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完整後設資料紀錄
DC 欄位 | 值 | 語言 |
---|---|---|
dc.contributor.advisor | 陳尊賢(Zueng-Sang Chen) | |
dc.contributor.author | Sih-Syuan Dai | en |
dc.contributor.author | 戴思瑄 | zh_TW |
dc.date.accessioned | 2021-05-13T06:49:16Z | - |
dc.date.available | 2019-08-25 | |
dc.date.available | 2021-05-13T06:49:16Z | - |
dc.date.copyright | 2017-08-25 | |
dc.date.issued | 2017 | |
dc.date.submitted | 2017-08-17 | |
dc.identifier.citation | 土壤污染管制標準。中華民國100年1月31日行政院環境保護署環署土字第1000008495號令修正發布。
王明光。2000。高嶺石和蛇紋岩礦物。土壤環境礦物學。藝軒圖書出版社。 pp. 199-236. 余俊德。2013。玄武岩及蛇紋岩母質土壤之性質與六價鉻生成之比較。國立屏東科技大學環境工程與科學研究所碩士論文。 吳景翰。2009。不同施肥條件下蛇紋石土壤中重金屬之溶出特性與水稻吸收量。國立屏東科技大學環境工程與科學研究所碩士論文。 許正一、蔡衡。2011。蛇紋岩土壤之特性及其重金屬含量偏高問題。臺灣礦業。63:12-26。 張育禎、陳谷汎。2015。過硫酸鹽氧化法技術發展及污染整治應用。土壤地下水污染整治。2:231-241。 許淳淳。2010。各種化學氧化法處理柴油污染蛇紋岩土壤鉻及鎳之溶出。國立臺灣大學農業化學系所碩士論文。 梁振儒。2007。淺談土壤及地下水污染現地過硫酸鹽化學氧化整治法。台灣土壤及地下水環境保護協會簡訊。23:13-20。 陳尊賢、李依庭。2012。農作物中重金屬與有機污染物檢測技術及調查評估-農作食用作物鎳鉻含量監測。行政院農委會農糧暑委託計畫 (計畫編號:101農科-14.2.3-糧-Z1(3))。期末報告。 陳尊賢、林季燕、邱相禎。2014。土壤環境管理及肥料開發與利用技術研究-土壤銅鋅標準放寬對水稻吸收銅鋅之影響。行政院農委會農糧暑委託計畫 (計畫編號: 103農科-8.1.1-糧-Z1(1))。研究成果報告。 陳肇夏。1998。臺灣的變質岩。臺灣地質系列第11號,經濟部中央地質調查所編印。144頁。 微波輔助酸消化法。中華民國100年1月31日行政院環境保護署環署土字第1000008495號令修正發布。 潘昱睿。2011。過硫酸鹽活化反應對處理農藥2,4-D污染之適用性試驗。國立中興大學環境工程學系碩士論文。 劉滄棽、郭鴻裕、朱戩、連深。2007。台灣東部蛇紋岩母質化育土壤地區重金屬特性之初探。臺灣農業研究。56:65-78。 賴允傑、何秉宜。2013。農地土壤母質品質背景調查計畫。(計畫編號: EPA-100-GA-103-02-A240)。期末報告。 賴允傑、何秉宜。2014。農地土壤母質品質背景調查計畫(第二期)。(計畫編號: EPA-102-GA13-03-A128)。期末報告。 謝明昇。2012。Fenton-like 試劑對蛇紋岩土壤中溶解重金屬與產生六價鉻之影響。國立屏東科技大學環境工程與科學研究所碩士論文。 Alloway, B. J. 2013. Heavy metals in soils: trace metals and metalloids in soils and their bioavailability (3rd ed). Springer, Netherlands, pp. 53-75, 313–327. Adriano, D. C. 2001. Trace elements in terrestrial environments (2nd ed.). Springer, New York, pp. 678-702. Bartlett, R. J. and B. R. James. 1982. Chromium. In A.L. Page et al. (eds.) Methods of soil analysis. Part 2. Chemical and microbiological properties(2nd ed). Agronomy Monograph. Madison, Wisconsin, USA, pp. 683-693. Becquer, T., C. Quantin, M. Sicot, and J. P. Boudot. 2003. Chromium availability in ultramafic soils from New Caledonia. Sci. Total Environ. 301:251-261. Bohn, H. L., B. L. McNeal, and G. A. O’connor. 2001. Soil chemistry (3rd ed). John Wiley & Sons, Inc., New York, pp. 109-125. Brady, N. C. and R. R. Weil. 2010. Elements of the nature and properties of soil (3rd ed). New Jersey,Pearson Education, Inc. Chen, K. F., C. M. Kao, L. C. Wu, and S. H. Liang. 2009. MTBE degradation by ferrous ironactivated persulfate oxidation: Feasibility and kinetics studies. Water Environ. Res. 81: 687-694. Cheng, C. H., S. H. Jien, H. Tsai, Y. H. Chang, Y. C. Chen and Z. Y. Hseu. 2009. Geochemical element differentiation in serpentine soils from the ophiolite complexes, eastern Taiwan. Soil Sci. 174:283-291. Cheng, C. H., S. H. Jien, Y. lizuka, H. Tsai, Y. H. Chang and Z. Y. Hseu. 2011. Pedogenic chromium and nickel partitioning in serpentine soils along a toposequence. Soil Sci. Soc. Am. J. 75:659-668. Eary, L. E. and D. Rai. 1988. Chromate removal from aqueous wastes by reduction with ferrous ion. Environ. Sci. Technol. 22:972-977. Fendorf, S. E. 1995. Surface reactions of chromium in soils and waters. Geoderma 67:55-71. Gardner, W. H. 1986. Water content. In A. Klute et al. (eds.) Methods of soil analysis. Part 1. Physical and mineralogical method (2nd ed). Agronomy monograph, Madison, Wisconsin, USA, pp. 503-505 Gee, G.W., and J.W. Bauder. 1986. Partical-size analysis. In A. Klute et al. (eds.) Methods of soil analysis. Part 1. Physical and mineralogical methods. (2nd ed). Agronomy monograph, Madison, Wisconsin, USA, pp. 383-411. Harter, R. D. 1983. Effect of soil pH on adsorption of lead, copper, zinc, and nickel. Soil Sci. Soc. Am. J. 47:47-51. House, D.A. 1962. Kinetics and mechanism of oxidations by peroxydisulfate. Chem. Rev. 62:185–203. Hseu, Z. Y., S. W. Su, H. Y. Lai, H. Y. Guo, T. C. Chen and Z. S. Chen. 2010. Remediation techniques and heavy metal uptake by different rice varieties in metal-contaminated soils of Taiwan: new aspects for food safety regulation and sustainable agriculture. Soil Sci. Plant Nutr. 56:31-52. Huang, J. H., F. Huang, L. Evans, and S. Glasauer. 2015. Vanadium: Global (bio)geochemistry. Chem. Geol. 417:68-89. Huang, C. P., H. A. Ellistt, and R. M. Ashmes. 1997. Interfacial reactions and the fate of heavy metals in soil-water systems. J. Water Poll. Control Fed. 49:745-756 Huang, K.C., R. A. Couttenye, and G. E. Hoag. 2002. Kinetics of heat-assisted persulfate oxidation of methyl-tert-butyl ether (MTBE). Chemosphere 49:413–420. Huling, S.G., B. E. Pivet., 2006. Engineering issue: in-situ chemical oxidation, USEPA Office of Research and Development, Cincinnati, OH. (EPA/600/ R-06/072.) ITRC (International Technology and Regulatory Cooperation). 2005. Technical and regulatory guidance for in-situ chemical oxidation of contaminated soil and groundwater ( 2nd ed). Washington, D.C. Johnson, W. R., and Proctor, J. 1981. Growth of serpentine and nonserpentine races of Festuca rubra in solutions simulating the chemical conditions in a toxic serpentine soil. J. Ecol. 69:855–869. Kabata-Pendias, A. 2001. Trace elements in soils and plants (3rd ed). CRC Press, Boca Raton, NY, pp121-131, 146-150, 266-272, 325-330. Kabata-Pendias, A. 2004. Soil-plant transfer of trace elements an environmental issue. Geoderma 122:143-149. Kaur, K. and M. Crimi. 2015. Cadmium mobility with persulfate chemical oxidation: effects of soil properties and activation methods. J. Environ. Eng. 141:04014084-1-7. Kaur, K. and M. Crimi. 2014. Release of chromium from soils with persulfate chemical oxidation. Groundwater 52:748-755. Kierczak, J., A. Pędziwiatr, J. Waroszewski, and M. Modelska. 2016. Mobility of Ni, Cr and Co in serpentine soils derived on various ultrabasic bedrocks under temperate climate. Geoderma 268:78-91. Kim, J. G. and J. B. Dixon. 2002. Oxidation and fate of chromium in soils. J. Soil Sci. Plant. Nutr. 48:483–490. Ko, C. H., P. J. Chen, S. H. Chen, F. C. Chang, F. C. Lin, and K. K. Chen. 2010. Extraction of chromium, copper, and arsenic from CCA-treated wood using biodegradable chelating agents. Bioresour. Technol. 101:1528–1531. Kolthoff, I. M. and E. M. Carr. 1953. Volumetric determination of persulfate in the presence of organic substances. Anal. Chem. 25:298-301. Kolthoff, I. M., A. I. Medal, and H. P. Raaen. 1951. The reaction between ferrous iron and peroxides. IV. Reaction with potassium persulfate. J. Am. Chem. Soc. 73:1733-1739. Kumarathilaka, P., C. Oze, and M. Vithanage. 2016. Perchlorate mobilization of metals in serpentine soils. Appl. Geochem. 74:203-209. Kumpiene, J., A. Lagerkvist, and C. Maurice. 2008. Stabilization of As, Cr, Cu, Pb and Zn in soil using amendments–A review. Waste Manag. 28:215-225. Liang, C., Bruell, M. C. Marley, and K. L. Sperry. 2003. Thermally activated persulfate oxidation of trichloroethylene (TCE) and 1,1,1-trichloroethane (TCA) in aqueous systems and soil slurries. Soil Sediment Contam. 12:207–228. Liang, C. J., C.F. Huang, N. Mohanty and R. M. Kurakalva. 2008. A rapid spectrophotometric determination of persulfate anion in ISCO. Chemosphere 73:1540-1543. Liang, C., C. J. Bruell, M. C. Marley, and K. L. Sperry. 2004a. Persulfate oxidation for in situ remediation of TCE. I. Activated by ferrous ion with and without a persulfate–thiosulfate redox couple. Chemosphere 55:1213-1223. Liang, C., C. J. Bruell, M. C. Marley, and K. L. Sperry. 2004b. Persulfate oxidation for in situ remediation of TCE. II. Activated by chelated ferrous ion. Chemosphere 55:1225-1233. Lim, T. T., J. H. Tay, and J. Y. Wang. 2004. Chelating-agent enhanced heavy metal extraction from a contaminated acidic soil. J. Environ. Eng. 130:59–66. Lipctnska-Kochany, E., G. Sprah, and S. Harms. 1995. Influence of some groundwater and surface waters constituents on the degradation of 4-chlorophenol by the fenton reaction. Chemosphere 30:9-20. Loeppert, R. H. and Inskeep W. P. 1982. Iron. In A.L. Page et al. (eds.) Methods of soil analysis. Part 2. Chemical and microbiological properties (2nd ed). Agronomy Monograph, Madison, Wisconsin, USA, pp. 649-650. McLean, E. O. 1982. Soil pH and lime requirement. In A.L. Page et al. (eds.) Methods of soil analysis. Part 2. Chemical and microbiological properties (2nd ed). Agronomy Monograph, Madison, Wisconsin, USA, pp. 199-224. Mehra, O. P., and M. L. Jackson. 1960. Iron oxides removed from soils and clays by s dithionite-citrate system buffered with sodium bicarbonate. Clays Clay Miner. 7:317-327. Namgung, S., M. J. Kwon, N. P. Qafoku, and G. Lee. 2014. Cr(OH)3 (s) oxidation induced by surface catalyzed Mn (II) oxidation. Environ. Sci. Technol. 48:10760-10768. Nelson, D. W., and L. E. Sommers. 1982. Total carbon, organic carbon, and organic matter. In A.L. Page et al. (eds.) Methods of soil analysis. Part 2. Chemical and microbiological properties(2nd ed). Agronomy Monograph, Madison, Wisconsin, USA, pp. 539-579. Oze, C., S. Fendorf, D. K. Bird, and R. G. Coleman. 2004. Chromium geochemistry in serpentinized ultramafic rocks and serpentine soils from the Franciscan complex of California. Am. J. Sci. 304:67-101. Reijonen, I., M. Metzler, and H. Hartikainen. 2016. Impact of soil pH and organic matter on the chemical bioavailability of vanadium species: The underlying basis for risk assessment. Environ. Pollut. 210:371-379. Rock, M. L., B. R. James, and G. R. Helz. 2001. Hydrogen peroxide effects on chromium oxidation state and solubility in four diverse, chromium-enriched soils. Environ. Sci. Technol. 35:4054-4059. Sass, B.M. and D. Rai. 1987. Solubility of amorphous chromium(III)-iron(III) hydroxide solid solutions. Inorg. Chem. 26: 2228-2232. Siegrist, R. L., M. Crimi, and T. J. Simpkin. 2003. In-situ chemical oxidation for groundwater remediation. Springer, NY, USA, pp.147-191. Shallari, S., C. Schwartz, A. Hasko, and J. L. Morel. 1998. Heavy metals in soils and plants of serpentine and industrial sites of Albania. Sci. Total Environ. 209:133-142. Sra, K. S., N. R. Thomson, and J. F. Backer. 2010. Persistence of persulfate in uncontaminated aquifer materials. Environ. Sci. Technol. 44:3098-3104. Sutherland, R. A. and F. M. G. Tack. 2003. Fractionation of Cu, Pb and Zn in certified reference soils SRM 2710 and SRM 2711 using the optimized BCR sequential extraction procedure. Adv. Environ. Res. 8:37-50. Takeno, N. 2005. Atlas of Eh-pH diagrams: Intercomparison of thermodynamic databases. Geological survey of Japan open file report No.419. Taylor, M., J. Van Staden. 1994. Spectrophotometric determination of vanadium (IV) and vanadium (V) in each other's presence: Review. Analyst 119:1263–1276. Tessier, A., P. G. C. Campbell, and M. Bisson. 1979. Sequential extraction procedure for the speciation of particulate trace metals. Anal. Chem. 51: 844-851. Thomas, G. W. 1982. Exchangeable cation. In A.L. Page et al. (eds.) Methods of soil analysis. Part 2. Chemical and microbiological properties (2nd ed). Agronomy Monograph, Madison, Wisconsin, USA, pp. 149-157. U.S. EPA. 2004. How to evaluate alternative cleanup technologies for underground storage tank sites: A guide for corrective action plan reviewers, EPA 510/R-04/002. Wanty, R.B., and M. B. Goldhaber. 1992. Thermodynamics and kinetics of reactions involving vanadium in natural systems: accumulation of vanadium in sedimentary rocks. Geochim. Cosmochim. Acta 56:1471–1483. | |
dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/2758 | - |
dc.description.abstract | 過硫酸鹽是整治油品污染土壤之現地化學氧化法 (In situ chemical oxidation, ISCO) 常用的氧化劑,可透過活化產生氧化還原電位 (Redox potential, Eh) 較高的自由基以降解有機污染物。蛇紋岩土壤具高背景值濃度的鉻、鎳與鈷,其中六價鉻在環境中較三價鉻易移動且是已知的致癌物。許多研究指出使用ISCO後土壤pH或Eh值會改變,可能使土壤重金屬的溶出及價態變化,但使用過硫酸鹽整治蛇紋岩土壤或重金屬污染土壤時,其重金屬釋出動態機制至今尚未明瞭,因此本研究目的為添加不同活化處理的過硫酸鹽與土壤反應,以瞭解重金屬釋出情形。蛇紋岩土壤來自臺灣東部,重金屬污染土壤則採自彰化縣。批次實驗於土壤分別添加只有過硫酸根之未活化、兩種Fe2+濃度活化及鹼活化過硫酸根等四種處理反應並取樣測定。結果顯示過硫酸鹽濃度會隨時間消耗而減少並釋出H+,使溶液pH值下降,影響土壤膠體的表面電荷及吸附性,增加重金屬溶出,而重金屬的溶出量亦取決重金屬鍵結型態。在本研究條件下,過硫酸根殘留量較實際高,所以重金屬釋出量可能較高,污染土壤溶液可有鉻55.9 mg/L、鎳59.5 mg/L、銅112 mg/L及鋅168 mg/L的釋出量,蛇紋岩土壤溶液,以鹼活化的處理可釋出最高濃度為5.9 mg Cr (VI)/L,因為高pH值下鉻主要以六價存在。於此研究條件及結果下,並僅以氧化能力與移動性較高的六價鉻為考量,可知105 mM Fe2+活化過硫酸鹽之處理有較佳氧化能力,雖然會使土壤釋出較高濃度的重金屬,但因為Fe2+濃度較高,會與目標污染物競爭自由基且也會還原六價鉻,導致生成六價鉻的濃度較低,雖然過硫酸根的殘留量較現地應用時高出許多,會較推薦105 mM Fe2+活化過硫酸鹽處理於整治應用上。 | zh_TW |
dc.description.abstract | Persulfate is a common oxidant used for in situ chemical oxidation (ISCO), and it is usually activated by amendments such as Fe2+, EDTA-Fe2+ or alkaline to generate free radical which had higher redox potential to degrade the target pollutants. Serpentines soils contain high natural background concentrations of Cr, Ni and Co. However, Cr (VI) is carcinogenic and more mobile than Cr (III). Soil pH and Eh change after using ISCO and thus affect the mobility of heavy metals in soils. Three serpentine soils were collected from eastern Taiwan and anthropogenic polluted soils were sampled from Changhua county in western Taiwan. To explore heavy metals released from serpentine soils and polluted soils with different persulfate treatments, soils were spiked persulfate activated by two concentrations of Fe2+ and alkaline. The results showed that the concentration of remained persulfate decreased with time and generated H+ caused pH decreased, and thus increased heavy metals released. In this syudy, the polluted soils released 55.9 mg Cr/L, 59.5 mg Ni/L, 112 mg Cu/L, and 168 mg Zn/L were higher than serpentine soils because of the high level exchangeable fraction . Additionally, released Cr (VI) was higher from serpentine soils than polluted soils, and the alkaline activated treatment had highest content (5.9 mg Cr (VI)/L ) because of high pH value. Under the condition of this study, heavy metals may release more than in real condition because of higher concentration of persulfate remained. However, concerning about redox potential and Cr (VI) release, 105 mM Fe2+ activated treatment is better than other treatments because it had higher redox potential and Fe2+ may compete free radical and reduce Cr (VI). | en |
dc.description.provenance | Made available in DSpace on 2021-05-13T06:49:16Z (GMT). No. of bitstreams: 1 ntu-106-R04623018-1.pdf: 7028207 bytes, checksum: fd92c4a832c87d99d28a9012321568f4 (MD5) Previous issue date: 2017 | en |
dc.description.tableofcontents | 中文摘要 I
英文摘要 II 目錄 III 表目錄 V 圖目錄 VI 第一章 前言 1 第二章 文獻回顧 2 2.1現地化學氧化法 2 2.1.1 過硫酸鹽 5 2.1.2 以Fe2+活化過硫酸鹽 5 2.1.3 螯合鐵活化 6 2.1.4 鹼活化 7 2.1.5 熱活化過硫酸鹽 7 2.2 現地化學氧化法造成土壤中重金屬溶出 8 2.3蛇紋岩土壤 10 2.3.1 蛇紋岩 10 2.3.2 蛇紋岩土壤特性 10 2.4重金屬特性 13 2.4.1 鉻 16 2.4.2 鎳 18 2.4.3 鈷 19 2.4.4 銅 21 2.4.5 鋅 21 2.4.6 釩 23 第三章 材料與方法 26 3.1 供試土壤之採集 26 3.2 土壤基本特性分析 28 3.3化學氧化法對土壤重金屬之釋出 34 3.4 統計分析 36 第四章 結果與討論 37 4.1 供試土壤基本特性 37 4.2 過硫酸根化學氧化法與土壤反應試驗 43 4.2.1 溶液中過硫酸根殘留量 43 4.2.2 溶液中pH值與Eh值之變化 45 4.2.3 土壤中金屬之釋出 53 4.2.3.1 鉻釋出 53 4.2.3.2 鎳釋出 65 4.2.3.3 鈷釋出 72 4.2.3.4 釩釋出 78 4.2.3.5 銅釋出 82 4.2.3.6 鋅釋出 88 第五章 結論 94 第六章 參考文獻 95 | |
dc.language.iso | zh-TW | |
dc.title | 過硫酸鹽化學氧化法對蛇紋岩及重金屬污染土壤重金屬之釋出 | zh_TW |
dc.title | Release of heavy metals from serpentine and heavy metals-polluted soils by chemical oxidation using persulfate | en |
dc.type | Thesis | |
dc.date.schoolyear | 105-2 | |
dc.description.degree | 碩士 | |
dc.contributor.coadvisor | 許正一(Zeng-Yei Hseu) | |
dc.contributor.oralexamcommittee | 李達源(Dar-Yuan Lee),鄒裕民(Yu-Min Tzou),劉雨庭(Yu-Ting Liu) | |
dc.subject.keyword | 鉻,鎳,現地化學氧化法,過硫酸鹽,蛇紋岩土壤, | zh_TW |
dc.subject.keyword | Chromium,nickel,in situ chemical oxidation,persulfate,serpentine soil, | en |
dc.relation.page | 102 | |
dc.identifier.doi | 10.6342/NTU201703705 | |
dc.rights.note | 同意授權(全球公開) | |
dc.date.accepted | 2017-08-18 | |
dc.contributor.author-college | 生物資源暨農學院 | zh_TW |
dc.contributor.author-dept | 農業化學研究所 | zh_TW |
顯示於系所單位: | 農業化學系 |
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