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標題: | 雜環盤狀液晶材料設計與合成及其在負電型有機場效電晶體之應用 Design and Synthesis of Heterocyclic Discotic Liquid Crystal Materials and Their Application for N-Type Organic Field-Effect Transistors |
作者: | Chieh Chu 朱傑 |
指導教授: | 劉陵崗(Ling-Kang Liu) |
關鍵字: | 負電型,有機場效電晶體,盤狀液晶, N-Type,OFETs,Discotic Liquid Crystals, |
出版年 : | 2007 |
學位: | 碩士 |
摘要: | 我們成功合成出以quinoxaline為主體架構,並帶有含氟取代及不含氟取代長碳鏈之液晶材料。利用熱重量分析儀和循環伏特安培儀來確認其熱穩定性和還原電位,並以偏光顯微鏡、熱差式掃描卡計儀、及變溫粉末X光繞射儀來鑑定其中間相。這些具液晶相的分子成膜在矽基板上或是以自組裝薄膜修飾後的矽基板上時,其排列方向及表面型態,分別藉由粉末X光繞射儀和原子力顯微鏡來研究。我們成功利用親氟及斥氟的作用力來使分子能夠以垂直排列的方式在PFTS修飾的矽基板表面上,這提供了一個新的準則來設計能應用在有機場效電晶體的有機半導體材料。 Three series of quinoxaline-based liquid crystal materials with or without semifluorinated alkyl chains have been successfully synthesized. Their thermal stabilities, reduction potentials, and mesophase characteristics have been examined by TGA, CV, POM, DSC, and temperature-dependent PXRD, respectively. The molecular orientation and their film morphology on the substrate (SiO2/Si) with or without SAMs also have investigated by PXRD and AFM. The control of molecular orientation, to be perpendicular to the substrate treated with PFTS via fluorophilic/fluorophobic interaction, has been achieved. This method provides a new molecular design principle enabling desired molecular alignment of organic semiconducting materials for organic field-effect transistors. |
URI: | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/28557 |
全文授權: | 有償授權 |
顯示於系所單位: | 化學系 |
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