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| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 邱文英(Wen-Yun Chiu) | |
| dc.contributor.author | Tai-You Chen | en |
| dc.contributor.author | 陳泰佑 | zh_TW |
| dc.date.accessioned | 2021-06-13T01:33:41Z | - |
| dc.date.available | 2007-10-10 | |
| dc.date.copyright | 2007-07-18 | |
| dc.date.issued | 2007 | |
| dc.date.submitted | 2007-07-12 | |
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| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/30061 | - |
| dc.description.abstract | 本研究主要分成三個部分，第一部分是合成出具有酸鹼緩衝效果的聚苯胺，在鹽酸的酸性水溶液下以起始劑過硫酸銨進行氧化聚合反應，製備出中間氧化態聚苯胺，並控制其本身的酸鹼值為中性，以達到對酸液或鹼液都能將其酸鹼值調節到中性的效果。
第二部份主要是製備出具兩性緩衝效果的氧化鋅奈米顆粒，利用水熱合成法在低溫低濃度下製備出奈米等級的氧化鋅，並改變反應時的溫度和反應溶液，使用TEM觀察奈米氧化鋅在不同的反應條件下有何不同的形態和大小，並探討其原因。 第三部份則是利用Pickering Emulsion Polymerization的方法製備出聚苯胺/氧化鋅奈米乳膠顆粒，將第二部份所合成的氧化鋅奈米顆粒去當作聚苯胺乳化聚合中的界面劑，製備出聚苯胺/氧化鋅複合顆粒。然後再利用FTIR、XRD、TGA去探討複合顆粒的結構及熱性質，並用TEM觀察其形態，最後則是在不同的酸鹼液下測試其酸鹼緩衝特性。 | zh_TW |
| dc.description.abstract | This research includes three parts. In the first part, we synthesized polyaniline with capability to control the pH of acid(base) solutions at neutrality. Aniline dissolved in hydrochloric acid solution and was initiated by ammonium persulfate. Finally we got the emeraldine type of polyaniline. And we controlled its pH at about 7, so it can be a pH buffer to both acid and base solution.
In the second part, we prepared Zinc oxide, another pH buffer to both acid and base. We synthesized nano-size particles of zinc oxide via the novel hydrothermal process with relative low concentration and temperature. We also observed and discussed the variation of morphology of the obtained zinc oxide with different solvents and reaction temperature by TEM. In the last part, we tried to combine the products mentioned above through the novel method, Pickering emulsion polymerization. We take particles of zinc oxide we made in the second part as the surfactants of the emulsion polymerization of polyaniline to synthesize ZnO/PANI composite particles. Then we discussed it by FTIR, XRD, TGA and TEM. | en |
| dc.description.provenance | Made available in DSpace on 2021-06-13T01:33:41Z (GMT). No. of bitstreams: 1 ntu-96-R94524036-1.pdf: 5592754 bytes, checksum: 3890421eadb7c798fc1663ee92ac8943 (MD5) Previous issue date: 2007 | en |
| dc.description.tableofcontents | 目錄
摘要 I Abstract II 目錄 III 圖索引 VI 表索引 VIII 第一章 緒論 1 第二章 文獻回顧 2 2-1 乳化聚合反應[109] 2 2-1.1 乳化聚合反應的成核機構 4 2-1.1-1 微胞成核理論(micellar nucleation) 4 2-1.1-2 均質成核理論(homogeneous nucleation) 5 2-1.1-3 凝聚成核理論(coagulative nucleation) 6 2-1.1-4 單體液滴成核(monomer droplet nucleation) 7 2-1.2 以固體為界面劑穩定乳液(Pickering emulsion) 8 2-2 兩性粒子：奈米氧化鋅(ZnO) 9 2-3 導電高分子：聚苯胺(polyaniline) 10 2-3.1聚苯胺歷史 10 2-3.2 聚苯胺的合成方式 11 2-3.3. 聚苯胺的聚合機制 11 2-3.4聚苯胺的結構 13 2-3.5導電高分子的摻雜方法 14 2-3.6改善聚苯胺加工性的方法 14 2-3.7聚苯胺應用 15 2-4 有機-無機摻合複合材料 20 第三章 實驗 22 3-1 實驗藥品 22 3-2實驗儀器 25 3-3 實驗流程圖 28 3-3.1 合成鹼式中間氧化態聚苯胺(Emeraldine base, EB) 29 3-3.2 以水熱合成法合成奈米氧化鋅 30 3-3.3 以固體為界面劑穩定乳液乳化聚合法合成氧化鋅/聚苯胺乳膠顆粒(ZnO/PANI) 31 3-4 實驗步驟 32 3-4.1合成中間氧化態聚苯胺 32 3-4.2以水熱合成法合成奈米氧化鋅 32 3-4.3以固體為界面劑穩定乳液乳化聚合法合成氧化鋅/聚苯胺乳膠顆粒(ZnO/PANI) 33 3-4.4 測定樣品的酸鹼緩衝性質 34 3-5實驗儀器分析 35 第四章 結果與討論 38 4-1合成中間氧化態聚苯胺 38 4-1.1 前言 38 4-1.2 中間氧化態聚苯胺對酸鹼緩衝效果的影響 38 4-2以水熱合成法合成奈米氧化鋅 39 4-2.1 前言 39 4-2.2 奈米氧化鋅的形態和酸鹼緩衝效果的影響 39 4-3以固體為界面劑穩定乳液乳化聚合法合成氧化鋅/聚苯胺乳膠顆粒(ZnO/PANI) 41 4-3.1 前言 41 4-3.2 苯胺單體/氧化鋅的重量比對複合顆粒性質的影響 42 4-3.3甲苯/水的體積比對複合顆粒性質的影響 44 4-3.4超音波震盪的時間對複合顆粒性質的影響 45 4-3.5不同油相溶液對複合顆粒性質的影響 47 4-3.6 不同形態的氧化鋅對複合顆粒性質的影響 49 4-3.7 由文獻上去比較聚苯胺/氧化鋅複合顆粒的FTIR圖譜變化 50 4-3.8 由TEM圖觀察聚苯胺/氧化鋅複合顆粒的形態 52 結論 53 參考文獻 55 | |
| dc.language.iso | zh-TW | |
| dc.subject | 聚苯胺polyaniline | zh_TW |
| dc.subject | Pickering emulsion Polymerization | zh_TW |
| dc.subject | 氧化鋅zinc oxide | zh_TW |
| dc.subject | 複合乳膠顆粒 | zh_TW |
| dc.subject | pH值緩衝 | zh_TW |
| dc.subject | Pickering emulsion polymerization | en |
| dc.subject | pH buffering | en |
| dc.subject | composite particles | en |
| dc.subject | zinc oxide | en |
| dc.subject | polyaniline | en |
| dc.title | 利用Pickering乳化聚合法製備具酸鹼緩衝性質的氧化鋅/聚苯胺奈米複合顆粒 | zh_TW |
| dc.title | Synthesis of pH buffering ZnO/PANI nanocomposites by Pickering emulsion polymerization | en |
| dc.type | Thesis | |
| dc.date.schoolyear | 95-2 | |
| dc.description.degree | 碩士 | |
| dc.contributor.oralexamcommittee | #VALUE! | |
| dc.subject.keyword | Pickering emulsion Polymerization,聚苯胺polyaniline,氧化鋅zinc oxide,複合乳膠顆粒,pH值緩衝, | zh_TW |
| dc.subject.keyword | Pickering emulsion polymerization,polyaniline,zinc oxide,composite particles,pH buffering, | en |
| dc.relation.page | 79 | |
| dc.rights.note | 有償授權 | |
| dc.date.accepted | 2007-07-17 | |
| dc.contributor.author-college | 工學院 | zh_TW |
| dc.contributor.author-dept | 化學工程學研究所 | zh_TW |
| 顯示於系所單位： | 化學工程學系 | |
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