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| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 廖文彬(Wen-Bin Liau) | |
| dc.contributor.author | Kuan-Ta Tzeng | en |
| dc.contributor.author | 曾冠達 | zh_TW |
| dc.date.accessioned | 2021-06-08T07:07:01Z | - |
| dc.date.copyright | 2008-09-02 | |
| dc.date.issued | 2008 | |
| dc.date.submitted | 2008-08-22 | |
| dc.identifier.citation | 1. Kitani, A.; Kaya, M.; Yano, J.; Yoshikawa, K.; Sasaki, K., Synthetic Metals 1987, 18, (1-3), 341-346.
2. Bernard, M. C.; Bich, V. T.; Goff, A. H.-L., Synthetic Metals 1999, 101, (1-3), 811-812. 3. K. Nishio et al., J. Power Sources 1995, 56, 189. 4. Lai, E. K. W.; Beattie, P. D.; Holdcroft, S., Synthetic Metals 1997, 84, (1-3), 87-88. 5. Adams, P. N.; Monkman, A. P., Synthetic Metals 1997, 87, (2), 165-169. 6. Adams, P. N.; Laughlin, P. J.; Monkman, A. P., Synthetic Metals 1996, 76, (1-3), 157-160. 7. Wang, B.; Tang, J.; Wang, F., Synthetic Metals 1986, 13, (4), 329-334. 8. Koziel, K.; Lapkowski, M.; Lefrant, S., Synthetic Metals 1995, 69, (1-3), 217-218. 9. Cao, Y.; Smith, P.; Heeger, A. J., Synthetic Metals 1992, 48, (1), 91-97. 10. Nicolas-Debarnot, D.; Poncin-Epaillard, F., Analytica Chimica Acta 2003, 475, (1-2), 1-15. 11. Sengupta, P. P.; Barik, S.; Adhikari, B., Materials & Manufacturing Processes 2006, 21, (3), 263-270. 12. Stejskal, J.; Kratochvil, P.; Radhakrishnan, N., Synthetic Metals 1993, 61, (3), 225-231. 13. Meixiang, W., Journal of Polymer Science Part A: Polymer Chemistry 1992, 30, (4), 543-549. 14. Meixiang Wan, J. Y., Journal of Applied Polymer Science 1995, 55, (3), 399-405. 15. Rannou, P.; Nechtschein, M.; Travers, J. P.; Berner, D.; Woher, A.; Djurado, D., Synthetic Metals 1999, 101, (1-3), 734-737. 16. Wolter, A.; Rannou, P.; Travers, J. P.; Gilles, B.; Djurado, D., Physical Review B 1998, 58, (12), 7637. 17. Sixou, B.; Mermilliod, N.; Travers, J. P., Physical Review B 1996, 53, (8), 4509. 18. 呂宗昕, 圖解奈米科技與光觸媒. p 178-179. 19. Linsebigler, A. L.; Lu, G.; Yates, J. T., Chem. Rev. 1995, 95, (3), 735-758. 20. E. M. Levin; C. R. Robbins; H. F. McMurdie; M. K. Reser, In Phase diagrams for Ceramist, The American Ceramic Society inc.: 1975; Vol. 76, pp 4150-4999. 21. Mattox, D. M., Thin Solid Films 1991, 204, (1), 25-32. 22. W. Feng; E. Sun; A. Fujii; H. C. Wu; K. Niihara; K, Y., Bulltein of the Chemical Society of Japan 2000, 73, 2627. 23. Xia, H.; Wang, Q., Chem. Mater. 2002, 14, (5), 2158-2165. 24. Somani, P. R.; Marimuthu, R.; Mulik, U. P.; Sainkar, S. R.; Amalnerkar, D. P., Synthetic Metals 1999, 106, (1), 45-52. 25. Gurunathan, K.; Trivedi, D. C., Materials Letters 2000, 45, (5), 262-268. 26. Sathiyanarayanan, S.; Azim, S. S.; Venkatachari, G., Electrochimica Acta 2007, 52, (5), 2068-2074. 27. Ram, M. K.; Yavuz, O.; Lahsangah, V.; Aldissi, M., Sensors and Actuators B: Chemical 2005, 106, (2), 750-757. 28. Tai, H.; Jiang, Y.; Xie, G.; Yu, J.; Chen, X., Sensors and Actuators B: Chemical 2007, 125, (2), 644-650. 29. Ma, X.; Wang, M.; Li, G.; Chen, H.; Bai, R., Materials Chemistry and Physics 2006, 98, (2-3), 241-247. 30. Pouget, J. P.; Jozefowicz, M. E.; Epstein, A. J.; Tang, X.; MacDiarmid, A. G., Macromolecules 1991, 24, (3), 779-789. 31. Xia, Y.; Wiesinger, J. M.; MacDiarmid, A. G.; Epstein, A. J., Chem. Mater. 1995, 7, (3), 443-445. 32. S. Palaniappan, B. H. N., Journal of Polymer Science Part A: Polymer Chemistry 1994, 32, (13), 2431-2436. 33. Kim, S.; Chung, I. J., Synthetic Metals 1998, 97, (2), 127-133. 34. Hagiwara, T.; Yamaura, M.; Iwata, K., Synthetic Metals 1988, 25, (3), 243-252. | |
| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/26344 | - |
| dc.description.abstract | 本研究利用原位聚合法合成二氧化鈦/聚苯胺的混摻結構，有別於傳統的物理混摻，結構為聚苯胺包覆奈米二氧化鈦的核殼粒子。藉由TEM、EDS觀察確認包覆情況與元素分析；利用SEM觀察成膜後表面情況與量測導電度。因為二氧化鈦/聚苯胺薄膜表面會產生龜裂現象，故添加聚乙烯醇使表面平坦。
利用XRD瞭解二氧化鈦/聚苯胺的晶體結構；利用UV和FTIR瞭解當添加二氧化鈦後對聚苯胺作用力的影響；利用TGA去探討當添加二氧化鈦後對熱重量損失溫度的改良；熱穩定性的實驗中，可觀察到添加二氧化鈦可增加聚苯胺的熱穩定性，並且得知薄膜劣化與擴散作用相關；感測性質的實驗中，因PVA含量過高，無法得知其結果。 | zh_TW |
| dc.description.abstract | The thesis was to study the structure of titania/polyaniline hybrid structure by using in-situ polymerization. Different from the traditional physical blends, the structure was titania being wrapped by polyaniline to form the core-shell particles. The condition of wraps and element analysis were checked by TEM and EDS. The surface condition and the conductivity of the film were observed by SEM. We added the Poly(vinyl alcohol) to prevent from the surface crack of titania/polyaniline.
The crystal structure of titania/polyaniline was showed by XRD. The effect of polyaniline after adding the titania was understood by UV and FTIR. The improvement of weight-loss temperature after adding the titania was known by TGA. Adding titania could increase the thermal stability of polyaniline from the experiment of thermal stability. It was indicated that the aging effect was related to diffusion. The sensing of the film could not be understood because of too high volume fraction of PVA. | en |
| dc.description.provenance | Made available in DSpace on 2021-06-08T07:07:01Z (GMT). No. of bitstreams: 1 ntu-97-R94549005-1.pdf: 2396146 bytes, checksum: 32978849c321ce0c7a19617200632958 (MD5) Previous issue date: 2008 | en |
| dc.description.tableofcontents | 口試委員會審定書.....................iii
誌謝........................................... v 中文摘要................................................vii 英文摘要................................................................ix 目錄.............................................................................xi 圖目錄...................................xiv 表目錄........................................................................xvii 第一章 前言......................................................................1 第二章 文獻回顧及原理..................................................................3 2-1 導電高分子聚苯胺............3 2-1-1聚苯胺簡介................................................................3 2-1-2聚苯胺的合成......................................................5 2-1-3聚苯胺的摻雜..................................7 2-1-4聚苯胺的紅外光吸收光譜.........................................9 2-1-5聚苯胺的UV-Vis吸收光譜..........................................11 2-1-6聚苯胺導電性質的穩定性..............................................12 2-1-7聚苯胺的劣化與導電度關係.................................13 2-2 二氧化鈦簡介...................................................16 2-2-1二氧化鈦光觸媒...........................................16 2-2-2二氧化鈦製備方法........................................21 2-3 二氧化鈦/聚苯胺...................................................24 2-3-1二氧化鈦/聚苯胺的合成及應用...............................................24 2-3-2二氧化鈦/聚苯胺薄膜的感測...................................................27 第三章 實驗部分......................................................29 3-1 實驗流程...............................................29 3-2 實驗藥品......................................34 3-3 實驗儀器...............................................36 3-4 實驗方法........................................39 3-4-1合成二氧化鈦/聚苯胺..............................39 3-4-2合成純聚苯胺.............................40 3-4-3二氧化鈦/聚苯胺薄膜製備.........................41 3-4-4聚苯胺薄膜製備............................................42 3-4-5性質分析.............................................44 第四章 結果與討論.................................48 4-1 二氧化鈦/聚苯胺合成..................................48 4-1-1二氧化鈦與聚苯胺.............................................48 4-1-2二氧化鈦/聚苯胺複合材料...................................48 4-1-3 EDS量測.......................................................49 4-1-4導電度量測...........................................49 4-1-5添加聚乙烯醇製備二氧化鈦/聚苯胺薄膜..............51 4-2 光學性質分析..........................................52 4-2-1 XRD量測.................................53 4-2-2 UV-Vis量測..................................................54 4-2-3 FTIR量測...............................................54 4-3 熱性質分析................................................55 4-3-1熱重量損失分析........................55 4-3-2熱穩定性實驗........................................57 4-4 感測性質分析............................................63 第五章 結論.......................................65 參考文獻....................................................................66 附錄.................................................69 | |
| dc.language.iso | zh-TW | |
| dc.subject | 聚苯胺 | zh_TW |
| dc.subject | 感測 | zh_TW |
| dc.subject | 二氧化鈦 | zh_TW |
| dc.subject | 混摻 | zh_TW |
| dc.subject | 熱穩定性 | zh_TW |
| dc.subject | titania | en |
| dc.subject | sensing | en |
| dc.subject | thermal stability | en |
| dc.subject | hybrid | en |
| dc.subject | polyaniline | en |
| dc.title | 二氧化鈦/聚苯胺混摻結構之製備 | zh_TW |
| dc.title | The Fabrication of Titania/Polyaniline hybrid structure | en |
| dc.type | Thesis | |
| dc.date.schoolyear | 96-2 | |
| dc.description.degree | 碩士 | |
| dc.contributor.oralexamcommittee | 邱文英(Wen-Yen Chiu),曾勝茂(Sheng-Mao Tseng) | |
| dc.subject.keyword | 二氧化鈦,聚苯胺,混摻,熱穩定性,感測, | zh_TW |
| dc.subject.keyword | titania,polyaniline,hybrid,thermal stability,sensing, | en |
| dc.relation.page | 68 | |
| dc.rights.note | 未授權 | |
| dc.date.accepted | 2008-08-22 | |
| dc.contributor.author-college | 工學院 | zh_TW |
| dc.contributor.author-dept | 高分子科學與工程學研究所 | zh_TW |
| 顯示於系所單位： | 高分子科學與工程學研究所 | |
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