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  1. NTU Theses and Dissertations Repository
  2. 理學院
  3. 物理學系
請用此 Handle URI 來引用此文件: http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/30321
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dc.contributor.advisor陳永芳(Yang-Fang Chen)
dc.contributor.authorSheng-Chih Huangen
dc.contributor.author黃聖智zh_TW
dc.date.accessioned2021-06-13T02:01:06Z-
dc.date.available2008-07-20
dc.date.copyright2007-07-20
dc.date.issued2007
dc.date.submitted2007-07-06
dc.identifier.citationChapter 1
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Chapter 2
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Chapter 3
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dc.identifier.urihttp://tdr.lib.ntu.edu.tw/jspui/handle/123456789/30321-
dc.description.abstractWe perform measurements of the photoluminescence (PL) and the time-resolved PL on type-II CdSe/ZnTe core/shell quantum dots (QDs). First of all, we compare the dependence of PL and time-resolved PL on temperature and find that exciton would redistribute into larger dots at low temperature, with the recombination dominated by the radiative part. As increasing the temperature, the nonradiative part becomes dominant and the main mechanism arises from the ionization of exciton and the interaction between exciton and LO-phonon. Additionally, we observe that the radiative recombination time varies linearly with the linewidth of PL.
In the measurement of excitation power dependent time-resolved PL, it is found that the radiative recombination time decreases with increasing power and may be attributed to the band bending effect due to the spatially photoexcited carriers in a type-II band alignment. In the last section, detected photon energy dependent time-resolved PL reveals that the radiative recombination time is proportional to cube of the size of QDs and this relationship may arise from the quantum confinement effect.
en
dc.description.provenanceMade available in DSpace on 2021-06-13T02:01:06Z (GMT). No. of bitstreams: 1
ntu-96-R94222035-1.pdf: 879939 bytes, checksum: f01629fa94d431d14fd39fe5ee6743b3 (MD5)
Previous issue date: 2007
en
dc.description.tableofcontentsList of Figures III
1. Introduction 1
2. Theoretical Background 7
2.1 Photoluminescence 7
2.1.1 Introduction 7
2.1.2 Principles and Applications of Photoluminescence 7
2.1.3 Apparatus of Photoluminescence Measurement 10
2.2 Band Gap and Exciton Binding Energy in Quantum Dots 13
2.2.1 Effective Band Gap of the Type-I QDs 13
2.2.2 Binding Energy of Exciton of the Type-II QDs 14
2.3 Time-Domain Lifetime 17
2.3.1 Introduction 17
2.3.2 Meaning of the Lifetime or Decay Time 18
2.3.3 Lifetimes of Band Edge Excitons in CdSe QDs 20
2.3.4 Apparatus of Time-Resolved Photoluminescence 22
3. Optical Properties and Relaxation Dynamics of Type-II CdSe/ZnTe Core/Shell Quantum Dots 32
3.1 Introduction 32
3.2 Experiments 35
3.2.1 Sample Preparation 35
3.2.2 Measurement 37
3.3 Results and Discussion 38
3.3.1 Temperature Dependent Photoluminescence and Time-Resolved PL 38
3.3.2 Excitation Power Dependent Time-Resolved PL 44
3.3.3 Photon Energy Dependent Time-Resolved PL 46
3.4 Summary 49
4. Conclusion 68
dc.language.isoen
dc.subject硒化鎘/銻化鋅zh_TW
dc.subject第二類型zh_TW
dc.subject核殼結構zh_TW
dc.subject鬆弛zh_TW
dc.subject光學性zh_TW
dc.subject量子點zh_TW
dc.subjectquantum doten
dc.subjectopticalen
dc.subjectrelaxationen
dc.subjectCdSe/ZnTeen
dc.subjectcore/shellen
dc.title第二類型硒化鎘/銻化鋅核殼結構量子點之光學性質及鬆弛機制研究zh_TW
dc.titleOptical Properties and Relaxation Dynamics of Type-II CdSe/ZnTe Core/Shell Quantum Dotsen
dc.typeThesis
dc.date.schoolyear95-2
dc.description.degree碩士
dc.contributor.oralexamcommittee沈志霖(Jih-lin Shen),林泰源(Tai-Yuan Lin)
dc.subject.keyword光學性,鬆弛,第二類型,硒化鎘/銻化鋅,核殼結構,量子點,zh_TW
dc.subject.keywordoptical,relaxation,CdSe/ZnTe,core/shell,quantum dot,en
dc.relation.page67
dc.rights.note有償授權
dc.date.accepted2007-07-09
dc.contributor.author-college理學院zh_TW
dc.contributor.author-dept物理研究所zh_TW
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