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完整後設資料紀錄
DC 欄位 | 值 | 語言 |
---|---|---|
dc.contributor.advisor | 余政靖(Cheng-Ching Yu) | |
dc.contributor.author | Chin-Shin Chen | en |
dc.contributor.author | 陳晉仕 | zh_TW |
dc.date.accessioned | 2021-06-13T00:08:00Z | - |
dc.date.available | 2007-07-31 | |
dc.date.copyright | 2007-07-31 | |
dc.date.issued | 2007 | |
dc.date.submitted | 2007-07-27 | |
dc.identifier.citation | [1] Agreda V.H., Partin, L.R., Heise, W.H. (1990) 'High-purity methyl acetate via reactive distillation.' Chemical Enginering Progress, 86(2): 40-46.
[2] Al-Arfaj M.A. and Luyben W.L. (2000) 'Effect of number of fractionating trays on reactive distillation performance.' AIChE Journal 46(12): 2417-2425. [3] Barbosa D. and Doherty M.F. (1988a) 'Design and minimum-reflux calculations for single-feed multicomponent reactive distillation columns.' Chemical Engineering Science 43(7): 1523-1537. [4] Barbosa D., Doherty, M.F. (1988b) 'Simple distillation of homogeneous reactive mixtures.' Chemical Engineering. Science 43(3): 541-550. [5] Bessling B., Schembecker G., Simmrock, K.H. (1997) 'Design of processes with reactive distillation line diagrams.' Industrial & Engineering Chemistry Research 36(8): 3032-3042. [6] Cardoso M.F., Salcedo R.L., Feyo de Azevedo S., Barbosa D. (2000) 'Optimization of reactive distillation processes with simulated annealing.' Chemical Engineering Science 55(21): 5059-5078. [7] Chadda N., Malone M.F., Doherty M.F. (2001) 'Effect of chemical kinetics on feasible splits for reactive distillation.' AIChE Journal 47(3): 590-601 [8] Chadda N., Malone M.F., Doherty M.F. (2002). 'Feasibility and synthesis of hybrid reactive distillation systems.' AIChE Journal 48(12): 2754-2768 [9] Cheng Y.C. and Yu C.C. (2005). 'Effects of feed tray locations to the design of reactive distillation and its implication to control.' Chemical Engineering Science 60(17): 4661-4677. [10] Ciric A.R. and Gu D. (1994). 'Synthesis of nonequilibrium reactive distillation processes by MINLP optimization.' AIChE Journal 40(9): 1479-1487. [11] Doherty M.F. and Malone M.F. (2001) Conceptual Design of Distillation Systems. New York, McGraw-Hill. [12] Dragomir R.M. and Jobson M. (2005) 'Conceptual design of single-feed hybrid reactive distillation columns.' Chemical Engineering Science 60(16): 4377-4395 [13] Groemping M., Dragomir R.M., Jobson, M. (2004) 'Conceptual design of reactive distillation columns using stage composition lines.' Chemical Engineering and Processing 43(3): 369-382. [14] Guo Z., Chin, J., Lee, J.W. (2004) 'Feasibility of continuous reactive distillation with azeotropic mixtures.' Industrial and Engineering Chemistry Research 43(14): 3758-3769. [15] Hauan S., Ciric A.R., Westerberg A.W., Lien, K.M. (2000) 'Difference points in extractive and reactive cascades. I - basic properties and analysis.' Chemical Engineering Science 55(16): 3145-3159. [16] Hauan S., Westerberg A.W., Lien K.M. (2000) 'Phenomena-based analysis of fixed points in reactive separation systems.' Chemical Engineering Science 55(6): 1053-1075. [17] Hoffmaster W.R. and Hauan, S. (2006) 'Using feasible regions to design and optimize reactive distillation columns with ideal VLE.' AIChE Journal 52(5): 1744-1753. [18] Huss R.S., Chen F., Malone M.F., Doherty M.F. (2003) 'Reactive distillation for methyl acetate production.' Computers and Chemical Engineering 27(12): 1855-1866. [19] Kaymak D.B. and Luyben W.L. (2004a) 'Design of distillation columns with external side reactors.' Industrial and Engineering Chemistry Research 43(25): 8049-8056. [20] Kaymak D.B. and Luyben W.L. (2004b). 'Effect of the chemical equilibrium constant on the design of reactive distillation columns.' Industrial and Engineering Chemistry Research 43(14): 3666-3671. [21] Kaymak D.B. and Luyben W.L. (2004c) 'Quantitative Comparison of Reactive Distillation with Conventional Multiunit Reactor/Column/Recycle Systems for Different Chemical Equilibrium Constants.' Industrial and Engineering Chemistry Research 43(10): 2493-2507. [22] Kaymak D.B., Luyben W.L., Smith Iv, O.J. (2004) 'Effect of relative volatility on the quantitative comparison of reactive distillation and conventional multi-unit systems.' Industrial and Engineering Chemistry Research 43(12): 3151-3162. [23] Lee J.W. (2002) 'Feasibility studies on quaternary reactive distillation systems.' Industrial and Engineering Chemistry Research 41(18): 4632-4642 [24] Lee J.W., Hauan S., Lien K.M., Westerberg A.W. (2000) 'Difference points in extractive and reactive cascades. II - generating design alternatives by the lever rule for reactive systems.' Chemical Engineering Science 55(16): 3161-3174. [25] Lee J.W., Hauan S., Westerberg A.W. (2001) 'Feasibility of a reactive distillation column with ternary mixtures.' Industrial and Engineering Chemistry Research 40(12): 2714-2728. [26] Lee J.W. and Westerberg A.W. (2000) 'Visualization of stage calculations in ternary reacting mixtures.' Computers and Chemical Engineering 24(2): 639-644. [27] Luyben W.L. (2000) 'Economic and dynamic impact of the use of excess reactant in reactive distillation systems.' Industrial and Engineering Chemistry Research 39(8): 2935-2946. [28] Matsuyama H. and Nishimura H. (1977) 'Topological and thermodynamic classification of ternary vapor-liquid equilibria.' Journal of Chemical Engineering of Japan 10(3): 181-187. [29] Mohl K.D., Kienle A., Gilles E.D., Rapmund P., Sundmacher K., Hoffman U. (1999) 'Steady state multiplicities in reactive distillation columns for the production of fuel ethers MTBE and TAME: theoretical analysis and experimental verification.' Chemical Engineering Journal 72(3): 1029-1043. [30] Stichlmair J. and Frey T. (2001) 'Mixed-integer nonlinear programming optimization of reactive distillation processes.' Industrial and Engineering Chemistry Research 40(25): 5978-5982. [31] Subawalla H. and Fair J.R. (1999). 'Design guidelines for solid-catalyzed reactive distillation systems.' Industrial and Engineering Chemistry Research 38(10): 3696-3709. [32] Sundmacher K. and Kienle A. (2003). Reactive Distillation:Status and Future Directions, Wiley-VCH Verlag GmbH & Co. KGaA:Weinheim, Germany [33] Tang Y.T., Chen Y.W., Huang, H.P., Yu C.C., Hung S. B., Lee M. J. (2005) 'Design of reactive distillations for acetic acid esterification.' AIChE Journal 51(6): 1683-1699. [34] Taylor R. and Krishna R. (2000) 'Modelling reactive distillation.' Chemical Engineering Science 55(22): 5183-5229. [35] Tung, S.T. and Yu C.C. (2007) 'Effects of relative volatility ranking to the design of reactive distillation.' AIChE Journal 53(5): 1278-1297. | |
dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/28428 | - |
dc.description.abstract | 摘要
反應蒸餾程序具有經濟上的優勢,特別在可逆反應或是共沸現象出現時。但是迭代設計過程非常耗時,透過可行性分析能檢查程序是否可行,藉由刪除不可行的設計,化學工程設計師將能節省大量嘗試錯誤的時間,但是反應蒸餾塔的捷徑式設計與可行性分析至目前為止仍尚未發展完全。Guo等人曾對反應性三成份共沸系統可行性進行系統化分析,方法為Lee等人所發展的反應差異點圖形化逐板運算。此法有兩個限制,一為需要正向反應,二為產品能由蒸餾或是反應蒸餾達到。在本工作中發現可行性分析方法可透過容許逆反應來增強,給出較正確的可行性預測。兩個理論性的概念也被發現,分別是:一、反應平衡線上的汽液向量反轉與否跟該逐板運算的可行性結果一致。二、反應共沸點就是化學平衡下無限回流比逐板運算的極限點。可行性分析能藉二概念來簡化並加速。全部共113個三成份餾餘組成圖形(RCM)中,本工作將可行的由原先的Guo等人所預測的27個增加到48個,全部可行的RCM在本工作中分類為四種不同的類別,分別是:一、可行於反應平衡線與產品具有相同區間。二、可行於大的平衡常數。三、可行於小的平衡常數。四、可行於合適的平衡常數。也針對第二個類別提出不可行的情況下,利用多塔組態來生產的解決方案與分析方法。第三、第四個類別仍需由Guo等人提出使用entrainer的方式來得到高純度產品。共沸系統可行性也推廣到不同的沸點排序,發現為鏡向關係,這些結論均與模擬結果相符。最後進行理想三成份A↔B+C系統的可行性分析、最適設計與動態控制,發現可行性分析的確能幫助我們找到較具經濟優勢的設計架構,並且該架構具有動態上的可操控性。 | zh_TW |
dc.description.abstract | Abstract
The reactive distillation offers significant economic advantages in some systems, especially when reactions are reversible and/or when azeotropes are presented. The feasibility analysis helps us to check whether a process is feasible or not. It is crucial and important because there are fewer methods for shortcut designs and the iterative design is always time-consuming in reactive distillation column. A lot of time would be saved for the design procedures of reactive distillation by getting rid of infeasible cases and focusing on the feasible ones. Systematical research on feasibility analysis of ternary azeotropic systems has been done by Guo et al (Guo et all, 2004). The analysis method they used is tray-by-tray calculations with difference point. There are two feasibility criteria, which are positive reaction extent is required and products can be reached by distillation or reactive distillation. In this work, we find that the feasibility analysis of reactive distillation in this method can be augmented by admitting the reverse reaction which can be demanded by excess positive reaction. And two conecepts which could be used to accelerate the feasibility analysis are shown. The first one is that vectors at equilibrium line and tray-by-tray calculations method with difference point are equivalent in feasibility analysis. And pinch points of tray-by-tray calculations under chemical equilibrium and infinite reflux ratio is just the reactive azeotrope. The number of feasible cases are increased from 27 to 48 in 113 all possible ternary configurations. Nine cases are feasible with low equilibrium constants, and twelve cases could be feasible with proper equilibrium constants. Those results are compared well with reactive distillation column simulations. Design and control of ternary ideal system, A↔B+C, are also be explored. Better design, both on economical and energy saving, could be found by using the result of feasibility analysis. And the designs are shown to be workable in dynamic. | en |
dc.description.provenance | Made available in DSpace on 2021-06-13T00:08:00Z (GMT). No. of bitstreams: 1 ntu-96-R94524070-1.pdf: 1669542 bytes, checksum: 55e173d74297461a3e75d028b785bda3 (MD5) Previous issue date: 2007 | en |
dc.description.tableofcontents | 致謝 I
摘要 III Abstract V 目錄 VI 圖索引 VIII 表索引 XI 1 緒論 1 1.1 前言 1 1.2 文獻回顧 2 1.3 研究動機與目的 5 1.4 組織章節 5 2 可行性分析方法與模擬方法 7 2.1 前言 7 2.2 介紹 7 2.2.1 共沸點(Azeotrope) 7 2.2.2 餾餘曲線圖RCM (Residue Curve Map) 8 2.2.3 RCM的拓墣數學研究與命名 11 2.2.4 反應蒸餾共沸點(Reactive Azeotrope) 13 2.2.5 反應差異點 (Reaction Difference Point) 16 2.3 模型與假設 18 2.4 可行性分析方法 20 2.4.1 反應差異點之圖形化逐板計算 20 2.4.2 逆反應 25 2.4.3 汽液平衡向量 26 2.4.4 反應蒸餾共沸與可行性分析 28 2.5 模擬方法 29 3 可行系統分類 34 3.1 前言 34 3.2 類別 A 34 3.3 類別 B 40 3.4 類別C 43 3.5 類別D 52 3.6 單根反應蒸餾塔不可行之處理:類別B 56 3.7 總結與比較 60 4 三成份理想系統穩態設計 63 4.1 前言 63 4.2 模型與假設 63 4.3 穩態設計最適化 67 4.4 最適化結果 68 4.4.1 系統I=L+H 68 4.4.2 反應平衡常數對系統H=I+L的影響 72 4.4.3 系統H=I+L程序架構Ⅰ 74 4.4.4 系統H=I+L程序架構Ⅱ 78 4.5 討論 80 5 理想系統動態模擬與控制 81 5.1 前言 81 5.2 溫度控制 82 5.2.1 靈敏度分析 84 5.2.2 非方形相對增益 86 5.2.3 控制器參數調諧方法 89 5.2.4 溫度控制動態模擬結果 90 6 結論 96 附錄A TAC計算公式 98 參考文獻 100 | |
dc.language.iso | zh-TW | |
dc.title | 反應性蒸餾三成份系統可行性分析:分解反應 | zh_TW |
dc.title | Feasibility of Ternary Reactive Distillation Systems:
Decomposition Reaction | en |
dc.type | Thesis | |
dc.date.schoolyear | 95-2 | |
dc.description.degree | 碩士 | |
dc.contributor.oralexamcommittee | 陳誠亮(Cheng-Liang Chen),錢義隆(I-Lung Chien),汪上曉(Shan-Hill Wong),黃琦聰(Chi-Tsung Huang) | |
dc.subject.keyword | 反應蒸餾,可行性, | zh_TW |
dc.subject.keyword | Reactive Distiilation,Feasibility, | en |
dc.relation.page | 102 | |
dc.rights.note | 有償授權 | |
dc.date.accepted | 2007-07-30 | |
dc.contributor.author-college | 工學院 | zh_TW |
dc.contributor.author-dept | 化學工程學研究所 | zh_TW |
顯示於系所單位: | 化學工程學系 |
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