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完整後設資料紀錄
DC 欄位 | 值 | 語言 |
---|---|---|
dc.contributor.advisor | 李公哲 | |
dc.contributor.author | Yen-Wei Liao | en |
dc.contributor.author | 廖彥偉 | zh_TW |
dc.date.accessioned | 2021-06-08T07:18:55Z | - |
dc.date.copyright | 2008-07-30 | |
dc.date.issued | 2008 | |
dc.date.submitted | 2008-07-24 | |
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dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/26644 | - |
dc.description.abstract | 本研究是利用熱處理,TFT-LCD廢玻璃與氟化化污泥進行玻璃陶瓷資材化研究,研究方式為先以試藥級藥品製備玻璃陶瓷,之後再以TFT-LCD玻璃與氟化鈣污泥取代試藥級配比,目的為了比較其差異性。本質驗共分為兩階段,第一階段先研究TFT-LCD玻璃與氟化鈣污泥之基本特性,包括:三成分分析、毒性特性溶出試驗、晶相分析;第二階段為研究試藥級玻璃陶瓷與包含TFT-LCD玻璃與氟化鈣污泥之玻璃陶瓷之性質分析,包括熱差分析、X射線繞射分析、觀察微觀結構,可評估取代之合適性。
實驗結果顯示,當TFT-LCD玻璃取代試藥級配比中的二氧化矽50%及氟化鈣污泥取代試藥級配比中的氧化鈣50%時,可得到最低熔流點1249℃,此時CaO+SiO2=47.08 (%),鹽基度CaO/SiO2=0.51;X射線繞射分析中指出,加入TFT-LCD玻璃與氟化鈣污泥玻璃陶瓷結晶強度較強,而結晶相為鈣長石(Anorthite),致使TFT-LCD 玻璃與氟化鈣污泥經熱處理後具資材化為玻璃陶瓷之潛力。 | zh_TW |
dc.description.abstract | The study was to waste utilize the TFT-LCD waste glass and CaF2 sludge into glass-ceramics through thermal process. The research method was first to produce glass-ceramics with laboratory chemicals, then the laboratory chemicals were replaced by TFT-LCD waste glass and CaF2 sludge. In order to compare the difference between each other. The experiments were divided into two stages: (1) to study basic characterization of TFT-LCD waste glass and CaF2 sludge, including three constituents analysis, TCLP, and SEM. (2) to study the properties of laboratory chemical glass-ceramics with and without the replacement of TFT-LCD waste glass and CaF2 sludge, including DTA, XRD, and SEM.
The experimental results showed that lowest pouring temperature was 1249℃when laboratory chemical SiO2 were replaced by 50 % TFT-LCD waste glass and CaO were replaced by 50 % CaF2 sludge. CaO+SiO2=47.08 (%) and basicity ( CaO / SiO2 )= 0.51was corresponding to the lowest pouring temperature of 1249℃. XRD results showed that intensity of crystallization is better in glass-ceramics with TFT-LCD waste glass and CaF2 sludge, the crystallization phase is Anorthite, so that FT-LCD waste glass and CaF2 sludge prccess production has the potential to be used as glass-ceramics by thermal treatment. | en |
dc.description.provenance | Made available in DSpace on 2021-06-08T07:18:55Z (GMT). No. of bitstreams: 1 ntu-97-R95541132-1.pdf: 5331695 bytes, checksum: f0d264bf330eb3b8313945b4eddea378 (MD5) Previous issue date: 2008 | en |
dc.description.tableofcontents | 第一章 前言.....................................................................................................................1
1.1 研究緣起....................................................................................................................1 1.1.1 TFT-LCD製程廢玻璃..............................................................................................1 1.1.2 氟化鈣污泥.............................................................................................................1 1.2 研究目的與內容........................................................................................................2 第二章 文獻回顧.............................................................................................................3 2.1 陶瓷............................................................................................................................3 2.1.1 古典陶瓷.................................................................................................................3 2.1.2 新陶瓷.....................................................................................................................4 2.2玻璃陶瓷及相關研究..................................................................................................5 2.2.1 玻璃陶瓷.................................................................................................................5 2.2.2 成分系統.................................................................................................................9 2.2.3 成核劑.....................................................................................................................9 2.2.4 製程.......................................................................................................................11 2.3 粉末燒結原理..........................................................................................................11 2.3.1 燒結過程...............................................................................................................12 2.3.2 影響燒結之因素...................................................................................................12 2.4 廢棄物製成微晶材料之相關研究..........................................................................14 2.4.1 玻璃質熔渣...........................................................................................................14 2.4.2 微晶材料...............................................................................................................15 2.5 製程微晶材料廢棄物種類......................................................................................15 2.5.1 都市焚化灰渣.......................................................................................................15 2.5.2 火力發電廠飛灰...................................................................................................16 2.5.3 污泥.......................................................................................................................16 2.5.4 廢棄玻璃...............................................................................................................17 2.6 熔融技術之相關研究..............................................................................................21 2.6.1 熔融之特色...........................................................................................................23 2.6.2 冷卻方式...............................................................................................................26 2.6.3 熔渣資源化...........................................................................................................27 2.6.4 成分、熔流點與鹽基度之關係.............................................................................28 2.7 氟化鈣污泥之相關研究..........................................................................................31 2.7.1 污泥來源...............................................................................................................31 2.7.2 氟化鈣污泥資源化方式.......................................................................................32 第三章 實驗材料、設備與方法.....................................................................................34 3.1 實驗材料與設備......................................................................................................34 3.1.1 實驗材料...............................................................................................................34 3.1.2 實驗設備...............................................................................................................35 3.2 分析儀器及實驗分析方法......................................................................................39 3.2.1 三成份分析...........................................................................................................39 3.2.2 試驗錐試驗...........................................................................................................40 3.2.3 化學成分分析.......................................................................................................40 3.2.4 毒性溶出試驗.......................................................................................................41 3.2.5 X光粉末繞射分析.................................................................................................42 3.2.6熱差分析.................................................................................................................43 3.3試驗流程與內容........................................................................................................43 3.4實驗設計....................................................................................................................46 3.4.1起始玻璃製備.........................................................................................................46 3.4.2玻璃陶瓷製備.........................................................................................................47 3.4.3 DTA升溫條件........................................................................................................48 第四章 結果與討論.......................................................................................................49 4.1 TFT-LCD玻璃/氟化鈣污泥基本性質分析..............................................................49 4.1.1氟化鈣污泥之三成分分析.....................................................................................49 4.1.2元素組成及重金屬分析.........................................................................................50 4.1.3毒性特性溶出試驗.................................................................................................54 4.1.4晶相分析及微觀分析.............................................................................................55 4.2成分與熔流溫度之探討............................................................................................59 4.2.1起始玻璃成分與熔流溫度之關係.........................................................................59 4.3廢棄物取代試藥級配比與鹽基度對熔流溫度下降之效果....................................60 4.4 DTA分析...................................................................................................................67 4.4.1起始玻璃與DTA之探討........................................................................................68 4.5 TFT-LCD廢玻璃/氟化鈣汙泥之玻璃陶瓷化探討..................................................69 4.5.1 XRD圖譜分析與討論...........................................................................................70 4.5.2 SEM觀察................................................................................................................76 4.6黏度試驗及其應用....................................................................................................81 4.6.1黏度與工作溫度之討論.........................................................................................84 第五章 結論與建議.......................................................................................................86 5.1 結論..........................................................................................................................86 5.2 建議..........................................................................................................................87 第六章 參考文獻...........................................................................................................88 | |
dc.language.iso | zh-TW | |
dc.title | TFT-LCD 廢玻璃/氟化鈣污泥熱處理資材化之研究 | zh_TW |
dc.title | Materialization Study of TFT-LCD waste glass and CaF2
Sludge by thermal treatment | en |
dc.type | Thesis | |
dc.date.schoolyear | 96-2 | |
dc.description.degree | 碩士 | |
dc.contributor.oralexamcommittee | 王鯤生,楊萬發 | |
dc.subject.keyword | 玻璃陶瓷,鹽基度,熱差分析,X射線繞射分析, | zh_TW |
dc.subject.keyword | glass-ceramics,basicity,DTA,XRD, | en |
dc.relation.page | 91 | |
dc.rights.note | 未授權 | |
dc.date.accepted | 2008-07-27 | |
dc.contributor.author-college | 工學院 | zh_TW |
dc.contributor.author-dept | 環境工程學研究所 | zh_TW |
顯示於系所單位: | 環境工程學研究所 |
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