請用此 Handle URI 來引用此文件：
http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/27989完整後設資料紀錄
| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 吳紀聖 | |
| dc.contributor.author | Yi-Ting Wu | en |
| dc.contributor.author | 吳怡亭 | zh_TW |
| dc.date.accessioned | 2021-06-12T18:32:00Z | - |
| dc.date.available | 2007-08-02 | |
| dc.date.copyright | 2007-08-02 | |
| dc.date.issued | 2007 | |
| dc.date.submitted | 2007-08-01 | |
| dc.identifier.citation | [1] K. Ishibashi, A. Fujishima, T. Watanabe, K. Hashimoto, Quantum yields of
active oxidative species formed on TiO2 photocatalyst, Journal of Photochemistry and Photobiology A: Chemistry, 134(2000), 139-142. [2] H. Tahiri, N. Serpone, R. L. Mao, Application of concept of relative photonic efficiencies and surface characterization of a new titania photocatalyst designed for environmental remediation, Journal of Photochemistry and Photobiology A: Chemistry, 93(1996), 199-203. [3] A. Fujishima, T. N. Rao, D. A. Tryk, Titanium dioxide photocatalysis, Journal of Photochemistry and Photobiology C: Photochemistry Reviews, 1(2000), 1-21. [4] E. M. Levin, C. R. Robbins, H. F. McMurdie, M. K. Reser, Phase Diagrams for Ceramists, The American Ceramic Society, inc., 76(1975), 4150-4999. [5] U. Diebold, The Surface Science of Titanium Dioxide, Surface Science Reports, 48(2003), 53-229. [6] R. Sanjines, H. Tang, H. Berger, F. Gozzo, G. Margaritondo, F. Levy, Electronic structure of anatase TiO2 oxide, Journal of Applied Physics, 75, 6(1994), 2945-2951. [7] L. Kavan, M. Gratzel, S.E. Gilbert, C. Klemenz, H.J. Scheel, Electrochemical and Photoelectrochemical Investigation of Single-Crystal Anatase, Journal of the American Chemical Society, 118(1996), 716-6723. [8] M. R. Hoffmann, S. T. Martin, W. Choi, D. W. Bahnemann, Environmental applications of semiconductor photocatalysis, Chemical Reviews, 95(1995), 69-96. 98 [9] 黃朝偉, 原位紅外線偵測二氧化碳在光觸媒上之光催化反應, 國立台 灣大學碩士論文, 2006 [10] H. Yamashita, H. Nishiguchi, N. Kamada, M. Anpo, Photocatalytic reduction of CO2 with H2O on TiO2 and Cu/TiO2 catalysts, Research on Chemical Intermediates, 20(1994), 815-823. [11] K. Hirano, K. Inoue, T. Yatsu, Photocatalysed reduction of CO2 in aqueous TiO2 suspension mixed with copper powder, Journal of Photochemistry of Photobiology A: Chemistry, 64(1992), 255-258. [12] M. Anpo, H. Yamashita, Y. Ichihashi, S. Ehara, Photocatalytic reduction of CO2 with H2O on various titanium oxide catalysts, Journal of Electroanalytical Chemistry, 396(1995), 21-26. [13] Y. Zhu, L. Zhang, W. Yao, L. Cao, The Chemical state and properties of doped TiO2 film photocatalyst prepared using the Sol-gel method with TiCl4 as a precursor, Applied Surface Science, 158(2000), 32-37. [14] H. Bosch and F. Janssen, Formation and control of nitrogen oxides, Catalysis Today, 2(1988), 369-379 [15] G. Qi and R. T. Yang*, Characterization and FTIR Studies of MnOx-CeO2 Catalyst for Low-Temperature Selective Catalytic Reduction of NO with NH3, The Journal of Physical Chemistry. B , 108(2004), 15738-15747 [16] W. Sjoerd Kijlstra, Danny S. Brands, Eduard K. Poels, and Alfred Bliek, Mechanism of the Selective Catalytic Reduction of NO by NH3 over MnOx/Al2O3：I. Adsorption and Desorption of the Single Reaction Components, Journal of Catalysis, 171(1997), 208-218. [17] W. Sjoerd Kijlstra, Danny S. Brands, Eduard K. Poels, and Alfred Bliek, Mechanism of the Selective Catalytic Reduction of NO with NH3 over MnOx/Al2O3 II. Reactivity of Adsorbed NH3 and NO Complexes, Journal of 99 Catalysis, 171(1997), 219-230. [18] Donovan A. Pena, Balu S. Uphade, and Panagiotis G. Smirniotis, TiO2-supported metal oxide catalysts for low-temperature selective catalytic reduction of NO with NH3 : I. Evaluation and characterization of first row transition metals, Journal of Catalysis, 221(2004), 421-431. [19] E.E. Miró, G. Imoberdorf, J. Vassallo, J.O. Petunchi*, SCR of NOx with CH3OH on H-mordenite: mechanism and reaction intermediates, Applied Catalysis B: Environmental , 22(1999), 305-318. [20] Satoshi Kameoka,* Yuji Ukisu and Tatsuo Miyadera, Selective catalytic reduction of NOx with CH3OH, C2H5OH and C3H6 in the presence of O2 over Ag/Al2O3 catalyst : Role of surface nitrate species, Physical Chemistry Chemical Physics, 2(2000), 367-372. [21] B. Wichterlová, P. Sazama, J.P. Breen,∗, R. Burch, C.J. Hill, , L. C apek, Z. Sobalík, An in situ UV–vis and FTIR spectroscopy study of the effect of H2 and CO during the selective catalytic reduction of nitrogen oxides over a silver alumina catalyst, Journal of Catalysis, 235(2005), 195-200. [22] P. Sazama, , L. C apek, H. Drobná, Z. Sobalík, J. Dedecek, K. Arve, B. Wichterlová∗, Enhancement of decane-SCR-NOx over Ag/alumina by hydrogen. Reaction kinetics and in situ FTIR and UV–vis study, Journal of Catalysis, 232(2005), 302-317. [23] Gongshin Qi, Ralph T. Yang ∗, Fabrizio C. Rinaldi, Selective catalytic reduction of nitric oxide with hydrogen over Pd-based catalysts, Journal of Catalysis, 237(2006), 381-392. [24] G.M. Tonetto, D.E. Damiani∗, Performance of Pd-Mo/ -Al2O3 catalysts for the selective reduction of NO by methane, Journal of Molecular Catalysis A: Chemical, 202(2003), 289-303. 100 [25] K. Hadjiivanov, B. Tsyntsarski, E. Ivanova, D. Klissurski and Ts. Marinova∗, FTIR mechanistic studies on the selective catalytic reduction of NOx by methane and ethane over supported cobalt catalysts, Surface and Interface Analysis, 32(2001), 205-209. [26] Zhen Yan, Chao-Xian Xiao, and Yuan Kou *, NOx-catalyzed gas-phase activation of methane: in situ IR and mechanistic studies, Catalysis Letters, 85(2003), 3-4. [27] Teuvo Maunula*, Juha Ahola, Hideaki Hamada, Reaction mechanism and kinetics of NOx reduction by methane on In/ZSM-5 under lean conditions, Applied Catalysis B: Environmental, 64(2006), 13-24. [28] Hanna Harelind Ingelstena*, and Magnus Skoglundh, Mechanistic study of lean NO2 reduction by propane over HZSM-5 in the presence of water, Catalysis Letters, 106(2006), 15-19. [29] H. H. Ingelsten∗, D. Zhao, A. Palmqvist, M. Skoglundh, Mechanistic study of the influence of surface acidity on lean NO2 reduction by propane in HZSM-5, Journal of Catalysis, 232(2005), 68-79. [30] Yawu Chi and Steven S. C. Chuang, Infrared Study of NO Adsorption and Reduction with C3H6 in the Presence of O2 over CuO/Al2O3, Journal of Catalysis, 190(1999), 75-91. [31] A. Fritz, V. Pitchon*, The current state of research on automotive lean NOx catalysis, Applied Catalysis B: Environmental, 13(1997), 1-25. [32] Naoki Takahashi ,* Hirofumi Shinjoh, Tomoko Iijima, Tadashi Suzuki, Kiyoshi Yamazaki, Koji Yokota, Hiromasa Suzuki, Naoto Miyoshi, Shin-ichi Matsumoto, Tsuneyuki Tanizawa, Toshiaki Tanaka ,Syu-shi Tateishi, Kouichi Kasahara, The new concept 3-way catalyst for automotive lean-burn engine: NOx storage and reduction catalyst, Catalysis Today, 27(1996), 63-69. 101 [33] A. Fujishima, K. Honda, Electrochemical Photolysis of Water at a Semiconductor Electrode, Nature, 238(1972), 37-38. [34] T. Inoue, A. Fujishima, S. Konishi, K. Honda, Photoelectrocatalytic reduction of carbon dioxide in aqueous suspensions of semiconductor powders, Nature, 277(1979), 637-638. [35] R. Nakamura, A. Imanishi, K. Murakoshi, Y. Nakato, In Situ FTIR Studies of Primary Intermediates of Photocatalytic Reactions on Nanocrystalline TiO2 films in Contact with Aqueous Solutions, Journal of The American Chemical Society, 125(2003), 7443-7450. [36] R. Nakamura, Y. Nakata, Primary Intermediates of Oxygen Photoevolutin Reaction on TiO2 (Rutile) Particles, Revealed by in Situ FTIR Absorption and Photoluminescence Measurements, Journal of The American Chemical Society, 126(2004), 1290-1298. [37] D. C. Hurum, A. G. Agrios, K. A. Gray, T. Rajh, M. C. Thurnauer, Explaining the Enhanced Photocatalytic Activity of Degussa P25 Mixed-Phase TiO2 Using EPR, Journal of Physical Chemistry B, 107(2003), 4545-4549. [38] H. Einaga, A. Ogata, S. Futamura, T. Ibusuki, The stabilization of active oxygen species by Pt supported on TiO2, Chemical Physics Letters, 338(2001), 303-307. [39] M. Anpo, N. Aikawa, Y. Kubokawa, Photocatalytic Hydrogenation of Alkynes and Alkenes with Water over TiO2 Pt-Loading Effect on the Primary Processes, Journal of Physical Chemistry, 88(1984), 3998-4000. [40] Z. Li, G. Xu, G. B. Hoflund,In situ IR studies on the mechanism of methane oxidation over Pd/Al2O3 and Pd/Co3O4 catalysts, Fuel Processing Technology, 84(2003), 1-11 [41] B. D. Cullity, S. R. Stock, Elements of X-ray Diffraction, 3th edition, 102 Prentice Hall, New Jersey, (2002), p.92. [42] D. Bao, X. Yao, N. Wakiya, K. Shinozaki, N. Mizutani, Band gap energies of sol-gel-derived SrTiO3 thin films, Applied Physics Letters, 79, 23(2001), 3767-3769. [43] B. George and P. Mclntyre, Analytical Chemistry by Open Learning(紅外 線光譜分析法)(翁瑞裕 編譯，曹君曼 校定), John Wiley and Sons, Business and Technology Education council(高立圖書有限公司，台北縣), p.102-104. [44] HARRIC Scientific Corporation, The Praying MantisTM User’s Manual, Harrick Scientific Corporation, NY U.S., 2003, p.9-p.18. [45] J. Muhlebach, K. Muller, and G. Schwarzenbach, The Peroxo Complexes of Titanium, Inorganic Chemistry, 9(1970), 2381-2390. [46] Kentaro Teramura, Tsunehiro Tanaka,* and Takuzo Funabiki, Photoassisted Selective Catalytic Reduction of NO with Ammonia in the Presence of Oxygen over TiO2, Langmuir, 19(2003), 1209-1214. [47] Konstantin Hadjiivanov,Vladimir Bushev, Margarita Kantcheva, and Dimitar Klissurski, Infrared Spectroscopy Study of the Species Arising during NO2 Adsorption on TiO2(Anatase), Langmuir, 10(1994), 464-471. [48] A. A Davydov, Infrared Spectroscopy of Adsorbed Species on the Surface of Transition Metal Oxides (C. H. Rochester Ed.), John Wiley and Sons, Chichester, New York, 1990, p.33-35. [49] A. A Davydov, Infrared Spectroscopy of Adsorbed Species on the Surface of Transition Metal Oxides (C. H. Rochester Ed.), John Wiley and Sons, Chichester, New York, 1990, p.6-7. [50] B. George and P. Mclntyre, Analytical Chemistry by Open Learning (紅外 線光譜分析法) (翁瑞裕 編譯, 曹君曼 校訂), John Wiley and Sons, Business and Technology Education council (高立圖書有限公司, 台北縣), p.189. 103 [51] C.-H. Lin and H. Bai, Adsorption Behavior of Moisture over a Vanadia/Titania Catalyst: A Study for the Selective Catalytic Reduction Process, Industrial and Engineering Chemistry Research, 43(2004), 5983-5988. [52] S. H. Szczepankiewicz, A. J. Colussi, M. R. Hoffmann, Infrared Spectra of Photoinduced Species on Hydroxylated Titania Surfaces, Journal of Physical Chemistry B, 104(2000), 9842-9850. [53] A. A Davydov, Infrared Spectroscopy of Adsorbed Species on the Surface of Transition Metal Oxides (C. H. Rochester Ed.), John Wiley and Sons, Chichester, New York, 1990, p.25. [54] J. Zhang, T. Ayusawa, M. Minagawa, K. Kinugawa, H. Yamashita, M. Matsuoka and M. Anpo, Investigations of TiO2 Photocatalysts for the Decomposition of NO in the Flow System, Journal of Catalysis, 198(2001), 1-8. [55] A. A. Davydov, Infrared Spectroscopy of Adsorbed Species on the Surface of Transition Metal Oxides (C. H. Rochester Ed.), John Wiley and Sons, Chichester, New York, 1990, p.8-24. [56] L.-F. Liao, C.-F. Lien, D.-L. Shieh, M.-T. Chen, and J.-L. Lin*, FTIR Study of Adsorption and Photoassisted Oxygen Isotopic Exchange of Carbon Monoxide, Carbon Dioxide, Carbonate, and Formate on TiO2, The Journal of Physical Chemistry. B, 106(2002), 11240-11245. [57] R. Nakamura and Y. Nakato*, Primary Intermediates of Oxygen Photoevolution Reaction on TiO2 (Rutile) Particles, Revealed by in Situ FTIR Absorption and Photoluminescence Measurements, Journal of The American Chemical Society, 126(2004), 1290-1298. [58] A. S. Elmi, and P. Forzatti ,G. Busca*, Mechanism of Selective Methanol Oxidation over Vanadium Oxide-Titanium Oxide Catalysts: A FT-IR and Flow Reactor Study, J. Phys. Chem., 91(1987), 5263-5269. 104 [59] 鄭宇廷, 原位紅外線偵測一氧化氮在光觸媒上之光催化氧化反應,國 立台灣大學碩士論文,2005 [60] T. Nobukawa, M. Yoshida, S. Kameoka,S. Ito,K. Tomishige, K. Kunimori,In-Situ Observation of Reaction Intermediate in the Selective Catalytic Reduction of N2O with CH4 over Fe Ion-Exchanged BEA Zeolite Catalyst for the Elucidation of Its Reaction Mechanism Using FTIR, J. Phys. Chem. B, 108(2004), 4071-4079. [61] Margarita Kantcheva, Identification, Stability, and Reactivity of NOx Species Adsorbed on Titania-Supported Manganese Catalysts, Journal of Catalysis, 204(2001), 479–494. [62] R. Burch *, P.J. Millington, Selective reduction of nitrogen oxides by hydrocarbons under lean-burn conditions using supported platinum group metal catalysts, Catalysis Today, 26(1995), 185-206. [63] B. J. Lee, M. C. Kuo and S. H. Chien*, In situ FT-IR studies of NO decomposition on Pt /TiO2 catalyst under UV irradiation, Resarch on Chemical Intermediate, Vol. 29, No. 7-9(2003), 817-826. [64] I. Nakamura, S. Sugihara, and K. Takeuchi, Mechanism for NO Photooxidation over the Oxygen-Deficient TiO2 Powder under Visible Light Irradiation, Chemistry Letters, 11(2000),1276-1277. [65] D. V. Pozdnyakov and V. N. Fillmonov, Use of IR Spectroscopy to Investigate Chemisorptions of Nitric Oxide and Nitrogen Dioxide on Metallic Oxides, Kinetics and Catalysis, 14(1973), 655-660. [66] F. C. Meunier, J. P. Breen, V. Zuzaniuk, M. Olsson, and J. R. H. Ross, Mechanistic Aspects of the Selective Reduction of NO by Propene over Alumina and Silver–Alumina Catalysts, Journal of Catalysis, 187(1999), 493-505. [67] Masaaki Haneda, Nicolas Bion, Marco Daturi, Jacques Saussey, 105 Jean-Claude Lavalley, Daniel Duprez, and Hideaki Hamada, In Situ Fourier Transform Infrared Study of the Selective Reduction of NO with Propene over Ga2O3–Al2O3, Journal of Catalysis, 206(2002), 114-124 [68] N. Ulagappan and H. Frei*, Mechanistic Study of CO2 Photoreduction in Ti Silicalite Molecular Sieve by FT-IR Spectroscopy, The Journal of Physical Chemistry. A, 104(2000), 7834-7839. [69] G. Ramis, G. Busca, V. Lorenzelli, and P. Rorzatti, Fourier Transform Infrared Study of the Adsorption and Coadsorption of Nitrix Oxide, Nitrogen Dioxide and Ammonia on TiO Anatase, Applied Catalysis, 64(1990) 243-257. [70] M. M. Kantcheva, V. Ph. Bushev and K. I. Hadjiivanov, Nitrogen Dioxide Adsorption on Deuteroxylated Titania (Anatase), Journal of the Chemical Society. Faraday transactions, 88(1992), 3087-3089. [71] Jeffrey R. S. Brownson, M. Isabel Tejedor-Tejedor, and Marc A. Anderson*, Photoreactive Anatase Consolidation Characterized by FTIR Spectroscopy, Chem. Mater., 17(2005), 6304-6310. [72] Konstantin Hadjiivanov* and Helmut Knozinger, Species formed after NO adsorption and NO+ O2 co-adsorption on TiO2 : an FTIR spectroscopic study, Physical Chemistry Chemical Physics, 2(2000), 2803-2806. [73] J.L. Valverde, A. de Lucas, F. Dorado, A. Romero, P.B. Garc´ıa*, Study by in situ FTIR of the SCR of NO by propene on Cu2+ ion-exchanged Ti-PILC, Journal of Molecular Catalysis A: Chemical, 230(2005), 23-28. [74] Changbin Zhang , Hong He *, Ken-ichi Tanaka, Catalytic performance and mechanism of a Pt/TiO2 catalyst for the oxidation of formaldehyde at room temperature, Applied Catalysis B: Environmental, 65(2006), 37-43. [75] I-H. Tseng, W.-C. Chang, Jeffrey C. S. Wu, Photoreduction of CO2 using sol-gel derived titania and titania-supported copper catalysts, Applied Catalysis 106 B: Environmental 37 (2002), 37-48. [76] R. F. Howe and M. Gratzel, EPR Study of Hydrated Anatase under UV Irradiation, Journal of Physical Chemistry B, 91(1987), 3906-3909. [77] Thermo Electron Corporation, Your Complete Sample Catalog for FT-IR and FT-Raman Spectrometers, Thermo Electron Corporation, Madison, Wisconsin USA, 2002, p.129. | |
| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/27989 | - |
| dc.description.abstract | 氮氧化物(NOx)為一般人們所熟知的空氣污染物，本實驗欲探討
在低溫下(100℃以下)，以光驅動的方式是否也能達到選擇性還原的 目的，運用原位傅立葉轉換紅外線光譜儀(In situ Fourier Transform Infrared Spectroscopy)，可以觀察反應中間體，進而瞭解反應機制。 本實驗用熱水解法（thermal-hydrolysis method）製備光觸媒純二氧化 鈦和1wt%白金負載的二氧化鈦。光觸媒催化反應是以紫外光為光 源。本實驗觀察在25、50 及100℃下，甲烷與一氧化氮同時吸附在 二氧化鈦與1wt%白金負載的二氧化鈦上。照光後，大部分的甲烷在 光催化反應中形成了甲酸及二氧化碳。一氧化氮在吸附時變成二氧化 氮、雙牙基亞硝酸和單牙基硝酸，照光後雙牙基亞硝酸消失，取而代 之的是雙牙基硝酸、單牙基硝酸以及異氰酸鹽NCO 的產生，許多文 獻視其為選擇性吸附之中間產物，又加上本研究也觀察到NH2，故推 測在本實驗中，照光可以促進部分一氧化氮催化變成氮氣，進而達到 低溫選擇性還原的目的。 | zh_TW |
| dc.description.abstract | NOx is a well-known air pollutant. We propose to remediate NOx by
photo catalytic reduction at low temperature (<100℃). In situ FTIR was used to observe reaction intermediates and to explore possible mechanisms. The thermal-hydrolysis method was used to prepare TiO2 and 1wt% Pt-TiO2 photocatalysts. UV light was used as light source. The reactants, CH4 and NO, are adsorbed on the photocatalyst (TiO2 or 1wt% Pt-TiO2), the reaction was performed at three temperatures (25, 50 and 100℃). Under light irradiation, most of the CH4 is converted to formic acid and CO2. When NO is adsorbed on the photocatalyst, it becomes NO2, bidentate nitrites and monodentate nitrate. After light irradiation, bidentate nitrite disappears, while bidentate nitrate, monodentate nitrate and isocyanate are generated. Literatures suggest that NCO is the main intermediate in the selective catalytic reduction (SCR) process. In addition, NH2 was also observed in this experiment. Finally it is concluded that NO can be reduced to N2 by low temperature SCR under light irradiation. | en |
| dc.description.provenance | Made available in DSpace on 2021-06-12T18:32:00Z (GMT). No. of bitstreams: 1 ntu-96-R94524009-1.pdf: 2105414 bytes, checksum: fdf6ac2c545a7cd063a875b4821afe32 (MD5) Previous issue date: 2007 | en |
| dc.description.tableofcontents | 摘要...................................................................................................................... I
Abstract ...............................................................................................................II 目錄................................................................................................................... III 圖目錄................................................................................................................ V 表目錄..............................................................................................................XII 第一章 緒論................................................................................................... 1 第二章 文獻回顧........................................................................................... 2 2-1 研究背景相關文獻回顧......................................................................... 2 2-1-1 二氧化鈦簡介................................................................................. 2 2-1-2 一氧化氮選擇性還原相關文獻回顧........................................... 6 2-2 紅外線偵測相關文獻回顧................................................................... 10 2-2-1 二氧化鈦光催化反應與其紅外線偵測實驗............................... 10 2-2-2 甲烷氧化反應與其偵測圖譜....................................................... 14 2-2-3 一氧化氮選擇性還原反應與其相關偵測圖譜............................ 16 第三章 實驗部分........................................................................................... 18 3-1 化學藥品與器材資料........................................................................... 18 3-1-1 藥品................................................................................................ 18 3-1-2 器材................................................................................................ 19 3-2 觸媒製備............................................................................................... 20 3-3 觸媒特性檢測....................................................................................... 22 3-3-1 X 光繞射儀.................................................................................... 22 3-3-2 紫外線-可見光光譜儀................................................................... 25 3-3-3 傅立葉轉換紅外線光譜儀............................................................ 27 IV 3-4 原位傅利葉轉換紅外線偵測光反應系統........................................... 30 3-4-1 反應系統........................................................................................ 30 3-4-2 光反應器........................................................................................ 31 3-4-3 原位一氧化氮與甲烷之光催化反應............................................ 33 第四章 實驗結果........................................................................................... 35 4-1 原位傅立葉轉換紅外線光譜儀偵測光催化....................................... 35 4-1-1 前處理............................................................................................ 35 4-1-2 觸媒TiO2 進行甲烷吸附與照光作用.......................................... 41 4-1-3 觸媒TiO2 進行一氧化氮吸附與照光作用.................................. 43 4-1-4 觸媒Pt-TiO2 進行一氧化氮吸附與照光作用............................. 46 4-1-5 觸媒TiO2 在25℃進行一氧化氮和甲烷的吸附與照光作用..... 51 4-1-5-1 先通入甲烷再通入一氧化氮後照光.................................... 51 4-1-5-2 先通入一氧化氮再通入甲烷後照光.................................... 54 4-1-5-3 同時通入一氧化氮與甲烷後照光........................................ 57 4-1-6 觸媒Pt-TiO2 在25℃進行一氧化氮和甲烷的吸附與照光作用60 4-1-7 觸媒TiO2 在50℃進行一氧化氮和甲烷的吸附與照光作用..... 66 4-1-8 觸媒Pt-TiO2 在50℃進行一氧化氮和甲烷的吸附與照光作用69 4-1-9 觸媒TiO2 在100℃進行一氧化氮和甲烷的吸附與照光作用... 73 4-1-10 觸媒Pt-TiO2 在100℃進行一氧化氮和甲烷的吸附與照光作用 .................................................................................................................. 76 4-1-11 觸媒TiO2 在100℃進行一氧化氮和甲烷的吸附（不照光）. 81 4-2 X 光繞射儀............................................................................................ 82 4-3 紫外線-可見光光譜儀........................................................................... 83 第五章 結果討論........................................................................................... 84 5-1 不同溫度下一氧化氮與甲烷吸附在同一觸媒後照光比較............... 84 5-2 同溫度下一氧化氮與甲烷吸附在不同觸媒後照光比較................... 87 5-3 一氧化氮與甲烷光催化之可能機制推導............................................ 92 第六章 結論..................................................................................................... 96 第七章 參考文獻............................................................................................. 97 附錄................................................................................................................. 107 | |
| dc.language.iso | zh-TW | |
| dc.subject | 選擇性還原 | zh_TW |
| dc.subject | 一氧化氮 | zh_TW |
| dc.subject | 甲烷 | zh_TW |
| dc.subject | 原位傅立葉轉換紅外線光譜 | zh_TW |
| dc.subject | NO | en |
| dc.subject | in situ FTIR | en |
| dc.subject | SCR | en |
| dc.subject | CH4 | en |
| dc.title | 原位紅外線研究一氧化氮與甲烷在光觸媒上之光催化
反應 | zh_TW |
| dc.title | In situ FT-IR Study of Photocatalytic NO and CH4
Reaction on Photocatalysts | en |
| dc.type | Thesis | |
| dc.date.schoolyear | 95-2 | |
| dc.description.degree | 碩士 | |
| dc.contributor.oralexamcommittee | 莊顯成,簡淑華 | |
| dc.subject.keyword | 一氧化氮,甲烷,選擇性還原,原位傅立葉轉換紅外線光譜, | zh_TW |
| dc.subject.keyword | NO,CH4,SCR,in situ FTIR, | en |
| dc.relation.page | 114 | |
| dc.rights.note | 有償授權 | |
| dc.date.accepted | 2007-08-01 | |
| dc.contributor.author-college | 工學院 | zh_TW |
| dc.contributor.author-dept | 化學工程學研究所 | zh_TW |
| 顯示於系所單位： | 化學工程學系 | |
文件中的檔案：
| 檔案 | 大小 | 格式 | |
|---|---|---|---|
| ntu-96-1.pdf 未授權公開取用 | 2.06 MB | Adobe PDF |
系統中的文件，除了特別指名其著作權條款之外，均受到著作權保護，並且保留所有的權利。