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| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 邱勝賢(Sheng-Hsien Chiu) | |
| dc.contributor.author | Sheng-Yao Hsueh | en |
| dc.contributor.author | 薛聖耀 | zh_TW |
| dc.date.accessioned | 2021-06-08T06:06:06Z | - |
| dc.date.copyright | 2007-07-26 | |
| dc.date.issued | 2007 | |
| dc.date.submitted | 2007-07-23 | |
| dc.identifier.citation | 1. (a) Nicolaou, K. C.; Vourloumis, D.; Winssinger, N.; Baran, P. S. Angew. Chem. Int. Ed. 2000, 39, 44–122.
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J. 1997, 3, 530–537; (b) Tung, C.; Lin, Y.; Moon, W.; Weissleder, R. ChemBioChem 2002, 3, 784–786; (c) Arunkumar, E.; Chithra, P.; Ajayaghosh, A. J. Am. Chem. Soc. 2004, 126, 6590–6598; (d) Ros-Lis, J. V.; García, B.; Jiménez, D.; Martínez-Mánez, R.; Sancenón, Soto, F., J., Gonzalvo, F.; Valldecabres, M. C. J. Am. Chem. Soc. 2004, 126, 4064–4065; (e) Ajayaghosh, A. Acc. Chem. Res. 2005, 38, 449–459; f) Arunkumar, E.; Forbes, C. C.; Noll, B. C.; Smith, B. D. J. Am. Chem. Soc. 2005, 127, 3288–3289; (g) Arunkumar, E.; Fu, N.; Smith, B. D. Chem. Eur. J. 2006, 12, 4684–4690 48. Thuéry, P.; Masci, B. Supramolecular Chemistry 2003, 15, 95 49. Crystal data for [(6,2,Na2)•4MeCN][2ClO4]: [C74H80O14N4Na2][ClO4]2, Mr = 1494.30, monoclinic, space group p21/n, a = 14.8664(2), b = 12.0495 (2), c = 20.3540 (3) Å, V = 3624.53 (9) Å3, ρcalcd = 1.369 g cm–3, μ(MoKα) = 0.181 mm–1, T = 295(2) K, orange columns; 8119 independent measured reflections, F2 refinement, R1 = 0.0696, wR2 =0.1915. 50. (a) Bigelow, R. W.; Freund, H. J. Chem. Phys. 1986, 107, 159–174; (b) Law, K. Y. J. Photochem. Photobiol. A 1994, 84, 123–132. 51. Crystal data for [(7,2,Na2)•4MeCN][2BF4]: [C84H100O14N6Na2][BF4]2, Mr = 1637.30, triclinic, space group pî, a = 13.5847 (2), b = 13.7701 (2), c = 14.2357 (2) Å, V = 2230.43 (6) Å, ρcalcd = 1.219 g cm–3, μ(MoKα) = 0.101 mm–1, T = 295(2) K, orange cubes; 7859 independent measured reflections, F2 refinement, R1 = 0.0730, wR2 = 0.2305. 52. Crystal data for [(2,Na2)•2MeCN•CH2Cl2•H2O][2BF4]: [C57H66O13N2Cl2Na2][BF4]2, Mr = 1277.62, trigonal, space group a = 21.3476 (4), b = 21.3476 (4), c = 26.1494 (4) Å, V = 10320.3 (3) Å3, ρcalcd = 1.233 g cm–3, μ(MoKα) = 0.184 mm–1, T = 295(2) K, colorless plates; 6056 independent measured reflections, F2 refinement, R1 = 0.1487, wR2 = 0.4145. Crystal data for [(2,K2)•3MeCN][2PF6]: [C58H69O12N3K2][PF6]2, Mr = 1368.30, monoclinic, space group p21/n, a = 15.5177 (8), b = 15.0057 (9), c = 15.1762 (8) Å, V = 3211.9 (3) Å3, ρcalcd =1.415 g cm–3, μ(MoKα) = 0.292 mm–1, T = 295(2) K, colorless plates; 7246 independent measured reflections, F2 refinement, R1 = 0.0980, wR2 = 0.2431. | |
| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/25235 | - |
| dc.description.abstract | 金屬離子與分子籠鍵結所產生的模板效應可順利引導兩種不同的兩個客體分子(蒽醌及方酸衍生物)進入分子籠的中心空腔而形成準車輪烷類錯合物，有趣的是在Li+、Na+、K+、Cs+等鹼金屬中，僅有鈉離子具有如此的模板效應。由於此超分子系統在進行錯合與解離的過程中可產生明顯的顏色或螢光變化，因此或有成為具光學輸出之分子開關的潛力。 | zh_TW |
| dc.description.abstract | A molecular cage forms pseudorotaxane-like complexes with threaded anthraquinone and squaraine units in the presence of templating alkali metal ions, with high selectively for Na+ ions. This ion-specific templating effect was easy to monitor because the complexation and decomplexation of the pseudorotaxane complexes in solution occurred with significant color changes that were detectable to the naked eye. | en |
| dc.description.provenance | Made available in DSpace on 2021-06-08T06:06:06Z (GMT). No. of bitstreams: 1 ntu-96-R93223071-1.pdf: 1354206 bytes, checksum: c009f3bbc8fa1da39bcb954ecd88b182 (MD5) Previous issue date: 2007 | en |
| dc.description.tableofcontents | 摘 要 I
Abstract Ⅱ 論文發表 Ⅲ 目 錄 IV 式 子 V 圖 表 VI 表 格 VIII 壹、導 論 1 1.1 前言 1 1.2 超分子化學的發展與冠醚的起源 3 1.3 超分子系統 6 1.3.1 氫鍵 6 1.3.2 金屬－配位基 8 1.3.3 pi-pi疊合 1.3.4 疏水作用力 12 貳、結果與討論 14 2.1 研究動機 14 2.2 分子籠2的設計與合成及預期功能 17 2.3 分子籠2與蒽醌3之錯合體 18 2.4 分子籠2與蒽醌4之錯合體 23 2.5 分子籠2與鈉、鉀離子鍵結的探討 28 參、結 論 30 肆、實驗部份 31 伍、參考文獻 35 | |
| dc.language.iso | zh-TW | |
| dc.subject | 以鈉離子為模板 | zh_TW |
| dc.subject | Highly Selective Sodium ion Templated | en |
| dc.title | 以鈉離子為模板合成具有光學訊號輸出之準車輪烷 | zh_TW |
| dc.title | Highly Selective Na+-Templated Formation of [2]Pseudorotaxanes Exhibiting Significant
Optical Outputs | en |
| dc.type | Thesis | |
| dc.date.schoolyear | 95-2 | |
| dc.description.degree | 碩士 | |
| dc.contributor.oralexamcommittee | 徐秀福(Hsiu-Fu Hsu),賴建成(Chien-Chen Lai) | |
| dc.subject.keyword | 以鈉離子為模板, | zh_TW |
| dc.subject.keyword | Highly Selective Sodium ion Templated, | en |
| dc.relation.page | 39 | |
| dc.rights.note | 未授權 | |
| dc.date.accepted | 2007-07-23 | |
| dc.contributor.author-college | 理學院 | zh_TW |
| dc.contributor.author-dept | 化學研究所 | zh_TW |
| 顯示於系所單位： | 化學系 | |
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