻,二唑,體異質接面有機太陽能電池, | zh_TW |
dc.subject.keyword | carbazole,thiophene,benzothiadiazole,bulk heterojunction solar cell, | en |
dc.relation.page | 111 | |
dc.rights.note | 有償授權 | |
dc.date.accepted | 2011-08-02 | |
dc.contributor.author-college | 工學院 | zh_TW |
dc.contributor.author-dept | 高分子科學與工程學研究所 | zh_TW |
顯示於系所單位: | 高分子科學與工程學研究所 |
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